The irreversible motion of an open quantum system can be represented through an ensemble of state vectors following a stochastic dynamics with piecewise deterministic paths. It is shown that this representation leads to a natural definition of the rate of quantum entropy production. The entropy production rate is expressed in terms of the von Neumann entropy and of the numbers of quantum jumps corresponding to the various decay channels of the open system. The proof of the positivity and of the convexity of the entropy production rate is given. Monte Carlo simulations of the stochastic dynamics of a driven qubit and of a $Λ$-configuration involving a dark state are performed in order to illustrate the general theory.
For classical nonequilibrium systems, the separation of the total entropy production into the adiabatic and nonadiabatic contributions is useful for understanding irreversibility in nonequilibrium thermodynamics. In this article, we formulate quantum analogs for driven open quantum systems describable by quantum jump trajectories by applying a quantum stochastic thermodynamics. Our main conclusions are based on a quantum formulation of the local detailed balance condition.
Dependency on the preparation of state for the Heisenberg uncertainty principle can be removed with the help of entropy uncertainty principle. The shortness of the uncertainty principle (UP) can be overcome with the help of the concept of Shannon's information entropy (SE). In this article, we have shown that UP in terms of SE holds for a position-dependent effective mass system. We have considered the Dirac system with a mass-jump at the origin. We have proved the existence of a lower bound for a UP for this position-dependent effective mass.
We consider an open quantum system for which only a subset of all possible transitions are accessible, while the remaining ones are hidden from direct observation. Using a modification of the notion of quantum jump trajectories we introduce the coarse-grained hidden entropy, which quantifies the entropy production in the hidden subsystem conditioned on our observations of the visible part. The entropy production consisting of the sum of visible and coarse-grained hidden entropy is shown to satisfy an integral fluctuations theorem. Depending on the nature of the continuously occurring measureme…
In the theory of open quantum systems interaction is a fundamental concepts in the review of the dynamics of open quantum systems. Correlation, both classical and quantum one, is generated due to interaction between system and environment. Here, we recall the quantity which well known as total entropy production. Appearance of total entropy production is due to the entanglement production between system an environment. In this work, we discuss about the role of the total entropy production for detecting non-Markovianity. By utilizing the relation between total entropy production and total corr…
Unified entropy production in finite quantum systems
Independent Researcher（独立研究者）；Department of Information and Communication Engineering, Graduate School of Information Science and Technology, The University of Tokyo（东京大学信息理工学系研究科信息通信工程学系）
Entropy production is a key quantity characterizing nonequilibrium systems. However, it can often be difficult to compute in practice, as it requires detailed information about the system and the dynamics it undergoes. This becomes even more difficult in the quantum domain, and if one is interested in generic nonequilibrium reservoirs, for which the standard thermal recipes no longer apply. In this paper, we derive an upper bound for the entropy production in terms of the entropy flux for a class of systems for which the flux is given in terms of a system's observable. Since currents are often…
Thermodynamic irreversibility is well characterized by the entropy production arising from non-equilibrium quantum processes. We show that the entropy production of a quantum system undergoing open-system dynamics can be formally split into a term that only depends on population unbalances, and one that is underpinned by quantum coherences. The population unbalances are found to contribute to both an entropy flux and an entropy production rate. The decoherence, on the other hand, contributes only to the entropy production rate. This allows us to identify a genuine quantum contribution to the e…
We examine the conjecture that entropy production in subsystems of a given system can be used as a dynamical criterion for quantum chaos in the latter. Numerical results are presented for finite dimensional spin systems as also for the quantum baker's map. Of especial importance is the power spectrum of the entropy production which gets progressively more and more broad-banded as the degree of correlation in the Hamiltonian matrix is made to decrease.
We explore the notion of generated entropy in open quantum systems. We focus on the study of the discrete-time quantum walk on the line, from the entropy production perspective. We argue that the evolution of the coin can be modeled as an open two-level system that exchanges energy with the lattice at some effective temperature that depends on the initial state. The entropy balance shows that there is a positive entropy production during the evolution, in accordance with the second law of thermodynamics.
We develop a martingale theory to describe fluctuations of entropy production for open quantum systems in nonequilbrium steady states. Using the formalism of quantum jump trajectories, we identify a decomposition of entropy production into an exponential martingale and a purely quantum term, both obeying integral fluctuation theorems. An important consequence of this approach is the derivation of a set of genuine universal results for stopping-time and infimum statistics of stochastic entropy production. Finally we complement the general formalism with numerical simulations of a qubit system.
The author calls attention to previous work with related results, which has escaped scrutiny before the publication of the article "Nonlinear quantum evolution with maximal entropy production", Phys.Rev.A63, 022105 (2001).
We consider open quantum systems weakly coupled to a heat reservoir and driven by arbitrary time-dependent parameters. We derive exact microscopic expressions for the nonequilibrium entropy production and entropy production rate, valid arbitrarily far from equilibrium. By using the two-point energy measurement statistics for system and reservoir, we further obtain a quantum generalization of the integrated fluctuation theorem put forward by Seifert [PRL 95, 040602 (2005)].
The second law of nonequilibrium thermodynamics within the open system paradigm (a small system coupled to one or multiple baths) is derived. This is done by showing positivity of entropy production for arbitrary Hamiltonian dynamics for a large class of initial states. Using the recently introduced notion of observational entropy, shortcomings of previous approaches are overcome. I apologize that the actual abstract of the manuscript is longer than the arXiv guidelines allow and therefore not displayed here.
