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arXiv 2604.03467physics.flu-dyncond-mat.soft
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基于固体的建模方法用于简单屈服应力流体:流变转变、超量和松弛

A Solid-Based Approach for Modeling Simple Yield-Stress Fluids: Rheological Transitions, Overshoot and Relaxation

Kyungpook National University(庆北国立大学);Ajou University(亚洲大学)

Jehyeok Choi, Ju Min Kim, Kwang Soo Cho

AI总结:

本文提出了一种基于固体的本构方程,用于描述简单屈服应力流体的流变特性,该模型能够准确预测启动剪切过程中的应力超量,揭示超量源于均质机制而非等向硬化或空间非均质微结构演变。

摘要:

屈服应力流体在自然泥石流和工业应用如二次电池电极浆料和直接墨水书写中广泛存在。尽管提出了多种本构方程,但很少有模型能够成功预测屈服应力流体的稳态和瞬态流变行为。本文提出了一种本构方程,通过Zener型黏弹性固体元件与附加的线性阻尼器并联,结合非线性粘度模型、流动规则、回应力演化方程和Kroner-Lee分解,提供对简单屈服应力流体流变特性的全面描述。该模型满足材料框架不变性原理,并在启动剪切、蠕变和应力松弛测试中与实验观测一致地再现了流变特性。特别地,本文提出的黏弹性固体基本构方程能够准确预测启动剪切过程中的应力超量。重要的是,超量源于一种均质机制,正常应力差增强了应力不变量,从而加速了塑性响应,而不是来自等向硬化或空间非均质微结构演变。

英文摘要:

Yield-stress fluids are ubiquitous and encountered in diverse fields ranging from natural muddy flows to industrial applications such as secondary battery electrode slurries and direct ink writing. Despite the proposal of various constitutive equations, few models have been shown to successfully predict both steady and transient rheological behaviors in yield-stress fluids. In this study, a constitutive equation is hereby proposed, offering a comprehensive description of the rheological characteristics observed in simple yield-stress fluids, excluding thixotropy, such as the Carbopol dispersion. The constitutive equation is derived from a Zener-type viscoelastic solid element combined with an additional linear dashpot connected in parallel, together with a nonlinear viscosity model, a flow rule, an evolution equation for the back stress, and the Kroner-Lee decomposition. This combination satisfies the principle of material frame invariance. The proposed model successfully reproduces the rheological characteristics qualitatively in a manner consistent with experimental observations conducted during start-up shear, creep, and stress relaxation tests. In particular, the present viscoelastic solid-based constitutive equation is shown to accurately predict stress overshoot during start-up shear. Importantly, the overshoot is found to originate from a homogeneous mechanism in which normal stress difference enhances the stress invariant and thereby accelerates the plastic response, rather than from isotropic hardening or spatially heterogeneous microstructural evolution. This study is expected to facilitate a deeper understanding of the intricate dynamics governing the flow of yield-stress fluids.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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