arXivDaily arXiv每日学术速递 周一至周五更新
arXiv physics/9611027physics.chem-ph
收藏

自适应代数模型在甲烷振动光谱中的应用

Application of a symmetry-adapted algebraic model to the vibratioinal spectrum of methane

R. Lemus, F. Perez-Bernal, A. Frank, R. Bijker, J. M. Arias

摘要:

在一个自适应代数模型的框架下研究了甲烷的伸缩振动和弯曲振动。该模型基于一维Morse势在$U(2)$代数上的实现。对于44个观测到的能量,我们得到了一个与r.m.s.偏差为1.16 cm $^{-1}$,比以前的代数计算精确一个数量级。

英文摘要:

The stretching and bending vibrations of methane are studied in the framework of a symmetry-adapted algebraic model. The model is based on the realization of the one-dimensional Morse potential in terms of a $U(2)$ algebra. For the 44 observed energies we obtain a fit with a r.m.s. deviation of 1.16 cm$^{-1}$ which is an order of magnitude more accurate than previous algebraic calculations.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

↑