We extend the results on decoherence in the thermodynamic limit [M. Frasca, Phys. Lett. A {\bf 283}, 271 (2001)] to general Hamiltonians. It is shown that N independent particles, initially properly prepared, have a set of observables behaving classically in the thermodynamic limit. This particular set of observables is then coupled to a quantum system that in this way decoheres so to have the density matrix in a mixed form. This gives a proof of the generality of this effect.
We take up the question why the initial entropy in the universe was small, in the context of evolution of the entropy of a classical system. We note that coarse-graining is a an important aspect of entropy evaluation which can reverse the direction of the increase in entropy, i.e., the direction of thermodynamic arrow of time. Then we investigate the role of decoherence in the selection of coarse-graining and explain how to compute entropy for a decohered classical system. Finally, we argue that the requirement of low initial entropy imposes constraints on the decoherence process.
We prove a generalization of the classic Groenewold-Lindblad entropy inequality, combining decoherence and the quantum Bayes theorem into a simple unified picture where decoherence increases entropy while observation decreases it. This provides a rigorous quantum-mechanical version of the second law of thermodynamics, governing how the entropy of a system (the entropy of its density matrix, partial-traced over the environment and conditioned on what is known) evolves under general decoherence and observation. The powerful tool of spectral majorization enables both simple alternative proofs of …
This work investigates the influence of directional properties of decoherence on kinetics rate equations. The physical reality is understood as a chain of unitary and decoherence events. The former are quantum-deterministic, while the latter introduce uncertainty and increase entropy. For interactions of matter and antimatter, two approaches are considered: symmetric decoherence, which corresponds to conventional symmetric (CP-invariant) thermodynamics, and antisymmetric decoherence, which corresponds to antisymmetric (CPT-invariant) thermodynamics. Radiation, in its interactions with matter a…
It is shown how classical states, meant as states representing a classical object, can be produced in the thermodynamic limit, retaining the unitary evolution of quantum mechanics. Besides, using a simple model of a single spin interacting with a spin-bath, it is seen how decoherence, with the off-diagonal terms in the density matrix going to zero, can be obtained when the number of the spins in the bath is taken to go formally to infinity. In this case, indeed, the system appears to flop at a frequency being formally infinity that, from a physical standpoint, can be proved equivalent to a tim…
Local and global approaches to the thermodynamics of pure decoherence processes in open quantum systems
University of Freiburg（弗赖堡大学）；Università degli Studi di Milano（米兰大学）；INFN, Sezione di Milano（意大利国家核物理研究所米兰分部）；EUCOR Centre for Quantum Science and Quantum Computing, University of Freiburg（弗赖堡大学EUCOR量子科学与量子计算中心）
The current stage of quantum computing technology, called noisy intermediate-scale quantum (NISQ) technology, is characterized by large errors that prohibit it from being used for real applications. In these devices, decoherence, one of the main sources of error, is generally modeled by Markovian master equations such as the Lindblad master equation. In this work, the decoherence phenomena are addressed from the perspective of the steepest-entropy-ascent quantum thermodynamics (SEAQT) framework in which the noise is in part seen as internal to the system. The framework is as well used to descr…
We investigate the thermodynamics of a quench realized by turning on an interaction generating pure decoherence. We characterize the work probability distribution function, also with a fluctuation relation, a lower bound of the work and by considering some physical examples.
