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arXiv 2504.02499astro-ph.EPphysics.ao-phphysics.geo-ph
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跨半径谷的平均分子量梯度

The Gradient of Mean Molecular Weight Across the Radius Valley

Kevin Heng, James E. Owen, Meng Tian

AI总结:

本文通过第一性原理CHOSSi释气模型研究亚海王星大气化学,预测跨半径谷存在由核心氧逸度驱动的平均分子量梯度,揭示较小亚海王星大气更少以氢为主。

摘要:

光致蒸发塑造了观测到的小型系外行星半径,并约束了大气质量和核心质量的潜在分布。然而,与这些分布相对应的大气化学多样性仍未得到阐明。我们建立了一个第一性原理的碳-氢-氧-硫-硅(CHOSSi)释气模型,该模型考虑了高压下的非理想气体行为(通过逸度)以及水和氢溶解于熔体中的趋势(通过溶解度定律)。我们利用数据驱动的半径谷约束来确定亚海王星的表面大气压力与熔体温度之间的关系。岩石核心质量较小的亚海王星保留的原始氢包层较少,导致热量保持较少,并降低这些核心表面的熔体温度。较低的熔体温度在热力学上导致含碳、氧、硫和硅的分子相对于分子氢占主导地位,这自然产生了平均分子量的多样性。我们的地球化学释气计算稳健地预测了跨半径谷的平均分子量梯度,其中该梯度的强度主要由熔融核心的氧逸度驱动,而不是由大气的碳富集(或“金属量”)驱动。预测较小的亚海王星具有较少以氢为主的大气。观测到的化学与释气化学之间的精确关系需要理解核心附近的对流如何与光球层附近的大尺度大气环流(由恒星加热驱动)相互作用,以及光化学的影响。

英文摘要:

Photo-evaporation shapes the observed radii of small exoplanets and constrains the underlying distributions of atmospheric and core masses. However, the diversity of atmospheric chemistries corresponding to these distributions remains unelucidated. We develop a first-principles carbon-hydrogen-oxygen-sulfur-silicon (CHOSSi) outgassing model that accounts for non-ideal gas behavior (via fugacities) at high pressures, as well as the tendency for water and hydrogen to dissolve in melt (via solubility laws). We use data-driven radius valley constraints to establish the relationship between the atmospheric surface pressures and melt temperatures of sub-Neptunes. Sub-Neptunes with less massive rocky cores retain less of their primordial hydrogen envelopes, which leads to less heat retention and diminished melt temperatures at the surfaces of these cores. Lower melt temperatures lead thermodynamically to the dominance of carbon-, oxygen-, sulfur- and silicon-bearing molecules over molecular hydrogen, which naturally produce a diversity of mean molecular weights. Our geochemical outgassing calculations robustly predict a gradient of mean molecular weight across the radius valley, where the strength of this gradient is primarily driven by the oxygen fugacity of the molten cores and not by the carbon enrichment (or "metallicity") of the atmosphere. Smaller sub-Neptunes are predicted to have less hydrogen-dominated atmospheres. The precise relationship between the observed and outgassed chemistries requires an understanding of how convection near the core interacts with large-scale atmospheric circulation (driven by stellar heating) near the photosphere, as well as the influence of photochemistry.

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