We present lifetime measurements of the 7S1/2 level and the 6p manifold of rubidium. We use a timecorrelated single-photon counting technique on a sample of 85Rb atoms confined and cooled in a magneto-optic trap. The upper state of the 5P1/2 repumping transition serves as the resonant intermediate level for twophoton excitation of the 7s level. A probe laser provides the second step of the excitation, and we detect the decay of atomic fluorescence to the 5P3/2 level at 741 nm. The decay process feeds the 6p manifold that decays to the 5s ground state emitting UV photons. We measure lifetimes of 88.07 +- 0.40 and 120.7 +- 1.2 ns for the 7S1/2 level and 6p manifold, respectively; the hyperfine splitting of the 7S1/2 level is 282.6 +- 1.6 MHz. The agreement with theoretical calculations confirms the understanding of the wave functions involved and provides confidence on the possibility of extracting weak interaction constants from a parity nonconservation measurement.
We present a measurement of the hyperfine splitting of the 6S$_{1/2}$ excited level of rubidium using two photon absorption spectroscopy in a glass cell. The values we obtain for the magnetic dipole constant A are 239.18(03) MHz and 807.66(08) MHz for $^{85}$Rb and $^{87}$Rb, respectively. The combination of the magnetic moments of the two isotopes and our measurements show a hyperfine anomaly in this atomic excited state. The observed hyperfine anomaly difference has a value of $_{87}δ_{85}=-0.0036(2)$ due to the finite distribution of nuclear magnetization, the Bohr-Weisskopf effect.
Measurements of rubidium lifetime in a dark magneto-optical trap (DMOT) was performed at various populations of the bright and dark hyperfine states of the trapped atoms. The rubidium lifetime in the trap appeared to be shorter if the atom spent more time in the bright state. A simple explanation of this effect is based on the increase of the cross-section of rubidium collisions with the surrounding warm atoms upon rubidium electronic excitation.
We present a lifetime measurements of the 6s level of rubidium. We use a time-correlated single-photon counting technique on two different samples of rubidium atoms. A vapor cell with variable rubidium density and a sample of atoms confined and cooled in a magneto-optical trap. The 5P_{1/2} level serves as the resonant intermediate step for the two step excitation to the 6s level. We detect the decay of the 6s level through the cascade fluorescence of the 5P_{3/2} level at 780 nm. The two samples have different systematic effects, but we obtain consistent results that averaged give a lifetime …
Electric-dipole matrix elements for ns-n'p, nd-n'p, and 6d-4f transitions in Rb are calculated using a relativistic all-order method. A third-order calculation is also carried out for these matrix elements to evaluate the importance of the high-order many-body perturbation theory contributions. The all-order matrix elements are used to evaluate lifetimes of ns and np levels with n=6, 7, 8 and nd levels with n=4, 5, 6 for comparison with experiment and to provide benchmark values for these lifetimes. The dynamic polarizabilities are calculated for ns states of rubidium. The resulting lifetime a…
We present lifetime measurements of the $5D_{3/2}$ and $5D_{5/2}$ states of rubidium using the time correlated single photon counting method. We perform the experiment in a magneto-optical trap of $^{87}$Rb atoms using a two-step excitation with the trap laser at 780 nm as the first step. We record the 761.9 nm fluorescence from the decay of the $5D_{3/2}$ state to the $5P_{1/2}$ state, and measure the lifetime of the $5D_{3/2}$ state $τ=246.3(1.6)$ ns. We record the 420.2 nm fluorescence from the cascade decay of the $5D_{5/2}$ state to the $5S_{1/2}$ state through the $6P_{3/2}$ state, and e…
Here we report on measurements of the absolute absorption and dispersion properties of an isotopically pure 87Rb vapour for magnetic fields up to and including 0.6 T. We discuss the various regimes that arise when the hyperfine and Zeeman interactions have different magnitudes, and show that we enter the hyperfine Paschen- Back regime for fields greater than 0.33 T on the Rb D2 line. The experiment uses a compact 1 mm3 microfabricated vapour cell that makes it easy to maintain a uniform and large magnetic field with a small and inexpensive magnet. We find excellent agreement between the experi…
