The spontaneous emission rate of a radiating atom reaches its time-independent equilibrium value after an initial transient regime. In this paper we consider the associated relaxation effects of the spontaneous decay rate of atoms in dispersive and absorbing dielectric media for atomic transition frequencies near material resonances. A quantum mechanical description of such media is furnished by a damped-polariton model, in which absorption is taken into account through coupling to a bath. We show how all field and matter operators in this theory can be expressed in terms of the bath operators at an initial time. The consistency of these solutions for the field and matter operators are found to depend on the validity of certain velocity sum rules. The transient effects in the spontaneous decay rate are studied with the help of several specific models for the dielectric constant, which are shown to follow from the general theory by adopting particular forms of the bath coupling constant.
Using a recently developed formalism of quantization of radiation in the presence of absorbing dielectric bodies, the problem of photon tunneling through absorbing barriers is studied. The multilayer barriers are described in terms of multistep complex permittivities in the frequency domain which satisfy the Kramers--Kronig relations. From the resulting input--output relations it is shown that losses in the layers may considerably change the photon tunneling times observed in two-photon interference experiments. It is further shown that for sufficiently large numbers of layers interference fri…
The eletromagnetic field in a linear absorptive dielectric medium, is quantized in the framework of the damped polarization model. A Hamiltonian containing a reservoir with continuous degrees of freedom, is proposed. The reservoir minimally interacts with the dielectric polarization and the electromagnetic field. The Lagevin-Schrodinger equation is obtained as the equation of motion of the polarization field. The radiation reaction electromagnetic field is considered. For a homogeneous medium, the equations of motion are solved using the Laplace transformation method.
The theory developed by Gruner and Welsch [Phys. Rev. A 54, 1661 (1996)] for calculating the 1D input-output relations of the quantized electromagnetic field at dispersing and absorbing dielectric (multilayer) plates is generalized to the three-dimensional case. First a general recipe for the derivation of the reflection and transmission coefficients at an arbitrary body that separates two half spaces from each other is presented. The general theory is then applied to the case of planar multilayer structures, for which the Green tensor is well-known.
After giving an outline of the quantization scheme based on the microscopic Hopfield model of a dielectric bulk material, we show how the classical phenomenological Maxwell equations of the electromagnetic field in the presence of dielectric matter of given space- and frequency-dependent complex permittivity can be transferred to quantum theory. Including in the theory the interaction of the medium-assisted field with atomic systems, we present both the minimal-coupling Hamiltonian and the multipolar-coupling Hamiltonian in the Coulomb gauge. To illustrate the concept, we discuss the input--ou…
Recently two methods have been developed for the quantization of the electromagnetic field in general dispersing and absorbing linear dielectrics. The first is based upon the introduction of a quantum Langevin current in Maxwell's equations [T. Gruner and D.-G. Welsch, Phys. Rev. A 53, 1818 (1996); Ho Trung Dung, L. Knöll, and D.-G. Welsch, Phys. Rev. A 57, 3931 (1998); S. Scheel, L. Knöll, and D.-G. Welsch, Phys. Rev. A 58, 700 (1998)], whereas the second makes use of a set of auxiliary fields, followed by a canonical quantization procedure [A. Tip, Phys. Rev. A 57, 4818 (1998)]. We show that…
Starting from the quantized version of Maxwell's equations for the electromagnetic field in an arbitrary linear Kramers-Kronig dielectric, spontaneous decay of the excited state of a two-level atom embedded in a dispersive and absorbing medium is studied and the decay rate is calculated. The calculations are performed for both the (Clausius-Mosotti) virtual cavity model and the (Glauber-Lewenstein) real cavity model. It is shown that owing to nonradiative decay associated with absorption the rate of spontaneous decay sensitively depends on the cavity radius when the atomic transition frequency…
A quantization scheme for the phenomenological Maxwell theory of the full electromagnetic field in an inhomogeneous three-dimensional, dispersive and absorbing dielectric medium is developed. The classical Maxwell equations with spatially varying and Kramers-Kronig consistent permittivity are regarded as operator-valued field equations, introducing additional current- and charge-density operator fields in order to take into account the noise associated with the dissipation in the medium. It is shown that the equal-time commutation relations between the fundamental electromagnetic fields $\hat …
The phenomenological Maxwell field is quantized for arbitrarily space- and frequency-dependent complex permittivity. The formalism takes account of the Kramers--Kronig relation and the dissipation-fluctuation theorem and yields the fundamental equal-time commutation relations of QED. Applications to the quantum-state transformation at absorbing and amplifying four-port devices and to the spontaneous decay of an excited atom in the presence of absorbing dielectric bodies are discussed.
