Thermodynamics entails a set of mathematical conditions on quantum Markovian dynamics. In particular, strict energy conservation between the system and environment implies that the dissipative dynamical map commutes with the unitary system propagator. Employing spectral analysis we prove the general form of the ensuing master equation. We compare this result to master equations obtained from standard microscopic derivations. The obtained formal structure can be employed to test the compatibility of approximate derivations with thermodynamics. For example, it designates that global master equations are the compatible choice. The axiomatic approach sheds light on the validity of the secular approximation in microscopic derivations, the form of the steady state in heat transport phenomena, and indicates the lack of exceptional points in the dynamics of open quantum systems.
We propose a list of conditions that consistency with thermodynamics imposes on linear and nonlinear generalizations of standard unitary quantum mechanics that assume a set of true quantum states without the restriction $ρ^2=ρ$ even for strictly isolated systems and that are to be considered in experimental tests of the existence of intrinsic (spontaneous) decoherence at the microscopic level.
We introduce a generalized approach to characterize the non-Markovianity of quantum dynamical maps via breakdown of monotonicity of thermodynamic functions. By adopting an entropy-based formulation of quantum thermodynamics, we use the relationship between heat and entropy to propose a measure of non-Markovianity based on the heat flow for single-qubit quantum evolutions. This measure can be applied for unital dynamical maps that do not invert the sign of the internal energy. Under certain conditions, it can also be extended for other thermodynamic functions, such as internal energy and work f…
We connect two key concepts in quantum information: compatibility and divisibility of quantum channels. Two channels are compatible if they can be both obtained via marginalization from a third channel. A channel divides another channel if it reproduces its action by sequential composition with a third channel. (In)compatibility is of central importance for studying the difference between classical and quantum dynamics. The relevance of divisibility stands in its close relationship with the onset of Markovianity. We emphasize the simulability character of compatibility and divisibility, and, d…
Perimeter Institute for Theoretical Physics（圆周理论物理研究所）；Universidad Complutense de Madrid（马德里康普顿斯大学）；ICFO-Institut de Ciències Fotòniques, The Barcelona Institute of Science and Technology（巴塞罗那科学技术学院光子科学研究所）；Princeton University（普林斯顿大学）；ICREA（加泰罗尼亚研究与高等研究院）；Institute for Quantum Optics and Quantum Information（量子光学与量子信息研究所）
Causality is a seminal concept in science: Any research discipline, from sociology and medicine to physics and chemistry, aims at understanding the causes that could explain the correlations observed among some measured variables. While several methods exist to characterize classical causal models, no general construction is known for the quantum case. In this work, we present quantum inflation, a systematic technique to falsify if a given quantum causal model is compatible with some observed correlations. We demonstrate the power of the technique by reproducing known results and solving open …
We introduce a general framework for the construction of completely positive dynamical evolutions in the presence of system-environment initial correlations. The construction relies upon commutativity of the compatibility domain obtained by considering the marginals with respect to the environmental degrees of freedom of the considered class of correlated states. Our approach allows to consider states whose discord is not necessarily zero and explicitly show the non-uniqueness of the completely positive extensions of the obtained dynamical map outside the compatibility domain. The relevance of…
Master equations of Lindblad type have attained prominent status in the fields of quantum optics and quantum information since they are guaranteed to satisfy fundamental notions of quantum dynamics such as complete positivity. When Lindblad operators are used to describe thermal reservoirs in contact with an open quantum system, the fundamental laws of thermodynamics and the fluctuation-dissipation theorem provide additional mandatory criteria. We show several examples of innocent-looking Lindblad operators which have questionable properties in this regard. Compatibility criteria between Hamil…
We take the view that the standard von Neumann definition, in which the entropy $S^{vN}$ of a pure state is zero, is in evident conflict with the statement of the second law that the entropy of the universe $S_{univ}$ increases in spontaneous processes, $ ΔS_{univ} > 0$. Here we seek an alternative entropy of the universe $S_{univ}$ that is in accord with the second law, in a spirit not dissimilar to von Neumann himself in lesser-known work. We perform simulations of time dependent dynamics for a previously developed \cite{polyadbath} model quantum system becoming entangled with a quantum envi…
We consider the dynamical properties of dissipative continuous-time quantum walks on directed graphs. Using a large-deviation approach we construct a thermodynamic formalism allowing us to define a dynamical order parameter, and to identify transitions between dynamical regimes. For a particular class of dissipative quantum walks we propose a quantum generalization of the the classical PageRank vector, used to rank the importance of nodes in a directed graph. We also provide an example where one can characterize the dynamical transition from an effective classical random walk to a dissipative …
Despite its enormous empirical success, the formalism of quantum theory still raises fundamental questions: why is nature described in terms of complex Hilbert spaces, and what modifications of it could we reasonably expect to find in some regimes of physics? Here we address these questions by studying how compatibility with thermodynamics constrains the structure of quantum theory. We employ two postulates that any probabilistic theory with reasonable thermodynamic behavior should arguably satisfy. In the framework of generalized probabilistic theories, we show that these postulates already i…
Classical thermodynamics is built with the concept of equilibrium states. However, it is less clear how equilibrium thermodynamics emerges through the dynamics that follows the principle of quantum mechanics. In this paper, we develop a theory to study the exact nonequilibrium thermodynamics of quantum systems that is applicable to arbitrary small systems, even for single particle systems, in contact with a reservoir. We generalize the concept of temperature into nonequilibrium regime that depends on the detailed dynamics of quantum states. When we apply the theory to the cavity system and the…
We consider a recently proposed model of driven open quantum microcircuit [F. Pellegrini et al., Phys. Rev. Lett. 107, 060401 (2011)] amenable to experimental investigations. We show that such an open quantum system provides a concrete physical instance where to prove that modeling its time-evolution with a dynamics lacking complete positivity conflicts with the second law of thermodynamics.
Thermodynamics serves as a universal means for studying physical systems from an energy perspective. In recent years, with the establishment of the field of stochastic and quantum thermodynamics, the ideas of thermodynamics have been generalized to small fluctuating systems. Independently developed in mathematics and statistics, the optimal transport theory concerns the means by which one can optimally transport a source distribution to a target distribution, deriving a useful metric between probability distributions, called the Wasserstein distance. Despite their seemingly unrelated nature, a…
We prove Lieb-Robinson bounds and the existence of the thermodynamic limit for a general class of irreversible dynamics for quantum lattice systems with time-dependent generators that satisfy a suitable decay condition in space.
We study the fundamental limitations of cooling to absolute zero for a qubit, interacting with a single mode of the electromagnetic field. Our results show that the dynamical Casimir effect, which is unavoidable in any finite-time thermodynamic cycle, forbids the attainability of the absolute zero of temperature, even in the limit of an infinite number of cycles.
An important yet perplexing result from work in the 90s and 00s is the near-unity value of the ratio of fluctuations in the vacuum energy density of quantum fields to the mean in a collection of generic spacetimes. This was done by way of calculating the noise kernels which are the correlators of the stress-energy tensor of quantum fields. In this paper we revisit this issue via a quantum thermodynamics approach, by calculating two quintessential thermodynamic quantities: the heat capacity and the quantum compressibility of some model geometries filled with a quantum field at high and low temp…
