Optical phase curves of hot Jupiters can reveal global scattering properties. We implement a Bayesian inference framework for optical phase curves with flux contributions from: reflected light from a potentially inhomogeneous atmosphere, thermal emission, ellipsoidal variations, Doppler beaming, and stellar rotation via a Gaussian process in the time domain. We probe for atmospheric homogeneity and time-variability using the reflected light inferences for highly precise Kepler light curves of five hot Jupiters. We also investigate the scattering properties which constrain the most likely condensates in the inhomogeneous atmospheres. Cross validation prefers inhomogeneous albedo distributions for Kepler-7 b and Kepler-41 b, and a weak preference for inhomogeneity for KOI-13 b. None of the five planets exhibit significant variations in geometric albedo on one-year timescales, in agreement with theoretical expectations. We show that analytic reflected light phase curves with isotropic multiple scattering are in excellent agreement with full Rayleigh multiple scattering calculations, allowing for accelerated and analytic inference. In a case study of Kepler-41 b, we identify perovskite, forsterite, and enstatite as possible scattering species consistent with the reflected light phase curves, with condensate particle radii in the range 0.01-0.1 micron.
Turbulent vertical transport driven by double-diffusive shear instabilities is identified as likely important in hot exoplanet atmospheres. In hot Jupiter atmospheres, the resulting vertical mixing appears sufficient to alleviate the nightside cold trap, thus facilitating the maintenance of nocturnal clouds on these planets. The strong level of vertical mixing expected near hot Jupiter thermal photospheres will impact their atmospheric chemistry and even their vertical structures where cloud radiative feedback proves important.
The past twenty years have revealed the diversity of planets that exist in the Universe. It turned out that most of exoplanets are different from the planets of our Solar System and thus, everything about them needs to be explored. Thanks to current observational technologies, we are able to determine some information about the atmospheric composition, the thermal structure and the dynamics of these exoplanets, but many questions remain still unanswered. To improve our knowledge about exoplanetary systems, more accurate observations are needed and that is why the Exoplanet Characterisation Obs…
Atmospheric compositions for rocky exoplanets will depend strongly on the bulk planetary composition and the orbital position of the planet. Non-traditional gases may be present in the atmospheres of exceptionally hot planets. Atmospheres of more clement planets will depend on the abundances of volatiles acquired during planet formation and atmospheric removal processes, including escape, condensation, and reaction with the surface. While the observations of exoplanet atmospheres to date has focused on giant planets, a series of new space and ground-based observatories over the coming decade w…
At the dawn of the first discovery of exoplanets orbiting sun-like stars in the mid-1990s, few believed that observations of exoplanet atmospheres would ever be possible. After the 2002 Hubble Space Telescope detection of a transiting exoplanet atmosphere, many skeptics discounted it as a one-object, one-method success. Nevertheless, the field is now firmly established, with over two dozen exoplanet atmospheres observed today. Hot Jupiters are the type of exoplanet currently most amenable to study. Highlights include: detection of molecular spectral features; observation of day-night temperatu…
Exoplanets are now being discovered in profusion. However, to understand their character requires spectral models and data. These elements of remote sensing can yield temperatures, compositions, and even weather patterns, but only if significant improvements in both the parameter retrieval process and measurements are achieved. Despite heroic efforts to garner constraining data on exoplanet atmospheres and dynamics, reliable interpretation has oftimes lagged ambition. I summarize the most productive, and at times novel, methods employed to probe exoplanet atmospheres, highlight some of the mos…
To ensure robust constraints are placed on exoplanet atmospheric transmission spectra, future observations need to obtain high signal-to-noise ratio (SNR) measurements assuming smaller amplitude molecular signatures than those of clear solar metallicity atmospheres. Analyzing 37 exoplanet transmission spectra we find clear solar molecular features are measured in <7% of cases.