We studied magneto-optical resonances caused by excited-state level crossings in a nonzero magnetic field. Experimental measurements were performed on the transitions of the $D_2$ line of rubidium. These measured signals were described by a theoretical model that takes into account all neighboring hyperfine transitions, the mixing of magnetic sublevels in an external magnetic field, the coherence properties of the exciting laser radiation, and the Doppler effect. Good agreement between the experimental measurements and the theoretical model could be achieved over a wide range of laser power de…
We present an experimental scheme that produces Doppler-free spectra of the $5s \to 6p $ second resonance transition in atomic rubidium. The experiment uses the saturation of the cascade fluorescence that occurs when thermal rubidium atoms interact with two counterpropagating $420 $ nm laser beams of comparable intensity. Part of the excited atomic population goes through the $5p_{3/2}$ level which then decays by emission of $780$ nm photons. Narrow dips appear in this otherwise broad $780$ nm fluorescence, which allows resolution of the $6p_{3/2}$ hyperfine structure. A rate equation model is…
We studied alignment-to-orientation conversion caused by excited-state level crossings in a nonzero magnetic field of both atomic rubidium isotopes. Experimental measurements were performed on the transitions of the $D_2$ line of rubidium. These measured signals were described by a theoretical model that takes into account all neighboring hyperfine transitions, the mixing of magnetic sublevels in an external magnetic field, the coherence properties of the exciting laser radiation, and the Doppler effect. In the experiments laser induced fluorescence (LIF) components were observed at linearly p…
I searched for the ground state 6.8 and 9.2 GHz hyperfine transitions of rubidium and cesium toward M- and L-dwarfs that show Rb and Cs optical resonance lines. The optical lines can pump the hyperfine transitions, potentially forming masers. These spin-flip transitions of Rb and Cs are the principal transitions used in atomic clocks (the $^{133}$Cs hyperfine transition defines the second). If they are detected in stellar atmospheres, these transitions would provide exceptionally precise clocks that can be used as accelerometers, as exoplanet detectors, as probes of the predictions of general …
We report on measurements on the 5S-6P rubidium transition frequencies for rubidium isotopes with an absolute uncertainty of better than \SI{450}{kHz} for the 5S $\rightarrow$ 6P$_{1/2}$ transition and \SI{20}{kHz} for the 5S $\rightarrow$ 6P$_{3/2}$ transition, achieved by saturation absorption spectroscopy. From the results we derive the hyperfine splitting with an accuracy of \SI{460}{kHz} and \SI{30}{kHz}, respectively. We also verify the literature values for the isotope shifts as well as magnetic dipole constant and the electric quadrupole constant.
We study the Doppler-broadened absorption of a weak monochromatic probe beam in a thermal rubidium vapour cell on the D lines. A detailed model of the susceptibility is developed which takes into account the absolute linestrengths of the allowed electric dipole transitions and the motion of the atoms parallel to the probe beam. All transitions from both hyperfine levels of the ground term of both isotopes are incorporated. The absorption and refractive index as a function of frequency are expressed in terms of the complementary error function. The absolute absorption profiles are compared with…
We demonstrate subpicosecond-time-scale population transfer between the pair of hyperfine ground states of atomic rubidium using a single laser-pulse. Our scheme utilizes the geometric and dynamic phases induced during Rabi oscillation through the fine-structure excited state in order to construct an $X$ rotation gate for the hyperfine-state qubit system. Experiment performed with a femtosecond laser and cold rubidium atoms, in a magneto-optical trap, shows over 98\% maximal population transfer between the clock states.
