Time evolution operator in quantum mechanics can be changed into a statistical operator by a Wick rotation. This strict relation between statistical mechanics and quantum evolution can reveal deep results when the thermodynamic limit is considered. These results translate in a set of theorems proving that these effects can be effectively at work producing an emerging classical world without recurring to any external entity that in some cases cannot be properly defined. In a many-body system has been recently shown that Gaussian decay of the coherence is the rule with a duration of recurrence more and more small as the number of particles increases. This effect has been observed experimentally. More generally, a theorem about coherence of bulk matter can be proved. All this takes us to the conclusion that a well definite boundary for the quantum to classical world does exist and that can be drawn by the thermodynamic limit, extending in this way the deep link between statistical mechanics and quantum evolution to a high degree.
We consider a simple one dimensional system consisting of two particles interacting with a $δ$-potential and we discuss a rigorous derivation of the asymptotic wave function of the system in the limit of small mass ratio. We apply the result to the explicit computation of the decoherence effect induced by scattering in a concrete example of quantum evolution.
We extend the results on decoherence in the thermodynamic limit [M. Frasca, Phys. Lett. A {\bf 283}, 271 (2001)] to general Hamiltonians. It is shown that N independent particles, initially properly prepared, have a set of observables behaving classically in the thermodynamic limit. This particular set of observables is then coupled to a quantum system that in this way decoheres so to have the density matrix in a mixed form. This gives a proof of the generality of this effect.
We prove a quantum version of the second law of thermodynamics: the (quantum) Boltzmann entropy increases if the initial (zero time) density matrix decoheres, a condition generally satisfied in Nature. It is illustrated by a model of wave-packet reduction, the Coleman-Hepp model, along the framework introduced by Sewell in his approach to the quantum measurement problem. Further models illustrate the monotonic-versus-non-monotonic behavior of the quantum Boltzmann entropy in time. As a last closely related topic, decoherence, which was shown by Narnhofer and Thirring to enforce macroscopic pur…
We present a rigorous analysis of the phenomenon of decoherence for general N-level systems coupled to reservoirs of free massless bosonic fields. We apply our general results to the specific case of the qubit. Our approach does not involve master equation approximations and applies to a wide variety of systems which are not explicitly solvable.
We take up the question why the initial entropy in the universe was small, in the context of evolution of the entropy of a classical system. We note that coarse-graining is a an important aspect of entropy evaluation which can reverse the direction of the increase in entropy, i.e., the direction of thermodynamic arrow of time. Then we investigate the role of decoherence in the selection of coarse-graining and explain how to compute entropy for a decohered classical system. Finally, we argue that the requirement of low initial entropy imposes constraints on the decoherence process.
This work investigates the influence of directional properties of decoherence on kinetics rate equations. The physical reality is understood as a chain of unitary and decoherence events. The former are quantum-deterministic, while the latter introduce uncertainty and increase entropy. For interactions of matter and antimatter, two approaches are considered: symmetric decoherence, which corresponds to conventional symmetric (CP-invariant) thermodynamics, and antisymmetric decoherence, which corresponds to antisymmetric (CPT-invariant) thermodynamics. Radiation, in its interactions with matter a…
Local and global approaches to the thermodynamics of pure decoherence processes in open quantum systems
University of Freiburg（弗赖堡大学）；Università degli Studi di Milano（米兰大学）；INFN, Sezione di Milano（意大利国家核物理研究所米兰分部）；EUCOR Centre for Quantum Science and Quantum Computing, University of Freiburg（弗赖堡大学EUCOR量子科学与量子计算中心）
The current stage of quantum computing technology, called noisy intermediate-scale quantum (NISQ) technology, is characterized by large errors that prohibit it from being used for real applications. In these devices, decoherence, one of the main sources of error, is generally modeled by Markovian master equations such as the Lindblad master equation. In this work, the decoherence phenomena are addressed from the perspective of the steepest-entropy-ascent quantum thermodynamics (SEAQT) framework in which the noise is in part seen as internal to the system. The framework is as well used to descr…
It is shown how classical states, meant as states representing a classical object, can be produced in the thermodynamic limit, retaining the unitary evolution of quantum mechanics. Besides, using a simple model of a single spin interacting with a spin-bath, it is seen how decoherence, with the off-diagonal terms in the density matrix going to zero, can be obtained when the number of the spins in the bath is taken to go formally to infinity. In this case, indeed, the system appears to flop at a frequency being formally infinity that, from a physical standpoint, can be proved equivalent to a tim…
Various physical effects resulting from decoherence are discussed in the algebraic framework. In particular, it is shown that the environment may induce not only classical properties like superselection rules, pointer states or even classical behavior of the quantum system, but, what is more, it also allows the transition from statistical description of infinite quantum systems to quantum mechanics of systems with a finite number of degrees of freedom. It is shown that such transition holds for the quantum spin system in the thermodynamic limit interacting with the phonon field.