Warm Neptune- and sub-Neptune-sized exoplanets in orbits smaller than Mercury's are thought to have experienced extensive atmospheric evolution. Here we propose that a potential outcome of this atmospheric evolution is the formation of helium-dominated atmospheres. The hydrodynamic escape rates of Neptune- and sub-Neptune-sized exoplanets are comparable to the diffusion-limited escape rate of hydrogen, and therefore the escape is heavily affected by diffusive separation between hydrogen and helium. A helium atmosphere can thus be formed -- from a primordial hydrogen-helium atmosphere -- via at…
It is possible to learn a great deal about exoplanet atmospheres even when we cannot spatially resolve the planets from their host stars. In this chapter, we overview the basic techniques used to characterize transiting exoplanets - transmission spectroscopy, emission and reflection spectroscopy, and full-orbit phase curve observations. We discuss practical considerations, including current and future observing facilities and best practices for measuring precise spectra. We also highlight major observational results on the chemistry, climate, and cloud properties of exoplanets.
Much of the focus of exoplanet atmosphere analysis in the coming decade will be at infrared wavelengths, with the planned launches of the James Webb Space Telescope (JWST) and the Wide-Field Infrared Survey Telescope (WFIRST). However, without being placed in the context of broader wavelength coverage, especially in the optical and ultraviolet, infrared observations produce an incomplete picture of exoplanet atmospheres. Scattering information encoded in blue optical and near-UV (NUV) observations can help determine whether muted spectral features observed in the infrared are due to a hazy/clo…
Sulfur gases significantly affect the photochemistry of planetary atmospheres in our Solar System, and are expected to be important components in exoplanet atmospheres. However, sulfur photochemistry in the context of exoplanets is poorly understood due to a lack of chemical-kinetics information for sulfur species under relevant conditions. Here, we study the photochemical role of hydrogen sulfide (H2S) in warm CO2-rich exoplanet atmospheres (800 K) by carrying out laboratory simulations. We find that H2S plays a significant role in photochemistry, even when present in the atmosphere at relati…
Characterizing the atmospheres of extrasolar planets is the new frontier in exoplanetary science. The last two decades of exoplanet discoveries have revealed that exoplanets are very common and extremely diverse in their orbital and bulk properties. We now enter a new era as we begin to investigate the chemical diversity of exoplanets, their atmospheric and interior processes, and their formation conditions. Recent developments in the field have led to unprecedented advancements in our understanding of atmospheric chemistry of exoplanets and the implications for their formation conditions. We …
Photochemical hazes are important opacity sources in temperate exoplanet atmospheres, hindering current observations from characterizing exoplanet atmospheric compositions. The haziness of an atmosphere is determined by the balance between haze production and removal. However, the material-dependent removal physics of the haze particles is currently unknown under exoplanetary conditions. Here we provide experimentally-measured surface energies for a grid of temperate exoplanet hazes to characterize haze removal in exoplanetary atmospheres. We found large variations of surface energies for haze…
Scattered lights from terrestrial exoplanets provide valuable information about the planetary surface. Applying the surface reconstruction method proposed by Fujii et al. (2010) to both diurnal and annual variations of the scattered light, we develop a reconstruction method of land distribution with both longitudinal and latitudinal resolutions. We find that one can recover a global map of an idealized Earth-like planet on the following assumptions: 1) cloudless, 2) a face-on circular orbit, 3) known surface types and their reflectance spectra 4) no atmospheric absorption, 5) known rotation ra…
The field of exoplanets is quickly expanding from just the detection of new planets and the measurement of their most basic parameters, such as mass, radius and orbital configuration, to the first measurements of their atmospheric characteristics, such as temperature, chemical composition, albedo, dynamics and structure. Here I will overview some of the main findings on exoplanet atmospheres until September 2010, first from space and just in the past two years also from the ground.
