We apply a full-polaron master equation and a weak-coupling non-Markovian master equation to describe the steady-state time-averaged properties of a driven two-level system, an electron coherently tunneling between double quantum dots (DQDs), interacting with a bosonic phonon bath. Comparing the results obtained using these two master equations with those from a recent DQD experiment and its corresponding weak-coupling theoretical method, we find that the original parameter set used in the experiment and theoretical method is not in the weak-coupling parameter regime. By using the full-polaron master equation with a slight adjustment on only the value of the interdot separation in the original experimental parameter set, we find that a reasonable fit to the experimentally measured time-averaged steady-state population data can be achieved. The adjusted interdot separation is within the possible values allowed by the geometry of the surface gates that define the DQD in the experiment. Our full-polaron equation approach does not require the special renormalization scheme employed in their weak-coupling theoretical method, and can still describe the experimental results of driving-induced phonon-enhanced steplike shoulder behaviors in the experiment. This demonstrates that the full-polaron master equation approach is a correct and efficient tool to describe the steady-state properties of a driven spin-boson model in the case of strong system-environment coupling.
We derive a many-site version of the non-Markovian time-convolutionless polaron master equation [S. Jang et al., J. Chem Phys. 129, 101104 (2008)] to describe electronic excitation dynamics in multichromophoric systems. By treating electronic and vibrational degrees of freedom in a combined frame (polaron frame), this theory is capable of interpolating between weak and strong exciton-phonon coupling and is able to account for initial non-equilibrium bath states and spatially correlated environments. Besides outlining a general expression for the expected value of any electronic system observab…
We introduce an intuitive and semi-analytical polaron master equation approach to model pulse-driven population inversion and emitted single photons from a quantum dot exciton. The master equation theory allows one to identify important phonon-induced scattering rates analytically, and fully includes the role of the time-dependent pump field. As an application of the theory, we first study a quantum dot driven by a time-varying laser pulse on and off resonance, showing the population inversion caused by acoustic phonon emission in direct agreement with recent experiment of Quilter {\em et al.}…
Center for Theoretical Physics of Complex Systems, Institute for Basic Science (IBS)（复杂系统理论物理中心，韩国基础科学研究所）；College of Physics and Electronic Engineering and Center for Computational Sciences, Sichuan Normal University（四川师范大学物理与电子工程学院及计算科学中心）；Universidad de Granada（格拉纳达大学）
In this paper, we apply the polaron master equation, which offers the possibilities to interpolate between weak and strong system-bath coupling, to study how system-bath couplings affect charge transfer processes in Photosystem II reaction center (PSII RC) inspired quantum heat engine (QHE) model in a wide parameter range. The effects of bath correlation and temperature, together with the combined effects of these factors are also discussed in details. The results show a variety of dynamical behaviours. We interpret these results in terms of noise-assisted transport effect and dynamical locali…
Steady-state observables, such as occupation numbers and currents, are crucial experimental signatures in open quantum systems. The time-convolutionless (TCL) master equation, which is both exact and time-local, is an ideal candidate for the perturbative computation of such observables. We develop a diagrammatic approach to evaluate the steady-state TCL generator based on operators rather than superoperators. We obtain the steady-state occupation numbers, extend our formulation to the calculation of currents, and provide a simple physical interpretation of the diagrams. We further benchmark ou…
Unitary transformations can allow one to study open quantum systems in situations for which standard, weak-coupling type approximations are not valid. We develop here an extension of the variational (polaron) transformation approach to open system dynamics, which applies to arbitrarily large exciton transport networks with local environments. After deriving a time-local master equation in the transformed frame, we go on to compare the population dynamics predicted using our technique with other established master equations. The variational frame dynamics are found to agree with both weak coupl…
We investigate the quantum thermal transistor effect in nonequilibrium three-level systems by applying the polaron transformed Redfield equation combined with full counting statistics. The steady state heat currents are obtained via this unified approach over a wide region of system-bath coupling, and can be analytically reduced to the Redfield and nonequilibrium noninteracting blip approximation results in the weak and strong coupling limits, respectively. A giant heat amplification phenomenon emerges in the strong system-bath coupling limit, where transitions mediated by the middle thermal b…
