It is shown that a macroscopic superposition state of radiation, strongly interacting with an ensemble of two-level atoms, is removed generating a coherent state describing a classical radiation field, when the thermodynamic limit is taken on the unitary evolution obtained by the Schroedinger equation. Decoherence appears as a dynamical effect in agreement with a recent proposal [M. Frasca, Phys. Lett. A 283, 271 (2001)]. To prove that this effect is quite general, we show that this same behavior appears when a superposition of two Fock number states is also considered. Higher order corrections are computed showing that this result tends to become exact in the thermodynamic limit. It appears as a genuine example of intrinsic collapse of the wave function.
Schrödinger's illustration of an imaginary cat in a box, neither alive nor dead, leads to a question of whether and how long a macroscopic quantum superposition can exist in various situations. It is well known that a macroscopic superposition is destroyed very quickly by environmental effects called decoherence. On the contrary, it is often believed that a macroscopic superposition continues to "survive" if it is ideally isolated from its environment. In this paper, using a well-established measure of macroscopic superpositions and the eigenstate thermalization hypothesis, we show that macros…
The crucial role of ambient correlations in determining thermodynamic behavior is established. A class of entangled states of two macroscopic systems is constructed such that each component is in a state of thermal equilibrium at a given temperature, and when the two are allowed to interact heat can flow from the colder to the hotter system. A dilute gas model exhibiting this behavior is presented. This reversal of the thermodynamic arrow is a consequence of the entanglement between the two systems, a condition that is opposite to molecular chaos and shown to be unlikely in a low-entropy envir…
Microscopic physical laws are time-symmetric, hence, a priori there exists no preferential temporal direction. However, the second law of thermodynamics allows one to associate the "forward" temporal direction to a positive variation of the total entropy produced in a thermodynamic process, and a negative variation with its "time-reversal" counterpart. This definition of a temporal axis is normally considered to apply in both classical and quantum contexts. Yet, quantum physics admits also superpositions between forward and time-reversal processes, whereby the thermodynamic arrow of time becom…
Quantum mechanics allows the occurrence of events without having any definite causal order. Here, it is shown that the application of two different thermal channels in the causally inseparable order can enhance the potential to extract work, in contrast to any of their definite (separable) order of compositions. This enhancement is also possible even without assigning any thermodynamic resource value to the controlling qubit. Further, we provide the first non-trivial example of causal enhancement with non-unital pin maps, for which it is still not clear how to obtain a superposition of path st…
A heat engine undergoes a cyclic operation while in equilibrium with the net result of conversion of heat into work. Quantum effects such as superposition of states can improve an engine's efficiency by breaking detailed balance, but this improvement comes at a cost due to excess entropy generated from collapse of superpositions on measurement. We quantify these competing facets for a quantum ratchet comprised of an ensemble of pairs of interacting two-level atoms. We suggest that the measurement postulate of quantum mechanics is intricately connected to the second law of thermodynamics. More …
We consider two dilute gas Bose-Einstein condensates with opposite velocities from which a monochromatic light field detuned far from the resonance of the optical transition is coherently scattered. In the thermodynamic limit, when the relative fluctuations of the atom number difference between the two condensates vanish, the relative phase between the Bose-Einstein condensates may be established in a superposition state by detections of spontaneously scattered photons, even though the condensates have initially well-defined atom numbers. For a finite system, stochastic simulations show that t…
In the classical world, temperature is a measure of how hot or cold a physical object is. We never find a physical system which can be both hot and cold at the same time. Here, we show that for a quantum system, it is possible to have superposition of two temperatures which can lead to a situation that it can be found both in hot and cold state. We propose a physical mechanism for how to create a quantum state which is superposition of two temperatures. Furthermore, we define an operator for the inverse temperature and show that the thermal state is, in fact, an eigenstate of this operator. Th…
We obtain exact dynamics of a two-qubit central spin model (CSM) consisting of two interacting qubits homogeneously coupled to a spin bath via the $XXZ$-type coupling, with the bath initially prepared in linear superpositions of the symmetric Dicke states. Using the interaction picture Hamiltonian with respect to the non-spin-flipping part of the model, we derive a sequence of equations of motion within each magnetization sector satisfied by the probability amplitudes of the time-evolved state. These equations of motion admit analytical solutions for the single-qubit CSM in which one of the tw…
We showed that quantum mechanical superposition can sustain in the process of ion transfer in protein membrane for a substantial period, in spite of the presence of the interactions with environmental modes of molecular vibration. The spectral temperature, as defined in quantum thermodynamical framework plays a significant role in maintaining the coherence. The ratio of decoherence time and dwell time has been calculated, which can be directly related to the degree of coherence. The results shead new light to build quantum information system of entangled ionic states in the voltage gated biolo…
In the presence of conservation laws, superpositions of eigenstates of the corresponding conserved quantities cannot be generated by quantum dynamics. Thus, any such coherence represents a potentially valuable resource of asymmetry, which can be used, for example, to enhance the precision of quantum metrology or to enable state transitions in quantum thermodynamics. Here we ask if such superpositions, already present in a reference system, can be broadcast to other systems, thereby distributing asymmetry indefinitely at the expense of creating correlations. We prove a no-go theorem showing tha…
In this brief note, we compare two frameworks for characterizing possible operations in quantum thermodynamics. One framework considers Thermal Operations---unitaries which conserve energy. The other framework considers all maps which preserve the Gibbs state at a given temperature. Thermal Operations preserve the Gibbs state; hence a natural question which arises is whether the two frameworks are equivalent. Classically, this is true---Gibbs-Preserving Maps are no more powerful than Thermal Operations. Here, we show that this no longer holds in the quantum regime: a Gibbs-Preserving Map can g…
Rich quantum effects emerge when several quantum systems are indistinguishable from the point of view of the bath they interact with. In particular, delocalised excitations corresponding to coherent superposition of excited states appear and change drastically the dynamics and steady state of the systems. Such phenomena, which are central mechanisms of superradiance, present interesting properties for thermodynamics and potentially other quantum technologies. Indeed, a recent paper [Phys. Rev. A 99, 052105 (2019)] studies these properties in a pair of indistinguishable two-level systems and po…
The entanglement in quantum XY spin chains of arbitrary length is investigated via the geometric (measure of) entanglement. The emergence of entanglement is explained intuitively from the perspective of perturbations. The model is solved exactly and the energy spectrum is determined and analyzed in particular for the lowest two levels. The entanglement is obtained over the entire phase diagram, and its behavior can be used to delineate the boundaries in the phase diagram. For example, the field-derivative of the entanglement becomes singular along the critical line. The form of the divergence …
Regarded as one of the most fundamental concepts of classical mechanics and thermodynamics, work has received well-grounded definitions within the quantum framework since the 1970s, having being successfully applied to many contexts. Recent developments on the concept have taken place in the emergent field of quantum thermodynamics, where work is frequently characterized as a stochastic variable. Notwithstanding this remarkable progress, it is still debatable whether some sensible notion of work can be posed for a strictly quantum instance involving a few-particle system prepared in a pure sta…