We have measured the radiative lifetimes of ns, np and nd Rydberg states of rubidium in the range 28 < n < 45. To enable long-lived states to be measured, our experiment uses slow-moving Rb atoms in a magneto-optical trap (MOT). Two experimental techniques have been adopted to reduce random and systematic errors. First, a narrow-bandwidth pulsed laser is used to excite the target Rydberg state, resulting in minimal shot-to-shot variation in the initial state population. Second, we monitor the target state population as a function of time delay from the laser pulse using a short-duration, milli…
A data acquisition system is described that is designed to stabilize cooling and probe rates to maximize detection sensitivity and minimize possible systematic errors due to correlations between drifting experimental conditions and varying drive parameters. Experimental parameters that affect the Yb171 5D3/2 hyperfine state preparation and detection efficiency are characterized and optimized. A set of wait times for optimal sampling of the D3/2(F=2) lifetime is chosen and used to measure that lifetime with high statistical sensitivity. A systematic variation in this lifetime seems to be appare…
In this paper we report the development of the design verification model (DVM) of Rb atomic frequency standard. The Rb atomic frequency standard or clock has two distinct parts. One is the Physics Package where the hyperfine transitions produce the clock signal in the integrated filter cell configuration and the other is the electronic circuits which generate the resonant microwave hyperfine frequency, phase modulator and phase sensitive detector. In this paper the details of the Rb Physics package and the electronic circuits are given. The effect of putting the photo detector inside the micro…
The ground state hyperfine splitting values and the transition probabilities between the hyperfine structure components of high Z lithiumlike ions are calculated in the range $Z=49-83$. The relativistic, nuclear, QED and interelectronic interaction corrections are taken into account. It is found that the Bohr-Weisskopf effect can be eliminated in a combination of the hyperfine splitting values of the hydrogenlike and lithiumlike ions of an isotope. This gives a possibility for testing the QED effects in a combination of the strong electric and magnetic fields of the heavy nucleus. Using the ex…
This work presents accurate {\it ab initio} determination of the magnetic dipole (M1) and electric quadrupole (E2) hyperfine structure constants for the ground and a few low-lying excited states in $^{67}$Zn$^{+}$, which is one of the interesting systems in fundamental physics. The coupled-cluster (CC) theory within the relativistic framework has been used here in this calculations. Long standing demands for a relativistic and highly correlated calculations like CC can be able to resolve the disagreements among the lifetime estimations reported previously for a few low-lying states of Zn$^{+}$…
In the framework of the multiconfiguration Dirac-Hartree-Fock method, we investigate the transition properties of four excited states in the $2p^53s$ configuration of neutral neon. The electron correlation effects are taken into account systematically by using the active space approach. The effect of higher-order correlation on fine structures is shown. We also study the influence of the Breit interaction and find that it reduces the oscillator strength of the $^3P^o_1 - ^1S_0$ transition by 17%. It turns out that the inclusion of the Breit interaction is essential even for such a light atomic…
We observe a hyperfine anomaly in the measurement of the hyperfine splitting of the 6S_{1/2} excited level in rubidium. We perform two step spectroscopy using the 5S_{1/2}->5P_{1/2}->6S_{1/2} excitation sequence. We measure the splitting of the 6S1/2 level and obtain for the magnetic dipole constants of ^{85}Rb and ^{87}Rb A = 239.18(4) MHz and A=807.66(8) MHz, respectively. The hyperfine anomaly difference of_{87}delta_{85}=-0.0036(2) comes from the Bohr Weisskopf effect: a correction to the point interaction between the finite nuclear magnetization and the electrons, and agrees with that obt…
Parity- and time-reversal-symmetry violating interaction constants required for the interpretation of a recent measurement (arXiv:1704.07928 [physics.atom-ph]) of corresponding symmetry violations in the $Ω=1$ (${^3Δ}_1$) science state of the HfF$^+$ molecular ion are reported. Using a relativistic four-component all-electron multi-reference configuration interaction model the nucleon-electron scalar-pseudoscalar interaction constant is determined as $W_S = 20.0$ [kHz]. An updated result for the electron electric-dipole-moment effective electric field of $|E_{\text{eff}}| = 22.7 \left[\frac{\r…