In this work, dissipative effects from a phonon bath on the resonance fluorescence of a solid state two level system embedded in a high quality semiconductor microcavity and driven by an intense laser, are investigated. Within the density operator formalism, we derive a variational master equation valid for broader ranges of temperatures, pumping rates, and radiation-matter couplings, than previous studies. From the obtained master equation, fluorescence spectra for various thermal and exciting conditions are numerically calculated, and compared to those computed from weak coupling and polaron…
This work is concerned with determination of the steady-state structure of time-independent Lindblad master equations, especially those possessing more than one steady state. The approach here is to treat Lindblad systems as generalizations of unitary quantum mechanics, extending the intuition of symmetries and conserved quantities to the dissipative case. We combine and apply various results to obtain an exhaustive characterization of the infinite-time behavior of Lindblad evolution, including both the structure of the infinite-time density matrix and its dependence on initial conditions. The…
We propose a ground-state ansatz for the Ohmic spin-boson model that improves upon the variational treatment of Silbey and Harris for biased systems in the scaling limit. In particular, it correctly captures the smooth crossover behaviour expected for the ground-state magnetisation when moving between the delocalised and localised regimes of the model, a feature that the variational treatment is unable to properly reproduce, while it also provides a lower ground-state energy estimate in the crossover region. We further demonstrate the validity of our intuitive ground-state by showing that it l…
We consider a finite quantum system under slow driving and weakly coupled to thermal reservoirs at different temperatures. We present a systematic derivation of the quantum master equation for the density matrix and the out-of-time-order correlators. We start from the microscopic Hamiltonian and we formulate the equations ruling the dynamics of these quantities by recourse to the Schwinger-Keldysh non-equilibrium Green's function formalism, performing a perturbative expansion in the coupling between the system and the reservoirs. We focus on the adiabatic dynamics, which corresponds to conside…
In the study of open quantum systems, the polaron transformation has recently attracted a renewed interest as it offers the possibility to explore the strong system-bath coupling regime. Despite this interest, a clear and unambiguous analysis of the regimes of validity of the polaron transformation is still lacking. Here we provide such a benchmark, comparing second order perturbation theory results in the original untransformed frame, the polaron frame and the variational extension with numerically exact path integral calculations of the equilibrium reduced density matrix. Equilibrium quantit…
In the framework of theory of open quantum systems, we derive quantum master equations for the ultrastrong system-bath coupling regime and, more generally, the strong-decoherence regime. In this regime, the strong decoherence is complemented by slow relaxation processes. We use a generalization of the Foerster and modified Redfield peturbation theories known in theory of excitation energy transfer. Also, we show that the mean force Gibbs state in the corresponding limits are stationary for the derived master equations.
Master equations are commonly used to describe time evolution of open systems. We introduce a general method for calculating a Markovian solution of the Nakajima-Zwanzig generalized master equation. We do so for a time dependent transport of interacting electrons through a complex nano scale system in a photon cavity. The central system, described by 120 many-body states in a Fock space, is weakly coupled to the external leads. The very diverse relaxation times of the open system, reflecting radiative or non-radiative transitions, require information about the time evolution through many order…
We present an open-system master equation study of the coherent and incoherent resonance fluorescence spectrum from a two-level quantum system under coherent pulsed excitation. Several pronounced features which differ from the fluorescence under a constant drive are highlighted, including a multi-peak structure and a pronounced off-resonant spectral asymmetry, in stark contrast to the conventional symmetrical Mollow triplet. We also study semiconductor quantum dot systems using a polaron master equation, and show how the key features of dynamic resonance fluorescence change with electron--acou…
We study the transport of ultracold impurity atoms immersed in a Bose-Einstein condensate (BEC) and trapped in a tight optical lattice. Within the strong-coupling regime, we derive an extended Hubbard model describing the dynamics of the impurities in terms of polarons, i.e. impurities dressed by a coherent state of Bogoliubov phonons. Using a generalized master equation based on this microscopic model we show that inelastic and dissipative phonon scattering results in (i) a crossover from coherent to incoherent transport of impurities with increasing BEC temperature and (ii) the emergence of …
The Lindblad form guarantees complete positivity of a Markovian quantum master equation (QME). However, its microscopic derivation for a quantum system weakly interacting with a thermal bath requires several approximations, which may result in inaccuracies in the QME. Recently, various Lindbladian QMEs were derived without resorting to the secular approximation from the Redfield equation which does not guarantee the complete positivity. Here we explicitly calculate, in a perturbative manner, the equilibrium steady states of these Lindbladian QMEs. We compare the results with the steady state o…