Exoplanetary science is on the verge of an unprecedented revolution. The thousands of exoplanets discovered over the past decade have most recently been supplemented by discoveries of potentially habitable planets around nearby low-mass stars. Currently, the field is rapidly progressing towards detailed spectroscopic observations to characterise the atmospheres of these planets. While various surveys from space and ground are expected to detect numerous more exoplanets orbiting nearby stars, the imminent launch of JWST along with large ground-based facilities are expected to revolutionise exop…
Observational evidence for escaping exoplanet atmospheres has been obtained for a few exoplanets to date. It comes from strong transit signals detected in the ultraviolet, most notably in the wings of the hydrogen Lyman-$α$ (Ly$α$) line. However, the core of the Ly$α$ line is often heavily affected by interstellar absorption and geocoronal emission, limiting the information about the atmosphere that can be extracted from that part of the spectrum. Transit observations in atomic lines that are (a) sensitive enough to trace the rarefied gas in the planetary wind and (b) do not suffer from signif…
We propose a classification of exoplanet atmospheres based on their H, C, O, N element abundances below about 600 K. Chemical equilibrium models were run for all combinations of H, C, N, O abundances, and three types of solutions were found, which are robust against variations of temperature, pressure and nitrogen abundance. Type A atmospheres contain H2O, CH4, NH3 and either H2 or N2, but only traces of CO2 and O2. Type B atmospheres contain O2, H2O, CO2 and N2, but only traces of CH4, NH3 and H2. Type C atmospheres contain H2O, CO2, CH4 and N2, but only traces of NH3, H2 and O2. Other molecu…
Observations of exoplanet atmospheres have shown that aerosols, like in the Solar System, are common across a variety of temperatures and planet types. The formation and distribution of these aerosols are inextricably intertwined with the composition and thermal structure of the atmosphere. At the same time, these aerosols also interfere with our probes of atmospheric composition and thermal structure, and thus a better understanding of aerosols lead to a better understanding of exoplanet atmospheres as a whole. Here we review the current state of knowledge of exoplanet aerosols as determined …
Data suggest that most rocky exoplanets with orbital period $p$ $<$ 100 d ("hot" rocky exoplanets) formed as gas-rich sub-Neptunes that subsequently lost most of their envelopes, but whether these rocky exoplanets still have atmospheres is unknown. We identify a pathway by which 1-1.7 $R_{Earth}$ (1-10 $M_{Earth}$) rocky exoplanets with orbital periods of 10-100 days can acquire long-lived 10-2000 bar atmospheres that are H$_2$O-dominated, with mean molecular weight $>$10. These atmospheres form during the planets' evolution from sub-Neptunes into rocky exoplanets. H$_2$O that is made by reduc…
We report the detection of an atmosphere on a rocky exoplanet, GJ 1132 b, which is similar to Earth in terms of size and density. The atmospheric transmission spectrum was detected using Hubble WFC3 measurements and shows spectral signatures of aerosol scattering, HCN, and CH$_{4}$ in a low mean molecular weight atmosphere. We model the atmospheric loss process and conclude that GJ 1132 b likely lost the original H/He envelope, suggesting that the atmosphere that we detect has been reestablished. We explore the possibility of H$_{2}$ mantle degassing, previously identified as a possibility for…
Sulfur gases are common components in the volcanic and biological emission on Earth, and are expected to be important input gases for atmospheres on terrestrial exoplanets. We study the atmospheric composition and the spectra of terrestrial exoplanets with sulfur compounds (i.e., H2S and SO2) emitted from their surfaces. We use a comprehensive one-dimensional photochemistry model and radiative transfer model to investigate the sulfur chemistry in atmospheres ranging from reducing to oxidizing. The most important finding is that both H2S and SO2 are chemically short-lived in virtually all types…
Photochemistry induced by stellar UV flux should produce haze particles in exoplanet atmospheres. Recent observations indicate that haze and/or cloud layers exist in the atmospheres of exoplanets. However, photochemical processes in exoplanetary atmospheres remain largely unknown. We performed laboratory experiments with the PHAZER chamber to simulate haze formation in a range of exoplanet atmospheres (hydrogen-rich, water-rich, and carbon dioxide-rich at 300, 400, and 600 K), and observed the gas phase compositional change (the destruction of the initial gas and the formation of new gas speci…
By applying an one-dimensional aeronomic model of the upper atmosphere of the close-in giant planet HD 209458b, we study the reaction of the planetary atmosphere to an additional heating caused by the influence of a stellar flare. It is shown that the absorption of additional energy of the stellar flare in the extreme ultraviolet leads to local atmospheric heating, accompanied by formation of two shock waves, propagating in the atmosphere. We discuss possible observational manifestations of the shocks and feasibility of their detection.
