Multiple time correlation functions are found in the dynamical description of different phenomena. They encode and describe the fluctuations of the dynamical variables of a system. In this paper we formulate a theory of non-Markovian multiple-time correlation functions (MTCF) for a wide class of systems. We derive the dynamical equation of the {\it reduced propagator}, an object that evolve state vectors of the system conditioned to the dynamics of its environment, which is not necessarily at the vacuum state at the initial time. Such reduced propagator is the essential piece to obtain multiple-time correlation functions. An average over the different environmental histories of the reduced propagator permits us to obtain the evolution equations of the multiple-time correlation functions. We also study the evolution of MTCF within the weak coupling limit and it is shown that the multiple-time correlation function of some observables satisfy the Quantum Regression Theorem (QRT), whereas other correlations do not. We set the conditions under which the correlations satisfy the QRT. We illustrate the theory in two different cases; first, solving an exact model for which the MTCF are explicitly given, and second, presenting the results of a numerical integration for a system coupled with a dissipative environment through a non-diagonal interaction.
We explore the connection between two recently introduced notions of non-Markovian quantum dynamics and the validity of the so-called quantum regression theorem. While non-Markovianity of a quantum dynamics has been defined looking at the behaviour in time of the statistical operator, which determines the evolution of mean values, the quantum regression theorem makes statements about the behaviour of system correlation functions of order two and higher. The comparison relies on an estimate of the validity of the quantum regression hypothesis, which can be obtained exactly evaluating two points…
We find the conditions under which a quantum regression theorem can be assumed valid for non-Markovian master equations consisting in Lindblad superoperators with memory kernels. Our considerations are based on a generalized Born-Markov approximation, which allows us to obtain our results from an underlying Hamiltonian description. We demonstrate that a non-Markovian quantum regression theorem can only be granted in a stationary regime if the dynamics satisfies a quantum detailed balance condition. As an example we study the correlations of a two level system embedded in a complex structured r…
We investigate the entanglement dynamics of two initially entangled qubits interacting independently with two uncorrelated reservoirs beyond the Markovian approximation. Quite different from the Markovian reservoirs [C. E. Lopez et al., Phys. Rev. Lett. 101 (2008) 080503], we find that entanglement sudden birth (ESB) of the two reservoirs occurs without certain symmetry with respect to the entanglement sudden death (ESD) of the two qubits. A phenomenological interpretation of entanglement revival is also given.
In this paper, we analyze the evolution of the generalized Pauli channels governed by the memory kernel master equation. We provide necessary and sufficient conditions for the memory kernel to give rise to the legitimate (completely positive and trace-preserving) quantum evolution. In particular, we analyze a class of kernels generating the quantum semi-Markov evolution, which is a natural generalization of the Markovian semigroup. Interestingly, the convex combination of Markovian semigroups goes beyond the semi-Markov case. Our analysis is illustrated with several examples.
