While the quantum regression theorem (QRT) is the standard tool for computing multi-time correlation functions in open quantum systems, it relies on system-bath separability and an environment that remains in equilibrium, assumptions that are violated once dynamical correlations develop. Using the projection operator formalism, we derive an extension to the QRT that explicitly incorporates these correlation-induced corrections, enabling us to capture multi-time correlation functions in non-Markovian regimes. We apply this framework to the variational polaron master equation for the spin-boson model in ohmic and super-ohmic regimes, where the polaron transformation mixes system-bath degrees of freedom to produce a non-thermal effective environment. Benchmarking against numerically exact tensor-network simulations, we demonstrate quantitative agreement for single- and two-time observables, including linear-response spectra, even at strong coupling. Our approach broadens the reach of analytic master equations to multi-time observables in strong-coupling and non-Markovian regimes, where environmental memory effects and system-bath correlations are crucial.
We introduce an intuitive and semi-analytical polaron master equation approach to model pulse-driven population inversion and emitted single photons from a quantum dot exciton. The master equation theory allows one to identify important phonon-induced scattering rates analytically, and fully includes the role of the time-dependent pump field. As an application of the theory, we first study a quantum dot driven by a time-varying laser pulse on and off resonance, showing the population inversion caused by acoustic phonon emission in direct agreement with recent experiment of Quilter {\em et al.}…
We revisit the model of a quantum Brownian oscillator linearly coupled to an environment of quantum oscillators at finite temperature. By introducing a compact and particularly well-suited formulation, we give a rather quick and direct derivation of the master equation and its solutions for general spectral functions and arbitrary temperatures. The flexibility of our approach allows for an immediate generalization to cases with an external force and with an arbitrary number of Brownian oscillators. More importantly, we point out an important mathematical subtlety concerning boundary-value prob…
In this paper we study the decoherence and purity of a driven solid-state qubit in the Ohmic bath by using the method based on the master equation. At first, instead of solving the master equation we investigate the coefficients of the equation which describe the shift in frequency, diffusive, decoherence, and so on. It is shown that one of the coefficients (we called it decoherence coefficient) is crucial to the decoherence of the qubit in the model. Then we investigate the evolution of the purity of the state in the model. From the analysis of the purity we see that the decoherence time of t…
We apply a full-polaron master equation and a weak-coupling non-Markovian master equation to describe the steady-state time-averaged properties of a driven two-level system, an electron coherently tunneling between double quantum dots (DQDs), interacting with a bosonic phonon bath. Comparing the results obtained using these two master equations with those from a recent DQD experiment and its corresponding weak-coupling theoretical method, we find that the original parameter set used in the experiment and theoretical method is not in the weak-coupling parameter regime. By using the full-polaron…
We derive a many-site version of the non-Markovian time-convolutionless polaron master equation [S. Jang et al., J. Chem Phys. 129, 101104 (2008)] to describe electronic excitation dynamics in multichromophoric systems. By treating electronic and vibrational degrees of freedom in a combined frame (polaron frame), this theory is capable of interpolating between weak and strong exciton-phonon coupling and is able to account for initial non-equilibrium bath states and spatially correlated environments. Besides outlining a general expression for the expected value of any electronic system observab…
We study the transport of ultracold impurity atoms immersed in a Bose-Einstein condensate (BEC) and trapped in a tight optical lattice. Within the strong-coupling regime, we derive an extended Hubbard model describing the dynamics of the impurities in terms of polarons, i.e. impurities dressed by a coherent state of Bogoliubov phonons. Using a generalized master equation based on this microscopic model we show that inelastic and dissipative phonon scattering results in (i) a crossover from coherent to incoherent transport of impurities with increasing BEC temperature and (ii) the emergence of …