We prove a generalization of the classic Groenewold-Lindblad entropy inequality, combining decoherence and the quantum Bayes theorem into a simple unified picture where decoherence increases entropy while observation decreases it. This provides a rigorous quantum-mechanical version of the second law of thermodynamics, governing how the entropy of a system (the entropy of its density matrix, partial-traced over the environment and conditioned on what is known) evolves under general decoherence and observation. The powerful tool of spectral majorization enables both simple alternative proofs of …
We investigate the thermodynamics of a quench realized by turning on an interaction generating pure decoherence. We characterize the work probability distribution function, also with a fluctuation relation, a lower bound of the work and by considering some physical examples.
We present a detailed analysis of decoherence free subspaces and develop a rigorous theory that provides necessary and sufficient conditions for dynamically stable decoherence free subspaces. This allows us to identify a special class of decoherence free states which rely on incoherent generation of coherences. We provide examples of physical systems that support such states. Our approach employs Markovian master equations and applies primarily to finite-dimensional quantum systems.
When a quantum system is placed in thermal environments, we often assume that the system relaxes to the Gibbs state in which decoherence takes place in the system energy eigenbasis. However, when the coupling between the system and the environments is strong, the stationary state is not necessarily the Gibbs state due to environment-induced decoherence which can be interpreted as continuous measurement by the environments. Based on the einselection proposed by Zurek, we postulate that the Gibbs state is projected onto the pointer basis due to the continuous measurement. We justify the proposit…
We describe our recent results on the resonant perturbation theory of decoherence and relaxation for quantum system with many qubits. The approach represents a rigorous analysis of the phenomenon of decoherence and relaxation for general $N$-level systems coupled to reservoirs of the bosonic fields. We derive a representation of the reduced dynamics valid for all times $t\geq 0$ and for small but fixed interaction strength. Our approach does not involve master equation approximations and applies to a wide variety of systems which are not explicitly solvable.
The low-temperature regime of charge-qubit decoherence due to its Coulomb interaction with electrons tunneling through Luttinger liquid quantum-point contact (QPC) is investigated. The study is focused on quantum detector properties of Luttinger liquid QPC. It is shown, that in low-temperature limit the respective perturbative decoherence- and acquisition of information timescales both tend to diverge, thus, shadowing a true picture of low-temperature quantum detection for such quantum systems. Here I prove two general mathematical statements (S-theorem and S-lemma) about exact re-exponentiati…
We address the issue of the quantum-classical correspondence in chaotic systems using, as recently done by Zurek [e-print quant-ph/9802054], the solar system as a whole as a case study: this author shows that the classicality of the planetary motion is ensured by the environment-induced decoherence. We show that equivalent results are provided by the theories of spontaneous fluctuations and that these latter theories, in some cases, result in a still faster process of decoherence. We show that, as an additional benefit, the assumption of spontaneous fluctuation makes it possible to genuinely d…
Quantum decoherence is seen as an undesired source of irreversibility that destroys quantum resources. Quantum coherences seem to be a property that vanishes at thermodynamic equilibrium. Away from equilibrium, quantum coherences challenge the classical notions of a thermodynamic bath in a Carnot engines, affect the efficiency of quantum transport, lead to violations of Fourier's law, and can be used to dynamically control the temperature of a state. However, the role of quantum coherence in thermodynamics is not fully understood. Here we show that the relative entropy of a state with quantum …
Intrinsic decoherence in the thermodynamic limit is shown for a large class of many-body quantum systems in the unitary evolution in NMR and cavity QED. The effect largely depends on the inability of the system to recover the phases. Gaussian decaying in time of the fidelity is proved for spin systems and radiation-matter interaction.