We prove a quantum version of the second law of thermodynamics: the (quantum) Boltzmann entropy increases if the initial (zero time) density matrix decoheres, a condition generally satisfied in Nature. It is illustrated by a model of wave-packet reduction, the Coleman-Hepp model, along the framework introduced by Sewell in his approach to the quantum measurement problem. Further models illustrate the monotonic-versus-non-monotonic behavior of the quantum Boltzmann entropy in time. As a last closely related topic, decoherence, which was shown by Narnhofer and Thirring to enforce macroscopic pur…
We discuss a few mathematical aspects of random dynamical decoupling, a key tool procedure in quantum information theory. In particular, we place it in the context of discrete stochastic processes, limit theorems and CPT semigroups on matrix algebras. We obtain precise analytical expressions for expectation and variance of the density matrix and fidelity over time in the continuum-time limit depending on the system Lindbladian, which then lead to rough short-time estimates depending only on certain coupling strengths. We prove that dynamical decoupling does not work in the case of intrinsic (i…
Time evolution operator in quantum mechanics can be changed into a statistical operator by a Wick rotation. This strict relation between statistical mechanics and quantum evolution can reveal deep results when the thermodynamic limit is considered. These results translate in a set of theorems proving that these effects can be effectively at work producing an emerging classical world without recurring to any external entity that in some cases cannot be properly defined. In a many-body system has been recently shown that Gaussian decay of the coherence is the rule with a duration of recurrence m…
When a quantum system is placed in thermal environments, we often assume that the system relaxes to the Gibbs state in which decoherence takes place in the system energy eigenbasis. However, when the coupling between the system and the environments is strong, the stationary state is not necessarily the Gibbs state due to environment-induced decoherence which can be interpreted as continuous measurement by the environments. Based on the einselection proposed by Zurek, we postulate that the Gibbs state is projected onto the pointer basis due to the continuous measurement. We justify the proposit…
Statistical mechanics explains thermodynamics in terms of (quantum) mechanics by equating the entropy of a microstate of a closed system with the logarithm of the number of microstates in the macrostate to which it belongs, but the question `what is a macrostate?' has never been answered except in a vague, subjective, way. However Hawking's discovery of black hole evaporation led to a formula for black hole entropy with no subjective element. In this letter, we argue from this result, together with the assumption that `black hole thermodynamics is just ordinary thermodynamics applied to black …
The mechanism of the transition of a dynamical system from quantum to classical mechanics is one of the remaining challenges of quantum theory. Currently, it is considered to occur via decoherence caused by entanglement and/or stochastic interaction with a quantum environment. Here we prove that, in the absence of de-phasing environmental interaction, the asymptotic spatial wave function of any quantum system, propagating over distances and times large on an atomic scale but still microscopic, and subject to arbitrary deterministic fields, becomes proportional to the initial momentum wave func…
Exact solutions of the Caldeira-Leggett Master equation for the reduced density matrix for a free particle and for a harmonic oscillator system coupled to a heat bath of oscillators are obtained for arbitrary initial conditions. The solutions prove that the Fourier transform of the density matrix at time t with respect to (x + x')/2, where x and x' are the initial and final coordinates, factorizes exactly into a part depending linearly on the initial density matrix and a part independent of it. The theorem yields the exact initial state dependence of the density operator at time t and its even…
We address the issue of the quantum-classical correspondence in chaotic systems using, as recently done by Zurek [e-print quant-ph/9802054], the solar system as a whole as a case study: this author shows that the classicality of the planetary motion is ensured by the environment-induced decoherence. We show that equivalent results are provided by the theories of spontaneous fluctuations and that these latter theories, in some cases, result in a still faster process of decoherence. We show that, as an additional benefit, the assumption of spontaneous fluctuation makes it possible to genuinely d…
Quantum decoherence is seen as an undesired source of irreversibility that destroys quantum resources. Quantum coherences seem to be a property that vanishes at thermodynamic equilibrium. Away from equilibrium, quantum coherences challenge the classical notions of a thermodynamic bath in a Carnot engines, affect the efficiency of quantum transport, lead to violations of Fourier's law, and can be used to dynamically control the temperature of a state. However, the role of quantum coherence in thermodynamics is not fully understood. Here we show that the relative entropy of a state with quantum …
Intrinsic decoherence in the thermodynamic limit is shown for a large class of many-body quantum systems in the unitary evolution in NMR and cavity QED. The effect largely depends on the inability of the system to recover the phases. Gaussian decaying in time of the fidelity is proved for spin systems and radiation-matter interaction.
