We study the entropy production of an open quantum system surrounded by a complex environment consisting of several heat baths at different temperatures. The detailed balance is elaborated in view of the distinguishable channels provided by the couplings to different heat baths, and a refined entropy production rate is derived accordingly. It is demonstrated that the entropy production rates can characterize the quantum statistical property of the baths: the bosonic and fermionic baths display different behaviors in the high-temperature limit while they have the same asymptotic behavior at low temperature.
When an open system is contacted with several thermal baths, the entropy produced by the irreversible processes ($dS_{\mathrm{i}}=dS-\sum_α\textđQ_α/T_α$) keeps increasing, and this entropy production rate is always non-negative. But when the system is contacted with some non-thermal baths containing quantum coherence or squeezing, this entropy production formula does not apply. In this paper, we study the increasing rate of the mutual information between the open system and its environment. When the baths are canonical thermal ones, we prove that this mutual information production rate could …
The change of the von Neumann entropy of a set of harmonic oscillators initially in thermal equilibrium and interacting linearly with an externally driven quantum system is computed by adapting the Feynman-Vernon influence functional formalism. This quantum entropy production has the form of the expectation value of three functionals of the forward and backward paths describing the system history in the Feynman-Vernon theory. In the classical limit of Kramers-Langevin dynamics (Caldeira-Leggett model) these functionals combine to three terms, where the first is the entropy production functiona…
We consider a situation where an $N$-level system (NLS) is coupled to a heat bath without being necessarily thermalized. For this situation we derive general Jarzinski-type equations and conclude that heat and entropy is flowing from the hot bath to the cold NLS and, vice versa, from the hot NLS to the cold bath. The Clausius relation between increase of entropy and transfer of heat divided by a suitable temperature assumes the form of two inequalities which have already been considered in the literature. Our approach is illustrated by an analytical example.
We consider a situation where an $N$-level system (NLS) is coupled successively to two heat baths with different temperatures without being necessarily thermalized and approaches a steady state. For this situation we apply a general Jarzinski-type equation and conclude that heat and entropy is flowing from the hot bath to the cold one. The Clausius relation between increase of entropy and transfer of heat divided by a suitable temperature assumes the form of two inequalities. Our approach is illustrated by an analytical example. For the linear regime, i.~e., for small temperature differences b…
It is known that the equilibrium properties of open classical systems that are strongly coupled to a heat bath are described by a set of thermodynamic potentials related to the system's Hamiltonian of mean force. By adapting this framework to a more general class of non-equilibrium states, we show that the equilibrium properties of the bath can be well-defined, even when the system is arbitrarily far from equilibrium and correlated with the bath. These states, which retain a notion of temperature, take the form of conditional equilibrium distributions. For out-of-equilibrium processes we show …
Considering von Neumann expression for reduced density matrix as thermodynamic entropy of a system strongly coupled to baths, we use nonequilibrium Green's function (NEGF) techniques to derive bath and energy resolved expressions for entropy, entropy production, and information flows. The consideration is consistent with dynamic (quantum transport) description and expressions reduce to expected forms in limiting cases of weak coupling or steady-state. Formulation of the flows in terms of only system degrees freedom is convenient for simulation of thermodynamic characteristics of open nonequili…
A colloidal particle immersed in a bath of bacteria is a typical example of a passive particle in an active bath. To model this, we take an overdamped harmonically trapped particle subjected to a thermal and a non-equilibrium noise arising from the active bath. The harmonic well can be attributed to a laser trap or to the small amplitude motion of the sedimented colloid at the bottom of the capillary. In the long time, the system reaches a non-equilibrium steady state that can be described by an effective temperature. By adopting this notion of effective temperature, we investigate whether flu…
Entropy production of an active particle in an external potential is identified through a thermodynamically consistent minimal lattice model that includes the chemical reaction providing the propulsion and ordinary translational noise. In the continuum limit, a unique expression follows, comprising a direct contribution from the active process and an indirect contribution from ordinary diffusive motion. From the corresponding Langevin equation, this physical entropy production cannot be inferred through the conventional, yet here ambiguous, comparison of forward and time-reversed trajectories.…