Experiments involving ultracold molecules require sufficiently long lifetimes, which can be very short for excited rovibrational states in the molecular potentials. For alkali atoms such as rubidium, a lowest rovibrational molecular state can both be found in the electronic singlet and triplet configurations. The molecular singlet ground state is absolutely stable. However, the lowest triplet state can decay to a deeper bound singlet molecule due to a radiative decay mechanism that involves the interatomic spin-orbit interaction. We investigate this mechanism, and find the lifetime of rubidium…
Energies of np (n=6-9), ns (n=7-9), nd (n=6-8), and nf (n=5-6) states in Tl I and Pb II are obtained using relativistic many-body perturbation theory. Reduced matrix elements, oscillator strengths, transition rates, and lifetimes are determined for the 72 possible electric-dipole transitions. Electric-quadrupole and magnetic-dipole matrix elements are evaluated to obtain np(3/2) - mp(1/2) (n,m=6,7) transition rates. Hyperfine constants A are evaluated for a number of states in 205Tl. First-, second-, third-, and all-order corrections to the energies and matrix elements and first- and second-or…
Nonlinear magneto-optical resonances on the hyperfine transitions belonging to the D2 line of rubidium were changed from bright to dark resonances by changing the laser power density of the single exciting laser field or by changing the vapor temperature in the cell. In one set of experiments atoms were excited by linearly polarized light from an extended cavity diode laser with polarization vector perpendicular to the light's propagation direction and magnetic field, and laser induced fluorescence (LIF) was observed along the direction of the magnetic field, which was scanned. A low-contrast …
We use six years of accurate hyperfine frequency comparison data of the dual rubidium and caesium cold atom fountain FO2 at LNE-SYRTE to search for a massive scalar dark matter candidate. Such a scalar field can induce harmonic variations of the fine structure constant, of the mass of fermions and of the quantum chromodynamic mass scale, which will directly impact the rubidium/caesium hyperfine transition frequency ratio. We find no signal consistent with a scalar dark matter candidate but provide improved constraints on the coupling of the putative scalar field to standard matter. Our limits …
We implement a 4-level semiclassical model of a single pulse interacting with the hyperfine structure in ultracold rubidium aimed at control of population dynamics and quantum state preparation. We discuss a method based on pulse chirping to achieve population inversion between hyperfine states of the 5S shell. The results may prove useful for quantum operations with ultracold atoms.
Experimental signals of non-linear magneto-optical resonances at D1 excitation of natural rubidium in a vapor cell have been obtained and described with experimental accuracy by a detailed theoretical model based on the optical Bloch equations. The D1 transition of rubidium is a challenging system to analyze theoretically because it contains transitions that are only partially resolved under Doppler broadening. The theoretical model took into account all nearby transitions, the coherence properties of the exciting laser radiation, and the mixing of magnetic sublevels in an external magnetic fi…
Energy levels of 30 low-lying states of Lu2+ and allowed electric-dipole matrix elements between these states are evaluated using a relativistic all-order method in which all single, double and partial triple excitations of Dirac-Fock wave functions are included to all orders of perturbation theory. Matrix elements are critically evaluated for their accuracy and recommended values of the matrix elements are given together with uncertainty estimates. Line strengths, transition rates and lifetimes of the metastable 5d(3/2) and 5d(5/2) states are calculated. Recommended values are given for stati…
We have investigated energies, magnetic dipole hyperfine structure constants ($A_{hyf}$) and electric dipole (E1) matrix elements of a number of low-lying states of the triply ionized tin (Sn$^{3+}$) by employing relativistic coupled-cluster theory. Contributions from the Breit interaction and lower-order quantum electrodynamics (QED) effects in determination of above quantities are also given explicitly. These higher-order relativistic effects are found to be important for accurate evaluation of energies, while QED contributions are seen to be contributing significantly to the determination o…