Exoplanets with lower equilibrium temperatures than Earth and primordial hydrogen atmospheres that evaporate after formation should pass through transient periods where oceans can form on their surfaces, as liquid water can form below a few thousand bar pressure and H2-H2 collision-induced absorption provides significant greenhouse warming. The duration of the transient period depends on the planet size, starting H2 inventory and star type, with the longest periods typically occurring for planets around M-class stars. As pre-biotic compounds readily form in the reducing chemistry of hydrogen-r…
An error was detected in the code used for the analysis of the HD209458b sodium profile (Vidal-Madjar et al. 2011). Here we present an updated T-P profile and briefly discuss the consequences.
Transit observations of HD209458b in the UV revealed signatures of neutral magnesium escaping the planet's upper atmosphere. The absorption detected in the MgI line provides unprecedented information on the physical conditions at the altitude where the atmospheric blow-off takes place. Here we use a 3D model of atmospheric escape to estimate the transit absorption signatures in the MgI line of their host stars. The detectability of these signatures depends on the brightness of the star and the escape rate of neutral magnesium. We identify a sample of potentially evaporating exoplanets that cov…
Understanding a planet's atmosphere is a necessary condition for understanding not only the planet itself, but also its formation, structure, evolution, and habitability, This puts a premium on obtaining spectra, and developing credible interpretative tools with which to retrieve vital planetary information. However, for exoplanets these twin goals are far from being realized. In this paper, I provide a personal perspective on exoplanet theory and remote sensing via photometry and low-resolution spectroscopy. Though not a review in any sense, this paper highlights the limitations in our knowle…
Modeling the outflow of planetary atmospheres is important for understanding the evolution of exoplanet systems and for interpreting their observations. Modern theoretical models of exoplanet atmospheres become increasingly detailed and multicomponent, and this makes difficulties for engaging new researchers in the scope. Here, for the first time, we present the results of testing the gas-dynamic method incorporated in our aeronomic model, which has been proposed earlier. Undertaken tests support the correctness of the method and validate its applicability. For modeling the planetary wind, we …
The results of three-dimensional numerical simulations of the gas dynamics of the atmosphere of a "hot Jupiter" exoplanet during the passage of a coronal mass ejection (CME) from the central star are presented. These computations assumed the parameters for the stellar wind and the CME to be typical of the solar values. The characteristic variations of the flow pattern are considered for quasi-closed and closed (but appreciably distorted by the gravitational influence of the star) gaseous envelopes of the exoplanet. It is shown that a typical CME is sufficient to tear off the outer part of an a…
Rocky planets are common around other stars, but their atmospheric properties remain largely unconstrained. Thanks to a wealth of recent planet discoveries and upcoming advances in observing capability, we are poised to characterize the atmospheres of dozens of rocky exoplanets in this decade. Theoretical understanding of rocky exoplanet atmospheres has advanced considerably in the last few years, yielding testable predictions of their evolution, chemistry, dynamics and even possible biosignatures. Here we review key progress in this field to date and discuss future objectives. Our major concl…
Close-in exoplanets with highly eccentric orbits are subject to large variations in incoming stellar flux between periapse and apoapse. These variations may lead to large swings in atmospheric temperature, which in turn may cause changes in the chemistry of the atmosphere from higher CO abundances at periapse to higher CH4 abundances at apoapse. Here we examine chemical timescales for CO<->CH4 interconversion compared to orbital timescales and vertical mixing timescales for the highly eccentric exoplanets HAT-P-2b and CoRoT-10b. As exoplanet atmospheres cool, the chemical timescales for CO<->C…
