Igor Antoniazzi, Tomasz Woźniak, Amit Pawbake, Natalia Zawadzka, Magdalena Grzeszczyk, Zahir Muhammad, Weisheng Zhao, Jordi Ibáñez, Clement Faugeras, Maciej R. Molas, Adam Babiński
The effect of pressure on Raman scattering (RS) in the bulk HfS$_2$ is investigated under hydrostatic and non-hydrostatic conditions. The RS lineshape does not change significantly in the hydrostatic regime, showing a systematic blueshift of the spectral features. In a non-hydrostatic environment, seven peaks emerge in the spectrum ($P$=7 GPa) dominating the lineshape up to $P$=10.5 GPa. The change in the RS lineshape manifests a pressure-induced phase transition in HfS$_2$. The simultaneous observation of both low-pressure (LP) and high-pressure (HP) related RS peaks suggests the corresponding coexistence of two different phases over a large pressure range. We found that the HP-related phase is metastable, persisting during the decompression cycle down to $P$=1.2 GPa with the LP-related features finally recovering at even lower pressures. The angle-resolved polarized RS (ARPRS) performed under $P$=7.4 GPa revealed a strong in-plane anisotropy of both the LP-related A$_{1g}$ mode and the HP peaks. The anisotropy is related to the possible distortion of the structure induced by the non-hydrostatic component of the pressure. We describe the obtained results by the influence of the non-hydrostatic pressure on the observed phase transition. We interpret our results in terms of a distorted $Pnma$ phase as a possible HP induced structure of HfS$_2$.
Uniaxial anisotropy and enhanced magnetostriction of CoFe$_2$O$_4$ induced by reaction under uniaxial pressure with SPS
在这项研究中,我们比较了磁性和磁致伸缩性能的多晶CoFe $_2$ O $_4$丸,由三种不同的方法,重点是使用放电等离子烧结(SPS)。该技术允许在施加单轴压力的同时进行非常短的热处理阶段。SPS用于烧结钴铁氧体,但也用于进行相同陶瓷组合物的反应和烧结(反应烧结)。磁性和磁致伸缩测量表明,SPS反应烧结诱导单轴各向异性,而不是一个简单的烧结过程的情况下。然后,诱导的各向异性预计是单轴压力下的反应的结果。这种各向异性增强了样品的磁致伸缩性能,其中获得了$-229$ ~ppm的最大纵向磁致伸缩。由于所需的处理时间短(22分钟),该过程可以是磁退火的有希望的替代方案。
Pressure-induced spin reorientation transition in layered ferromagnetic insulator Cr2Ge2Te6
研究了层状铁磁绝缘体Cr2 Ge 2 Te 6(CGT)在2GPa静水压下的各向异性磁电阻效应。磁化的易磁化轴方向是从AMR饱和特征中推断的,在存在和不存在所施加的压力。在零施加压力下,易轴沿着c方向或垂直于层。在施加>1 GPa的流体静压时,单轴各向异性切换到易平面各向异性,这在零磁场下将平衡磁化从c轴驱动到ab平面,这相当于巨大的磁各向异性能量变化(>100%)。随着温度在居里温度范围内升高,AMR效应特征逐渐减小并消失。我们的第一性原理计算证实了巨大的磁各向异性能量的变化与中等压力,并分配其起源增加的离位自旋轨道相互作用的Te原子,由于较短的Cr-Te距离。这种压力诱导的自旋重取向转变在三维铁磁体中非常罕见,但它可能是与CGT具有类似晶体结构的其他层状铁磁体所共有的,因此提供了一种控制磁各向异性的独特方法。
Pressure-Induced Zero-Gap Semiconducting State in Organic Conductor $α$-(BEDT-TTF)$_2$I$_3$ Salt
我们显示了准二维有机导体$α$ -(BEDT-TTF)$_2$ I $_3$盐中的零能隙半导体(ZGS)态,其在沿a轴(BEDT-TTF分子的堆叠轴)的单轴压力下出现。ZGS状态是在费米点周围存在具有线性色散的带谱的狄拉克锥的状态,该狄拉克锥连接未被占据的(电子)带和被占据的(空穴)带。频谱表现出很大的各向异性的速度,这取决于从费米点的方向。通过改变一个紧束缚模型的几个转移能的大小与四个网站每个晶胞,它表明,ZGS状态存在于一个很宽的压力范围内,并归因于大的各向异性的转移能沿堆叠轴。