According to the eigenstate thermalization ansatz, matrices representing generic few body observables take on a specific form when displayed in the eigenbasis of a chaotic Hamiltonian. We examine the effect of environmental induced decoherence on the dynamics of observables that conform with said eigenstate thermalization ansatz. The obtained result refers to a description of the dynamics in terms of an integro-differential equation of motion of the Nakajima-Zwanzig form. We find that environmental decoherence is equivalent to an exponential damping of the respective memory kernel. This statem…
The adiabatic theorem and "shortcuts to adiabaticity" for the adiabatic dynamics of time-dependent decoherence-free subspaces are explored in this paper. Starting from the definition of the dynamical stable decoherence-free subspaces, we show that, under a compact adiabatic condition, the quantum state follows time-dependent decoherence-free subspaces (the adiabatic decoherence free subspaces) into the target subspace with extremely high purity, even though the dynamics of the quantum system may be non-adiabatic. The adiabatic condition mentioned in the adiabatic theorem is very similar with t…
Conditional expectation values of quantum mechanical observables reflect unique non-classical correlations, and are generally sensitive to decoherence. We consider the circumstances under which such sensitivity to decoherence is removed, namely, when the measurement process is subjected to conservation laws. Specifically, we address systems with additive conserved quantities and identify sufficient conditions for the system state such that its coherence plays no role in the conditional expectation values of observables that commute with the conserved quantity. We discuss our findings for a spe…
It is shown that a macroscopic superposition state of radiation, strongly interacting with an ensemble of two-level atoms, is removed generating a coherent state describing a classical radiation field, when the thermodynamic limit is taken on the unitary evolution obtained by the Schroedinger equation. Decoherence appears as a dynamical effect in agreement with a recent proposal [M. Frasca, Phys. Lett. A 283, 271 (2001)]. To prove that this effect is quite general, we show that this same behavior appears when a superposition of two Fock number states is also considered. Higher order correction…
In quantum computation theory, quantum random walks have been utilized by many quantum search algorithms which provide improved performance over their classical counterparts. However, due to the importance of the quantum decoherence phenomenon, decoherent quantum walks and their applications have been studied on a wide variety of structures. Recently, a unified time-inhomogeneous coin-turning random walk with rescaled limiting distributions, Bernoulli, uniform, arcsine and semi-circle laws as parameter varies have been obtained. In this paper we study the quantum analogue of these models. We o…
We study the performance of dynamical decoupling in suppressing decoherence caused by soft-cutoff Gaussian noise, using short-time expansion of the noise correlations and numerical optimization. For the noise with soft cutoff at high frequencies, there exists no dynamical decoupling scheme to eliminate the decoherence to arbitrary orders of the short time, regardless of the timing or pulse shaping of the control under the population conserving condition. We formulate the equations for optimizing pulse sequences that minimizes decoherence up to the highest possible order of the short time for t…
In this paper we consider the model with decoherence operators introduced by [Brun,T.A, et.al, Phys.Rev.A 67 (2003) 032304] which has recently been considered in the two-dimensional setting by [Ampadu,C., Brun-Type Formalism for Decoherence in Two Dimensional Quantum Walks, Communication in Theoretical Physics To Appear, arXiv:1104.2061 (2011)] to obtain the limit of the decoherent quantum walk.
The basic ingredients of the `consistent histories' approach to quantum theory are a space $\UP$ of `history propositions' and a space $\D$ of `decoherence functionals'. In this article we consider such history quantum theories in the case where $\UP$ is given by the set of projectors $¶(\V)$ on some Hilbert space $\V$. We define the notion of a `physical symmetry of a history quantum theory' (PSHQT) and specify such objects exhaustively with the aid of an analogue of Wigner's theorem. In order to prove this theorem we investigate the structure of $\D$, define the notion of an `elementary deco…
Asher Peres' proof that a violation of No Cloning Theorem would imply a violation of the Second Law of Thermodynamics is shown not to take into account the algorithmic-information's contribution to the Thermodynamical Entropy of the semi-permeable membranes of Peres' engine.