Statistical mechanics explains thermodynamics in terms of (quantum) mechanics by equating the entropy of a microstate of a closed system with the logarithm of the number of microstates in the macrostate to which it belongs, but the question `what is a macrostate?' has never been answered except in a vague, subjective, way. However Hawking's discovery of black hole evaporation led to a formula for black hole entropy with no subjective element. In this letter, we argue from this result, together with the assumption that `black hole thermodynamics is just ordinary thermodynamics applied to black …
We experimentally and theoretically investigate the scattering of a photonic quantum field from another stored in a strongly interacting atomic Rydberg ensemble. Considering the many-body limit of this problem, we derive an exact solution to the scattering-induced spatial decoherence of multiple stored photons, allowing for a rigorous understanding of the underlying dissipative quantum dynamics. Combined with our experiments, this analysis reveals a correlated coherence-protection process in which the scattering from one excitation can shield all others from spatial decoherence. We discuss how…
A phase damping reservoir composed by $N$-bosons coupled to a system of interest through a cross-Kerr interaction is proposed and its effects on quantum superpo sitions are investigated. By means of analytical calculations we show that: i-) the reservoir induces a Gaussian decay of quantum coherences, and ii-) the inher ent incommensurate character of the spectral distribution yields irreversibility . A state-independent decoherence time and a master equation are both derived an alytically. These results, which have been extended for the thermodynamic limit, show that nondissipative decoherenc…
Quantum decoherence arises due to uncontrollable entanglement between a system with its environment. However the effects of decoherence are often thought of and modeled through a simpler picture in which the role of the environment is to introduce classical noise in the system's degrees of freedom. Here we establish necessary conditions that the classical noise models need to satisfy to quantitatively model the decoherence. Specifically, for pure-dephasing processes we identify well-defined statistical properties for the noise that are determined by the quantum many-point time correlation func…
A model for a quantum register $\cal R$ made of $N$ replicas of a $d$-dimensional quantum system (cell) coupled with the environment, is studied by means of a Born-Markov Master Equation (ME). Dissipation and decoherence are discussed in various cases in which a sub-decoherent enconding can be rigorously found. For the qubit case ($d=2$) we have solved, for small $N,$ the ME by numerical direct integration and studied, as a function of the coherence length $ξ_c$ of the bath, fidelity and decoherence rates of states of the register. For large enough $ξ_c$ the singlet states of the global $su(2)…
In this paper, the foundations of classical phenomenological thermodynamics are being thoroughly revisited. A new rigorous basis for thermodynamics is laid out in the main text and presented in full detail in the appendix. All relevant concepts, such as work, heat, internal energy, heat reservoirs, reversibility, absolute temperature and entropy, are introduced on an abstract level and connected through traditional results, such as Carnot's Theorem, Clausius' Theorem and the Entropy Theorem. The paper offers insights into the basic assumptions one has to make in order to formally introduce a p…
Conditional expectation values of quantum mechanical observables reflect unique non-classical correlations, and are generally sensitive to decoherence. We consider the circumstances under which such sensitivity to decoherence is removed, namely, when the measurement process is subjected to conservation laws. Specifically, we address systems with additive conserved quantities and identify sufficient conditions for the system state such that its coherence plays no role in the conditional expectation values of observables that commute with the conserved quantity. We discuss our findings for a spe…
A major test of the capabilities of modern quantum simulators and NISQ devices is the reliable realization of gauge theories, which constitute a gold standard of implementational efficacy. In addition to unavoidable unitary errors, realistic experiments suffer from decoherence, which compromises gauge invariance and, therefore, the gauge theory itself. Here, we study the effect of decoherence on the quench dynamics of a lattice gauge theory. Rigorously identifying the gauge violation as a divergence measure in the gauge sectors, we find at short times that it first grows diffusively $\simγt$ d…
The conventional interpretation of quantum mechanics, though it permits a correspondence to classical physics, leaves the exact mechanism of transition unclear. Though this was only of philosophical importance throughout the twentieth century, over the past decade new technological developments, such as quantum computing, require a more thorough understanding of not just the result of quantum emergence, but also its mechanism. Quantum decoherence theory is the model that developed out of necessity to deal with the quantum-classical transition explicitly, and without external observers. In this…
We propose a list of conditions that consistency with thermodynamics imposes on linear and nonlinear generalizations of standard unitary quantum mechanics that assume a set of true quantum states without the restriction $ρ^2=ρ$ even for strictly isolated systems and that are to be considered in experimental tests of the existence of intrinsic (spontaneous) decoherence at the microscopic level.
