We use a diode laser locked to a Rb transition as the frequency reference along with a scanning Michelson interferometer to make precise measurements on the $D_1$ and $D_2$ lines of potassium. The Rb reference frequency is known with sub-MHz accuracy. We obtain the following values for the energy levels: 12 985.169 60(13)(15) cm$^{-1}$ for the $4P_{1/2}$ state ($D_1$ line); 13 042.875 95(14)(15) cm$^{-1}$ for the $4P_{3/2}$ state ($D_2$ line); and 57.706 35(19)(15) cm$^{-1}$ for the $4P_{3/2}-4P_{1/2}$ fine-structure interval. The leading source of systematic error cancels in the determination of the interval. The errors represent about an order of magnitude improvement over tabulated values.
We report a precise measurement of the hyperfine interval in the ${2P}_{1/2}$ state of $^{7}$Li. The transition from the ground state ($D_1$ line) is accessed using a diode laser and the technique of saturated-absorption spectroscopy in hot Li vapor. The interval is measured by locking an acousto-optic modulator to the frequency difference between the two hyperfine peaks. The measured interval of 92.040(6)~MHz is consistent with an earlier measurement reported by us using an atomic-beam spectrometer [Das and Natarajan, J.\ Phys.\ B {\bf 41}, 035001 (2008)]. The interval yields the magnetic dip…
We demonstrate a technique for directly measuring the fine-structure interval in alkali atoms using two frequency-stabilized diode lasers. Each laser has a linewidth of order 1 MHz and precise tunability: one laser is tuned to a hyperfine transition in the D_1 line, and the other laser to a hyperfine transition in the D_2 line. The outputs of the lasers are fed into a scanning Michelson interferometer that measures the ratio of their wavelengths accurately. To illustrate the technique, we measure the fine-structure interval in Rb, and obtain a value of 237.6000(3)(5) cm^-1 for the hyperfine-fr…
We demonstrate a technique for precisely measuring hyperfine intervals in alkali atoms. The atoms form a three-level $Λ$ system in the presence of a strong control laser and a weak probe laser. The dressed states created by the control laser show significant linewidth reduction. We have developed a technique for Doppler-free spectroscopy that enables the separation between the dressed states to be measured with high accuracy even in room-temperature atoms. The states go through an avoided crossing as the detuning of the control laser is changed from positive to negative. By studying the separa…
We report a value for the $D_2$-line frequency of $^{39}$K with 0.25 ppb uncertainty. The frequency is measured using an evacuated ring-cavity resonator whose length is calibrated against a reference laser. The $D_2$ line presents a problem in identifying the line center because the closely-spaced energy levels of the excited state are not resolved. We use computer modelling of the measured spectrum to extract the line center and obtain a value of 391 015 578.040(75) MHz. In conjunction with our previous measurement of the $D_1$ line, we determine the fine-structure interval in the $4P$ state …
Configuration interaction in many-electron atoms may cause anomalies in the fine structure which make the intervals small and very sensitive to variation of the fine structure constant. Repeated precision measurements of these intervals over long period of time can put strong constrain on possible time variation of the fine structure constant. We consider the $5p^4 \ ^3$P$_{2,1,0}$ fine structure multiplet in the ground state of neutral tellurium as an example. Here the effect of change of the fine structure constant is enhanced about one hundred times in the relative change of the small energ…
We report on a theoretical calculation and a new experimental determination of the 1s3p ^3P_J fine structure intervals in atomic ^4He. The values from the theoretical calculation of 8113.730(6) MHz and 658.801(6) MHz for the nu_{01} and nu_{12} intervals, respectively, disagree significantly with previous experimental results. However, the new laser spectroscopic measurement reported here yields values of 8113.714(28) MHz and 658.810(18) MHz for these intervals. These results show an excellent agreement with the theoretical values and resolve the apparent discrepancy between theory and experim…