Detecting biosignatures, such as molecular oxygen in combination with a reducing gas, in the atmospheres of transiting exoplanets has been a major focus in the search for alien life. We point out that in addition to these generic indicators, anthropogenic pollution could be used as a novel biosignature for intelligent life. To this end, we identify pollutants in the Earth's atmosphere that have significant absorption features in the spectral range covered by the James Webb Space Telescope (JWST). We focus on tetrafluoromethane CF4 and trichlorofluoromethane (CCl3F), which are the easiest to de…
The search for signs of life through the detection of exoplanet atmosphere biosignature gases is gaining momentum. Yet, only a handful of rocky exoplanet atmospheres are suitable for observation with planned next-generation telescopes. To broaden prospects, we describe the possibilities for an aerial, liquid water cloud-based biosphere in the atmospheres of sub Neptune-sized temperate exoplanets, those receiving Earth-like irradiation from their host stars. One such planet is known (K2-18b) and other candidates are being followed up. Sub Neptunes are common and easier to study observationally …
(Abridged) Super Earth exoplanets are being discovered with increasing frequency and some will be able to retain stable H2-dominated atmospheres. We study biosignature gases on exoplanets with thin H2 atmospheres and habitable surface temperatures, by using a model atmosphere with photochemistry, and biomass estimate framework for evaluating the plausibilty of a range of biosignature gas candidates. We find that photochemically produced H atoms are the most abundant reactive species in H2 atmospheres. In atmospheres with high CO2 levels, atomic O is the major destructive species for some molec…
An important source of opacity in exoplanet atmospheres at short visible and near-UV wavelengths is Rayleigh scattering of light on molecules. It is accompanied by a related, albeit weaker process -- Raman scattering. We analyze the signatures of Raman scattering imprinted in the reflected light and the geometric albedo of exoplanets, which could provide information about atmospheric properties. Raman scattering affects the geometric albedo spectra of planets in following ways. Firstly, it causes filling-in of strong absorption lines in the incident radiation, thus producing sharp peaks in the…
Hot giant exoplanets are very exotic objects with no equivalent in the Solar System that allow us to study the behavior of atmospheres under extreme conditions. Their thermal and chemical day--night dichotomies associated with extreme wind dynamics make them intrinsically 3D objects. Thus, the common 1D assumption, relevant to study colder atmospheres, reaches its limits in order to be able to explain hot and ultra-hot atmospheres and their evolution in a consistent way. In this review, we highlight the importance of these 3D considerations and how they impact transit, eclipse and phase curve …
Clouds and hazes are commonplace in the atmospheres of solar system planets and are likely ubiquitous in the atmospheres of extrasolar planets as well. Clouds affect every aspect of a planetary atmosphere, from the transport of radiation, to atmospheric chemistry, to dynamics and they influence - if not control - aspects such as surface temperature and habitability. In this review we aim to provide an introduction to the role and properties of clouds in exoplanetary atmospheres. We consider the role clouds play in influencing the spectra of planets as well as their habitability and detectabili…
Some super Earths and mini Neptunes will likely have thick atmospheres that are not H2-dominated. We have developed a photochemistry-thermochemistry kinetic-transport model for exploring the compositions of thick atmospheres on super Earths and mini Neptunes, applicable for both H2-dominated atmospheres and non-H2-dominated atmospheres. Using this model to study thick atmospheres for wide ranges of temperatures and elemental abundances, we classify them into hydrogen-rich atmospheres, water-rich atmospheres, oxygen-rich atmospheres, and hydrocarbon-rich atmospheres. We find that carbon has to …
We present an analytical model for the transmission spectrum of a transiting exoplanet, showing that a cloud base can produce an observable inflection point in the spectrum. The wavelength and magnitude of the inflection can be used to break the degeneracy between the atmospheric pressure and the abundance of the main cloud material, however, the abundance still depends on cloud particle size. An observed inflection also provides a specific point on the atmospheric P-T profile, giving us a "thermometer" to directly validate or rule out postulated cloud species. We apply the model to the transi…