We present a formalism for studying the influence of dispersive and absorbing dielectric bodies on a radiating atom in the framework of quantization of the phenomenological Maxwell equations for given complex permittivities of the bodies. In Markov approximation, the rate of spontaneous decay and the line shift associated with it can then be related to the complex permittivities and geometries of the bodies via the dyadic Green function of the classical boundary value problem of electrodynamics -- a result which is in agreement with second-order calculations for microscopic model systems. The …
Spontaneous emission and Lamb shift of atoms in absorbing dielectrics are discussed. A Green's-function approach is used based on the multipolar interaction Hamiltonian of a collection of atomic dipoles with the quantised radiation field. The rate of decay and level shifts are determined by the retarded Green's-function of the interacting electric displacement field, which is calculated from a Dyson equation describing multiple scattering. The positions of the atomic dipoles forming the dielectrics are assumed to be uncorrelated and a continuum approximation is used. The associated unphysical …
Within the framework of exact quantum electrodynamics in dielectric, we study the topological Berry phase of a classically pumped $Λ$-type three-level atom, prepared initially in a superposition of its two pumped levels and located near a planar dielectric half-space with model permittivity of Lorentz type, interacts with a vacuum field. The effects of material losses, expressed in terms of the Green tensor of the dielectric-matter formation including dispersion and absorption, on the topological Berry phase of the photon transition between the pumped levels have been studied. The outcomes are…
Recently the influence of dielectric and geometrical properties on the Casimir force between dispersing and absorbing multilayered plates in the zero-temperature limit has been studied within a 1D quantization scheme for the electromagnetic field in the presence of causal media [R. Esquivel-Sirvent, C. Villarreal, and G.H. Cocoletzi, Phys. Rev. Lett. 64, 052108 (2001)]. In the present paper a rigorous 3D analysis is given, which shows that for complex heterostructures the 1D theory only roughly reflects the dependence of the Casimir force on the plate separation in general. Further, an extensi…
A general theory of the interaction of the quantized electromagnetic field with atoms in the presence of dispersing and absorbing dielectric bodies of given Kramers--Kronig consistent permittivities is developed. It is based on a source-quantity representation of the electromagnetic field, in which the electromagnetic-field operators are expressed in terms of a continuous set of fundamental bosonic fields via the Green tensor of the classical problem. Introducing scalar and vector potentials, the formalism is extended in order to include in the theory the interaction of the quantized electroma…
Recently a quantization scheme for the phenomenological Maxwell theory of the full electromagnetic field in an inhomogeneous three-dimensional, dispersive, and absorbing dielectric medium has been developed and applied to a system consisting of two infinite half-spaces with a common planar interface (H.T. Dung, L. Knoell, and D.-G. Welsch, Phys. Rev. A 57, in press). Here we show that the scheme, which is based on the classical Green-tensor integral representation of the electromagnetic field, applies to any inhomogeneous medium. For this purpose we prove that the fundamental equal-time commut…
Dielectric four-port devices play an important role in optical quantum information processing. Since for causality reasons the permittivity is a complex function of frequency, dielectrics are typical examples of noisy quantum channels, which cannot preserve quantum coherence. To study the effects of quantum decoherence, we start from the quantized electromagnetic field in an arbitrary Kramers--Kronig dielectric of given complex permittivity and construct the transformation relating the output quantum state to the input quantum state, without placing restrictions on the frequency. We apply the …
A study of the effects of absorption on the nonlinear process of parametric down conversion is presented. Absorption within the nonlinear medium is accounted for by employing the framework of macroscopic QED and the Green tensor quantization of the electromagnetic field. An effective interaction Hamiltonian, which describes the nonlinear interaction of the electric field and the linear noise polarization field, is used to derive the quantum state of the light leaving a nonlinear crystal. The signal and idler modes of this quantum state are found to be a superpositions of the electric and noise…
A formalism for studying spontaneous decay of an excited two-level atom in the presence of dispersing and absorbing dielectric bodies is developed. An integral equation, which is suitable for numerical solution, is derived for the atomic upper-state-probability amplitude. The emission pattern and the power spectrum of the emitted light are expressed in terms of the Green tensor of the dielectric-matter formation including absorption and dispersion. The theory is applied to the spontaneous decay of an excited atom at the center of a three-layered spherical cavity, with the cavity wall being mod…
We extend Schwinger's ideas regarding sonoluminescence by explicitly calculating the Bogolubov coefficients relating the QED vacuum states associated with changes in a dielectric bubble. Sudden (non-adiabatic) changes in the refractive index lead to an efficient production of real photons with a broadband spectrum, and a high-frequency cutoff that arises from the asymptotic behaviour of the dielectric constant.