Direct evidence of excitation of the 5p3/2 -> 6p3/2 electric dipole forbidden transition in atomic rubidium is presented. The experiments were performed in a room temperature rubidium cell with continuous wave extended cavity diode lasers. Optical-optical double resonance spectroscopy with counterpropagating beams allows the detection of the non-dipole transition free of Doppler broadening. The 5p3/2 state is prepared by excitation with a laser locked to the maximum F cyclic transition of the D2 line, and the forbidden transition is produced by excitation with a 911 nm laser. Production of the…
Hyperfine quenching rates of the lowest-energy metastable $^3P_0$ and $^3P_2$ states of Mg, Ca, Sr, and Yb atoms are computed. The calculations are carried out using ab initio relativistic many-body methods. The computed lifetimes may be useful for designing novel ultra-precise optical clocks and trapping experiments with the $3P_2$ fermionic isotopes. The resulting natural widths of the $^3P_0 -> ^1S_0$ clock transition are 0.44 mHz for $^{25}$Mg, 2.2 mHz for $^{43}$Ca, 7.6 mHz for $^{87}$Sr, 43.5 mHz for $^{171}$Yb, and 38.5 mHz for $^{173}$Yb. Compared to the bosonic isotopes, the lifetime …
We report on a precision measurement of the $D$ line tune-out wavelength of $^{87}$Rubidium in the hyperfine ground state $|F=1, m_F=0,\pm1 \rangle$ manifold at 790 nm, where the scalar ac Stark shifts of the $D_1$ and the $D_2$ lines cancel. This wavelength is sensitive to usually neglected contributions from vector and tensor ac Stark shifts, transitions to higher principle quantum numbers, and core electrons. The ac Stark shift is probed by Kapitza-Dirac scattering of a Rubidium Bose-Einstein condensate in a one-dimensional optical lattice in free space and controlled magnetic environment. …
In this paper, we describe two complementary non-linear spectroscopy methods which both allow to achieve Doppler-free spectra of atomic gases. First, saturated absorption spectroscopy is used to investigate the structure of the $5{\rm S}_{1/2}\to 5{\rm P}_{3/2}$ transition in rubidium. Using a slightly modified experimental setup, Doppler-free two-photon absorption spectroscopy is then performed on the $5{\rm S}_{1/2}\to 5{\rm D}_{5/2}$ transition in rubidium, leading to accurate measurements of the hyperfine structure of the $5{\rm D}_{5/2}$ energy level. In addition, electric dipole selectio…
We present direct measurements of the hyperfine splitting of Rydberg states in rubidium 87 using Electromagnetically Induced Transparency (EIT) spectroscopy in a room-temperature vapour cell. With this method, and in spite of Doppler-broadening, line-widths of 3.7 MHz FWHM, i.e. significantly below the intermediate state natural linewidth are reached. This allows resolving hyperfine splittings for Rydberg s-states with n=20...24. With this method we are able to determine Rydberg state hyperfine splittings with an accuracy of approximately 100 kHz. Ultimately our method allows accuracies of ord…
The exquisite properties of Rydberg levels make them particularly appealing for emerging quantum technologies. The lifetime of low-angular-momentum laser-accessible levels is however limited to a few $100\,μ\mathrm{s}$ by optical transitions and microwave blackbody radiation (BBR) induced transfers at room temperature. A considerable improvement would be obtained with the few $10\,\mathrm{ms}$ lifetime of circular Rydberg levels in a cryogenic environment reducing the BBR temperature. We demonstrate the preparation of long-lived circular Rydberg levels of laser-cooled Rubidium atoms in a cryos…
In this paper, we used the multiconfiguration Dirac-Fock method to compute with high precision the influence of the hyperfine interaction on the $[Ar]3d^{10} 4s4p ^3P_0$ level lifetime in Zn-like ions for stable and some quasi-stable isotopes of nonzero nuclear spin between Z=30 and Z=92. The influence of this interaction on the $[Ar]3d^{10} 4s4p ^3P_1 - [Ar]3d^{10} 4s4p ^3P_0$ separation energy is also calculated for the same ions.
The multiconfiguration Dirac-Hartree-Fock (MCDHF) model has been employed to calculate the transition rates between the nine lowest levels of radium. The dominant rates were then used to evaluate the radiative lifetimes. The decay of the metastable $ 7s7p ^3 P_0 $ state through 2-photon E1M1 and hyperfine induced channels is also studied.