By varying the profiles of stellar extreme ultraviolet (EUV) spectral energy distribution (SED), we tested the influences of stellar EUV SEDs on the physical and chemical properties of the escaping atmosphere. We apply our model to study four exoplanets, HD\,189733b, HD\,209458b, GJ \,436b, and Kepler-11b. We found that the total mass loss rates of an exoplanet, which are determined mainly by the integrated fluxes, are moderately affected by the profiles of the EUV SED, but the composition and species distributions in the atmosphere can be dramatically modified by the different profiles of the…
Until recently, infrared observations of exoplanetary atmospheres have typically been interpreted using models that assumed solar elemental abundances. With the chemical composition fixed, attempts have been made to classify hot Jupiter atmospheres on the basis of stellar irradiation. However, recent observations have revealed deviations from predictions based on such classification schemes, and chemical compositions retrieved from some datasets have also indicated non-solar abundances. In hot hydrogen-dominated atmospheres, the C/O ratio critically influences the relative concentrations of se…
We present a time-dependent radiative model for the atmosphere of extrasolar planets that takes into account the eccentricity of their orbit. In addition to the modulation of stellar irradiation by the varying planet-star distance, the pseudo-synchronous rotation of the planets may play a significant role. We include both of these time-dependent effects when modeling the planetary thermal structure. We investigate the thermal structure, and spectral characteristics for time-dependent stellar heating for two highly eccentric planets. Finally, we discuss observational aspects for those planets s…
Multi-wavelength transit and secondary-eclipse light-curve observations are some of the most powerful techniques to probe the thermo-chemical properties of exoplanets. Although the large planet-to-star brightness contrast and few available spectral bands produce data with low signal-to-noise ratios, a Bayesian approach can robustly reveal what constraints we can set, without over-interpreting the data. Here I performed an end-to-end analysis of transiting exoplanet data. I analyzed space-telescope data for three planets to characterize their atmospheres and refine their orbits, investigated co…
Formation of hazes at microbar pressures has been explored by theoretical models of exoplanet atmospheres to explain Rayleigh scattering and/or featureless transmission spectra, however observational evidence of aerosols in the low pressure formation environments has proved elusive. Here, we show direct evidence of aerosols existing at $\sim$1 microbar pressures in the atmosphere of the warm sub-Saturn WASP-69b using observations taken with Space Telescope Imaging Spectrograph (STIS) and Wide Field Camera 3 (WFC3) instruments on the Hubble Space Telescope. The transmission spectrum shows a wav…
We present a comprehensive photochemistry model for exploration of the chemical composition of terrestrial exoplanet atmospheres. The photochemistry model is designed from the ground up to have the capacity to treat all types of terrestrial planet atmospheres, ranging from oxidizing through reducing, which makes the code suitable for applications for the wide range of anticipated terrestrial exoplanet compositions. The one-dimensional chemical transport model treats up to 800 chemical reactions, photochemical processes, dry and wet deposition, surface emission and thermal escape of O, H, C, N …
Since the discovery of the first extrasolar planet more than twenty years ago, we have discovered nearly four thousand planets orbiting stars other than the Sun. Current observational instruments (on board the Hubble Space Telescope, Spitzer, and on ground-based facilities) have allowed the scientific community to obtain important information on the physical and chemical properties of these planets. However, for a more in-depth characterisation of these worlds, more powerful telescopes are needed. Thanks to the high sensitivity of their instruments, the next generation of space observatories (…
Terrestrial exoplanets likely form initial atmospheres through outgassing during and after accretion, although there is currently no first-principles understanding of how to connect a planet's bulk composition to its early atmospheric properties. Important insights into this connection can be gained by assaying meteorites, representative samples of planetary building blocks. We perform laboratory outgassing experiments that use a mass spectrometer to measure the abundances of volatiles released when meteorite samples are heated to 1200 $^{\circ}$C. We find that outgassing from three carbonaceo…