The whispering gallery modes (WGMs) of quartz microspheres are investigated for the purpose of strong coupling between single photons and atoms in cavity quantum electrodynamics (cavity QED). Within our current understanding of the loss mechanisms of the WGMs, the saturation photon number, n, and critical atom number, N, cannot be minimized simultaneously, so that an "optimal" sphere size is taken to be the radius for which the geometric mean, (n x N)^(1/2), is minimized. While a general treatment is given for the dimensionless parameters used to characterize the atom-cavity system, detailed c…
Using carefully designed hybrid metal-dielectric resonators, we study molecular optomechanics in the strong coupling regime ($g_{\rm }^2/ω_m {>} κ$), which manifests in anharmonic emission lines in the sideband-resolved region of the cavity-emitted spectrum ($κ{<}ω_m$). This nonlinear optomechanical strong coupling regime is enabled through a metal-dielectric cavity system that yields not only deep sub-wavelength plasmonic confinement, but also dielectric-like confinement times that are more than two orders of magnitude larger than those from typical localized plasmon modes. These hybrid metal…
Spontaneous decay of an excited atom near a dispersing and absorbing microsphere of given complex permittivity that satisfies the Kramers-Kronig relations is studied, with special emphasis on a Drude-Lorentz permittivity. Both the whispering gallery field resonances below the band gap (for a dielectric sphere) and the surface-guided field resonances inside the gap (for a dielectric or a metallic sphere) are considered. Since the decay rate mimics the spectral density of the sphere-assisted ground-state fluctuation of the radiation field, the strengths and widths of the field resonances essenti…
The Ullersma model for the damped harmonic oscillator is coupled to the quantised electromagnetic field. All material parameters and interaction strengths are allowed to depend on position. The ensuing Hamiltonian is expressed in terms of canonical fields, and diagonalised by performing a normal-mode expansion. The commutation relations of the diagonalising operators are in agreement with the canonical commutation relations. For the proof we replace all sums of normal modes by complex integrals with the help of the residue theorem. The same technique helps us to explicitly calculate the quantu…
The decay rate and the classical radiation power of an excited molecule (atom) located in the center of a dispersive and absorbing dielectric sphere taken as a simple model of a cavity are calculated adopting the Onsager model for the local field. The local-field correction factor to the external (radiation and absorption) power loss of the molecule is found to be $|3ε(ω)/[3ε(ω)+1]|^2$, with $ε(ω)$ being the dielectric function of the sphere. However, local-field corrections to the total decay rate (power loss) of the molecule are found to be much more complex, including those to the decay rat…
We build up a consistent theory of quantum electrodynamics in the presence of macroscopic polarizable media. We use the Huttner-Barnett model of a dispersive and absorbing dielectric medium and formulate the theory in terms of interacting quantum fields. We integrate out the damped polaritons by using diagrammatic techniques and find an exact expression for the displacement field (photon) propagator in the presence of a dispersive and absorbing dielectric half-space. This opens a new route to traceable perturbative calculations of the same kind as in free-space quantum electrodynamics. As a wo…
By using the Green-function concept of quantization of the electromagnetic field in dispersing and absorbing media, the quantized field in the presence of a dispersing and absorbing dielectric multilayer plate is studied. Three-dimensional input-output relations are derived for both amplitude operators in the ${\bf k}$-space and the field operators in the coordinate space. The conditions are discussed, under which the input-output relations can be expressed in terms of bosonic operators. The theory applies to both (effectively) free fields and fields, created by active atomic sources inside an…
In recent years, a rigorous quantum mechanical model for the interaction between light and macroscopic dispersive, lossy dielectrics has emerged -macroscopic QED- allowing the application of the usual methods of quantum field theory. Here, we apply time dependent perturbation theory to a general class of problems involving time dependent lossy, dispersive dielectrics. The model is used to derive polariton excitation rates in three illustrative cases, including that of a travelling Gaussian perturbation to the susceptibility of an otherwise infinite homogeneous dielectric, motivated by recent e…
