The axisymmetric deformation and motion of interacting droplets in an imposed temperature gradient is considered using boundary-integral techniques for slow viscous motion. Results showing temporal drop motion, deformations and separation are presented for equal-viscosity fluids. The focus is on cases when the drops are of equal radii or when the smaller drop trails behind the larger drop. For equal-size drops, our analysis shows that the motion of a leading drop is retarded while the motion of the trailing one is enchanced compared to the undeformable case. The distance between the centers of equal-sized deformable drops decreases with time. When a small drop follows a large one, two patterns of behavior may exist. For moderate or large initial separation the drops separate. However, if the initial separation is small there is a transient period in which the separation distance initially decreases and only afterwards the drops separate. This behavior stems from the multiple time scales that exist in the system.
The swimming of a deformable planar slab in a viscous incompressible fluid is studied on the basis of the Navier-Stokes equations. A continuum of plane wave displacements, symmetric on both sides of the slab and characterized by a polarization angle, allows optimization of the swimming efficiency with respect to polarization. The mean swimming velocity and mean rate of dissipation are calculated to second order in the amplitude of the stroke. The optimum efficiency depends on the ratio of viscosity and mass density of the fluid. For high viscosity a stroke is found with significantly higher ef…
The swimming of a deformable uniform sphere is studied in second order perturbation theory in the amplitude of the stroke. The effect of the first order reaction force on the first order center of mass velocity is calculated in linear response theory by use of Newton's equation of motion. The response is characterized by a dipolar admittance, which is shown to be proportional to the translational admittance. As a consequence the mean swimming velocity, calculated in second order perturbation theory, depends on the added mass of the sphere. The mean swimming velocity and the mean rate of dissip…
In studies on Marangoni type motion of particles the surface tension is often approximated as a linear function of temperature. For deformable particles in a linear external temperature gradient far from the reference point this approximation yields a negative surface tension which is physically unrealistic. It is shown that H.Zhou and R.H.Davis J. Colloid Interface Sci., n.181,60,1996 presented calculation where the leading deformable drop moved into a region of negative surface tension. With respect numerical studies the restriction of the migration of two deformable drops is given in terms …
The migration characteristics of a suspended deformable droplet in a parallel plate microchannel is studied, both analytically and numerically, under the combined influence of a constant temperature gradient in the transverse direction and an imposed pressure driven flow. Any predefined transverse position in the micro channel can be attained by the droplet depending on the applied temperature gradient in the cross-stream direction or how small the droplet is with respect to the channel width. For the analytical solution, an asymptotic approach is used, where we neglect any effect of inertia o…
Deformable elastic bodies in viscous and viscoelastic media constitute a large portion of synthetic and biological complex fluids. We present a parallelized 3D-simulation methodology which fully resolves the momentum balance in the solid and fluid domains. An immersed boundary algorithm is exploited known as the immersed finite element method (IFEM) which accurately determines the internal forces in the solid domain. The scheme utilized has the advantages of requiring no costly re-meshing, handling finite Reynold's number, as well as incorporating non-linear viscoelasticity in the fluid domain…
It is generally accepted that the Worthington jet occurs when a droplet impacts onto a liquid pool. However, in this experimental study of the impact of viscous droplets onto a less-viscous liquid pool, we identify another jet besides the Worthington jet, forming a two-jet phenomenon. The two jets, a surface-climbing jet and the Worthington jet, may appear successively during one impact event. By carefully tuning the impact condition, we find that the two-jet phenomenon is jointly controlled by the droplet-pool viscosity ratio, the droplet Weber number, and the droplet-pool miscibility. The me…
We consider an axisymmetric, freely suspended fluid drop with surface tension, whose viscosity is so large that both inertia and forcing by an external fluid can be ignored. We show that whatever be the initial condition, pinchoff can never occur.