We investigate the energy transfer dynamics in a donor-acceptor model by developing a time-local master equation technique based on a variational transformation of the underlying Hamiltonian. The variational transformation allows a minimisation of the Hamiltonian perturbation term dependent on the system parameters, and consequently results in a versatile master equation valid over a range of system-bath coupling strengths, temperatures, and environmental spectral densities. While our formalism reduces to the well-known Redfield, Foerster and polaron forms in the appropriate limits, in general…
We derive a family of stochastic master equations describing homodyne measurement of multi-qubit diagonal observables in circuit quantum electrodynamics. In the regime where qubit decay can be neglected, our approach replaces the polaron-like transformation of previous work, which required a lengthy calculation for the physically interesting case of three qubits and two resonator modes. The technique introduced here makes this calculation straightforward and manifestly correct. Using this technique, we are able to show that registers larger than one qubit evolve under a non-Markovian master eq…
Feedback control is expected to considerably protect quantum states against decoherence caused by interaction between the system and environment. Especially, Markovian feedback scheme developed by Wiseman can modify the properties of decoherence and eventually recover the purity of the steadystate of the corresponding master equation. This paper provides a condition for which the modified master equation has a pure steady state. By applying this condition to a two-qubit system, we obtain a complete parametrization of the feedback Hamiltonian such that the steady state becomes a maximally entan…
We study the excitonic dynamics of a driven quantum dot under the influence of a phonon environment, going beyond the weak exciton-phonon coupling approximation. By combining the polaron transform and time-local projection operator techniques we develop a master equation that can be valid over a much larger range of exciton-phonon coupling strengths and temperatures than the standard weak-coupling approach. For the experimentally relevant parameters considered here, we find that the weak-coupling and polaron theories give very similar predictions for low temperatures (below 30 K), while at hig…
We propose and investigate a pump-probe spectroscopy scheme to unveil the time-resolved dynamics of fermionic or bosonic impurities immersed in a harmonically trapped Bose-Einstein condensate. In this scheme a pump pulse initially transfers the impurities from a noninteracting to a resonantly interacting spin-state and, after a finite time in which the system evolves freely, the probe pulse reverses this transition. This directly allows to monitor the nonequilibrium dynamics of the impurities as the dynamical formation of coherent attractive or repulsive Bose polarons and signatures of their i…
We present a master equation describing the interaction of light with dielectric objects of arbitrary sizes and shapes. The quantum motion of the object, the quantum nature of light, as well as scattering processes to all orders in perturbation theory are taken into account. This formalism extends the standard master equation approach to the case where interactions among different modes of the environment are considered. It yields a genuine quantum description, including a renormalization of the couplings and decoherence terms. We apply this approach to analyze cavity cooling of the center-of-…
We study two anisotropically interacting spins coupled to optical phonons; we restrict our analysis to the regime of strong coupling to the environment, to the antiadiabatic region, and to the subspace with zero value for $S^z_T$ (the z-component of the total spin). In the case where each spin is coupled to a different phonon bath, we assume that the system and the environment are initially uncorrelated (and form a simply separable state) in the polaronic frame of reference. By analyzing the {polaron} dynamics through non-Markovian quantum master equation, we find that the system manifests a s…
For open systems described by the quantum master equation (QME), we investigate the excess entropy production under quasistatic operations between nonequilibrium steady states. The average entropy production is composed of the time integral of the instantaneous steady entropy production rate and the excess entropy production. We propose to define average entropy production rate using the average energy and particle currents, which are calculated by using the full counting statistics with QME. The excess entropy production is given by a line integral in the control parameter space and its integ…
For the multi-mode Dicke model in a transport setting that exhibits collective boson transmissions, we construct the equation of motion for the cumulant generating function. Approximating the exact system of equations at the level of cumulant generating function and system operators at lowest order, allows us to recover master equation results of the Full Counting Statistics for certain parameter regimes at very low cost of computation. The thermodynamic limit, that is not accessible with the master equation approach, can be derived analytically for different approximations.