We consider the resonant van der Waals interaction between two correlated identical two-level atoms (at least one of which being excited) within the framework of macroscopic cavity quantum electrodynamics in linear, dispersing and absorbing media. The interaction of both atoms with the body-assisted electromagnetic field of the cavity is assumed to be strong. Our time-independent evaluation is based on an extended Jaynes-Cummings model. For a system prepared in a superposition of its dressed states, we derive the general form of the van der Waals forces, using a Lorentzian single mode approxim…
Within leading-order perturbation theory, the Casimir-Polder potential of a ground-state atom placed within an arbitrary arrangement of dispersing and absorbing linear bodies can be expressed in terms of the polarizability of the atom and the scattering Green tensor of the body-assisted electromagnetic field. Based on a Born series of the Green tensor, a systematic expansion of the Casimir-Polder potential in powers of the susceptibilities of the bodies is presented. The Born expansion is used to show how and under which conditions the Casimir-Polder force can be related to microscopic many-at…
We have fabricated an atom chip device which combines the circuitry for magnetic trapping of cold atoms with high-finesse optical resonators suitable for cavity QED in the single-atom strong coupling regime. Fabry-Perot optical resonators with finesse F > 2 X 10^5 were formed between a micropatterned on-chip planar mirror with lateral dimension of < 100 um and a curved mirror suspended above the chip. The strong and rapid thermal coupling between on-chip electrical and optical elements was utilized to stabilize the cavity mirror separation with servo bandwidth exceeding 100 kHz during simulate…
Within the framework of exact quantization of the electromagnetic field in dispersing and absorbing media the input-output problem of a high-$Q$ cavity is studied, with special emphasis on the absorption losses in the coupling mirror. As expected, the cavity modes are found to obey quantum Langevin equations, which could be also obtained from quantum noise theories, by appropriately coupling the cavity modes to dissipative systems, including the effect of the mirror-assisted absorption losses. On the contrary, the operator input-output relations obtained in this way would be incomplete in gene…
We present a first-principles derivation of spatial atomic-sublevel decoherence near dielectric and metallic surfaces. The theory is based on the electromagnetic-field quantization in absorbing dielectric media. We derive an expression for the time-variation of the off-diagonal matrix element of the atomic density matrix for arbitrarily shaped substrates. For planar multilayered substrates we find that for small lateral separations of the atom's possible positions the spatial coherence decreases quadratically with the separation and inversely to the squared atom-surface distance.
In a companion paper [quant-ph/9904013] we have investigated several variations of Schwinger's proposed mechanism for sonoluminescence. We demonstrated that any realistic version of Schwinger's mechanism must depend on extremely rapid (femtosecond) changes in refractive index, and discussed ways in which this might be physically plausible. To keep that discussion tractable, the technical computations in that paper were limited to the case of a homogeneous dielectric medium. In this paper we investigate the additional complications introduced by finite-volume effects. The basic physical scenari…
The decay of an excited atom in the presence of a medium that both scatters and absorbs radiation is studied with the help of a quantum-electrodynamical model. The medium is represented by a half space filled with a randomly distributed set of non-overlapping spheres, which consist of a linear absorptive dielectric material. The absorption effects are described by means of a quantized damped-polariton theory. It is found that the effective susceptibility of the bulk does not fully account for the medium-induced change in the atomic decay rate. In fact, surface effects contribute to the modific…
The influence of the size and shape of a dispersing and absorbing dielectric body on the local-field corrected spontaneous-decay of an excited atom embedded in the body is studied on the basis of the real-cavity model. By means of a Born expansion of the Green tensor of the system it is shown that to linear order in the susceptibility of the body the decay rate exactly follows Tomas's formula found for the special case of an atom at the center of a homogeneous dielectric sphere [Phys. Rev. A 63, 053811 (2001)]. It is further shown that for an atom situated at the interior of an arbitrary diele…
We extend our approach to the Casimir effect between absorbing dielectric multilayers [M. S. Tomas, Phys. Rev. A 66, 052103 (2002)] to magnetodielectric systems. The resulting expression for the force is used to numerically explore the effect of the medium dispersion on the attractive/repulsive force in a metal-magnetodielectric system described by the Drude-Lorentz permittivities and permeabilities.