We determine the maximal work extractable via a cyclic Hamiltonian process from a positive-temperature ($T>0$) microcanonical state of a $N\gg 1$ spin bath. The work is much smaller than the total energy of the bath, but can be still much larger than the energy of a single bath spin, e.g. it can scale as ${\cal O}(\sqrt{N\ln N})$. Qualitatively same results are obtained for those cases, where the canonical state is unstable (e.g., due to a negative specific heat) and the microcanonical state is the only description of equilibrium. For a system coupled to a microcanonical bath the concept of fr…
We present a scheme to evaluate thermodynamic variables for a system coupled to a heat bath under a time-dependent external force using the quasi-static Helmholtz energy from the numerically "exact" hierarchical equations of motion (HEOM). We computed the entropy produced by a spin system strongly coupled to a non-Markovian heat bath for various temperatures. We showed that when changes to the external perturbation occurred sufficiently slowly, the system always reached thermal equilibrium. Thus, we calculated the Boltzmann entropy and the von Neumann entropy for an isothermal process, as well…
This is an analysis of the additivity of the entropy of thermodynamical systems with finite heat baths. It is presented an expression for the physical entropy of weakly interacting ergodic systems, and it is shown that it is valid for both the microcanonical (constant energy), the Boltzmann-Gibbs canonical (infinite heat bath) and the Tsallis (finite heat bath) ensembles. This physical entropy may be written as a variant of Tsallis entropy. It becomes an additive function after a suitable choice of additive constants, in a procedure reminiscent to the solution presented by Gibbs to the paradox…
The nonequilibrium thermodynamics feature of a Brownian motor is investigated by obtaining exact time-dependent solutions. This in turn enables us to investigate not only the long time property (steady-state) but also the short time the behavior of the system. The general expressions for the free energy, entropy production ${\dot e}_{p}(t)$ as well as entropy extraction ${\dot h}_{d}(t)$ rates are derived for a system that is genuinely driven out of equilibrium by time-independent force as well as by spatially varying thermal background. We show that for a system that operates between hot and …
We study the relationship between (non-)Markovian evolutions, established correlations, and the entropy production rate. We consider a system qubit in contact with a thermal bath and in addition the system is strongly coupled to an ancillary qubit. We examine the steady state properties finding that the coupling leads to effective temperatures emerging in the composite system, and show that this is related to the creation of correlations between the qubits. By establishing the conditions under which the system reaches thermal equilibrium with the bath despite undergoing a non-Markovian evoluti…
The canonical ensemble describes an open system in equilibrium with a heat bath of fixed temperature. The probability distribution of such a system, the Boltzmann distribution, is derived from the uniform probability distribution of the closed universe consisting of the open system and the heat bath, by taking the limit where the heat bath is much larger than the system of interest. Alternatively, the Boltzmann distribution can be derived from the Maximum Entropy Principle, where the Gibbs-Shannon entropy is maximized under the constraint that the mean energy of the open system is fixed. To ma…
In an Information machine system's dynamics gets affected by the attached information reservoir. Second law of thermodynamics can be apparently violated for this case. In this article we have derived second law for an information machine, when the system is connected to multiple heat baths along with a work source and a single information reservoir. Here a sequence of bits written on a tape is considered as an information reservoir. We find that the bath entropy production during a time interval is restricted by the change of Shannon entropy of the composite system (system + information reserv…
Maxwell's demon is the quintessential example of information control, which is necessary for designing quantum devices. In thermodynamics, the demon is an intelligent being who utilizes the entropic nature of information to sort excitations between reservoirs, thus lowering the total entropy. So far, implementations of Maxwell's demon have largely been limited to Markovian baths. In our work, we study the degree to which such a demon may be assisted by non-Markovian effects using a superconducting circuit platform. The setup is two baths connected by a demon-controlled qutrit interface, allowi…