In this paper, we apply the polaron master equation, which offers the possibilities to interpolate between weak and strong system-bath coupling, to study how system-bath couplings affect charge transfer processes in Photosystem II reaction center (PSII RC) inspired quantum heat engine (QHE) model in a wide parameter range. The effects of bath correlation and temperature, together with the combined effects of these factors are also discussed in details. The results show a variety of dynamical behaviours. We interpret these results in terms of noise-assisted transport effect and dynamical locali…
An approach based on a non-Markovian time-convolutionless polaron master equation is used to probe the quantum dynamics of a chromophore-qubit in a super-Ohmic bath. Utilizing a measure of non-Markovianity based on dynamical fixed points, we study the effects of the environment temperature and the coupling strength on the non-Markovian behavior of the chromophore in a super-Ohmic bath. It is found that an increase in the temperature results in a reduction in the backflow information from the environment to the chromophore, and therefore, a suppression of non-Markovianity. In the weak coupling …
We investigate the entanglement dynamics of continuous-variable quantum channels in terms of an entangled squeezed state of two cavity fields in a general non-Markovian environment. Using the Feynman-Vernon influence functional theory in the coherent-state representation, we derive an exact master equation with time-dependent coefficients reflecting the non-Markovian influence of the environment. The influence of environments with different spectral densities, e.g., Ohmic, sub-Ohmic, and super-Ohmic, is numerically studied. The non-Markovian process shows its remarkable influences on the entan…
In the study of open quantum systems, the polaron transformation has recently attracted a renewed interest as it offers the possibility to explore the strong system-bath coupling regime. Despite this interest, a clear and unambiguous analysis of the regimes of validity of the polaron transformation is still lacking. Here we provide such a benchmark, comparing second order perturbation theory results in the original untransformed frame, the polaron frame and the variational extension with numerically exact path integral calculations of the equilibrium reduced density matrix. Equilibrium quantit…
This article has to do with the derivation and solution of the Fokker--Planck equation associated to the momentum-independent Wigner function, of a particle subjected to a harmonic external field and immersed in a ohmic thermal bath of quantum harmonic oscillators. The strategy employed is a simplified version of the phenomenological approach of Schramm, Jung and Grabert of interpreting the operators as c-numbers to derive the adjoint equation arising from a twofold transformation of the Wigner function of the entire phase space. The statistical properties of the random noise comes from the in…
Center for Theoretical Physics of Complex Systems, Institute for Basic Science (IBS)（复杂系统理论物理中心，韩国基础科学研究所）；College of Physics and Electronic Engineering and Center for Computational Sciences, Sichuan Normal University（四川师范大学物理与电子工程学院及计算科学中心）；Universidad de Granada（格拉纳达大学）
We consider a model of non-Markovian Quantum Brownian motion that consists of an harmonic oscillator bilinearly coupled to a thermal bath, both via its position and momentum operators. We derive the master equation for such a model and we solve the equations of motion for a generic Gaussian system state. We then investigate the resulting evolution of the first and second moments for both an Ohmic and a super-Ohmic spectral density. In particular, we show that, irrespective of the specific form of the spectral density, the coupling with the momentum enhances the dissipation experienced by the s…
Developed originally for the Holstein polaron, the Davydov D1 ansatz is an efficient, yet extremely accurate trial state for time-dependent variation of the spin-boson model [J. Chem. Phys. 138, 084111 (2013)]. In this work, the Dirac-Frenkel time-dependent variational procedure utilizing the Davydov D1 ansatz is implemented to study entanglement dynamics of two qubits under the influence of two independent baths. The Ohmic spectral density is used without the Born-Markov approximation or the rotating-wave approximation. In the strong coupling regime finite-time disentanglement is always found…
We derive an exact non-Markovian master equation that generalizes the previous work [Hu, Paz and Zhang, Phys. Rev. D {\bf 45}, 2843 (1992)] to damped harmonic oscillators with time-varying parameters. This is achieved by exploiting the linearity of the system and operator solution in Heisenberg picture. Our equation governs the non-Markovian quantum dynamics when the system is modulated by external devices. As an application, we apply our equation to parity kick decoupling problems. The time-dependent dissipative coefficients in the master equation are shown to be modified drastically when the…