The present study deals with the effect of interfacial slip on the deformation and emulsion rheology of a dilute suspension of droplets in a linear flow. The droplets are laden with surfactants that are bulk-insoluble and get transported only along the interface. An asymptotic approach is adopted for the present analysis in order to tackle the nonlinearity present due to deformation of droplets. The analysis is carried out under two different limiting scenarios namely: surface diffusion-dominated-surfactant transport and surface convection-dominated surfactant transport. For either of the limi…
In the present study, we investigate the cross-stream migration of a deformable droplet suspended in a non-isothermal Poiseuille flow in the presence of bulk-insoluble surfactants. Owing to the non-linearity present in the system of governing equations, an asymptotic approach is adopted, in an effort to capture the intricate and non-trivial coupling between the various influencing parameters. With the assumption of negligible inertia in fluid flow and convective transport of thermal energy, we obtain the droplet migration velocity through small-deformation perturbation analysis for two differe…
The physico-chemistry of surfactants (amphiphilic surface active agents) is often used to control the dynamics of viscous drops and bubbles. Surfactant sorption kinetics has been shown to play a critical role in the deformation of drops in extensional and shear flows, yet to the best of our knowledge these kinetics effects on a viscous drop in an electric fieldhave not been accounted for. In this paper we numerically investigate the effects of sorption kinetics on a surfactant-covered viscous drop in an electric field. Over a range of electric conductivity and permittivity ratios between the i…
Liquid drops start spreading directly after coming into contact with a solid sub- strate. Although this phenomenon involves a three-phase contact line, the spread- ing motion can be very fast. We experimentally study the initial spreading dy- namics, characterized by the radius of the wetted area, for viscous drops. Using high-speed imaging with synchronized bottom and side views gives access to 6 decades of time resolution. We show that short time spreading does not exhibit a pure power-law growth. Instead, we find a spreading velocity that decreases logarithmically in time, with a dynamics i…
We present convincing evidence of a direct connection between the pressure drop, viscous dissipation, and the turbulent energy spectrum. We use this finding to explain Nikuradse's experimental results of pressure drop for turbulent flows in rough pipes, in terms of a modified Kolmogorov length scale that varies with the surface roughness. Furthermore, we use Laufer's measurements of turbulent energy spectra in pipe flow to calculate -- to a good approximation -- the turbulent component of the pressure drop directly from an averaged turbulent energy spectrum. We also show that the incompressibi…
We simulate the impact of a viscous liquid drop onto a smooth dry solid surface. As in experiments, when ambient air effects are negligible, impact flattens the falling drop without producing a splash. The no-slip boundary condition at the wall produces a boundary layer inside the liquid. Later, the flattening surface of the drop traces out the boundary layer. As a result, the eventual shape of the drop is a "pancake" of uniform thickness except at the rim, where surface tension effects are significant. The thickness of the pancake is simply the height where the drop surface first collides wit…
The behavior of a magnetic fluid drop lying on a solid horizontal surface and surrounded by a nonmagnetic liquid under the action of a uniform magnetic field which is rotating in a vertical plane with low frequency (of the order of 1 Hz) has been investigated experimentally. Shape deformation and translatory motion of the drop were observed and studied. The drop translation velocity for different field amplitudes and field frequencies has been measured.
Viscous flows through configurations manufactured from soft materials apply both pressure and shear stress at the solid-liquid interface, leading to deformation of the cross-section, which affects the flow rate-pressure drop relation. Conventionally, calculating this flow rate-pressure drop relation requires solving the complete elastohydrodynamic problem, which couples the fluid flow and elastic deformation. In this work, we use the reciprocal theorems for Stokes flow and linear elasticity to derive a closed-form expression for the flow rate-pressure drop relation in deformable channels, bypa…
The non-linear interaction between air and a water droplet just prior to high-speed impingement on a surface is a phenomenon that has been researched extensively and occurs in a number of industrial settings. The role that surface deformation plays in an air cushioned impact of a liquid droplet is considered here. In a two-dimensional framework, assuming small density and viscosity ratios between the air and the liquid, a reduced system of integro-differential equations is derived governing the liquid droplet free-surface shape, the pressure in the thin air film and the deformation of the surf…