We propose and demonstrate pump-probe spectroscopy of rubidium absorption which reveals the sub-Doppler hyperfine structure of the $^{5}$S$_{1/2} \leftrightarrow$ $^{5}$P$_{3/2}$ (D2) transitions. The counter propagating pump and probe lasers are independently tunable in frequency, with the probe operating at the single-photon-level. The two-dimensional spectrum measured as the laser frequencies are scanned shows fluorescence, Doppler-broadened absorption dips and sub-Doppler features. The detuning between the pump and probe lasers allows compensation of the Doppler shift for all atomic veloci…
The decay of Rydberg-atom-ion molecules (RAIMs) due to non-adiabatic couplings between electronic potential energy surfaces is investigated. We employ the Born-Huang representation and perform numerical simulations using a Crank-Nicolson algorithm. The non-adiabatic lifetimes of rubidium RAIMs for the lowest ten vibrational states, $ν$, are computed for selected Rydberg principal quantum numbers, $n$. The non-adiabatic lifetimes are found to generally exceed the radiative Rydberg-atom lifetimes. We observe and explain a trend of the lifetimes as a function of $ν$ and $n$, and attribute irregul…
A systematic study of Ca+ atomic properties is carried out using high-precision relativistic all-order method where all single, double, and partial triple excitations of the Dirac-Fock wave functions are included to all orders of perturbation theory. Reduced matrix elements, oscillator strengths, transition rates, and lifetimes are determined for the levels up to n = 7. Recommended values and estimates of their uncertainties are provided for a large number of electric-dipole transitions. Electric-dipole scalar polarizabilities for the 5s, 6s, 7s, 8s, 4p, 5p, 3d, and 4d states and tensor polari…
Energies of ns[1/2] (n= 6-9), np[j] (n = 6-8), nd[j] (n= 6-7), and 5f[j] states in neutral Au and Au-like ions with nuclear charges Z = 80 - 83 are calculated using relativistic many-body perturbation theory. Reduced matrix elements, oscillator strengths, transition rates and lifetimes are determined for the 30 possible nl[j]-n'l'[j'] electric-dipole transitions. Results for a limited number states ns[1/2], np[j] (n= 6-7) and 6d[j] are obtained in the relativistic single-double (SD) approximation, where single and double excitations of Dirac-Fock wave functions are included to all orders in pe…
Energy levels, wavelengths, lifetimes and hyperfine structure constants for the isotopes of the first and second spectra of radium, Ra I and Ra II have been compiled. Wavelengths and wave numbers are tabulated for 226Ra and for other Ra isotopes. Isotope shifts and hyperfine structure constants of even and odd-A isotopes of neutral radium atom and singly ionized radium are included. Experimental lifetimes of the states for both neutral and ionic Ra are also added, where available. The information is beneficial for present and future experiments aimed at different physics motivations using neut…
We describe a method for determining the radiative decay properties of a molecule by studying the saturation of laser-induced fluorescence and the associated power broadening of spectral lines. The fluorescence saturates because the molecules decay to states that are not resonant with the laser. The amplitudes and widths of two hyperfine components of a spectral line are measured over a range of laser intensities and the results compared to a model of the laser-molecule interaction. Using this method we measure the lifetime of the A(v'=0) state of CaF to be tau=19.2 \pm 0.7 ns, and the Franck-…
We demonstrate low-loss measurement of the hyperfine ground state of Rubidium atoms in a dipole trap array of five sites by state dependent fluorescence detection. The presence of atoms and their internal states are minimally altered by utilizing circularly polarized probe light and a strictly controlled quantization axis. We achieve mean state detection fidelity of \(97\%\) without correcting for imperfect state preparation or background losses, and \(98.7\%\) when corrected. After state detection and correction for background losses, the probability of atom loss due to the state measurement …
The photorecombination spectrum of 48Ti18+ was measured employing the merged electron-ion beams technique at a heavy-ion storage ring. The experimental electron-ion collision energy range 0-80 eV comprises all dielectronic recombination (DR) resonances associated with 2s->2p (Delta N =0) core excitations as well as trielectronic recombination (TR) resonances that involve 2s2->2p2 core double-excitations. At low collision energies DR resonances are observed that are associated with the excitation of metastable 2s2p 3P0 primary ions with nearly infinite lifetime for the isotope 48Ti with zero nu…