We put forth a new class of quantum master equations that correctly reproduce the asymptotic state of an open quantum system beyond the infinitesimally weak system-bath coupling limit. Our method is based on incorporating the knowledge of the reduced steady state into its dynamics. The correction not only steers the reduced system towards a correct steady state but also improves the accuracy of the dynamics, thereby refining the archetypal Born-Markov weak-coupling second-order master equations. In case of equilibrium, since a closed form for the steady state exists in terms of a mean force Gi…
We consider the accurate investigation of the energy current and its components, heat and work, in some boundary driven quantum spin systems. The expressions for the currents, as well as the associated Lindblad master equation, are obtained via a repeated interaction scheme. We consider small systems in order to analytically compute the steady distribution to study the current in the steady state. Asymmetrical XXZ and quantum Ising models are detailed analyzed. For the XXZ chain we present cases in which different compositions of heat and work currents, obtained via the repeated interaction pr…
We present a generic quantum master equation whose dissipative dynamics autonomously stabilizes a harmonic oscillator in the n=1 Fock state. A multi-mode optomechanical system is analyzed and shown to be an example of a physical system obeying this model. We show that the optomechanical setup enables preparation of a mechanical oscillator in a nonclassical steady state, and that this state indeed approaches a single phonon Fock state in the ideal parameter regime. The generic model may be useful in other settings, such as cavity or circuit quantum electrodynamics or trapped ion physics.
We investigate pump-induced exciton inversion in a quantum-dot cavity system with continuous wave drive. Using a polaron-based master equation, we demonstrate excited-state populations above 0.9 for an InAs dot at a phonon bath temperature of 4K. In an exciton-driven system, the dominant mechanism is incoherent excitation from the phonon bath. For cavity driving, the mechanism is phonon-mediated switching between ground- and excited-state branches of the ladder of photon states, as quantum trajectory simulations clearly show. The exciton inversion as a function of detuning is found to be quali…
We analyse the quantum dynamics of a nanomechanical resonator coupled to a normal-state single-electron transistor (SET). Starting from a microscopic description of the system, we derive a master equation for the SET island charge and resonator which is valid in the limit of weak electro-mechanical coupling. Using this master equation we show that, apart from brief transients, the resonator always behaves like a damped harmonic oscillator with a shifted frequency and relaxes into a thermal-like steady state. Although the behaviour remains qualitatively the same, we find that the magnitude of t…
We provide a self-contained review of master equation approaches to modelling phonon effects in optically driven self-assembled quantum dots. Coupling of the (quasi) two-level excitonic system to phonons leads to dissipation and dephasing, the rates of which depend on the excitation conditions, intrinsic properties of the QD sample, and its temperature. We describe several techniques, which include weak-coupling master equations that are perturbative in the exciton-phonon coupling, as well as those based on the polaron transformation that can remain valid for strong phonon interactions. We add…
We address the structure of the Liouvillian superoperator for a broad class of bosonic and fermionic Markovian open systems interacting with stationary environments. We show that the accurate application of the partial secular approximation in the derivation of the Bloch-Redfield master equation naturally induces a symmetry on the superoperator level, which may greatly reduce the complexity of the master equation by decomposing the Liouvillian superoperator into independent blocks. Moreover, we prove that, if the steady state of the system is unique, one single block contains all the informati…
In a recent Letter, Guarnieri et al. [1] reported on the possibility of generating steady-state coherence (SSC) in the energy basis of a two-level system by the sole action of a single thermal bath also for weak system-bath coupling and due to a composite form of this interaction. The results are based on a time-local Bloch-Redfield master equation without secular approximation and the associated set of Bloch equations, all derived in the Supplemental Material (SM) of Ref. [1]. We comment that the results reported by the authors present both technical flaws and conceptual limitations that subs…
We present a theoretical study of a superconducting charge qubit dispersively coupled to a transmission line resonator. Starting from a master equation description of this coupled system and using a polaron transformation, we obtain an exact effective master equation for the qubit. We then use quantum trajectory theory to investigate the measurement of the qubit by continuous homodyne measurement of the resonator out-field. Using the same porlaron transformation, a stochastic master equation for the conditional state of the qubit is obtained. From this result, various definitions of the measur…
We show that open quantum systems of two-level atoms symmetrically coupled to a single-mode photon field can be efficiently simulated by applying a SU(4) group theory to quantum master equations. This is important since many foundational examples in quantum optics fall into this class. We demonstrate the method by finding exact solutions for many-atom open quantum systems such as lasing and steady state superradiance.
Starting from the Liouville-von Neumann equation, under a weak coupling limit we derive the Lindblad master equation for the one-dimensional quantum Ising model in a Markov approximation and a rotating wave approximation. We also prove that the steady solution of the Lindblad equation is the canonical distribution independent of the dissipation rate.
