In the field of atom optics, the basis of many experiments is a two level atom coupled to a light field. The evolution of this system is governed by a master equation. The irreversible components of this master equation describe the spontaneous emission of photons from the atom. For many applications, it is necessary to minimize the effect of this irreversible evolution. This can be achieved by having a far detuned light field. The drawback of this regime is that making the detuning very large makes the timestep required to solve the master equation very small, much smaller than the timescale of any significant evolution. This makes the problem very numerically intensive. For this reason, approximations are used to simulate the master equation which are more numerically tractable to solve. This paper analyses four approximations: The standard adiabatic approximation; a more sophisticated adiabatic approximation (not used before); a secular approximation; and a fully quantum dressed-state approximation. The advantages and disadvantages of each are investigated with respect to accuracy, complexity and the resources required to simulate. In a parameter regime of particular experimental interest, only the sophisticated adiabatic and dressed-state approximations agree well with the exact evolution.
Open-system dynamics play a key role in the experimental and theoretical study of cavity optomechanical systems. In many cases, the quantum Langevin equations have enabled excellent models for optical decoherence, yet a master-equation approach to the fully nonlinear optomechanical Hamiltonian has thus far proven more elusive. To address this outstanding question and broaden the mathematical tool set available, we derive a solution to the Lindblad master equation that models optical decoherence for a system evolving with the nonlinear optomechanical Hamiltonian. The method combines a Lie-algeb…
We provide the exact non-Markovian master equation for a two-level system interacting with a thermal bosonic bath, and we write the solution of such a master equation in terms of the Bloch vector. We show that previous approximated results are particular limits of our exact master equation. We generalize these results to more complex systems involving an arbitrary number of two-level systems coupled to different thermal baths, providing the exact master equations also for these systems. As an example of this general case we derive the master equation for the Jaynes-Cummings model.
This is a derivation of the quantum-optical master equation using coarse-graining of time, which brings new insights into a decades old technique. My derivation is quite similar to derivations using quantum stochastic methods or Kraus operators, though I go through the derivation without explicitly invoking any of these concepts, so it may be easier to follow as an introduction. I also address the major pitfall of nearly all microscopic derivations of the master equation, namely that they assume the state of the system and bath factorize for all times. I show why this assumption actually holds…
We investigate the thermodynamic consistency of the master equation description of heat transport through an optomechanical system attached to two heat baths, one optical and one mechanical. We employ three different master equations to describe this scenario: (i) The standard master equation used in optomechanics, where each bath acts only on the resonator that it is physically connected to; (ii) the so-called dressed-state master equation, where the mechanical bath acts on the global system; and (iii) what we call the global master equation, where both baths are treated non-locally and affec…
The Hamiltonian of mean force is a widely used concept to describe the modification of the usual canonical Gibbs state for a quantum system whose coupling strength with the thermal bath is non-negligible. Here we perturbatively derive general approximate expressions for the Hamiltonians of mean force in the weak-coupling approximation and in the high-temperature one. We numerically analyse the accuracy of the corresponding expressions and show that the precision of the Bloch-Redfield equantum master equation can be improved if we replace the original system Hamiltonian by the Hamiltonian of me…
We present the Born-Markov approximated Redfield quantum master equation (RQME) description for an open system of non-interacting particles (bosons or fermions) on an arbitrary lattice of $N$ sites in any dimension and weakly connected to multiple reservoirs at different temperatures and chemical potentials. The RQME can be reduced to the Lindblad equation, of various forms, by making further approximations. By studying the $N=2$ case, we show that RQME gives results which agree with exact analytical results for steady state properties and with exact numerics for time-dependent properties, ove…
Master equations are a useful tool to describe the evolution of open quantum systems. In order to characterize the mathematical features and the physical origin of the dynamics, it is often useful to consider different kinds of master equations for the same system. Here, we derive an exact connection between the time-local and the integro-differential descriptions, focusing on the class of commutative dynamics. The use of the damping-basis formalism allows us to devise a general procedure to go from one master equation to the other and vice-versa, by working with functions of time and their La…
Non-Markovian dissipative dynamics of two coupled qubits in independent reservoirs: a comparison between exact solutions and master equation approaches
We introduce a systematic approximation for an efficient evaluation of Born--Markov master equations for steady state transport studies in open quantum systems out of equilibrium: the energy resolved master equation approach. The master equation is formulated in the eigenbasis of the open quantum system and build successively by including eigenstates with increasing grandcanonical energies. In order to quantify convergence of the approximate scheme we introduce quality factors to check preservation of trace, positivity and hermiticity. Furthermore, we discuss different types of master equation…
Open systems dynamics: Simulating master equations in the computer
主方程可能是任何研究耗散量子光学的人最基本的方程。在这种情况下，在计算机中编码和模拟这些方程的有效方法是非常有用的，在这篇笔记中，我试图以一种全面的方式介绍我是如何做到这一点的，重点是Matlab，但使其足够通用，以便可以直接翻译为任何其他语言或软件的选择。我的大部分方法都是从胡安·何塞·加西亚-里波尔（Juan José García-Ripoll）那里继承来的（他的数学能力我怎么称赞都不为过），我在这里和那里改变它们，以适应我（相当有限的）数字大脑的工作方式，并尽可能地将它们与我如何理解它们背后的理论联系起来。目前，笔记集中在如何编码主方程并找到它们的稳态，但我希望很快我就能用时间演化方法更新它们，包括如何处理依赖于时间的主方程。在过去的4年里，我在各种不同的背景下测试了这些方法，包括电路量子电动力学，激光问题，光学参量振荡器和光机系统。评论和（建设性的）批评是非常欢迎的，并将适当的信贷和承认。