It is shown that a generalization of the fluctuation-dissipation theorem places an upper bound on the figure of merit for any quantum gate designed to entangle spatially-separated qubits. The bound depends solely on the spectral properties of the environment. The bound applies even to systems performing a quantum computation within a decoherence-free subspace, but might be optimized by the use of non-equilibrium squeezed states of the environment, or by using an environment system constructed to have response confined to certain frequencies.
Fluctuation theorems are fundamental results in non-equilibrium thermodynamics. Considering the fluctuation theorem with respect to the entropy production and an observable, we derive a new thermodynamic uncertainty relation which also applies to non-cyclic and time-reversal non-symmetric protocols. Furthermore, we investigate the relation between the thermodynamic uncertainty relation and the correlation between the entropy and the observable.
Recent advances in experimental techniques allow one to measure and control systems at the level of single molecules and atoms. Here gaining information about fluctuating thermodynamic quantities is crucial for understanding nonequilibrium thermodynamic behavior of small systems. To achieve this aim, stochastic thermodynamics offers a theoretical framework, and nonequilibrium equalities such as Jarzynski equality and fluctuation theorems provide key information about the fluctuating thermodynamic quantities. We review the recent progress in quantum fluctuation theorems, including the studies o…
Thermodynamic uncertainty relations (TURs) place strict bounds on the fluctuations of thermodynamic quantities in terms of the associated entropy production. In this work we identify the tightest (and saturable) matrix-valued TUR that can be derived from the exchange fluctuation theorems describing the statistics of heat and particle flow between multiple systems. Our result holds for both quantum and classical systems, undergoing general non-Markovian and non-stationary processes. Moreover, it provides bounds not only for the variances, but also for the correlations between thermodynamic quan…
In this essay a quantum-dualistic, perspectival and synchronistic interpretation of quantum mechanics is further developed in which the classical world-from-decoherence which is perceived (decoherence) and the perceived world-in-consciousness which is classical (collapse) are not necessarily identified. Thus, Quantum Reality or "{\it unus mundus}" is seen as both i) a physical non-perspectival causal Reality where the quantum-to-classical transition is operated by decoherence, and as ii) a quantum linear superposition of all classical psycho-physical perspectival Realities which are governed b…
In this work we examine the effect of phase-space noncommutativity on some typically quantum properties such as quantum beating, quantum information, and decoherence. To exemplify these issues we consider the two-dimensional noncommutative quantum harmonic oscillator whose components behavior we monitor in time. This procedure allows us to determine how the noncommutative parameters are related to the missing information quantified by the linear quantum entropy and by the mutual information between the relevant Hilbert space coordinates. Particular questions concerning the thermodynamic limit …
The low-temperature regime of charge-qubit decoherence due to its Coulomb interaction with electrons tunneling through Luttinger liquid quantum-point contact (QPC) is investigated. The study is focused on quantum detector properties of Luttinger liquid QPC. It is shown, that in low-temperature limit the respective perturbative decoherence- and acquisition of information timescales both tend to diverge, thus, shadowing a true picture of low-temperature quantum detection for such quantum systems. Here I prove two general mathematical statements (S-theorem and S-lemma) about exact re-exponentiati…
We present a general method to undertake a thorough analysis of the thermodynamics of the quantum jump trajectories followed by an arbitrary quantum harmonic network undergoing linear and bilinear dynamics. The approach is based on the phase-space representation of the state of a harmonic network. The large deviation function associated with this system encodes the full counting statistics of exchange and also allows one to deduce for fluctuation theorems obeyed by the dynamics. We illustrate the method showing the validity of a local fluctuation theorem about the exchange of excitations betwe…
This work brings together Keldysh non-equilibrium quantum theory and thermodynamics, by showing that a real-time diagrammatic technique is an equivalent of stochastic thermodynamics for non-Markovian quantum machines (heat engines, refrigerators, etc). Symmetries are found between quantum trajectories and their time-reverses on the Keldysh contour, for any interacting quantum system coupled to ideal reservoirs of electrons, phonons or photons. These lead to quantum fluctuation theorems the same as the well-known classical ones (Jarzynski and Crooks equalities, integral fluctuation theorem, etc…
