The Hamiltonian of mean force is a widely used concept to describe the modification of the usual canonical Gibbs state for a quantum system whose coupling strength with the thermal bath is non-negligible. Here we perturbatively derive general approximate expressions for the Hamiltonians of mean force in the weak-coupling approximation and in the high-temperature one. We numerically analyse the accuracy of the corresponding expressions and show that the precision of the Bloch-Redfield equantum master equation can be improved if we replace the original system Hamiltonian by the Hamiltonian of mean force.
We consider a pair of dipoles for which direct electrostatic dipole-dipole interactions may be significantly larger than the coupling to transverse radiation. We derive a master equation using the Coulomb gauge, which naturally enables us to include the inter-dipole Coulomb energy within the system Hamiltonian rather than the interaction. In contrast, the standard master equation for a two- dipole system, which depends entirely on well-known gauge-invariant S-matrix elements, is usually derived using the multipolar gauge, wherein there is no explicit inter-dipole Coulomb interaction. We show u…
A longstanding tool to characterize the evolution of open Markovian quantum systems is the GKSL (Gorini-Kossakowski-Sudarshan-Lindblad) master equation. However, in some cases, open quantum systems can be effectively described with non-Hermitian Hamiltonians, which have attracted great interest in the last twenty years due to a number of unconventional properties, such as the appearance of exceptional points. Here, we present a short review of these two different approaches aiming in particular to highlight their relation and illustrate different ways of connecting non-Hermitian Hamiltonian to…
These lecture notes from the 2019 Les Houches Summer School on Quantum Information Machines provides a pedagogical introduction to the theory of non-reciprocal quantum interactions and devices. The goal is connect various approaches and concepts, including Hamiltonians encoding synthetic gauge fields, scattering descriptions, quantum master equations, and non-Hermitian Hamiltonians. The importance of having both non-trivial synthetic gauge fields and dissipation for obtaining non-reciprocal interactions is stressed. Connections to broader topics such as quantum reservoir engineering and the qu…
We study the properties of a refined weak coupling limit that preserves complete positivity in order to describe non-Markovian dynamics in the spin-boson model. With this tool, we show the system presents a rich and new non-Markovian phenomenology. This implies a dynamical difference between entanglement and coherence: the latter undergoes revivals whereas the former not, despite the induced dynamics being fully incoherent. In addition, the evolution presents "quasieternal" non-Markovianity, becoming non-divisible at any time period where the system evolves qualitatively. Furthermore, the meth…
In this paper, we generalize the quantum Brownian motion to include momentum-dependent system-environment couplings. The conventional QBM model corresponds to the spacial case $W_k = V_k$. The generalized QBM is more complicated but the generalization is necessary. This is because the particle transition and the pair production between the system and the environment represent two very different physical processes, and usually cannot have the same coupling strengths. Thus, the conventional QBM model, which is well-defined at classical level, is hardly realized in real quantum physical world. We…
Open-system dynamics play a key role in the experimental and theoretical study of cavity optomechanical systems. In many cases, the quantum Langevin equations have enabled excellent models for optical decoherence, yet a master-equation approach to the fully nonlinear optomechanical Hamiltonian has thus far proven more elusive. To address this outstanding question and broaden the mathematical tool set available, we derive a solution to the Lindblad master equation that models optical decoherence for a system evolving with the nonlinear optomechanical Hamiltonian. The method combines a Lie-algeb…
The quantum master equation is a widespread approach to describing open quantum system dynamics. In this approach, the effect of the environment on the system evolution is entirely captured by the dynamical generator, providing a compact and versatile description. However, care needs to be taken when several noise processes act simultaneously or the Hamiltonian evolution of the system is modified. Here, we show that generators can be added at the master equation level without compromising physicality only under restrictive conditions. Moreover, even when adding generators results in legitimate…
High fidelity models, which support accurate device characterization and correctly account for environmental effects, are crucial to the engineering of scalable quantum technologies. As it ensures positivity of the density matrix, one preferred model for open systems describes the dynamics with a master equation in Lindblad form. The Linblad operators are rarely derived from first principles, resulting in dynamical models which miss those additional terms that must generally be added to bring the master equation into Lindblad form, together with concomitant other terms that must be assimilated…
Most future quantum devices, including quantum computers, require control that is broadband, meaning that the rate of change of the time-dependent Hamiltonian is as fast or faster than the dynamics it generates. In many areas of quantum physics, including quantum technology, one must include dissipation and decoherence induced by the environment. While Markovian master equations provide the only really efficient way to model these effects, these master equations are derived for constant Hamiltonians (or those with a discrete set of well-defined frequencies). In 2006, Alicky, Lidar, and Zanardi…
From the Hamiltonian connecting the inside and outside of an Fabry-Perot cavity, which is derived from the Maxwell boundary conditions at a mirror of the cavity, a master equation of a non-Lindblad form is derived when the cavity embeds matters, although we can transform it to the Lindblad form by performing the rotating-wave approximation to the connecting Hamiltonian. We calculate absorption spectra by these Lindblad and non-Lindblad master equations and also by the Maxwell boundary conditions in the framework of the classical electrodynamics, which we consider the most reliable approach. We…
The physics of Markovian open quantum systems can be described by quantum master equations. These are dynamical equations, that incorporate the Hamiltonian and jump operators, and generate the system's time evolution. Reconstructing the system's Hamiltonian and and its coupling to the environment from measurements is important both for fundamental research as well as for performance-evaluation of quantum machines. In this paper we introduce a method that reconstructs the dynamical equation of open quantum systems, directly from a set of expectation values of selected observables. We benchmark …
We show how random unitary dynamics arise from the coupling of an open quantum system to a static environment. Subsequently, we derive a master equation for the reduced system random unitary dynamics and study three specific cases: commuting system and interaction Hamiltonians, the short-time limit, and the Markov approximation.