This letter presents a theory on the coalescence of two spherical liquid droplets that are initially stationary. The evolution of the radius of a liquid neck formed upon coalescence was formulated as an initial value problem and then solved to yield an exact solution without free parameters, with its two asymptotic approximations reproducing the well-known scaling relations in the viscous and inertial regimes. The viscous-to-inertial crossover observed by Paulsen et al. [Phys. Rev. Lett. 106, 114501 (2011)] is also recovered by the theory, rendering the collapse of data of different viscositie…
In the present study we analytically investigate the deformation and bulk rheology of a dilute emulsion of surfactant-laden droplets suspended in a linear flow. We use an asymptotic approach to predict the effect of surfactant distribution on the deformation of a single droplet as well as the effective shear and extensional viscosity for the dilute emulsion. The non-uniform distribution of surfactants due to the bulk flow results in the generation of a Marangoni stress which affects both the deformation as well as the bulk rheology of the suspension. The present analysis is done for the limiti…
After decades of experimental, theoretical, and numerical research in fluid dynamics, many aspects of turbulence remain poorly understood. The main reason for this is often attributed to the multiscale nature of turbulent flows, which poses a formidable challenge. There are, however, properties of these flows whose roles and inter-connections have never been clarified fully. In this article, we present a new connection between the pressure drop, viscous dissipation, and the turbulent energy spectrum, which, to the best of our knowledge, has never been established prior to our work. We use this…
Discrete simulation methods are efficient tools to investigate the complex behaviors of complex fluids made of either dry granular materials or dilute suspensions. By contrast, materials made of soft and/or concentrated units (emulsions, foams, vesicles, dense suspensions) can exhibit both significant elastic particle deflections (Hertz-like response) and strong viscous forces (squeezed liquid). We point out that the gap between two particles is then not determined solely by the positions of their centers, but rather exhibits its own dynamics. We provide a new discrete numerical method, named …
In this study we attempt to explore the consequences of surfactant coating on the electrohydrodynamic manipulation of a drop motion in a plane Poiseuielle flow. In addition we consider bulk insoluble surfactants and a linear dependency of the surface tension on the surfactant concentration. Subsequently a double asymptotic perturbation method is used in terms of small electric Reynolds number and capillary number in the limit of a diffusion-dominated surfactant transport mechanism. Also going beyond the widely employed axisymmetric framework, the coupled system of governing differential equati…
Thin, viscous liquid films subjected to impact events can deform. Here we investigate free surface oil film deformations that arise due to the air pressure buildup under the impacting and rebouncing water drops. Using Digital Holographic Microscopy, we measure the 3D surface topography of the deformed film immediately after the drop rebound, with a resolution down to 20 nm. We first discuss how the film is initially deformed during impact, as a function of film thickness, film viscosity, and drop impact speed. Subsequently, we describe the slow relaxation process of the deformed film after the…
We study drop impacts on immiscible viscous liquid pool and investigate the formation of droplet surface craters using experimental and theoretical analysis. We attribute the formation of air craters to the rapid deceleration of the droplet due to viscous drag force. The droplet response to the external impulsive decelerating force induces oscillatory modes on the surface exposed to the air forming capillary waves that superimpose to form air craters of various shapes and sizes. We introduce a non-dimensional parameter ($Γ$), that is, the ratio of drag force to the capillary force acting on th…
After impact onto a smooth dry surface, a drop of viscous liquid initially spreads in the form of a thick lamella. If the drop splashes, it first emits a thin fluid sheet that can ultimately break up into droplets causing the splash. Ambient gas is crucial for creating this thin sheet. The time for sheet ejection, $t_{ejt}$, depends on impact velocity, liquid viscosity, gas pressure and molecular weight. A central air bubble is trapped below the drop at pressures even below that necessary for this sheet formation. In addition, air bubbles are entrained underneath the spreading lamella when the…
Deformable bodies in a 3-dimensional viscous flow: Vorticity-Stream vector formulation
Center for Interdisciplinary Research in Biology (CIRB), Collège de France, CNRS, Inserm, Université PSL（跨学科生物研究中心，法兰西学院，法国国家科学研究中心，法国国家健康与医学研究院，巴黎文理研究大学）；Facultat de Física, Universitat de Barcelona（巴塞罗那大学物理学院）；Instituto de Investigación Tecnológica (IIT) and Grupo Interdisciplinar de Sistemas Complejos (GISC), Universidad Pontificia Comillas（技术研究所和复杂系统跨学科小组，科米利亚斯宗座大学）；Institute of Nanoscience and Nanotechnology (IN2UB)（纳米科学与技术研究所）
In a companion paper [Pitrou, Phys. Rev. E 97, 043115 (2018)], a formalism allowing to describe viscous fibers as one-dimensional objects was developed. We apply it to the special case of a viscous fluid torus. This allows to highlight the differences with the basic viscous string model and with its viscous rod model extension. In particular, an elliptic deformation of the torus section appears because of surface tension effects, and this cannot be described by viscous string nor viscous rod models. Furthermore, we study the Rayleigh-Plateau instability for periodic deformations around the per…