We study the non-Markovianity and quantum speedup of a two-level atom (quantum system of interest) in a dissipative Jaynes-Cumming model, where the atom is embedded in a single-mode cavity, which is leaky being coupled to an external reservoir with Ohmic spectral density. We obtain the non-Markovianity characterized by using the probability of the atomic excited state and the negative decoherence rate in the time-local master equation. We also calculate the quantum speed limit time (QSLT) of the evolution process of the atom. The results show that, the atom-cavity coupling is the main physical…
We derive a family of stochastic master equations describing homodyne measurement of multi-qubit diagonal observables in circuit quantum electrodynamics. In the regime where qubit decay can be neglected, our approach replaces the polaron-like transformation of previous work, which required a lengthy calculation for the physically interesting case of three qubits and two resonator modes. The technique introduced here makes this calculation straightforward and manifestly correct. Using this technique, we are able to show that registers larger than one qubit evolve under a non-Markovian master eq…
We analyze the effect of environment on the gate operation of flux-biased phase qubits. We employ the master equation for a reduced density matrix of the qubit system coupled to an Ohmic environment, described by the Caldeira-Leggett model. Numerically solving this equation, we evaluate the gate error as a function of energy splitting between qubit states, junction capacitance, and temperature. The analysis is presented for single-quadrature microwave (control) pulses as well as for two-quadrature pulses, which lower the gate error significantly for idealized systems in the absence of environm…
We propose a ground-state ansatz for the Ohmic spin-boson model that improves upon the variational treatment of Silbey and Harris for biased systems in the scaling limit. In particular, it correctly captures the smooth crossover behaviour expected for the ground-state magnetisation when moving between the delocalised and localised regimes of the model, a feature that the variational treatment is unable to properly reproduce, while it also provides a lower ground-state energy estimate in the crossover region. We further demonstrate the validity of our intuitive ground-state by showing that it l…
When an optical emitter is strongly coupled to a vibrational bath the polaron transformation is often used to permit an accurate second-order Redfield master equation. However, the optical transition rates in the polaron frame are not analytic and approximations typically need to be made which result in the loss of anything other than simple additive effects of the two baths. In this paper, we derive an intuitive analytic expression for the polaron frame optical transition rates by means of a finite mode truncation of the vibrational bath. Using this technique, calculations of the transition r…
Unitary transformations can allow one to study open quantum systems in situations for which standard, weak-coupling type approximations are not valid. We develop here an extension of the variational (polaron) transformation approach to open system dynamics, which applies to arbitrarily large exciton transport networks with local environments. After deriving a time-local master equation in the transformed frame, we go on to compare the population dynamics predicted using our technique with other established master equations. The variational frame dynamics are found to agree with both weak coupl…
We study the dynamics of an impurity embedded in a trapped Bose-Einstein condensate (Bose polaron), by recalling the quantum Brownian motion model. It is crucial that the model considers a parabolic trapping potential to resemble the experimental conditions. Thus, we detail here how the formal derivation changes due to the gas trap, in comparison to the homogeneous gas. We first find that the presence of a gas trap leads to a new form of the bath-impurity coupling constant and a larger degree in the super-ohmicity of the spectral density. This is manifested as a different dependence of the sys…
In this work, dissipative effects from a phonon bath on the resonance fluorescence of a solid state two level system embedded in a high quality semiconductor microcavity and driven by an intense laser, are investigated. Within the density operator formalism, we derive a variational master equation valid for broader ranges of temperatures, pumping rates, and radiation-matter couplings, than previous studies. From the obtained master equation, fluorescence spectra for various thermal and exciting conditions are numerically calculated, and compared to those computed from weak coupling and polaron…
We consider the global thermal state of classical and quantum harmonic oscillators that interact with a reservoir. Ohmic damping of the oscillator can be exactly treated with a 1D scalar field reservoir, whereas general non-Ohmic damping is conveniently treated with a continuum reservoir of harmonic oscillators. Using the diagonalized Hamiltonian of the total system, we calculate a number of thermodynamic quantities for the damped oscillator: the mean force internal energy, mean force free energy, and another internal energy based on the free-oscillator Hamiltonian. The classical mean force en…
