Cross sections resulting from scattering that proceeds via an intermediate resonance are shown to be exceptionally controllable using a coherent superposition of only two intial states. Full quantum computations on F+HD(v=0;j=0,1) --> H+DF, D+HF, which exhibits a resonance in one of the reactive channels, support the formal arguments, showing that control is indeed vast. In this case the ratio of reactive integral cross sections can be altered by a factor of 62 (compared to a noncoherent factor of only 3.3), while the ratio of reactive differential cross sections can be altered by a factor of over 6000 (compared to a noncoherent factor of less than 7). These results constitute the first prediction of extensive quantum control in a collisional process.
Coherence has been remaining a key resource for numerous applications of quantum physics ranging from quantum metrology to quantum information. Here, we report a theoretical work on how maximally created coherence results in the squeezing of cavity field coupled to a coherently driven single quantum dot. We employ a recently developed polaron master equation theory for accurately incorporating the impact of exciton-phonon coupling on squeezing.
Using two different criteria for continuous variable systems we demonstrated that pump and probe beams became quantum correlated in a situation of Electromagnetically Induced Transparency in a sample of Rb atoms. Our result combines two important features for practical implementations in the field of quantum information processing. Namely, we proved the existence of entanglement between two macroscopic light beams, and this entanglement is intrinsically associated to a strong coherence in an atomic medium.
We suggest a technique to induce effective, controllable interactions between atoms that is based on Raman scattering into an optical mode propagating with a slow group velocity. The resulting excitation corresponds to the creation of spin-flipped atomic pairs in a way that is analogous to correlated photon emission in optical parametric amplification. The technique can be used for fast generation of entangled atomic ensembles, spin squeezing and applications in quantum information processing.
We study two ions confined in a Penning trap. We show that electronically highly excited states exist in which an electron is delocalized among the two ions forming a giant molecule of several micrometer size. At energies close to the top of the Coulomb barrier these molecular states can be regarded as superpositions of Rydberg states of individual ions. We illuminate the possibility to observe coherent charge transfer between the ions. Beyond a critical principal quantum number the electron can coherently tunnel through the Coulomb barrier to an adjacent doubly charged ion. The tunneling occu…
We show that a single, trapped, laser-driven atom in a high-finesse optical cavity allows for the quantum-coherent generation of entangled light pulses on demand. Schemes for generating simultaneous and temporally separated pulse pairs are proposed. The mechanical effect of the laser excitation on the quantum motion of the cold trapped atom mediates the entangling interaction between two cavity modes and between the two subsequent pulses, respectively. The entanglement is of EPR-type, and its degree can be controlled through external parameters. At the end of the generation process the atom is…
We explore entanglement generation between multiple optically levitated nanospheres interacting with a common optical cavity via the Coherent Scattering optomechanical interaction. We derive the many-particle Hamiltonian governing the unitary evolution of the system and show that it gives rise to quantum correlations among the various partitions of the setup, following a non-Markovian dynamics of entanglement birth, death and revivals. We also consider the effects of coupling the system to external environments and show that under reasonable experimental conditions entanglement between the mec…
Models of universal quantum computation in which the required interactions between register (computational) qubits are mediated by some ancillary system are highly relevant to experimental realisations of a quantum computer. We introduce such a universal model that employs a $d$-dimensional ancillary qudit. The ancilla-register interactions take the form of controlled displacements operators, with a displacement operator defined on the periodic and discrete lattice phase space of a qudit. We show that these interactions can implement controlled phase gates on the register by utilising geometri…
Quantum simulators employing cold atoms are among the most promising approaches to tackle quantum many-body problems. Nanophotonic structures are widely employed to engineer the bandstructure of light and are thus investigated as a means to tune the interactions between atoms placed in their vicinity. A key shortcoming of this approach is that excitations can decay into free photons, limiting the coherence of such quantum simulators. Here, we overcome this challenge by proposing to use a simple cubic three-dimensional array of atoms to produce an omnidirectional bandgap for light and show that…
Scalable architectures for quantum information technologies require to selectively couple long-distance qubits while suppressing environmental noise and cross-talk. In semiconductor materials, the coherent coupling of a single spin on a quantum dot to a cavity hosting fermionic modes offers a new solution to this technological challenge. Here, we demonstrate coherent coupling between two spatially separated quantum dots using an electronic cavity design that takes advantage of whispering-gallery modes in a two-dimensional electron gas. The cavity-mediated long-distance coupling effectively min…
A pulse shaping algorithm for a matter wave with the purpose of controlling a binary reaction has been designed. The scheme is illustrated for an Eley-Rideal reaction where an impinging matter-wave atom recombines with an adsorbed atom on a metal surface. The wave function of the impinging atom is shaped such that the desorbing molecule leaves the surface in a specific vibrational state.