The spontaneous relaxation rates for an atom in free space and close to an absorbing surface are calculated to various orders of the electromagnetic multipole expansion. The spontaneous decay rates for dipole, quadrupole and octupole transitions are calculated in terms of their respective primitive electric multipole moments and the magnetic relaxation rate is calculated for the dipole and quadrupole transitions in terms of their respective primitive magnetic multipole moments. The theory of electromagnetic field quantization in magnetoelectric materials is used to derive general expressions f…
The retarded dispersion interaction (Casimir interaction) between two dilute dielectric media at high temperatures is considered. The excited atoms are taken into account. It is shown that the perturbation technique can not be applied to this problem due to the divergence of integrals. A non-perturbative approach based on kinetic Green functions is implemented. We consider interaction between two atoms (one of them is excited0 embedded in an absorbing dielectric medium. We take into account possible absorption of photons in the medium, which solves the problem of divergence. The force between …
We consider a fibrillar medium with a continuous distribution of two-level atoms coupled to quantized electromagnetic fields. Perturbation theory is developed based on the current algebra satisfied by the atomic operators. The one-loop corrections to the dispersion relation for the polaritons and the dielectric constant are computed. Renormalization group equations are derived which demonstrate a screening of the two-level splitting at higher energies. Our results are compared with known results in the slowly varying envelope and rotating wave approximations. We also discuss the quantum sine-G…
Based on a unified approach to macroscopic QED that allows for the inclusion of amplification in a limited space and frequency range, we study the Casimir force as a Lorentz force on an arbitrary partially amplifying system of linearly locally responding (isotropic) magnetoelectric bodies. We demonstrate that the force on a weakly polarisable/magnetisable amplifying object in the presence of a purely absorbing environment can be expressed as a sum over the Casimir--Polder forces on the excited atoms inside the body. As an example, the resonant force between a plate consisting of a dilute gas o…
An exciting frontier in quantum information science is the realization and control of complex quantum many-body systems. Hybrid nanophotonic system with cold atoms has emerged as the paradigmatic platform for engineering long-range spin models from the bottom up, exploiting their modal geometry and group dispersion for tailored interactions. An important challenge is the physical limitation imposed by the photonic bath, constraining the types of local Hamiltonians that decompose the available physical models and restricting the spatial dimensions to that of the dielectric media. However, at th…
Any treatment of magnetic interactions between atoms, molecules and optical media must start at the form of the interaction energy. This forms the base on which predictions about any number of magnetic atom-light properties stands -- spontaneous decay rates and forces included. As is well-known, the Heaviside-Larmor duality symmetry of Maxwell's equations, where electric and magnetic quantities are exchanges, is broken by the usual form of the magnetic interaction energy. We argue that this symmetry can be restored by including general local-field effects, and that local fields should be treat…
We employ a recently developed quantization scheme for quasinormal modes (QNMs) to study a nonperturbative open cavity-QED system consisting of a hybrid metal-dielectric resonator coupled to a quantum emitter. This hybrid cavity system allows one to explore the complex coupling between a low $Q$ (quality factor) resonance and a high $Q$ resonance, manifesting in a striking Fano resonance, an effect that is not captured by traditional quantization schemes using normal modes or a Jaynes-Cummings (JC) type model. The QNM quantization approach rigorously includes dissipative coupling between the Q…
Several years ago Schwinger proposed a physical mechanism for sonoluminescence in terms of changes in the properties of the quantum-electrodynamic (QED) vacuum state. This mechanism is most often phrased in terms of changes in the Casimir Energy: changes in the distribution of zero-point energies and has recently been the subject of considerable controversy. The present paper further develops this quantum-vacuum approach to sonoluminescence: We calculate Bogolubov coefficients relating the QED vacuum states in the presence of a homogeneous medium of changing dielectric constant. In this way we…
Several years ago Schwinger proposed a physical mechanism for sonoluminescence in terms of photon production due to changes in the properties of the quantum-electrodynamic (QED) vacuum arising from a collapsing dielectric bubble. This mechanism can be re-phrased in terms of the Casimir effect and has recently been the subject of considerable controversy. The present paper probes Schwinger's suggestion in detail: Using the sudden approximation we calculate Bogolubov coefficients relating the QED vacuum in the presence of the expanded bubble to that in the presence of the collapsed bubble. In th…
Contemporary experiments in cavity quantum electrodynamics (cavity QED) with gas-phase neutral atoms rely increasingly on laser cooling and optical, magneto-optical or magnetostatic trapping methods to provide atomic localization with sub-micron uncertainty. Difficult to achieve in free space, this goal is further frustrated by atom-surface interactions if the desired atomic placement approaches within several hundred nanometers of a solid surface, as can be the case in setups incorporating monolithic dielectric optical resonators such as microspheres, microtoroids, microdisks or photonic crys…