The motion of a viscous drop is investigated when the interface is fully covered with a stagnant layer of surfactant in an arbitrary unsteady Stokes flow for the low surface Péclet number limit. The effect of the interfacial slip coefficient on the behavior of the flow field is also considered. The hydrodynamic problem is solved by the solenoidal decomposition method and the drag force is computed in terms of Faxen's laws using a perturbation ansatz in powers of the surface Péclet number. The analytical expressions for the migration velocity of the drop are also obtained in powers of the surfa…
The behaviour of a viscous drop squeezed between two horizontal planes is treated by both theory and experiment. When the squeezing force F is constant and surface tension is neglected, the theory predicts ultimate growth of the radius a~ t^{1/8}, in excellent agreement with our experiment. Surface tension at the drop boundary is included in the analysis, although negligibly small in the squeezing experiments. The circular evolution is found to be stable under small perturbations. If the force is reversed (F < 0), so that the plates are pulled or levered apart, the boundary of the drop is subj…
This letter presents a scaling theory of the coalescence of two viscous spherical droplets. An initial value problem was formulated and analytically solved for the evolution of the radius of a liquid neck formed upon droplet coalescence. Two asymptotic solutions of the initial value problem reproduce the well-known scaling relations in the viscous and inertial regimes. The viscous-to-inertial crossover experimentally observed by Paulsen et al. [Phys. Rev. Lett. 106, 114501 (2011)] manifests in the theory, and their fitting relation, which shows collapse of data of different viscosities onto a …
The experimental observation of D. Duft, T. Achtzehn, R. Muller, B. A. Huber, and T. Leisner, Nature 421, 128 (2003) on the sequential progression of the instability of a charged liquid drop points at the formation of a jet followed by the emission of progeny droplets as a crucial pathway of the Rayleigh fission process. In spite of considerable theoretical progress, a quantitative understanding of this breakup pathway through mathematical models has largely remained inconclusive. This limitation has mainly been due to the fact that the generally applied electrostatic boundary condition of the…
We study the phenomenon of the "walking droplet", by means of numerical fluid dynamics simulations using the Smoothed Particle Hydrodynamics numerical method. This phenomenon occurs when a millimetric drop is released on the surface of an oil of the same composition, contained in a tank and subjected to vertical oscillations of frequency and amplitude very close to the Faraday instability threshold. At appropriate values of the parameters of the system under study, the oil droplet jumps permanently on the surface of the vibrating liquid forming a localized wave-particle system, reminding the b…
Laminar flow in devices fabricated from soft materials causes deformation of the passage geometry, which affects the flow rate--pressure drop relation. For a given pressure drop, in channels with narrow rectangular cross-section, the flow rate varies as the cube of the channel height, so deformation can produce significant quantitative effects, including nonlinear dependence on the pressure drop [{Gervais, T., El-Ali, J., Günther, A. \& Jensen, K.\ F.}\ 2006 Flow-induced deformation of shallow microfluidic channels.\ \textit{Lab Chip} \textbf{6}, 500--507]. Gervais et. al. proposed a successfu…
The interface formation model is applied to describe the initial stages of the coalescence of two liquid drops in the presence of a viscous ambient fluid whose dynamics is fully accounted for. Our focus is on understanding (a) how this model's predictions differ from those of the conventionally used one, (b) what influence the ambient fluid has on the evolution of the shape of the coalescing drops and (c) the coupling of the intrinsic dynamics of coalescence and that of the ambient fluid. The key feature of the interface formation model in its application to the coalescence phenomenon is that …
We analyse small-amplitude oscillations of a weakly viscous electrically conducting liquid drop in a strong uniform DC magnetic field. An asymptotic solution is obtained showing that the magnetic field does not affect the shape eigenmodes, which remain the spherical harmonics as in the non-magnetic case. Strong magnetic field, however, constrains the liquid flow associated with the oscillations and, thus, reduces the oscillation frequencies by increasing effective inertia of the liquid. In such a field, liquid oscillates in a two-dimensional (2D) way as solid columns aligned with the field. Tw…
Using an electrical method and high-speed imaging we probe drop coalescence down to 10 ns after the drops touch. By varying the liquid viscosity over two decades, we conclude that at sufficiently low approach velocity where deformation is not present, the drops coalesce with an unexpectedly late crossover time between a regime dominated by viscous and one dominated by inertial effects. We argue that the late crossover, not accounted for in the theory, can be explained by an appropriate choice of length-scales present in the flow geometry.