Quantum cascaded systems offer the possibility to manipulate a target system with the quantum state of a source system. Here, we study in detail the differences between a direct quantum cascade and coherent/incoherent driving for the case of two coupled cavity-QED systems. We discuss qualitative differences between these excitations scenarios, which are particular strong for higher-order photon-photon correlations: $g^{(n)}(0)$ with $ n>2 $. Quantum cascaded systems show a behavior differing from the idealized cases of individual coherent/incoherent driving and allow to produce qualitatively d…
We demonstrate theoretically that the abstraction reaction $A+B_2 \to AB+B$ can be driven coherently and efficiently with quantum-degenerate bosonic or fermionic matter waves. We show that the initial stages of the reaction are dominated by quantum fluctuations, resulting in the appearance of macroscopic non-classical correlations in the final atomic and molecular fields. The dynamics associated with the creation of bosonic and of fermionic dimer-atom pairs are also compared. This study opens up a promising new regime of quantum degenerate matter-wave chemistry.
Engineering strong interactions between quantum systems is essential for many phenomena of quantum physics and technology. Typically, strong coupling relies on short-range forces or on placing the systems in high-quality electromagnetic resonators, restricting the range of the coupling to small distances. We use a free-space laser beam to strongly couple a collective atomic spin and a micromechanical membrane over a distance of one meter in a room-temperature environment. The coupling is highly tunable and allows the observation of normal-mode splitting, coherent energy exchange oscillations, …
We apply the quantum-walk approach recently proposed in arXiv:quant-ph-1506.04213 to a radical-pair reaction where realistic estimates for the intermediate transition rates are available. The well-known average hitting time from quantum walks can be adopted as a measure of how quickly the reaction occurs and we calculate this for varying degrees of dephasing in the radical pair. The time for the radical pair to react to a product is found to be independent of the amount of dephasing introduced, even in the limit of no dephasing where the transient population dynamics exhibit strong coherent os…
Strong light-matter interaction in cavity environments is emerging as a promising approach to control chemical reactions in a non-intrusive and efficient manner. The underlying mechanism that distinguishes between steering, accelerating, or decelerating a chemical reaction has, however, remained unclear, hampering progress in this frontier area of research. We leverage quantum-electrodynamical density-functional theory to unveil the microscopic mechanism behind the experimentally observed reduced reaction rate under cavity induced resonant vibrational strong light-matter coupling. We observe m…
The coherent control of spin qubits forms the basis of many applications in quantum information processing and nanoscale sensing, imaging and spectroscopy. Such control is conventionally achieved by direct driving of the qubit transition with a resonant global field, typically at microwave frequencies. Here we introduce an approach that relies on the resonant driving of nearby environment spins, whose localised magnetic field in turn drives the qubit when the environmental spin Rabi frequency matches the qubit resonance. This concept of environmentally mediated resonance (EMR) is explored expe…
We show that an atom can be coupled to a mechanical oscillator via quantum vacuum fluctuations of a cavity field enabling energy transfer processes between them. In a hybrid quantum system consisting of a cavity resonator with a movable mirror and an atom, these processes are dominated by two pair-creation mechanisms: the counterrotating (atom-cavity system) and dynamical Casimir interaction terms (optomechanical system). Because of these two pair-creation mechanisms, the resonant atom-mirror coupling is the result of high-order virtual processes with different transition paths well described …
Classical chemical kinetics use rate-equation models to describe how a reaction proceeds in time. Such models are sufficient for describing state transitions in a reaction where coherences between different states do not arise, or in other words, a reaction which contain only incoherent transitions. A prominent example reaction containing coherent transitions is the radical-pair model. The kinetics of such reactions is defined by the so-called reaction operator which determines the radical-pair state as a function of intermediate transition rates. We argue that the well-known concept of quantu…