We report on spiking dynamics of frequency up-converted emission at 420 nm generated on the 6P3/2-5S1/2 transition in Rb vapour two-photon excited to the 5D5/2 level with laser light at 780 and 776 nm. The spike duration is less than the natural lifetime of any excited level involved in the interaction with both continuous and pulsed pump radiation. The spikes at 420 nm are attributed to temporal properties of the directional emission at 5.23 μm generated on the population inverted 5D5/2-6P3/2 transition. A link between the spiking regime and cooperative effects is discussed. We suggest that t…
Employing two state-of-the-art methods, multiconfiguration Dirac--Hartree--Fock and second-order many-body perturbation theory, highly accurate calculations are performed for the lowest 272 fine-structure levels arising from the $2s^{2} 2p^{3}$, $2s 2p^{4}$, $2p^{5}$, $2s^{2} 2p^{2} 3l$~($l=s,p,d$), $2s 2p^{3}3l$ ($l=s,p,d$), and $2p^{4} 3l$ ($l=s,p,d$) configurations in nitrogen-like Ge XXVI. Complete and consistent atomic data, including excitation energies, lifetimes, wavelengths, hyperfine structures, Landé $g_{J}$-factors, and E1, E2, M1, M2 line strengths, oscillator strengths, and trans…
We consider the hyperfine structure, the atomic spectrum and the decay channels of the bound mu+ mu- system (dimuonium). The annihilation lifetimes of low-lying atomic states of the system lie in the nanosecond range range. The decay rates could be measured by detection of the decay products (high energy photons or electron-positron pairs). The hyperfine structure splitting of the dimuonic system and its decay rate are influenced by electronic vacuum polarization effects in the far time-like asymptotic region. This constitutes a previously unexplored kinematic regime. We evaluate next--to-lead…
We investigate cross-relaxation interactions between Tm and Al in Tm:YAG using two optical methods: spectral holeburning and stimulated echoes. These interactions lead to a reduction in the hyperfine lifetime at magnetic fields that bring the Tm hyperfine transition into resonance with an Al transition. We develop models for measured echo decay curves and holeburning spectra near a resonance, which are used to show that the Tm-Al interaction has a resonance width of 10~kHz and reduces the hyperfine lifetime to 0.5 ms. The antihole structure is consistent with an interaction dominated by the Al…
This work presents accurate ab initio determination of the hyperfine splitting for the ground state and few low-lying excited states of 113Cd+; important candidates for the frequency standard in the microwave region, using coupled-cluster theory (CC) in the relativistic framework. The calculated hyperfine splitting are well in agreement with recent experimental results. We have also carried out the lifetimes of the 5p2P1=2 and 5p2P3=2 states, which are in well agreement with recent experimental result (Moehring et al., PRA 73 023413, 2006). The roles of different electron correlation effects i…
We investigate the resonant motion of neutral spin-1/2-fermions in a magnetic guide. A wealth of unitary and anti-unitary symmetries is revealed in particular giving rise to a two-fold degeneracy of the energy levels. To compute the energies and decay widths of a large number of resonances the complex scaling method is employed. We discuss the dependence of the lifetimes on the angular momentum of the resonance states. In this context the existence of so-called quasi-bound states is shown. In order to approximately calculate the resonance energies of such states a radial Schrödinger equation i…
This report summarizes laboratory measurements of atomic wavelengths, energy levels, hyperfine and isotope structure, energy level lifetimes, and oscillator strengths. Theoretical calculations of lifetimes and oscillator strengths are also included. The bibliography is limited to species of astrophysical interest. Compilations of atomic data and internet databases are also included. Papers are listed in the bibliography in alphabetical order, with a reference number in the text. Comprehensive lists of references for atomic spectra can be found in the NIST Atomic Spectra Bibliographic Databases…
Molecular hydrogen ions in weakly bound states close to the first dissociation threshold are attractive quantum sensors for measuring the proton-to-electron mass ratio and hyperfine-induced ortho-para mixing. The experimental accuracy of previous spectroscopic studies relying on fast ion beams could be improved by using state-of-the-art ion trap setups. With the electric dipole moment vanishing in H$_2^+$ and preventing fast spontaneous emission, radiative lifetimes of the order of weeks are found. We include the effect of black-body radiation that can lead to photodissociation and rovibronic …
Practical implementation of quantum networks are likely to interface different types of quantum systems. When photonic interconnects link the systems together, they must preserve the quantum properties of the photon. These light-matter interfaces may be used as necessary communication tools, such as to synchronise photon arrival times for entanglement distribution. Trapped ions are strong candidates for communication nodes owing to their long qubit life time (C. Langer, et al., PRL., 238, 060502, (2005)) and high fidelity ion-photon entanglement (A. Stute, et al., Nat., 485, 482, (2012)), whil…