We explore signatures of the non-Markovianity in the time-resolved energy transfer processes for quantum open systems. Focusing on typical systems such as the exact solvable damped Jaynes-Cummings model and the general spin-boson model, we establish quantitative links between the time-resolved energy current and the symmetric logarithmic derivative quantum Fisher information (SLD-QFI) flow, one of measures quantifying the non-Markovianity, within the framework of non-Markovian master equations in time-local forms. From the relationships, we find in the damped Jaynes-Cummings model that the SLD…
In this paper we consider the modelling and simulation of open quantum systems from a device engineering perspective. We derive master equations at different levels of approximation for a Superconducting Quantum Interference Device (SQUID) ring coupled to an ohmic bath. We demonstrate that the master equations we consider produce decoherences that are qualitatively and quantitativly dependent on both the level of approximation and the ring's external flux bias. We discuss the issues raised when seeking to obtain Lindbladian dissipation and show, in this case, that the external flux (which may …
Using the exact path integral solution for the damped harmonic oscillator it is shown that in general there does not exist an exact dissipative Liouville operator describing the dynamics of the oscillator for arbitrary initial bath preparations. Exact non-stationary Liouville operators can be found only for particular preparations. Three physically meaningful examples are examined. An exact new master equation is derived for thermal initial conditions. Second, the Liouville operator governing the time-evolution of equilibrium correlations is obtained. Third, factorizing initial conditions are …
The urgent need for reliable simulation tools to match the extreme accuracy needed to control tailored quantum devices highlights the importance of understanding open quantum systems and their modeling. To this end, we compare here the commonly used Redfield and Lindblad master equations against numerically exact results in the case of one and two resonant qubits transversely coupled at a single point to a Drude-cut ohmic bath. All the relevant parameters are varied over a broad range which allows us to give detailed predictions about the validity and physically meaningful applicability of the…
Understanding the behaviour of a quantum system coupled to its environment is of fundamental interest in the general field of quantum technologies. It also has important repercussions on foundational problems in physics, such as the process of decoherence and the so-called quantum measurement problem. There have been many approaches to explore Markovian and non-Markovian dynamics within the framework of open quantum systems, but the richness of the ensuing dynamics is still not fully understood. In this paper we develop a non-Markovian extension of the standard Caldeira-Leggett model, based on…
We study two anisotropically interacting spins coupled to optical phonons; we restrict our analysis to the regime of strong coupling to the environment, to the antiadiabatic region, and to the subspace with zero value for $S^z_T$ (the z-component of the total spin). In the case where each spin is coupled to a different phonon bath, we assume that the system and the environment are initially uncorrelated (and form a simply separable state) in the polaronic frame of reference. By analyzing the {polaron} dynamics through non-Markovian quantum master equation, we find that the system manifests a s…
Due to the exponential increase of the numerical effort with the number of degrees of freedom, moving basis functions have a long history in quantum dynamics. In addition, spawning of new basis functions is routinely applied. Here we advocate the opposite process: the programmed removal of motional freedom of selected basis functions. This is a necessity for converged numerical results with respect to the size of a non-orthogonal basis, because generically two or more states approach each other too closely early on, rendering unstable the matrix inversion, required to make the equations of mot…
We analyze the evolution of a quantum Brownian particle starting from an initial state that contains correlations between this system and its environment. Using a path integral approach, we obtain a master equation for the reduced density matrix of the system finding relatively simple expressions for its time dependent coefficients. We examine the evolution of delocalized initial states (Schrödinger's cats) investigating the effectiveness of the decoherence process. Analytic results are obtained for an ohmic environment (Drude's model) at zero temperature.