We report the coherent coupling of two electron spins at a distance via virtual microwave photons. Each spin is trapped in a silicon double quantum dot at either end of a superconducting resonator, achieving spin-photon couplings up to around $g_s/2π= 40 \ \text{MHz}$. As the two spins are brought into resonance with each other, but detuned from the photons, an avoided crossing larger than the spin linewidths is observed with an exchange splitting around $2J/2π= 20 \ \text{MHz}$. In addition, photon-number states are resolved from the shift $2χ_s/2π= -13 \ \text{MHz}$ that they induce on the s…
Entangling gates for electron spins in semiconductor quantum dots are generally based on exchange, a short-ranged interaction that requires wavefunction overlap. Coherent spin-photon coupling raises the prospect of using photons as long-distance interconnects for spin qubits. Realizing a key milestone for spin-based quantum information processing, we demonstrate microwave-mediated spin-spin interactions between two electrons that are physically separated by more than 4 mm. Coherent spin-photon coupling is demonstrated for each individual spin using microwave transmission spectroscopy. An enhan…
Interferences emerge when multiple pathways coexist together leading towards the same result. A Recent study by Blasing and coworkers [PRL 121(7):073202] showed that in a photo-association reaction of Raman dressed spin orbit coupled $^{87}$Rb Bose Einstein Condensate when the reactant spin state is prepared in a coherent superposition of multiple bare spin states it leads to a destructive interference between reaction pathways. Here we report a theoretical study for a reaction scheme which leads to constructive quantum interference. This is achieved by changing the reactive scattering channel…
We address a fundamental question of quantum optics: Can a beam of light mediate coherent Hamiltonian interactions between two distant quantum systems? This is an intriguing question whose answer is not a priori clear, since the light carries away information about the systems and might be subject to losses, giving rise to intrinsic decoherence channels associated with the coupling. Our answer is affirmative and we derive a particularly simple sufficient condition for the interactions to be Hamiltonian: The light field needs to interact twice with the systems and the second interaction has to …
Phonons, and in particular surface acoustic wave phonons, have been proposed as a means to coherently couple distant solid-state quantum systems. Recent experiments have shown that superconducting qubits can control and detect individual phonons in a resonant structure, enabling the coherent generation and measurement of complex stationary phonon states. Here, we report the deterministic emission and capture of itinerant surface acoustic wave phonons, enabling the quantum entanglement of two superconducting qubits. Using a 2 mm-long acoustic quantum communication channel, equivalent to a 500 n…
Semiconductor qubits rely on the control of charge and spin degrees of freedom of electrons or holes confined in quantum dots (QDs). They constitute a promising approach to quantum information processing [1, 2], complementary to superconducting qubits [3]. Typically, semiconductor qubit-qubit coupling is short range [1, 2, 4, 5], effectively limiting qubit distance to the spatial extent of the wavefunction of the confined particle, which represents a significant constraint towards scaling to reach dense 1D or 2D arrays of QD qubits. Following the success of circuit quantum eletrodynamics [6], …
Beam splitter mediated entanglement of nonlinear photon-added coherent states was studied by Honarasa, Bagheri and Gharaati [1]. We believe that this work contains errors in numerical computations of linear entropy and Mandel parameter which lead to wrong conclusions. We point out the possible errors and describe the necessary corrections. The conclusions based on our arguments are in complete agreement with previously published literature.
We investigate the coherent energy transfer between two quantum systems mediated by a quantum bus. In particular, we consider the energy transfer process between two qubits, and how it can be influenced by using a third qubit or photons in a resonant cavity as mediators. Inspecting different figures of merit and considering both on and off-resonance configurations, we characterize the energy transfer performances. We show that, while the qubit-mediated transfer shows no advantages with respect to a direct coupling case, the cavity-mediated one is progressively more and more efficient as functi…
We propose a scheme enabling controlled quantum coherent interactions between separated nitrogen-vacancy centers in diamond in the presence of strong magnetic fluctuations. The proposed scheme couples nuclear qubits employing the magnetic dipole-dipole interaction between the electron spins and, crucially, benefits from the suppression of the effect of environmental magnetic field fluctuations thanks to a strong microwave driving. This scheme provides a basic building block for a full-scale quantum information processor or quantum simulator based on solid-state technology.