In order to explain discrepancies between theoretical predictions and experimental data for the helium fine structure, we check and recalculate all theoretical contributions up to orders mα^7 and m^2/Mα^6. The previous result for the mα^7 correction is improved by a much more accurate calculation of relativistic corrections to the Bethe logarithm. The theoretical values of the 2^3P_0-2^3P_1 and 2^3P_1-2^3P_2 fine structure intervals in helium are, correspondingly, ν_{01} = 29616946.2(1.6) kHz and ν_{12} = 2291177.3(1.6) kHz, with the uncertanties being due to higher-order effects. For the smal…
Large-scale {\em ab initio} QED calculations are performed for the $2p_{3/2}$--$2p_{1/2}$ fine-structure interval of Li-like ions with nuclear charges $Z = 5\,$--$\,92$. Improved theoretical predictions are obtained by combining together two complementary theoretical methods, namely, the approach that accounts for all orders in the binding nuclear strength and the nonrelativistic QED approach that accounts for all orders in the nonrelativistic electron-electron interaction. The resulting unified approach provides theoretical predictions which are more accurate than the available experimental r…
Calculational results are presented for the fine-structure splitting of the 2^3P state of helium and helium-like ions with the nuclear charge Z up to 10. Theoretical predictions are in agreement with the latest experimental results for the helium fine-structure intervals as well as with the most of the experimental data available for light helium-like ions. Comparing the theoretical value of the 2^3P_0-2^3P_1 interval in helium with the experimental result [T. Zelevinsky et al. Phys. Rev. Lett. 95, 203001 (2005)], we determine the value of the fine-structure constant αwith an accuracy of 31 pa…
We have applied an optical method to the measurement of the 2S hyperfine interval in atomic hydrogen. The interval has been measured by means of two-photon spectroscopy of the 1S-2S transition on a hydrogen atomic beam shielded from external magnetic fields. The measured value of the 2S hyperfine interval is equal to 177 556 860(15) Hz and represents the most precise measurement of this interval to date. The theoretical evaluation of the specific combination of 1S and 2S hyperfine intervals D_21 is in moderately good agreement with the value for D_21 deduced from our measurement.
We use Bloch oscillations to transfer coherently many photon momenta to atoms. Then we can measure accurately the ratio h/m_Rb and deduce the fine structure constant alpha. The velocity variation due to the Bloch oscillations is measured thanks to Raman transitions. In a first experiment, two Raman $π$ pulses are used to select and measure a very narrow velocity class. This method yields to a value of the fine structure constant alpha^{-1}= 137.035 998 84 (91) with a relative uncertainty of about 6.6 ppb. More recently we use an atomic interferometer consisting in two pairs of pi/2 pulses. We …
We demonstrate a technique to measure hyperfine structure using a frequency-stabilized diode laser and an acousto-optic modulator locked to the frequency difference between two hyperfine peaks. We use this technique to measure hyperfine intervals in the $5P_{3/2}$ state of $^{85}$Rb and obtain a precision of 20 kHz. We extract values for the magnetic-dipole coupling constant $A=25.038(5)$ MHz and the electric-quadrupole coupling constant $B=26.011(22)$ MHz. These values are a significant improvement over previous results.
We show that the relative effect of variation of the fine structure constant in microwave transitions between very close and narrow rotational-hyperfine levels may be enhanced 2-3 orders of magnitude in diatomic molecules like LaS, LaO, LuS, YbF, etc. The enhancement is a result of cancellation between the hyperfine and rotational intervals.