Beyond the conventional quantum regression theorem, a general formula for non-Markovian correlation functions of arbitrary system operators both in the time- and frequency-domain is given. We approach the problem by transforming the conventional time-nonlocal master equation into dispersed time-local equations-of-motion. The validity of our approximations is discussed and we find that the non-Markovian terms have to be included for short times. While calculations of the density matrix at short times suffer from the initial value problem, a correlation function has a well defined initial state.…
Quantum dynamical maps provide suitable mathematical representation of quantum evolutions. It is the very notion of complete positivity which provides a proper mathematical representation of quantum evolution and gives rise to the powerful generalization of unitary evolution of closed Hamiltonian systems. A prominent example of quantum evolution of an open system is a Markovian semigroup. In what follows, we analyze both the semigroups of positive and completely positive maps. In the latter case the dynamics is governed by the celebrated Gorini-Kossakowski-Lindblad-Sudarshan (GKLS) Master Equa…
Various engine types are thermodynamically equivalent in the quantum limit of small 'engine action'. Our previous derivation of the equivalence is restricted to Markovian heat baths and to implicit classical work repository (e.g., laser light in the semi-classical approximation). In this paper all the components, baths, batteries, and engine, are explicitly taken into account. To neatly treat non-Markovian dynamics we use mediating particles that function as a heat exchanger. We find that on top of the previously observed equivalence there is a higher degree of equivalence that cannot be achie…
The measurement-result-conditioned evolution of a system (e.g. an atom) with spontaneous emissions of photons is well described by the quantum trajectory (QT) theory. In this work we generalize the associated QT theory from infinitely wide bandwidth Markovian environment to the case of finite bandwidth non-Markovian environment. In particular, we generalize the treatment for arbitrary spectrum, which is not restricted by the specific Lorentzian case. We rigorously prove a general existence of a perfect scaling behavior jointly defined by the bandwidth of environment and the time interval betwe…
Computational framework for non-Markovian multi-emitter dynamics beyond the single-excitation limit
Pohang University of Science and Technology (POSTECH)（浦项科技大学）；Elmore Family School of Electrical and Computer Engineering, Purdue University（普渡大学埃尔默电气与计算机工程学院）
We construct a non-Markovian canonical dynamical map that accounts for systems correlated with the environment. The physical meaning of not completely positive maps is studied to obtain a theory of non-Markovian quantum dynamics. The relationship between inverse maps and correlations with the environment is established. A generalized non-Markovian master equation is derived from the canonical dynamical map that goes beyond the Kossakowski-Lindblad Markovian master equation. Non-equilibrium quantum thermodynamics can be be studied within this theory.
The dynamics of a system that is initially correlated with an environment is almost always non-Markovian. Hence it is important to characterise such initial correlations experimentally and witness them in physically realistic settings. One such setting is weak-field phase control, where chemical reactions are sought to be controlled by the phase of shaped weak laser pulses. In this manuscript, we show how weak quantum controllability can be combined with quantum preparations to witness initial correlations between the system and the environment. Furthermore we show how weak field phase control…
Markovian master equations provide a versatile tool for describing open quantum systems when memory effects of the environment may be neglected. As these equations are of an approximate nature, they often do not respect the laws of thermodynamics when no secular approximation is performed in their derivation. Here we introduce a Markovian master equation that is thermodynamically consistent and provides an accurate description whenever memory effects can be neglected. The thermodynamic consistency is obtained through a rescaled Hamiltonian for the thermodynamic bookkeeping, exploiting the fact…
A precise understanding of the influence of a quantum system's environment on its dynamics, which is at the heart of the theory of open quantum systems, is crucial for further progress in the development of controllable large-scale quantum systems. However, existing approaches to account for complex system-environment interaction in the presence of memory effects are either based on heuristic and oversimplified principles or give rise to computational difficulties. In practice, one can leverage on available experimental data and replace first-principles simulations with a data-driven analysis …
Quantum memory effects can be induced even when the degrees of freedom associated to the environment are not affected at all during the system evolution. In this paper, based on a bipartite representation of the system-environment dynamics, we found the more general interactions that lead to this class of quantum non-Markovian "casual bystander environments." General properties of the resulting dynamics are studied with focus on the system-environment correlations, a collisional measurement-based representation, and the quantum regression hypothesis. Memory effects are also characterized throu…
We propose a scheme in which the cooling of a mechanical resonator is achieved by exposing the optomechanical system to a non-Markovian environment. Because of the backflow from the non-Markovian environment, the phonon number can go beyond the conventional cooling limit in a Markovian environment. Utilizing the spectrum density obtained in the recent experiment [Nature Communications 6, 7606 (2015)], we show that the cooling process is highly effective in a non-Markovian environment. The analysis of the cooling mechanism in a non-Markovian environment reveals that the non-Markovian memory eff…
We present a general model of qubit dynamics which entails pure dephasing and dissipative time-local master equations. This allows us to describe the combined effect of thermalisation and dephasing beyond the usual Markovian approximation. We investigate the complete positivity conditions and introduce a heuristic model that is always physical and provides the correct Markovian limit. We study the effects of temperature on the non-Markovian behaviour of the system and show that the noise additivity property discussed by Yu and Eberly in Ref. [1] holds beyond the Markovian limit.