In this thesis we describe methods for avoiding the detrimental effects of decoherence while at the same time still allowing for computation of the quantum information. The philosophy of the method discussed in the first part of this thesis is to use a symmetry of the decoherence mechanism to find robust encodings of the quantum information. Stability, control, and methods for using decoherence-free information in a quantum computer are presented with a specific emphasis on decoherence due to a collective coupling between the system and its environment. Universal quantum computation on such co…
We study the decoherence dynamics of Majorana qubit braiding operations in a topological superconducting chain (TSC) system, in which the braiding is performed by controlling the electron-chemical potentials of the TSCs and the couplings between them. By solving rigorously the Majorana qubit dynamics, we show how the Majorana qubit coherence is generated through bogoliubon correlations formed by exchanging Majorana zero modes (MZMs) between two TSCs in braiding operations. Using the exact master equation, we demonstrate how MZMs and also the bogoliubon correlations dissipate due to charge fluc…
In quantum systems of a macroscopic size V, such as interacting many particles and quantum computers with many qubits, there exist pure states such that fluctuations of some intensive operator A is anomalously large, <δA^2> = O(V^0), which is much larger than that assumed in thermodynamics, <δA^2> = O(1/V). By making full use of the locality, we show, starting from Hamiltonians of macroscopic degrees of freedom, that such states decohere at anomalously fast rates when they are weakly perturbed from environments.
Geometric quantum discord is a well-defined measure of quantum correlation if Schatten 1-norm (trace norm) is adopted as a distance measure. Here, we analytically investigate the dynamical behavior of the 1-norm geometric quantum discord under the effect of decoherence. By starting from arbitrary Bell-diagonal mixed states under Markovian local noise, we provide the decays of the quantum correlation as a function of the decoherence parameters. In particular, we show that the 1-norm geometric discord exhibits the possibility of double sudden changes and freezing behavior during its evolution. F…
The usual mathematical formalism of quantum field theory is non-rigorous because it contains divergences that can only be renormalized by non-rigorous mathematical methods. The purpose of this paper is to present a method of subtraction of this divergences using the formalism of decoherence. This is achieved by replacing the standard renormalization method by a projector on a well defined Hilbert subspace. In this way a list of problems of the standard formalism disappears while the physical results of QFT remains valid. From it own nature, this formalism can be used in non-renormalizable theo…
We study the spontaneous decoherence of the coupled harmonic oscillators confined in a ring container, where the nearest-neighbor harmonic potentials are taken into consideration. Without any external symmetry breaking field or surrounding environment, the quantum superposition state prepared in the relative degrees of freedom gradually loses its quantum coherence spontaneously. This spontaneous decoherence is interpreted by the hidden couplings between the center-of-mass and relative degrees of freedoms, which actually originates from the symmetries of the ring geometry and corresponding nont…
The interplay between dissipation and internal interactions in quantum many-body systems gives rise to a wealth of novel phenomena. Here we investigate spin-1/2 chains with uniform local couplings to a Markovian environment using the time-dependent density matrix renormalization group (tDMRG). For the open XXZ model, we discover that the decoherence time diverges in the thermodynamic limit. The coherence decay is then algebraic instead of exponential. This is due to a vanishing gap in the spectrum of the corresponding Liouville superoperator and can be explained on the basis of a perturbative …
A possible solution of the information paradox can be sought in quantum information scrambling. In this paradigm, it is postulated that all information entering a black hole is rapidly and chaotically distributed across the event horizon making it impossible to reconstruct the information by means of any local measurement. However, in this scenario the effects of decoherence are typically ignored, which may render information scrambling moot in cosmological settings. In this work, we develop key steps towards a thermodynamic description of information scrambling in open quantum systems. In par…
The aim of this review is to show how ``ferromagnetic'' states, that is, states having a fully polarization, can produce intrinsic decoherence by unitary evolution. This effect can give an understanding of recent experiments on mesoscopic devices as quantum point contacts showing the 0.7 conductance anomaly and the wide number of data about saturation of dephasing time observed at very low temperatures, as a fully polarized two dimensional electron gas. But similar effects can be seen in different area of physics as for example the Dicke model describing the interaction of two-level systems wi…
In previous works, we introduced a geometric route to define our Ehrenfest Statistical Dynamics (ESD) and we proved that, for a simple toy-model, the resulting ESD does not preserve purity. We now take a step further: we investigate decoherence and pointer basis in the ESD model by considering some uncertainty in the degrees of freedom of a simple but realistic molecular model, consisting of two classical cores and one quantum electron. The Ehrenfest model is sometimes discarded as a valid approximation to non-adiabatic coupled quantum-classical dynamics because it does not describe the decohe…