We study the steady state of two coupled two-level atoms interacting with a non-equilibrium environment that consists of two heat baths at different temperatures. Specifically, we analyze four cases with respect to the configuration about the interactions between atoms and heat baths. Using secular approximation, the conventional master equation usually neglects steady-state coherence, even when the system is coupled with a non-equilibrium environment. When employing the master equation with no secular approximation, we find that the system coherence in our model, denoted by the off-diagonal t…
The local approach to construct master equation for a composite open system with a weak internal coupling is simple and seems reasonable. However, it is thermodynamic consistent only when the subsystems are resonantly coupled. Efforts are being made to understand the inconsistency and test the validity of the local master equation. We present a perturbative method to solve the steady-state solutions of linear local master equations, which are demonstrated by two simple models. The solving process shows the stationary state as the result of competition between incoherent operations and the unit…
Following the Dirac-Frenkel time-dependent variational principle, transient dynamics of a one-dimensional Holstein polaron with diagonal and off-diagonal exciton-phonon coupling in an external electric field is studied by employing the multi-D$_2$ {\it Ansatz}, also known as a superposition of the usual Davydov D$_2$ trial states. Resultant polaron dynamics has significantly enhanced accuracy, and is in perfect agreement with that derived from the hierarchy equations of motion method. Starting from an initial broad wave packet, the exciton undergoes typical Bloch oscillations. Adding weak exci…
Starting from a microscopic system-baths description, we derive the general conditions for a time-local quantum master equation (QME) to satisfy the first and second law of thermodynamics at the fluctuating level. Using counting statistics, we show that the fluctuating second law can be rephrased as a Generalized Quantum Detailed Balance condition (GQDB), i.e., a symmetry of the time-local generators which ensures the validity of the fluctuation theorem. When requiring in addition a strict system-bath energy conservation, the GQDB reduces to the usual notion of detailed balance which ensures Q…
We discuss recent findings about properties of quantum nonequilibrium steady states. In particular we focus on transport properties. It is shown that the time dependent density matrix renormalization method can be used successfully to find a stationary solution of Lindblad master equation. Furthermore, for a specific model an exact solution is presented.
We consider open quantum systems with dynamics described by master equations that have perturbative expansions in the system-environment interaction. We show that, contrary to intuition, full-time solutions of order-2n accuracy require an order-(2n+2) master equation. We give two examples of such inaccuracies in the solutions to an order-2n master equation: order-2n inaccuracies in the steady state of the system and order-2n positivity violations, and we show how these arise in a specific example for which exact solutions are available. This result has a wide-ranging impact on the validity of …
A system of two coupled oscillators, each of them coupled to an independent reservoir, is analysed. The analytical solution of the non-rotating wave master equation is obtained in the high-temperature and weak coupling limits. No thermal entanglement is found in the high-temperature limit. In the weak coupling limit the system converges to an entangled non-equilibrium steady state. A critical temperature for the appearance of quantum correlations is found.
This paper provides some necessary and sufficient conditions for a generalMarkovian Gaussian master equation to have a unique pure steady state. The conditions are described by simple matrix equations; thus the so-called environment engineering problem for pure-Gaussian-state preparation can be straightforwardly dealt with in the linear algebraic framework. In fact, based on one of those conditions, for an arbitrary given pure Gaussian state,we obtain a complete parametrization of the Gaussian master equation having that state as a unique steady state; this leads to a systematic procedure for …
We investigate two interacting open quantum systems whose time evolutions are governed by Markovian master equations. We show a class of coupled systems whose interaction leaves invariant the steady state of one of the systems, i.e., only one of the reduced steady states is sensitive to the interactions. A detailed proof with the help of the Trotter product formula is presented. We apply this general statement to a few models, one of which is the optomechanical coupling model where an optical cavity is coupled to a small mechanical oscillator.
We present a numerical method for the study of correlated quantum impurity problems out of equilibrium, which is particularly suited to address steady state properties within Dynamical Mean Field Theory. The approach, recently introduced in [Arrigoni et al., Phys. Rev. Lett. 110, 086403 (2013)], is based upon a mapping of the original impurity problem onto an auxiliary open quantum system, consisting of the interacting impurity coupled to bath sites as well as to a Markovian environment. The dynamics of the auxiliary system is governed by a Lindblad master equation whose parameters are used to…