We present a general quantum fluctuation theorem for the entropy production of an open quantum system coupled to multiple environments, not necessarily at equilibrium. Such a general theorem, when restricted to the weak-coupling and Markovian regime, holds for both local and global master equations, corroborating the thermodynamic consistency of local quantum master equations. The theorem is genuinely quantum, as it can be expressed in terms of conservation of a Hermitian operator, describing the dynamics of the system state operator and of the entropy change in the baths. The integral fluctua…
A model computational quantum thermodynamic network is constructed with two variable temperature baths coupled by a linker system, with an asymmetry in the coupling of the linker to the two baths. It is found in computational simulations that the baths come to "thermal equilibrium" at different bath energies and temperatures. In a sense, heat is observed to flow from cold to hot. A description is given in which a recently defined quantum entropy $S^Q_{univ}$ for a pure state "universe" continues to increase after passing through the classical equilibrium point of equal temperatures, reaching a…
Deriving the laws of thermodynamics from a microscopic picture is a central quest of statistical mechanics. This tutorial focuses on the derivation of the first and second law for closed and open quantum systems far from equilibrium, where such foundational questions also become practically relevant for emergent nanotechnologies. The derivation is based on a microscopic definition of five essential quantities: internal energy, thermodynamic entropy, work, heat and temperature. These definitions are shown to satisfy the phenomenological laws of nonequilibrium thermodynamics for a large class of…
We calculate exactly the time-dependent reduced density matrix for the central spin in the central-spin model with homogeneous Heisenberg couplings. Therefrom, the dynamics and the entanglement entropy of the central spin are obtained. A rich variety of behaviors is found, depending on the initial state of the bath spins. For an initially unpolarized unentangled bath, the polarization of the central spin decays to zero in the thermodynamic limit, while its entanglement entropy becomes maximal. On the other hand, if the unpolarized environment is initially in an eigenstate of the total bath spi…
The quantum thermodynamic behaviour of a charged oscillator in the presence of a magnetic field and coupled to a heat bath through different coupling schemes is obtained analytically. It is shown that finite dissipation substitutes the zero-coupling result of exponential decay of entropy by a power law behaviour at low temperature. For the coordinate-coordinates coupling scheme the low temperature explicit results for the case of Ohmic, exponentially correlated and more generalized heat bath models are derived. In all the above mentioned cases free energy and entropy vanish linearly with tempe…
When a quantum system is coupled to several heat baths at different temperatures, it eventually reaches a non-equilibrium steady state featuring stationary internal heat currents. These currents imply that entropy is continually being produced in the system at a constant rate. In this paper we apply phase-space techniques to the calculation of the Wigner entropy production on general linear networks of harmonic nodes. Working in the ubiquitous limit of weak internal coupling and weak dissipation, we obtain simple closed-form expressions for the entropic contribution of each individual quasi-pr…
Quantum measurement of a system can change its mean energy, as well as entropy. A selective measurement (classical or quantum) can be used as a "Maxwell's demon" to power a single-temperature heat engine, by decreasing the entropy. Quantum mechanically, so can a non-selective measurement, despite increasing the entropy of a thermal state. The maximal amount of work extractable following the measurement is given by the change in free energy: $W_{max}^{(non-)sel.}=ΔE_{meas}-T_{Bath}ΔS_{meas}^{(non-)sel.}$. This follows from the "generalized 2nd law for nonequilibrium initial state" [Hasegawa et.…
We investigate a total thermodynamic entropy production rate of an isolated quantum system. In particular, we consider a quantum model of coupled harmonic oscillators in a star configuration, where a central harmonic oscillator (system) is coupled to a finite number of surrounding harmonic oscillators (bath). In this model, when the initial state of the total system is given by the tensor product of the Gibbs states of the system and the bath, every harmonic oscillator is always in a Gibbs state with a time-dependent temperature. This enables us to define time-dependent thermodynamic entropy f…
A Hamiltonian-based model of many harmonically interacting massive particles that are subject to linear friction and coupled to heat baths at different temperatures is used to study the dynamic approach to equilibrium and non-equilibrium stationary states. Based on the exactly calculated dynamic approach to the stationary distribution, the functional that governs this approach, which is called the free entropy, is constructed. For the stationary distribution the free entropy becomes maximal and its time derivative is minimal and vanishes. Thus, the free entropy characterizes equilibrium as wel…