We study the entropy production of an open quantum system surrounded by a complex environment consisting of several heat baths at different temperatures. The detailed balance is elaborated in view of the distinguishable channels provided by the couplings to different heat baths, and a refined entropy production rate is derived accordingly. It is demonstrated that the entropy production rates can characterize the quantum statistical property of the baths: the bosonic and fermionic baths display different behaviors in the high-temperature limit while they have the same asymptotic behavior at low…
This paper is a continuation of the paper gr-qc/0203045 and is devoted to the problem of the arrow of time. A deterministic past-directed dynamics is constructed, which results in the retrodictive universe. A future-directed dynamics of the latter is indeterministic and reproduces standard probabilistic quantum dynamics. The arrow of time is inherent in the retrodictive universe as well as a future-directed increase of informational entropy.
We analyze a specific role of probability density gradients in the theory of irreversible transport processes. The classic Fisher information and information entropy production concepts are found to be intrinsically entangled with the very notion of the Markovian diffusion process and that of the related (local) momentum conservation law.
The nonadiabatic entropy production is a useful tool for the thermodynamic analysis of continuously dissipating, nonequilibrium steady states. For open quantum systems, two seemingly distinct definitions for the nonadiabatic entropy production have appeared in the literature, one based on the quantum relative entropy and the other based on quantum trajectories. We show that these two formulations are equivalent. Furthermore, this equivalence leads us to a proof of the monotonicity of the quantum relative entropy under a special class of completely-positive, trace-preserving quantum maps, which…
Bridging the second law of thermodynamics and microscopic reversible dynamics has been a longstanding problem in statistical physics. We here address this problem on the basis of quantum many-body physics, and discuss how the entropy production saturates in isolated quantum systems under unitary dynamics. First, we rigorously prove the saturation of the entropy production in the long time regime, where a total system can be in a pure state. Second, we discuss the non-negativity of the entropy production at saturation, implying the second law of thermodynamics. This is based on the eigenstate t…
The physics of driven-dissipative transitions is currently a topic of great interest, particularly in quantum optical systems. These transitions occur in systems kept out of equilibrium and are therefore characterized by a finite entropy production rate. However, very little is known about how the entropy production behaves around criticality and all of it is restricted to classical systems. Using quantum phase-space methods, we put forth a framework that allows for the complete characterization of the entropy production in driven-dissipative transitions. Our framework is tailored specifically…
We explore a recently introduced quantum thermodynamic entropy $S^Q_{univ}$ of a pure state of a composite system-environment computational "universe" with a simple system $\mathcal{S}$ coupled to a constant temperature bath $\mathcal{E}$. The principal focus is "excess entropy production" in which the quantum entropy change is greater than expected from the classical entropy-free energy relationship. We analyze this in terms of quantum spreading of time dependent states, and its interplay with the idea of a microcanonical shell. The entropy takes a basis-dependent Shannon information definiti…
For quantum systems with externally time-varied Hamiltonians a definition of operators of system's energy change rate (work per unit time) and entropy production observables is suggested and discussed in the context of rigorous statistical equalities (generalized fluctuation-dissipation relations) under the Jordan-symmetrized chronological operator ordering rule.
By using entropy and entropy production, we calculate the steady flux of some phenomena. The method we use is a competition method, $S_S/τ+σ={\it maximum}$, where $S_S$ is system entropy, $σ$ is entropy production and $τ$ is microscopic interaction time. System entropy is calculated from the equilibrium state by studying the flux fluctuations. The phenomena we study include ionic conduction, atomic diffusion, thermal conduction and viscosity of a dilute gas.
Linear, irreversible thermodynamics predicts that the entropy production rate can become negative. We demonstrate this prediction for metals under AC-driving whose conductivity is well-described by the Drude-Sommerfeld model. We then show that these negative rates are fully compatible with stochastic thermodynamics, namely, that the entropy production does fulfill a fluctuation theorem. The analysis is concluded with the observation that the stochastic entropy production as defined by the surprisal or ignorance of the Shannon information does not agree with the phenomenological approach.
For open systems described by the quantum master equation (QME), we investigate the excess entropy production under quasistatic operations between nonequilibrium steady states. The average entropy production is composed of the time integral of the instantaneous steady entropy production rate and the excess entropy production. We propose to define average entropy production rate using the average energy and particle currents, which are calculated by using the full counting statistics with QME. The excess entropy production is given by a line integral in the control parameter space and its integ…
We evaluate entropy production in a photovoltaic cell that is modeled by four electronic levels resonantly coupled to thermally populated field modes at different temperatures. We use a formalism recently proposed, the so-called multiple parallel worlds, to consistently address the nonlinearity of entropy in terms of density matrix. Our result shows that entropy production is the difference between two flows: a semiclassical flow that linearly depends on occupational probabilities, and another flow that depends nonlinearly on quantum coherence and has no semiclassical analog. We show that entr…
An operator equality on the entropy production for general quantum Markovian master equations is derived without resorting quantum stochastic trajectory and priori quantum definition of entropy production. We find that, the equality can be still interpreted as a consequence of time-reversal asymmetry of the nonequilibrium processes of the systems. In contrast with the classical case, however, the first order expansion of the equality does not directly related to the mean entropy production, which arises from noncommute property of operators in quantum physics.
We examine the dynamics of entanglement entropy of all parts in an open system consisting of a two-level dimer interacting with an environment of oscillators. The dimer-environment interaction is almost energy conserving. We find the precise link between decoherence and production of entanglement entropy. We show that not all environment oscillators carry significant entanglement entropy and we identify the oscillator frequency regions which contribute to the production of entanglement entropy. Our results hold for arbitrary strengths of the dimer-environment interaction, and they are mathemat…