An extremely useful evolution equation that allows systematically calculating the two-time correlation functions (CF's) of system operators for non-Markovian open (dissipative) quantum systems is derived. The derivation is based on perturbative quantum master equation approach, so non-Markovian open quantum system models that are not exactly solvable can use our derived evolution equation to easily obtain their two-time CF's of system operators, valid to second order in the system-environment interaction. Since the form and nature of the Hamiltonian are not specified in our derived evolution e…
We derive an extension of the quantum regression theorem to calculate out-of-time-order correlation functions in Markovian open quantum systems. While so far mostly being applied in the analysis of many-body physics, we demonstrate that out-of-time-order correlation functions appear naturally in optical detection schemes with interferometric delay lines, and we apply our extended quantum regression theorem to calculate the non-trivial photon counting fluctuations in split and recombined signals from a quantum light source.
The modeling of natural phenomena via a Markov process --- a process for which the future is independent of the past, given the present--- is ubiquitous in many fields of science. Within this context, it is of foremost importance to develop ways to check from the available empirical data if the underlying mechanism is indeed Markovian. A paradigmatic example is given by data processing inequalities, the violation of which is an unambiguous proof of the non-Markovianity of the process. Here, our aim is twofold. First we show the existence of a monogamy-like type of constraints, beyond data proc…
We use a non-Markovian approach to study the decoherence dynamics of a qubit in either a low- or high-frequency bath modeling the qubit environment. This approach is based on a unitary transformation and does not require the rotating-wave approximation. We show that for low-frequency noise, the bath shifts the qubit energy towards higher energies (blue shift), while the ordinary high-frequency cutoff Ohmic bath shifts the qubit energy towards lower energies (red shift). In order to preserve the coherence of the qubit, we also investigate the quantum Zeno effect in two cases: low- and high-freq…
We investigate dynamics of Gaussian states of continuous variable systems under Gaussianity preserving channels. We introduce a hierarchy of such evolutions encompassing Markovian, weakly and strongly non-Markovian processes, and provide simple criteria to distinguish between the classes, based on the degree of positivity of intermediate Gaussian maps. We classify all single-mode phase-insensitive Gaussian channels according to their non-Markovianity degree, and show that weak non-Markovianity has an operational significance as it leads to temporary amplification of Gaussian inputs beyond the …
The exploitation and characterization of memory effects arising from the interaction between system and environment is a key prerequisite for quantum reservoir engineering beyond the standard Markovian limit. In this paper we investigate a prototype of non-Markovian dynamics experimentally implementable with superconducting qubits. We rigorously quantify non-Markovianity highlighting the effects of the environmental temperature on the Markovian to non-Markovian crossover. We investigate how memory effects influence, and specifically suppress, the ability to perform work on the driven qubit. We…
We study the laser-driven Dicke model beyond the rotating-wave approximation. For weak coupling of the system to environmental degrees of freedom the dissipative dynamics of the emitter-cavity system is described by the Floquet master equation. Projection of the system evolution onto the emitter degrees of freedom results in non-Markovian behavior. We quantify the non-Markovianity of the resulting emitter dynamics and show that this quantity can be used as an indicator of the dissipative quantum phase transition occurring at high driving amplitudes.
By introducing a temporal change timescale $τ_{\text{A}}(t)$ for the time-dependent system Hamiltonian, a general formulation of the Markovian quantum master equation is given to go well beyond the adiabatic regime. In appropriate situations, the framework is well justified even if $τ_{\text{A}}(t)$ is faster than the decay timescale of the bath correlation function. An application to the dissipative Landau-Zener model demonstrates this general result. The findings are applicable to a wide range of fields, providing a basis for quantum control beyond the adiabatic regime.