Quantum optical systems, like trapped ions, are routinely described by master equations. The purpose of this paper is to introduce a master equation for two-sided optical cavities with spontaneous photon emission. To do so, we use the same notion of photons as in linear optics scattering theory and consider a continuum of traveling-wave cavity photon modes. Our model predicts the same stationary state photon emission rates for the different sides of a laser-driven optical cavity as classical theories. Moreover, it predicts the same time evolution of the total cavity photon number as the standa…
Based on a Liouville-space formulation of open systems, we present two methods to solve the quantum dynamics of coupled harmonic oscillators experiencing Markovian loss. Starting point is the quantum master equation in Liouville space which is generated by a Liouvillian that induces a Lie algebra. We show how this Lie algebra allows to define ladder operators that construct Fock-like eigenstates of the Liouvillian. These eigenstates are used to decompose the time-evolved density matrix and, together with the accompanying eigenvalues, provide insight into the transport properties of the lossy s…
We present a general master equation, correct to second order in the system-environment coupling strength, that takes into account the initial system-environment correlations. We assume that the system and its environment are in a joint thermal equilibrium state, and thereafter a unitary operation is performed to prepare the desired initial system state, with the system Hamiltonian possibly changing thereafter as well. We show that the effect of the initial correlations shows up in the second-order master equation as an additional term, similar in form to the usual second-order term describing…
Post-Markovian quantum master equations from classical environment fluctuations
在本文中，我们证明了两个常用的唯象后马尔可夫量子主方程可以推导出没有使用任何微扰近似。一个系统耦合到一个环境的特点是自经典的组态波动，后者服从马尔可夫动力学，定义了底层的物理模型。Shabani-Lidar方程[A. Shabani和D. A. Lidar，Phys.Rev.A71，020101（R）（2005）]及其相关的近似积分-微分核主方程是通过追踪两个不同的二分马尔可夫Lindblad动力学得到的，其中环境波动由附属系统考虑。此外，我们还找到了非马尔可夫系统动力学可以用测量轨迹系综来解释的条件，并给出了一种非马尔可夫量子跳跃方法。与最近的分析相反[L。Mazzola，E. M. Laine，H. P. Breuer，S. Maniscalco和J. Piilo，Phys.Rev.A81，062120（2010）]，我们还证明了这些主方程，即使具有指数记忆函数，也可能导致非马尔可夫效应，例如如果哈密顿系统不与耗散动力学耦合，则信息的环境到系统回流。
We consider an open quantum system described by a Lindblad-type master equation with two times-scales. The fast time-scale is strongly dissipative and drives the system towards a low-dimensional decoherence-free space. To perform the adiabatic elimination of this fast relaxation, we propose a geometric asymptotic expansion based on the small positive parameter describing the time-scale separation. This expansion exploits geometric singular perturbation theory and center-manifold techniques. We conjecture that, at any order, it provides an effective slow Lindblad master equation and a completel…
We theoretically investigate interactions between non-degenerate mechanical oscillators mediated by a time-dependent cavity field. We obtain a reduced master equation valid for all optomechanical systems operating in the weak coupling regime. This master equation includes all forms of decoherence and back-action due to the dissipation of the field mediating the interaction. We apply the master equation to study two resonant coupling schemes within a rotating-wave approximation: the beam splitter Hamiltonian and the two-mode parametric amplifier. In both cases, the effective unitary interaction…
If an open quantum system is initially uncorrelated from its environment, then its dynamics can be written in terms of a Lindblad-form master equation. The master equation is divided into a unitary piece, represented by an effective Hamiltonian, and a dissipative piece, represented by a hermiticity-preserving superoperator; however, the division of open system dynamics into unitary and dissipative pieces is non-unique. For finite-dimensional quantum systems, we resolve this non-uniqueness by specifying a norm on the space of dissipative superoperators and defining the canonical Hamiltonian to …
By exploiting the peculiarities of a recently introduced formalism for describing open quantum systems (the Parametric Representation with Environmental Coherent States) we derive an equation of motion for the reduced density operator of an open quantum system that has the same structure of the celebrated Gorini-Kossakowski-Sudarshan-Lindblad equation, but holds regardless of markovianity being assumed. The operators in our result have explicit expressions in terms of the Hamiltonian describing the interactions with the environment, and can be computed once a specific model is considered. We f…
Providing the microscopic behavior of a thermalization process has always been an intriguing issue. There are several models of thermalization, which often requires interaction of the system under consideration with the microscopic constituents of the macroscopic heat bath. With an aim to simulate such a thermalization process, here we look at the thermalization of a two-level quantum system under the action of a Markovian master equation corresponding to memory-less action of a heat bath, kept at a certain temperature, using a single-qubit ancilla. A two-qubit interaction Hamiltonian ($H_{th}…
We generalize the classical theory of Brownian motion so as to reckon with non-Markovian effects on both Klein-Kramers and Smoluchowski equations. For a free particle and a harmonic oscillator, it is shown that such non-Markovian effects account for the differentiability of the Brownian trajectories as well as the breakdown of the energy equipartition of statistical mechanics at short times in some physical situations. This non-Markovian approach is also extended to look at anomalous diffusion. Next, we bring in the dynamical-quantization method for investigating open quantum systems, which do…