We investigate the fundamental relation between entropy production rate and the speed of energy exchange between a system and baths in classical Markov processes. We establish the fact that quick energy exchange inevitably induces large entropy production in a quantitative form. More specifically, we prove two inequalities on instantaneous quantities: One is applicable to general Markov processes induced by heat baths, and the other is applicable only to systems with the local detailed-balance condition but is stronger than the former one. We demonstrate the physical meaning of our result by a…
We consider a system of two Brownian particles (say A and B), coupled to each other via harmonic potential of stiffness constant $k$. Particle-A is connected to two heat baths of constant temperatures $T_1$ and $T_2$, and particle-B is connected to a single heat bath of a constant temperature $T_3$. In the steady state, the total entropy production for both particles obeys the fluctuation theorem. We compute the total entropy production due to one of the particles called as partial or apparent entropy production, in the steady state for a time segment $τ$. When both particles are weakly intera…
Large entropy fluctuations in a nonequilibrium steady state of classical mechanics were studied in extensive numerical experiments on a simple 2-freedom model with the so-called Gauss time-reversible thermostat. The local fluctuations (on a set of fixed trajectory segments) from the average heat entropy absorbed in thermostat were found to be non-Gaussian. Approximately, the fluctuations can be discribed by a two-Gaussian distribution with a crossover independent of the segment length and the number of trajectories ('particles'). The distribution itself does depend on both, approaching the sin…
We study entropy production in nanoscale devices, which are coupled to finite heat baths. This situation is of growing experimental relevance, but most theoretical approaches rely on a formulation of the second law valid only for infinite baths. We fix this problem by pointing out that already Clausius' paper from 1865 contains an adequate formulation of the second law for finite heat baths, which can be also rigorously derived from a microscopic quantum description. This Clausius' inequality shows that nonequilibrium processes are less irreversible than previously thought. We use it to correc…
The mixing time of Markovian dissipative evolutions of open quantum many-body systems can be bounded using optimal constants of certain quantum functional inequalities, such as the modified logarithmic Sobolev constant. For classical spin systems, the positivity of such constants follows from a mixing condition for the Gibbs measure, via quasi-factorization results for the entropy. Inspired by the classical case, we present a strategy to derive the positivity of the modified logarithmic Sobolev constant associated to the dynamics of certain quantum systems from some clustering conditions on th…
We investigate how to coherently define entropy production for a process of transient relaxation in the Quantum Brownian Motion model for harmonic potential. We compare a form, called "Poised" (P), which after non-Markovian transients corresponds to a definition of heat as the change in the system Hamiltonian of mean force, with a recent proposal by Esposito (ELB) based on a definition of heat as the energy change in the bath. Both expressions yield a positive-defined entropy production and coincide for vanishing coupling strength, but their difference is proved to be always positive (after no…
The second law of thermodynamics can be described as the non-decreasing of the entropy in the irreversible thermodynamic process. Such phenomenon can be quantitatively evaluated with the irreversible entropy generation (IEG), which was recently found to follow a $1/τ$ scaling for the system under a long contact time $τ$ with the thermal bath. This scaling, predicted in many finite-time thermodynamic models, is of great potential in the optimization of heat engines, yet remains lack of direct experimental validation. In this letter, we design an experimental apparatus to test such scaling by co…
Here we present a model for a small system combined with an explicit entropy bath that is comparably small. The dynamics of the model is defined by a simple matrix, M. Each row of M corresponds to a macrostate of the system, e.g. net alignment, while the elements in the row represent microstates. The constant number of elements in each row ensures constant entropy, which allows reversible fluctuations, similar to information theory where a constant number of bits allows reversible computations. Many elements in M come from the microstates of the system, but many others come from the bath. Bypa…
Recently Allahverdyan and Nieuwenhuizen (cond-mat/0006404) argued that the second law of thermodynamics may be violated in a quantum system as a "consequence of quantum coherence in the presence of the slightly off-equilibrium nature of the bath." By using a standard result about relative entropy, we prove rigorously that the second law is never violated (and, in particular, a perpetual motion of the second kind can never be realized) in quantum systems no matter how strong ``quantum coherence'' is or no matter how far one goes from equilibrium.
