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arXiv 2402.19040cond-mat.mtrl-sci
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压力诱导的HfS$_2$光学各向异性

Pressure-induced optical anisotropy of HfS$_2$

Igor Antoniazzi, Tomasz Woźniak, Amit Pawbake, Natalia Zawadzka, Magdalena Grzeszczyk, Zahir Muhammad, Weisheng Zhao, Jordi Ibáñez, Clement Faugeras, Maciej R. Molas, Adam Babiński

AI总结:

本研究探究静水压与非静水压下压力对块体HfS$_2$拉曼散射的影响,发现非静水压下会发生压力诱导相变,高压相为亚稳态且存在面内各向异性,提出畸变Pnma相是其可能的高压结构。

摘要:

本研究在静水压与非静水压条件下,探究了压力对块体HfS$_2$拉曼散射(RS)的影响。在静水压区间内,拉曼散射的线形未发生显著变化,仅表现出光谱特征的系统性蓝移。在非静水压环境下,当压强P=7 GPa时,光谱中出现7个峰,这些峰在压强升至10.5 GPa的过程中始终主导着线形。拉曼散射线形的变化表明HfS$_2$发生了压力诱导的相变。低压(LP)与高压(HP)相关拉曼散射峰的同时观测结果显示,两种不同相在较宽的压强范围内共存。研究发现,高压相关相属于亚稳态,在卸压过程中可一直维持至压强P=1.2 GPa,低压相关的特征最终在更低的压强下恢复。在P=7.4 GPa条件下开展的角分辨偏振拉曼散射(ARPRS)测试显示,低压相关的A$_{1g}$模与高压峰均表现出强烈的面内各向异性。这种各向异性与压力的非静水压分量可能引发的结构畸变有关。本研究通过非静水压压力对所观测相变的影响来阐释所得结果,并将结果解读为:畸变的Pnma相是HfS$_2$可能的高压诱导结构。

英文摘要:

The effect of pressure on Raman scattering (RS) in the bulk HfS$_2$ is investigated under hydrostatic and non-hydrostatic conditions. The RS lineshape does not change significantly in the hydrostatic regime, showing a systematic blueshift of the spectral features. In a non-hydrostatic environment, seven peaks emerge in the spectrum ($P$=7 GPa) dominating the lineshape up to $P$=10.5 GPa. The change in the RS lineshape manifests a pressure-induced phase transition in HfS$_2$. The simultaneous observation of both low-pressure (LP) and high-pressure (HP) related RS peaks suggests the corresponding coexistence of two different phases over a large pressure range. We found that the HP-related phase is metastable, persisting during the decompression cycle down to $P$=1.2 GPa with the LP-related features finally recovering at even lower pressures. The angle-resolved polarized RS (ARPRS) performed under $P$=7.4 GPa revealed a strong in-plane anisotropy of both the LP-related A$_{1g}$ mode and the HP peaks. The anisotropy is related to the possible distortion of the structure induced by the non-hydrostatic component of the pressure. We describe the obtained results by the influence of the non-hydrostatic pressure on the observed phase transition. We interpret our results in terms of a distorted $Pnma$ phase as a possible HP induced structure of HfS$_2$.

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