We review our approach to the second law of thermodynamics, viewed as a theorem asserting the growth of the mean (Gibbs-von Neumann) entropy of quantum spin systems undergoing automorphic (unitary) adiabatic transformations. Non-automorphic interactions with the environment, although known to produce on the average a strict reduction of the entropy of systems with finite number of degrees of freedom, are proved to conserve the mean entropy on the average. The results depend crucially on two properties of the mean entropy, proved by Robinson and Ruelle for classical systems, and Lanford and Rob…
One general consequence of the Nernst theorem is derived, i.e., the various heat capacities of a thermodynamic system under different constraints approach zero as the temperature approaches absolute zero. The temperature dependence of the heat capacity of any thermodynamic system at ultra-low temperatures is revealed through this consequence. Moreover, the general form and the simplest expression of the heat capacities of thermodynamic systems at ultra-low temperatures are deduced. Some significant discussion and results are given. One new research method is provided by using this consequence.…
Non-equilibrium quantum thermodynamics is essential to describe new devices that operate far from the regime where the usual thermodynamical laws are obeyed. When quantum fluctuations dominate, defining and measuring work and heat, two central concepts in classical thermodynamics, is non-trivial. For driven, but otherwise isolated, quantum systems, work is a random variable associated with the change in the internal energy, as the first law of thermodynamics indicates. In this paper we present the design and the experimental implementation of a quantum work meter (QWM) operating on an ensemble…
We demonstrate that both Wigner's form of Bell's inequalities as well as a form of the second law of thermodynamics, as manifest in Carathéodory's principle, can be derived from the same simple experimental and statistical mechanical assumptions combined with the trivial behavior of integers. This suggests that Bell's theorem is merely a well-disguised statement of the second law. It also suggests that entanglement is necessary for quantum theory to be in full accord with the second law and thus builds on the results of Wiesniak, Vedral, and Brukner \cite{Marcin-Wiesniak:2008fv} who showed it …
In this work, we examine the validity of quantum adiabatic theorem in thermodynamic systems. For a $d$-dimensional quantum many-body system, we show that the duration time $τ_0$ required by its ground-state adiabatic process does not depend on the microscopic details, but the scaling dimension of the fidelity susceptibility $d_a$. Our result, therefore, provides a quantitative time scale of the quantum adiabatic theorem in thermodynamic systems. The quantum adiabatic theorem might be violated in case that the scaling dimension of the fidelity susceptibility is larger than the system's real dim…
Traditional thermodynamics governs the behaviour of large systems that evolve between states of thermal equilibrium. For these large systems, the mean values of thermodynamic quantities (such as work, heat and entropy) provide a good characterisation of the process. Conversely, there is ever-increasing interest in the thermal behaviour of systems that evolve quickly and far from equilibrium, and that are too small for their behaviour to be well-described by mean values. Two major fields of modern thermodynamics seek to tackle such systems: non-equilibrium thermodynamics, and the nascent field …
In this paper, the foundations of classical phenomenological thermodynamics are being thoroughly revisited. A new rigorous basis for thermodynamics is laid out in the main text and presented in full detail in the appendix. All relevant concepts, such as work, heat, internal energy, heat reservoirs, reversibility, absolute temperature and entropy, are introduced on an abstract level and connected through traditional results, such as Carnot's Theorem, Clausius' Theorem and the Entropy Theorem. The paper offers insights into the basic assumptions one has to make in order to formally introduce a p…
By assuming that a particle of energy hbar.omega is actually a dissipative system maintained in a nonequilibrium steady state by a constant throughput of energy (heat flow), the exact Schroedinger equation is derived, both for conservative and nonconservative systems. Thereby, only universal properties of oscillators and nonequilibrium thermostatting are used, such that a maximal model independence of the hypothesised sub-quantum physics is guaranteed. It is claimed that this represents the shortest derivation of the Schroedinger equation from (modern) classical physics in the literature, and …