Recently, the fundamental laws of thermodynamics have been reconsidered for small systems. The discovery of the fluctuation relations has spurred theoretical and experimental studies on thermodynamics of systems with few degrees of freedom. The concept of entropy production has been extended to the microscopic level by considering stochastic trajectories of a system coupled to a heat bath. However, the experimental observation of the microscopic entropy production remains elusive. We measure distributions of the microscopic entropy production in a single-electron box consisting of two islands …
We obtain an exact formula for the equilibrium free energy of a charged quantum particle moving in a harmonic potential in the presence of a uniform external magnetic field and linearly coupled to a heat bath of independent quantum harmonic oscillators through the momentum variables. We show that the free energy has a different expression than that for the coordinate-coordinate coupling between the particle and the heat-bath oscillators. For an illustrative heat-bath spectrum, we evaluate the free energy in the low-temperature limit, thereby showing that the entropy of the charged particle van…
The spin-boson model, often used in NMR and ESR physics, quantum optics and spintronics, is considered in a solvable limit to model a spin one-half particle interacting with a bosonic thermal bath. By applying external pulses to a non-equilibrium initial state of the spin, work can be extracted from the thermalized bath. It occurs on the timescale $\T_2$ inherent to transversal (`quantum') fluctuations. The work (partly) arises from heat given off by the surrounding bath, while the spin entropy remains constant during a pulse. This presents a violation of the Clausius inequality and the Thomso…
In statistical physics, entropy is generally logarithm of probability. Therefore, if dynamics is decomposed by log, entropy production should be decomposed properly. In the present work, log-decomposition of dynamics is introduced. By which time evolution operator is logarithmically decomposed into a symmetric operator and an asymmetric factor. Path probability and path entropy production are also systematically and intuitively decomposed into symmetric and asymmetric parts. From symmetric operator, non-adiabatic entropy production is derived, whereas adiabatic entropy production is from asymm…
By using entropy and entropy production, we calculate the steady flux of some phenomena. The method we use is a competition method, $S_S/τ+σ={\it maximum}$, where $S_S$ is system entropy, $σ$ is entropy production and $τ$ is microscopic interaction time. System entropy is calculated from the equilibrium state by studying the flux fluctuations. The phenomena we study include ionic conduction, atomic diffusion, thermal conduction and viscosity of a dilute gas.
We present a maximum entropy approach to analyze the internal dynamics of a small system in contact with a large bath e.g. a solute-solvent system. For the small solute, the fluctuations around the mean values of observables are not negligible and the probability distribution P(r) of the state space depends on the intricate details of the interaction of the solute with the solvent. Here, we employ a superstatistical approach: P(r) is expressed as a marginal distribution summed over the variation in β, the inverse temperature of the solute. The joint distribution P(β,r) is estimated by maximizi…
We investigate the stochastic behavior of a two-temperature Langevin system with non-Markovian thermal reservoirs. The model describes an overdamped Brownian particle in a quadratic potential and coupled to heat baths at different temperatures. The reservoirs are characterized by Gaussian white and colored noises and a dissipation memory kernel. The stationary states present non-trivial average rotational motion influenced by stochastic torques due to harmonic, friction and fluctuating thermal forces. However, the Markovian limit leads to a vanishing average torque produced by fluctuating ther…
Based on the Fokker-Planck and the entropy balance equations we have studied the relaxation of a dissipative dynamical system driven by external Ornstein-Uhlenbeck noise processes in absence and presence of nonequilibrium constraint in terms of the thermodynamically inspired quantities like entropy flux and entropy production. The interplay of nonequilibrium constraint, dissipation and noise reveals some interesting extremal nature in the time dependence of entropy flux and entropy production.
*First-principles derivation of the entropy production in erectric static conduction. *The second-order (symmetric) density matrix contributes to the entropy production. *New schemes of steady states formulated using a relaxation-type von Neumann equation. *Stationary temperature is introduced to characterize steady states. *The mechanism of the entropy production in steady states is also clarified.
We propose an alternative method to compute the entropy production of a classical underdamped nonequilibrium system in a continuous phase space. This approach has the advantage that it is not necessary to distinguish between even and odd-parity variables. We show that the method leads to the same local entropy production as in previous studies while the differential entropy production along a stochastic trajectory turns out to be different. This demonstrates that the differential entropy production in continuous phase space systems is not uniquely defined.
The second law of thermodynamics, which asserts the non-negativity of the average total entropy production of a combined system and its environment, is a direct consequence of applying Jensen's inequality to a fluctuation relation. It is also possible, through this inequality, to determine an upper bound of the average total entropy production based on the entropies along the most extreme stochastic trajectories. In this work, we construct an upper bound inequality of the average of a convex function over a domain whose average is known. When applied to the various fluctuation relations, the u…