Sensitivity to temporal variation of the fundamental constants may be strongly enhanced in transitions between narrow close levels of different nature. This enhancement may be realized in a large number of molecules due to cancelation between the ground state fine structure omega_f and vibrational interval omega_v (omega=omega_f - n omega_v is close to zero, delta omega/omega= K (2 delta alpha/alpha +0.5 delta mu/mu), K >>1, mu=m_p/m_e). The intervals between the levels are conveniently located in microwave frequency range and the level widths are very small. Required accuracy of the shift mea…
Positronium is an ideal system for the research of the QED, especially for the QED in bound state. The discrepancy of 3.9σis found recently between the measured HFS values and the QED prediction ($O(α^3)$). It might be due to the contribution of the unknown new physics or the systematic problems in the previous all measurements. We propose new method to measure HFS precisely and directly. A gyrotron, a novel sub-THz light source is used with a high-finesse Fabry-Pérot cavity to obtain enough radiation power at 203 GHz. The present status of the optimization studies and current design of the ex…
The $1\mathrm{s}n\mathrm{p}\,^3\mathrm{P}_J$ fine structure of high Rydberg states in helium has been measured by microwave spectroscopy of single-photon transitions from $1\mathrm{s}n\mathrm{s}\,^3\mathrm{S}_1$ levels in pulsed supersonic beams. For states with principal quantum numbers in the range from $n=34$ to 36, the $J = 0 \rightarrow 2$ and $J = 1 \rightarrow 2$ fine structure intervals were both observed. For values of $n$ between 45 and 51 only the larger $J = 0 \rightarrow 2$ interval was resolved. The experimental results are in good agreement with theoretical predictions. Detailed…
We demonstrate a new technique for measuring the absolute frequencies of atomic transitions. The technique uses a ring-cavity resonator whose length is calibrated using a reference laser locked to the D_2 line in {87}Rb. The frequency of this line is known to be 384 230 484.468(10) MHz. Using a second laser locked to the D_1 line of Rb, we measure the frequencies of various hyperfine transitions in the D_1 and D_2 lines with a precision of 30 kHz. We obtain the following values: 120.687(17) MHz and 406.520(25) MHz for the 5P_{1/2} hyperfine constant A in {85}Rb and {87}Rb; 377 107 385.623(50) …
For decades, improved theory and experiment of the $n=2$ $^3$P fine structure of helium have allowed for increasingly-precise tests of quantum electrodynamics, determinations of the fine-structure constant $α$, and limitations on possible beyond-the-Standard-Model physics. Here we use the new frequency-offset separated-oscillatory-fields (FOSOF) technique to measure the $2^3$P$_2\!\!\to\!2^3$P$_1$ interval. Our result of $2\,291\,176\,590(25)$~Hz represents a major step forward in precision for helium fine-structure measurements.
Precise numerical calculation of radiofrequency intervals between hyperfine sublevels of the $(37,35)$ state of the antiprotonic helium-4 atom is presented. Theoretical consideration includes the QED corrections of order $mα^6$ to the electron spin-orbit interaction. The effective Hamiltonian is derived using the formalism of the nonrelativistic quantum electrodynamics (NRQED).
A velocity-selective spectroscopy technique for studying the spectra from hot Rydberg gases is presented. This method provides high-resolution measurement of the spectrum interval. Based on this method, the velocity-selective hyperfine splitting of intermediate states is measured, as well as the Doppler-free fine-structure splitting of the Rydberg states via two-photon Rydberg excitation in a room-temperature 133Cs vapor cell. The experiment data and theoretical predictions show excellent agreement.
Corrections to energy levels in light muonic atoms are investigated in order $α^2(Zα)^4m$. We pay attention to corrections which are specific for muonic atoms and include the electron vacuum polarization loop. In particular, we calculate relativistic and relativistic-recoil two-loop electron vacuum polarization contributions. The results are obtained for the levels with $n=1,2$ and in particular for the Lamb shift ($2p_{1/2}-2s_{1/2}$) and fine-structure intervals ($2p_{3/2}-2p_{1/2}$) in muonic hydrogen, deuterium, and muonic helium ions.
The fine structure constant $α$ has a particular status in physics. Its precise determination is required to test the quantum electrodynamics (QED) theory. The constant $α$ is also a keystone for the determination of other fundamental physical constants, especially the ones involved in the framework of the future International System of units. This paper presents Paris experiment, where the fine structure constant is determined by measuring the recoil velocity of a rubidium atom when it absorbs a photon. The impact of the recent improvement of QED calculations of the electron moment anomaly an…