A rapid restoration of the bath state is usually required to induce Markovian dynamics for an open quantum system, which typically can be realized only in limits such as weak system-bath coupling and infinitely large bath. In this work, we investigate the Markovianity of a qubit system coupled to a single-qubit bath with the qubit bath being continuously refreshed by quantum cooling. A surprising result is that there exists a finite threshold for the cooling rate at which the system transitions from non-Markovian dynamics to Markovian dynamics, which is in sharp contrast to the usual understan…
It was recently shown [S. Lorenzo et al., Sci. Rep. 7, 42729 (2017)] that the presence of static disorder in a bosonic bath - whose normal modes thus become all Anderson-localised - leads to non-Markovianity in the emission of an atom weakly coupled to it (a process which in absence of disorder is fully Markovian). Here, we extend the above analysis beyond the weak-coupling regime for a finite-band bath so as to account for band edge effects. We study the interplay of these with static disorder in the emergence of non-Markovian behaviour in terms of a suitable non-Markovianity measure.
We investigate the single-photon scattering spectra of a giant atom coupled to a one dimensional waveguide via multiple connection points or a continuous coupling region. Using a full quantum mechanical method, we obtain the general analytic expressions for the single-photon scattering coefficients, which are valid in both the Markovian and the non-arkovian regimes. We summarize the influences of the non-dipole effects, mainly caused by the phases accumulated by photons traveling between coupling points, on the scattering spectra. We find that under the Markovian limit, the phase decay is detu…
We develop a formalism for modelling exact time dynamics in waveguide quantum electrodynamics (QED) using the real-space approach. The formalism does not assume any specific configuration of emitters and allows the study of Markovian dynamics fully analytically and non-Markovian dynamics semi-analytically with a simple numerical integration step. We use the formalism to study subradiance, superradiance and bound states in continuum. We discuss new phenomena such as subdivision of collective decay rates into symmetric and anti-symmetric subsets and non-Markovian superradiance effects that can l…
Parameter Estimation in a Continuously Monitored Non-Markovian Quantum System
Technische Universität Wien（维也纳工业大学）；Institute for Quantum Optics and Quantum Information (IQOQI), Austrian Academy of Sciences（奥地利科学院量子光学与量子信息研究所）；University of Basel（巴塞尔大学）；Universidad de La Laguna（拉帕鲁纳大学）
We treat several key stochastic equations for non-Markovian open quantum system dynamics and present a formalism for finding solutions to them via canonical perturbation theory, without making the Born-Markov or rotating wave approximations (RWA). This includes master equations of the (asymptotically) stationary, periodic, and time-nonlocal type. We provide proofs on the validity and meaningfulness of the late-time perturbative master equation and on the preservation of complete positivity despite a general lack of Lindblad form. More specifically, we show how the algebraic generators satisfy …
Quantum regression theorem is a very useful result in open quantum system and extensively used for computing multi-point correlation functions. Traditionally it is derived for two-time correlators in the Markovian limit employing the Schrödinger picture. In this paper we make use of the Heisenberg picture to derive quantum regression theorems for multi-time correlation functions which in the special limit reduce to the well known two-time regression theorem. For multi-time correlation function we find that the regression theorem takes the same form as it takes for two-time correlation function…
The decay of a local spin excitation in an inhomogeneous spin chain is evaluated exactly: I) It starts quadratically up to a spreading time t_{S}. II) It follows an exponential behavior governed by a self-consistent Fermi Golden Rule. III) At longer times, the exponential is overrun by an inverse power law describing return processes governed by quantum diffusion. At this last transition time t_{R} a survival collapse becomes possible, bringing the polarization down by several orders of magnitude. We identify this strongly destructive interference as an antiresonance in the time domain. These …
By modeling the interaction of a system with an environment through a renewal approach, we demonstrate that completely positive non-Markovian dynamics may develop some unexplored non-standard statistical properties. The renewal approach is defined by a set of disruptive events, consisting in the action of a completely positive superoperator over the system density matrix. The random time intervals between events are described by an arbitrary waiting-time distribution. We show that, in contrast to the Markovian case, if one performs a system-preparation (measurement) at an arbitrary time, the s…
We study the collective radiative decay of a system of two two-level emitters coupled to a one-dimensional waveguide in a regime where their separation is comparable to the coherence length of a spontaneously emitted photon. The electromagnetic field propagating in the cavity-like geometry formed by the emitters exerts a retarded backaction on the system leading to strongly non-Markovian dynamics. The collective spontaneous emission rate of the emitters exhibits an enhancement or inhibition beyond the usual Dicke super- and sub-radiance due to a self-consistent coherent time-delayed feedback.