Optical networks that distribute entanglement among quantum technologies will form a powerful backbone for quantum science but are yet to interface with leading quantum hardware such as superconducting qubits. Consequently, these systems remain isolated because microwave links at room temperature are noisy and lossy. Building connectivity requires interfaces that map quantum information between microwave and optical fields. While preliminary microwave-to-optical (M2O) transducers have been realized, developing efficient, low-noise devices that match superconducting qubit frequencies (gigahertz…
We report the observation of efficient and low-noise frequency conversion between two microwave modes, mediated by the motion of a mechanical resonator subjected to radiation pressure. We achieve coherent conversion of more than $10^{12}~\mathrm{photons/s}$ with a $95\mathrm{\%}$ efficiency and a $14~\mathrm{kHz}$ bandwidth. With less than $10^{-1}~\mathrm{photons \cdot s^{-1}\cdot Hz^{-1}}$ of added noise, this optomechanical frequency converter is suitable for quantum state transduction. We show the ability to operate this converter as a tunable beam splitter, with direct applications for ph…
We introduce an exactly solvable model to study decoherence of a central spin interacting with a spin bath where the coupling is mediated by phonons which we assume to be in a coherent state or thermal distribution. For the coherent state case, we find that the decoherence factor decays in a Gaussian fashion and it becomes independent of the phonon frequencies at short times. If the phonon energies are much larger than spin-phonon coupling or bath spins are fully polarized, decoherence time becomes independent of the initial phonon state. For the thermal state case, phonons play more important…
The coherent evolution of two atomic qubits mediated by a set of bosonic field modes is investigated. By assuming a specific encoding of the quantum states in the internal levels of the two atoms we show that entangling quantum gates can be realised, with high fidelity, even when a large number of mediating modes is involved. The effect of losses and imperfections on the gates' operation is also considered in detail.
The purpose of this paper is to present a comprehensive study of a coherent feedback network where the main component consists of two distant double quantum dot (DQD) qubits which are directly coupled to a cavity. This main component has recently been physically realized (van Woerkom, {\it et al.}, Microwave photon-mediated interactions between semiconductor qubits, Physical Review X, 8(4):041018, 2018). The feedback loop is closed by cascading this main component with a beamsplitter. The dynamics of this coherent feedback network is studied from three perspectives. First, an analytic form of …
The action reaction principle is violated in the standard formulation of Quantum Mechanics, so that its phase space is incomplete. Moreover, projection of state of a quantum system under indirect measurement, when there are alternative virtual paths and one of them is discarded by negative detection implies, according to the action reaction principle, a reaction on the detector, although its macroscopic state does not change. If all interactions are local, mediated by fields with relativistically causal evolution, some system, different from the particle which follows another path, must locall…
Long-range coherent interactions between quantum emitters are instrumental for quantum information and simulation technologies, but they are generally difficult to isolate from dissipation. Here, we show how such interactions can be obtained in photonic Weyl environments due to the emergence of an exotic bound state whose wavefunction displays power-law spatial confinement. Using an exact formalism, we show how this bound state can mediate coherent transfer of excitations between emitters, with virtually no dissipation and with a transfer rate that follows the same scaling with distance as the…
A spectroscopic application of the atom laser is suggested. The spectroscopy termed 2PACC employs the coherent properties of matter-waves from a two pulse atom laser. These waves are employed to control a gas-surface chemical recombination reaction. The method is demonstrated for an Eley-Rideal reaction of a hydrogen or alkali atom-laser pulse where the surface target is an adsorbed hydrogen atom. The reaction yields either a hydrogen or alkali hydride molecule. The desorbed gas phase molecular yield and its internal state is shown to be controlled by the time and phase delay between two atom-…
The energy charging of a quantum battery is analyzed in an open quantum setting, where the interaction between the battery element and the external power source is mediated by an ancilla system (the quantum charger) that acts as a controllable switch. Different implementations are analyzed putting emphasis on the interplay between coherent energy pumping mechanisms and thermalization.