UV radiation can induce photochemical processes in exoplanet atmospheres and produce haze particles. Recent observations suggest that haze and/or cloud layers could be present in the upper atmospheres of exoplanets. Haze particles play an important role in planetary atmospheres and may provide a source of organic material to the surface which may impact the origin or evolution of life. However, very little information is known about photochemical processes in cool, high-metallicity exoplanetary atmospheres. Previously, we investigated haze formation and particle size distribution in laboratory…
Helium escaping from the atmosphere of a nearby rocky exoplanet orbiting in a habitable zone
Harvard University（哈佛大学）；Carnegie Science Observatories（卡内基科学天文台）；Center for Astrophysics, Harvard & Smithsonian（哈佛-史密森天体物理中心）；School of Engineering and Applied Sciences, Harvard University（哈佛工程学院与应用科学学院）；Kavli Institute for Astrophysics and Space Research, Massachusetts Institute of Technology（麻省理工学院卡弗里天体物理学与空间研究所）；Department of Earth, Atmospheric and Planetary Sciences, Massachusetts Institute of Technology（麻省理工学院地球、大气和行星科学系）；Earth and Planets Laboratory, Carnegie Institution for Science（卡内基科学机构地球与行星实验室）；Space Telescope Science Institute（太空望远镜科学研究所）；Department of Physics & Astronomy, Johns Hopkins University（约翰斯·霍普金斯大学物理与天文系）；Department of Physics, Washington University（华盛顿大学物理系）
We apply the picket fence treatment to model the effects brought about by spectral lines on the thermal structure of irradiated atmospheres. The lines may be due to purely absorption processes, purely coherent scattering processes or some combination of absorption and scattering. If the lines arise as a pure absorption process, the surface layers of the atmosphere are cooler whereas this surface cooling is completely absent if the lines are due to pure coherent isotropic scattering. The lines also lead to a warming of the deeper atmosphere. The warming of the deeper layers is, however, indepen…
The transmission spectra of exoplanet atmospheres observed with the Hubble Space Telescope (HST) in the near-infrared range (1.1-1.65$μ$m) frequently show evidence for some combination of clouds and hazes. Identification of systematic trends in exoplanet clouds and hazes is potentially important for understanding atmospheric composition and temperature structure. Here we report on the analysis of spectral modulation using a large, uniformly processed sample of HST/WFC3 transit spectra from 62 exoplanets. The spectral retrieval includes the capability to detect and represent atmospheres in whic…
Emission spectroscopy is a promising technique to observe atmospheres of rocky exoplanets, probing both their chemistry and thermal profiles. We present HyDRo, an atmospheric retrieval framework for thermal emission spectra of rocky exoplanets. HyDRo does not make prior assumptions about the background atmospheric composition, and can therefore be used to interpret spectra of secondary atmospheres with unknown compositions. We use HyDRo to assess the chemical constraints which can be placed on rocky exoplanet atmospheres using JWST. Firstly, we identify the best currently-known rocky exoplanet…
We investigate the abiotic production of oxygen and its photochemical byproduct ozone through water vapor photolysis in moist atmospheres of temperate terrestrial exoplanets. The amount of water vapor available for photolysis in the middle atmosphere of a planet can be limited by an atmospheric cold-trap, the formation of which largely depends on the amount of non-condensable gases. We study this effect using a photochemical model coupled to a 1D radiative-convective equilibrium model in atmospheres with N2, CO2 and H2O as the main constituents. We find that in atmospheres with a low N2 invent…
The James Webb Space Telescope (JWST) will offer the first opportunity to characterize terrestrial exoplanets with sufficient precision to identify high mean molecular weight atmospheres, and TRAPPIST-1's seven known transiting Earth-sized planets are particularly favorable targets. To assist community preparations for JWST, we use simulations of plausible post-ocean-loss and habitable environments for the TRAPPIST-1 exoplanets, and test simulations of all bright object time series spectroscopy modes and all MIRI photometry filters to determine optimal observing strategies for atmospheric dete…