We investigate the sensing performance of a single-qubit quantum thermometer within a non-Markovian dynamical framework. By employing an exactly numerical hierarchical equations of the motion method, we go beyond traditional paradigms of the Born-Markov theory, the pure dephasing mechanism, and the weak-coupling approximation, which were commonly used in many previous studies of quantum thermometry. We find (i) the non-Markovian characteristics may boost the estimation efficiency, (ii) the sensitivity of quantum thermometry can be effectively optimized by engineering the proportions of differe…
We analyze precision bounds for a local phase estimation in the presence of general, non-Markovian phase noise. We demonstrate that the metrological equivalence of product and maximally entangled states that holds under strictly Markovian dephasing fails in the non-Markovian case. Using an exactly solvable model of a physically realistic finite bandwidth dephasing environment, we demonstrate that the ensuing non-Markovian dynamics enables quantum correlated states to outperform metrological strategies based on uncorrelated states using otherwise identical resources. We show that this conclusio…
We present a perturbation theory for non-Markovian quantum state diffusion (QSD), the theory of diffusive quantum trajectories for open systems in a bosonic environment [Physical Review {\bf A 58}, 1699, (1998)]. We establish a systematic expansion in the ratio between the environmental correlation time and the typical system time scale. The leading order recovers the Markov theory, so here we concentrate on the next-order correction corresponding to first-order non-Markovian master equations. These perturbative equations greatly simplify the general non-Markovian QSD approach, and allow for e…
The long-standing problem of nearly perfect photosynthetic yield in some types of bacteria and nearly all kinds of plants despite the interaction with a hot and noisy environment has witnessed quantum optical explanations in the last decade or so. Typically in these explanations, photosynthetic reaction centers are modeled as five-level quantum heat engines where the generation of Fano-type interference due to the coupling of discrete state transitions with a common Markovian reservoir is held responsible for the enhancement of the photosynthetic efficiency. In this work, we go beyond the Born…
The quantum regression formula for an open quantum system consists in an infinite hierarchy of conditions for its multi-time correlation functions, thus requiring full access to the total "system+environment" evolution, and providing a stronger requirement than CP-divisibility. Here, we analyze CP-divisibility and check the validity of quantum regression beyond the Born-Markov approximation (e.g. weak coupling limit) for a class of generalized spin-boson (GSB) models giving rise to a multi-level amplitude-damping evolution; in all cases, it is possible to engineer the system-bath coupling in s…
We deduce a class of non-Markovian completely positive master equations which describe a system in a composite bipartite environment, consisting of a Markovian reservoir and additional stationary unobserved degrees of freedom that modulate the dissipative coupling. The entanglement-induced memory effects can persist for arbitrary long times and affect the relaxation to equilibrium, as well as induce corrections to the quantum-regression theorem. By considering the extra degrees of freedom as a discrete manifold of energy levels, strong non-exponential behavior can arise, as for example power l…
The foundations of statistical mechanics, namely how equilibrium hypothesis emerges microscopically from quantum theory, is explored through investigating the environment-induced quantum decoherence processes. Based on the recent results on non-Markovian dynamics [Phys. Rev. Lett. 109, 170402 (2012)], we find that decoherence of quantum states manifests unexpected complexities. Indeed, an arbitrary given initial quantum state, under the influence of different reservoirs, can evolve into four different steady states: thermal, thermal-like, quantum memory and oscillating quantum memory states. T…
Detuned systems can spontaneously achieve a synchronous dynamics and display robust quantum correlations in different local and global dissipation regimes. Beyond the Markovian limit, information backflow from the environment becomes a crucial mechanism whose interplay with spontaneous synchronization is unknown. Considering a model of two coupled qubits, one of which interacts with a dissipative environment, we show that non-Markovianity is highly detrimental for the emergence of synchronization, for the latter can be delayed and hindered because of the presence of information backflow. The r…