We re-consider the old problem of Brownian motion in homogeneous high-temperature thermal environment. The semiclassical theory implies that the diffusion coefficient does not depend on whether the thermal fluctuations are correlated in space or disordered. We show that the corresponding quantum analysis exhibits a remarkable breakdown of quantum-to-classical correspondence. Explicit results are found for a tight binding model, within the framework of an Ohmic master equation, where we distinguish between on-site and on-bond dissipators. The breakdown is second-order in the inverse temperature…
High fidelity models, which support accurate device characterization and correctly account for environmental effects, are crucial to the engineering of scalable quantum technologies. As it ensures positivity of the density matrix, one preferred model for open systems describes the dynamics with a master equation in Lindblad form. The Linblad operators are rarely derived from first principles, resulting in dynamical models which miss those additional terms that must generally be added to bring the master equation into Lindblad form, together with concomitant other terms that must be assimilated…
Quantum transport in disordered systems is studied using a polaron-based master equation. The polaron approach is capable of bridging the results from the coherent band-like transport regime governed by the Redfield equation to incoherent hopping transport in the classical regime. A non-monotonic dependence of the diffusion coefficient is observed both as a function of temperature and system-phonon coupling strength. In the band-like transport regime, the diffusion coefficient is shown to be linearly proportional to the system-phonon coupling strength, and vanishes at zero coupling due to Ande…
The transient dynamics of quantum coherence of Gaussian states are investigated. The state is coupled to an external environment which can be described by a Fano-Anderson type Hamiltonian. Solving the quantum Langevin equation, we obtain the Greens functions which are used to compute the time evolved first and second moments of the quadrature operators. From the quadrature operator moments, we construct the covariance matrix which is used to measure the coherence in the system. The coherence is measured using the relative entropy of coherence measure. We consider three different classes of spe…
By repeatedly measuring a quantum system, the evolution of the system can be slowed down (the quantum Zeno effect) or sped up (quantum anti-Zeno effect). We study these effects for a single two-level system coupled to a collection of harmonic oscillators. Previously, such systems have been studied in both the weak and the strong system-environment coupling regimes. In this paper, we apply a polaron transformation in a manner that allows us to study the quantum Zeno and anti-Zeno effects for a large variety of system-environment parameters. Using this approach, we reproduce previous results for…
By using the Redfield form of the master equation, we investigate the decoherence times of a double quantum dot charge qubit (DQDCQ) in three different cases, namely when it is coupled to (I) the piezoelectric coupling phonon bath (PCPB), (II) the deformation coupling phonon bath (DCPB), and (III) the Ohmic bath. It is found that our results for case (I) and (II) are in the same magnitude with those obtained via the exact path integral methods, while for case (III), the decoherence time is in well agreement with the experimental value.
We investigate the energy transfer dynamics in a donor-acceptor model by developing a time-local master equation technique based on a variational transformation of the underlying Hamiltonian. The variational transformation allows a minimisation of the Hamiltonian perturbation term dependent on the system parameters, and consequently results in a versatile master equation valid over a range of system-bath coupling strengths, temperatures, and environmental spectral densities. While our formalism reduces to the well-known Redfield, Foerster and polaron forms in the appropriate limits, in general…
Comparison of the standard and dressed-picture master equations for the quantum Rabi model in the ultrastrong coupling regime
Institute of Physics, University of Brasília（巴西利亚大学物理研究所）；International Center of Physics, Institute of Physics, University of Brasília（巴西利亚大学物理研究所国际物理中心）
We present an open-system master equation study of the coherent and incoherent resonance fluorescence spectrum from a two-level quantum system under coherent pulsed excitation. Several pronounced features which differ from the fluorescence under a constant drive are highlighted, including a multi-peak structure and a pronounced off-resonant spectral asymmetry, in stark contrast to the conventional symmetrical Mollow triplet. We also study semiconductor quantum dot systems using a polaron master equation, and show how the key features of dynamic resonance fluorescence change with electron--acou…
Considering two non-interacting qubits in the context of open quantum systems, it is well known that their common environment may act as an entangling agent. In a perturbative regime the influence of the environment on the system dynamics can effectively be described by a unitary and a dissipative contribution. For the two-spin Boson model with (sub-) Ohmic spectral density considered here, the particular unitary contribution (Lamb shift) easily explains the buildup of entanglement between the two qubits. Furthermore it has been argued that in the adiabatic limit, adding the so-called countert…