From the Navier-Stokes-Korteweg (NSK) equations, the exact relations between the fundamental surface physical quantities for two-phase viscous flow with diffuse interface are derived, including density gradient, shear stress, vorticity, pressure, enstrophy flux and surface curvature. These theoretical results provide a solid foundation of the boundary/interfacial vorticity dynamics and a new tool for analysis of complex interfacial phenomena in two-phase viscous flows. To demonstrate the application of the developed results, simulation of a droplet impacting and spreading on a solid wall is co…
A partially-wetting sessile drop is driven by a sinusoidal pressure field that produces capillary waves on the liquid/gas interface. The analysis presented in Part 1 of this series (Bostwick & Steen 2014) is extended by computing response diagrams and phase shifts for the viscous droplet, whose three phase contact-line moves with contact-angle that is a smooth function of the contact line speed. Viscous dissipation is incorporated through the viscous potential flow approximation and the critical Ohnesorge number bounding regions beyond which a given mode becomes over-damped is computed. Davis …
We analyze the steady non-Newtonian fluid-structure interaction between the flow of an Oldroyd-B fluid and a deformable channel. Specifically, we provide a theoretical framework for calculating the leading-order effect of the fluid's viscoelasticity on the flow rate-pressure drop relation and on the deformation of the channel's elastic wall. We first identify the characteristic scales and dimensionless parameters governing the fluid-structure interaction in slender and shallow channels. Applying the lubrication approximation for the flow and employing a perturbation expansion in powers of the …
The Navier-Stokes equations and boundary conditions for viscous fluids of capillary size are formulated in curvilinear coordinates associated with a geometry of the fluid-gas interface. As a result, the fluid dynamics of drops and menisci can be described taking into account an influence of gravitational forces and flows on the surface shape. This gives a convenient basis for respective numerical studies. Estimations of the effects are presented for the case of an evaporating sessile drop.
The coalescence of two liquid drops surrounded by a viscous gas is considered in the framework of the conventional model. The problem is solved numerically with particular attention to resolving the very initial stage of the process which only recently has become accessible both experimentally and computationally. A systematic study of the parameter space of practical interest allows the influence of the governing parameters in the system to be identified and the role of viscous gas to be determined. In particular, it is shown that the viscosity of the gas suppresses the formation of toroidal …
When a liquid drop falls on a solid substrate, the air layer in between them delays the occurrence of liquid--solid contact. For impacts on smooth substrates, the air film can even prevent wetting, allowing the drop to bounce off with dynamics identical to that observed for impacts on superamphiphobic materials. In this article, we investigate similar bouncing phenomena, occurring on viscous liquid films, that mimic atomically smooth substrates, with the goal to probe their effective repellency. We elucidate the mechanisms associated to the bouncing to non-bouncing (floating) transition using …
We investigate both experimentally and numerically the impact of liquid drops on deep pools of aqueous glycerol solutions with variable pool viscosity and air pressure. With this approach we are able to address drop impacts on substrates that continuously transition from low-viscosity liquids to almost solids. We show that the generic corolla spreading out from the impact point consists of two distinct sheets, namely an ejecta sheet fed by the drop liquid and a second sheet fed by the substrate liquid, which evolve on separated timescales. These two sheets contribute to a varying extent to the…
A classic result due to G.I.Taylor is that a drop placed in a uniform electric field becomes a prolate or oblate spheroid, which is axisymmetrically aligned with the applied field. We report an instability and symmetry-breaking transition to obliquely oriented, steady and unsteady shapes in strong fields. Our experiments reveal novel droplet behaviors such as tumbling, shape oscillations, and chaotic dynamics even under creeping flow conditions. A theoretical model, which includes anisotropy in the polarization relaxation due to drop asphericity and charge convection due to drop fluidity, eluc…
We study the instability development during a viscous liquid drop impacting a smooth substrate, using high speed photography. The onset time of the instability highly depends on the surrounding air pressure and the liquid viscosity: it decreases with air pressure with the power of minus two, and increases linearly with the liquid viscosity. From the real-time dynamics measurements, we construct a model which compares the destabilizing stress from air with the stabilizing stress from liquid viscosity. Under this model, our experimental results indicate that at the instability onset time, the tw…
The shear induced collective diffusivity in an emulsion of viscous drops, specifically as a function of viscosity ratio, was numerically computed. An initially randomly packed layer of viscous drops spreading due to drop-drop interactions in an imposed shear has been simulated. The shear induced collective diffusivity coefficient was computed using a self-similar solution of the drop concentration profile. We also obtained the collective diffusivity computing the dynamic structure factor from the simulated drop positions--an analysis typically applied only to homogeneous systems. The two quant…
