arXivDaily arXiv每日学术速递 周一至周五更新
arXiv physics/9710012physics.chem-phnucl-th
收藏

原子团簇振动激发的对称性适应方法

A symmetry adapted approach to vibrational excitations in atomic clusters

A. Frank, R. Lemus, R. Bijker, F. Perez-Bernal, J. M. Arias

摘要:

一种特别适合于描述分子中强非谐振动光谱的代数方法可能是研究Na $^+_n$团簇振动光谱的一个合适的框架,其中近平坦的势能面和出现的近躺异构体已被报道。作为一个例子,我们描述了该模型,并将其应用到被$_4$,H $_3^+$,被$_3$和Na $_3^+$集群。

英文摘要:

An algebraic method especially suited to describe strongly anharmonic vibrational spectra in molecules may be an appropriate framework to study vibrational spectra of Na$^+_n$ clusters, where nearly flat potential energy surfaces and the appearance of close lying isomers have been reported. As an illustration we describe the model and apply it to the Be$_4$, H$_3^+$, Be$_3$ and Na$_3^+$ clusters.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

↑