The urgent need for reliable simulation tools to match the extreme accuracy needed to control tailored quantum devices highlights the importance of understanding open quantum systems and their modeling. To this end, we compare here the commonly used Redfield and Lindblad master equations against numerically exact results in the case of one and two resonant qubits transversely coupled at a single point to a Drude-cut ohmic bath. All the relevant parameters are varied over a broad range which allows us to give detailed predictions about the validity and physically meaningful applicability of the…
Here we present a Lindblad master equation that approximates the Redfield equation, a well known master equation derived from first principles, without significantly compromising the range of applicability of the Redfield equation. Instead of full-scale coarse-graining, this approximation only truncates terms in the Redfield equation that average out over a time-scale typical of the quantum system. The first step in this approximation is to properly renormalize the system Hamiltonian, to symmetrize the gains and losses of the state due to the environmental coupling. In the second step, we swap…
The time-convolutionless (TCL) quantum master equation provides a powerful tool to simulate reduced dynamics of a quantum system coupled to a bath. The key quantity in the TCL master equation is the so-called kernel or generator, which describes effects of the bath degrees of freedom. Since the exact TCL generators are usually hard to calculate analytically, most applications of the TCL generalized master equation have relied on approximate generators using second and fourth order perturbative expansions. By using the hierarchical equation of motion (HEOM) and extended HEOM methods, we present…
We analyze and compare three different schemes that can be used to generate entanglement between spin qubits in optically-active single solid-state quantum systems. Each scheme is based on first generating entanglement between the spin degree of freedom and either the photon number, the time bin, or the polarization degree of freedom of photons emitted by the systems. We compute the time evolution of the entanglement generation process by decomposing the dynamics of a Markovian master equation into a set of propagation superoperators conditioned on the cumulative detector photon count. We then…
An exactly solvable model for the multi-level system interacting with several reservoirs at zero temperatures is presented. Population decay rates and decoherence rates predicted by exact solution and several approximate master equations, which are widespread in physical literature, are compared. The space of parameters is classified with respect to different inequities between the exact and approximate rates.
Post-Markovian quantum master equations from classical environment fluctuations
在本文中，我们证明了两个常用的唯象后马尔可夫量子主方程可以推导出没有使用任何微扰近似。一个系统耦合到一个环境的特点是自经典的组态波动，后者服从马尔可夫动力学，定义了底层的物理模型。Shabani-Lidar方程[A. Shabani和D. A. Lidar，Phys.Rev.A71，020101（R）（2005）]及其相关的近似积分-微分核主方程是通过追踪两个不同的二分马尔可夫Lindblad动力学得到的，其中环境波动由附属系统考虑。此外，我们还找到了非马尔可夫系统动力学可以用测量轨迹系综来解释的条件，并给出了一种非马尔可夫量子跳跃方法。与最近的分析相反[L。Mazzola，E. M. Laine，H. P. Breuer，S. Maniscalco和J. Piilo，Phys.Rev.A81，062120（2010）]，我们还证明了这些主方程，即使具有指数记忆函数，也可能导致非马尔可夫效应，例如如果哈密顿系统不与耗散动力学耦合，则信息的环境到系统回流。
We derive a master equation for a superradiant medium which includes multilevel interference betwen the individual scatterers. The derivation relies on the Born-Markov approximation and implements the coarse graining formalism. The master equation fulfils the Lindblad form and contains terms describing single-atom multilevel interference, multi-atom interference between identical transitions, and multi-atom interference between different electronic transitions with parallel dipoles. This formalism is then applied to determine the excitation spectrum of two emitters using the parameters of the …
Master equation-based model for infrared-based magnetometry with nitrogen-vacancy centers in diamond cavities: a path to sub-picotesla sensitivity at sub-millimeter scales
The reduced dynamics of an open quantum system obtained from an underlying microscopic Hamiltonian can in general only approximately be described by a time local master equation. The quality of that approximation depends primarily on the coupling strength and the structure of the environment. Various such master equations have been proposed with different aims. Choosing the most suitable one for a specific system is not straight forward. By focusing on the accuracy of the reduced dynamics we provide a thorough assessment for a selection of methods (Redfield Equation, Quantum Optical Master Equ…
The quantum state of motion of a large and rotating polar molecule can lose coherence through the collisions with gas atoms. We show how the associated quantum master equation for the center of mass can be expressed in terms of the orientationally averaged differential and total scattering cross sections, for which we provide approximate analytic expressions. The master equation is then utilized to quantify collisional decoherence in a interference experiment with polar molecules.
Thermodynamics entails a set of mathematical conditions on quantum Markovian dynamics. In particular, strict energy conservation between the system and environment implies that the dissipative dynamical map commutes with the unitary system propagator. Employing spectral analysis we prove the general form of the ensuing master equation. We compare this result to master equations obtained from standard microscopic derivations. The obtained formal structure can be employed to test the compatibility of approximate derivations with thermodynamics. For example, it designates that global master equat…
Markovian master equations provide a versatile tool for describing open quantum systems when memory effects of the environment may be neglected. As these equations are of an approximate nature, they often do not respect the laws of thermodynamics when no secular approximation is performed in their derivation. Here we introduce a Markovian master equation that is thermodynamically consistent and provides an accurate description whenever memory effects can be neglected. The thermodynamic consistency is obtained through a rescaled Hamiltonian for the thermodynamic bookkeeping, exploiting the fact…