We solve a model that describes a stimulated conversion between ultracold bosonic atoms and molecules. The reaction is triggered by a linearly time-dependent transition throughout the Feshbach resonance. Our solution predicts a nonexponential dependence, with a dynamic phase transition, of the reaction efficiency on the transition rate. We find that the emerging phase can have a thermalized energy distribution with the temperature defined by the rate of the transition. This phase, however, has strong purely quantum correlations.
We study the possibility to use interaction between a polar molecule in the ground electronic and vibrational state and a Rydberg atom to construct two-qubit gates between molecular qubits and to coherently control molecular states. A polar molecule within the electron orbit in a Rydberg atom can either shift the Rydberg state, or form Rydberg molecule. Both the atomic shift and the Rydberg molecule states depend on the initial internal state of the polar molecule, resulting in molecular state dependent van der Waals or dipole-dipole interaction between Rydberg atoms. Rydberg atoms mediated in…
The realization of a coherent interface between distant charge or spin qubits in semiconductor quantum dots is an open challenge for quantum information processing. Here we demonstrate both resonant and non-resonant photon-mediated coherent interactions between double quantum dot charge qubits separated by several tens of micrometers. We present clear spectroscopic evidence of the collective enhancement of the resonant coupling of two qubits. With both qubits detuned from the resonator we observe exchange coupling between the qubits mediated by virtual photons. In both instances pronounced bri…
We propose and study the use of photon-mediated interactions for the generation of long-range steady-state entanglement between N atoms. Through the judicious use of coherent drives and the placement of the atoms in a network of Cavity QED systems, a balance between their unitary and dissipative dynamics can be precisely engineered to stabilize a long-range correlated state of qubits in the steady state. We discuss the general theory behind such a scheme, and present an example of how it can be used to drive a register of N atoms to a generalized W state and how the entanglement can be sustain…
Spin bath mediated long-lived coherent oscillations of NV centers in diamond
Bennett University（贝内特大学）；IIT Madras（印度理工学院马德拉斯分校）；Technische Universität Dortmund（多特蒙德工业大学）；Center For Quantum Information, Communication And Computing, IIT Madras（印度理工学院马德拉斯分校量子信息、通信与计算中心）；London center for Nanotechnology, UCL（伦敦纳米技术研究中心，伦敦大学学院）；SIAS, Krea University（克里亚大学SIAS学院）
The Wigner-Weisskopf-type model developed in [R. Alicki and F. Giraldi, J. Phys. B {\bf 44}, 154020 (2011)] is applied to the biological process of energy transfer from a large peripheral light harvesting antenna to the reaction center. This process is mediated by the Fenna-Matthews-Olson (FMO) photosynthetic complex with a remarkably high efficiency. The proposed model provides a simple resonance mechanism of this phenomenon employing exciton coherent motion and described by analytical formulas. A coupling to the vibrational environment is a necessary component of this mechanism as well as a …
Coherent control of reactants remains a longstanding challenge in quantum chemistry. In particular, we have studied laser-induced molecular formation (photoassociation) in a Raman-dressed spin-orbit-coupled 87Rb Bose-Einstein condensate, whose spin quantum state is a superposition of multiple bare spin components. In contrast to the notably different photoassociation-induced fractional atom losses observed for the bare spin components of a statistical mixture, a superposition state with a comparable spin composition displays the same fractional loss on every spin component. We interpret this a…
Excitation energy transfer (EET) and electron transfer (ET) are crucially involved in photosynthetic processes. In reality, the photosynthetic reaction center constitutes an open quantum system of EET and ET, which manifests an interplay of pigments, solar light and phonon baths. So far theoretical studies have been mainly based on master equation approaches in the Markovian condition. The non-Markovian environmental effect, which may play a crucial role, has not been sufficiently considered. In this work, we propose a mixed dynamic approach to investigate this open system. The influence of ph…