Entanglement within a given device provides a potential resource for quantum information processing. Entanglement between system and environment leads to decoherence (thus suppressing non-classical features within the system) but also opens up a route to robust and universal control. The latter is related to thermodynamic equilibrium, a generic behavior of bi-partite quantum systems. Fingerprints of this equilibrium behavior (including relaxation and stability) show up already far from the thermodynamic limit, where a complete solution of the underlying Schroedinger dynamics of the total syste…
It is well known that the dynamical mechanism of decoherence may cause apparent superselection rules, like that of molecular chirality. These `environment-induced' or `soft' superselection rules may be contrasted with `hard' superselection rules, like that of electric charge, whose existence is usually rigorously demonstrated by means of certain symmetry principles. We address the question of whether this distinction between `hard' and `soft' is well founded and argue that, despite first appearance, it might not be. For this we give a detailed and somewhat pedagogical exposition of the basic s…
We showed that quantum mechanical superposition can sustain in the process of ion transfer in protein membrane for a substantial period, in spite of the presence of the interactions with environmental modes of molecular vibration. The spectral temperature, as defined in quantum thermodynamical framework plays a significant role in maintaining the coherence. The ratio of decoherence time and dwell time has been calculated, which can be directly related to the degree of coherence. The results shead new light to build quantum information system of entangled ionic states in the voltage gated biolo…
We study measures of decoherence and thermalization of a quantum system $S$ in the presence of a quantum environment (bath) $E$. The entirety $S$$+$$E$ is prepared in a canonical thermal state at a finite temperature, that is the entirety is in a steady state. Both our numerical results and theoretical predictions show that measures of the decoherence and the thermalization of $S$ are generally finite, even in the thermodynamic limit, when the entirety $S$$+$$E$ is at finite temperature. Notably, applying perturbation theory with respect to the system-environment coupling strength, we find tha…
We derive rigorous lower bounds for the average ground-state energy per site $e^{(d)}$ of the quantum and classical Edwards-Anderson spin-glass model in dimensions $d = 2$ and $d = 3$ in the thermodynamic limit. For the classical model they imply that $e^{(2)} \ge -3/2$ and $e^{(3)} \ge -2.204...$.
In this work we examine the effect of phase-space noncommutativity on some typically quantum properties such as quantum beating, quantum information, and decoherence. To exemplify these issues we consider the two-dimensional noncommutative quantum harmonic oscillator whose components behavior we monitor in time. This procedure allows us to determine how the noncommutative parameters are related to the missing information quantified by the linear quantum entropy and by the mutual information between the relevant Hilbert space coordinates. Particular questions concerning the thermodynamic limit …
This article sets up a new formalism to investigate stochastic thermodynamics in the quantum regime, where stochasticity and irreversibility primarily come from quantum measurement. In the absence of any bath, we define a purely quantum component to heat exchange, that corresponds to energy fluctuations caused by measurement back-action. Energetic and entropic signatures of measurement induced irreversibility are then investigated for canonical experiments of quantum optics, and the energetic cost of counter-acting decoherence is characterized on a simple state-stabilizing protocol. By placing…
A state selected at random from the Hilbert space of a many-body system is overwhelmingly likely to exhibit highly non-classical correlations. For these typical states, half of the environment must be measured by an observer to determine the state of a given subsystem. The objectivity of classical reality-the fact that multiple observers can agree on the state of a subsystem after measuring just a small fraction of its environment-implies that the correlations found in nature between macroscopic systems and their environments are very exceptional. Building on previous studies of quantum Darwin…
We ask and answer a basic question about the length scales involved in quantum decoherence: how far apart in space do two parts of a quantum system have to be, before a common quantum environment decoheres them as if they were entirely separate? We frame this question specifically in a cold atom context. How far apart do two populations of bosons have to be, before an environment of thermal atoms of a different species (`buffer gas') responds to their two particle numbers separately? An initial guess for this length scale is the thermal coherence length of the buffer gas; we show that a standa…
The physical foundations of a variety of emerging technologies --- ranging from the applications of quantum entanglement in quantum information to the applications of nonequilibrium bulk and interface phenomena in microfluidics, biology, materials science, energy engineering, etc. --- require understanding thermodynamic entropy beyond the equilibrium realm of its traditional definition. This paper presents a rigorous logical scheme that provides a generalized definition of entropy free of the usual unnecessary assumptions which constrain the theory to the equilibrium domain. The scheme is base…
We give a first principles derivation of a master equation for the evolution of a quantum matter field in a linearly perturbed Minkowski spacetime, based solely on quantum field theory and general relativity. We make no additional assumptions nor introduce extra ingredients, as is often done in alternative quantum theories. When the quantum matter field is projected to a one-particle state, the master equation for a non-relativistic quantum particle in a weak gravitational field predicts decoherence in the energy basis, in contrast to most existing theories of gravitational decoherence. We poi…
