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arXiv 2304.04993cond-mat.supr-con
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等价组成对高熵REOBiS$_2$(RE = La, Ce, Pr, Nd, Sm, Gd)单晶超导性质的影响

Effects of equivalent composition on superconducting properties of high-entropy REOBiS$_2$ (RE = La, Ce, Pr, Nd, Sm, Gd) single crystals

Yuma Fujita, Masanori Nagao, Akira Miura, Daisuke Urushihara, Yoshikazu Mizuguchi, Yuki Maruyama, Satoshi Watauchi, Yoshihiko Takano, Isao Tanaka

AI总结:

本研究通过助熔剂法生长高熵REOBiS$_2$单晶,发现RE元素的等价与非等价构型显著影响其超导各向异性等性质,为调节超导转变温度提供了新方法。

摘要:

超导体受高熵合金(HEAs)影响;这些已在各种功能材料中得到研究。采用助熔剂法成功生长了在RE位具有HEAs的REOBiS$_2$(RE = La, Ce, Pr, Nd, Sm和Gd的不同组合)单晶。所得晶体呈板状(1 mm$^2$),具有发育良好的c面。Ce以三价(Ce$^{3+}$)和四价(Ce$^{4+}$)电子构型存在;在所有单晶中,RE位的Ce$^{4+}$浓度约为10 at%。单晶显示出1.2-4.2 K内零电阻的超导转变温度。晶体的超导转变温度、超导各向异性、电子比热系数和Debye温度与RE位的混合熵不相关。除电子比热系数外,这些参数作为混合熵函数的变化趋势在等价和非等价RE元素组成中表现出不同。因此,RE元素的构型影响REOBiS$_2$单晶的超导性质,暗示了一种调节转变温度的方法。

英文摘要:

Superconductors are influenced by high-entropy alloys (HEAs); these have been investigated in various functional materials. REOBiS$_2$ (RE = La, Ce, Pr, Nd, Sm, and Gd in different combinations) single crystals with HEAs at the RE-site were successfully grown using the flux method. The obtained crystals were plate-shaped (1 mm$^2$) with a well-developed c-plane. Ce was present in both trivalent (Ce$^{3+}$) and tetravalent (Ce$^{4+}$) electronic configurations; the concentration of Ce$^{4+}$ at the RE-site was approximately 10 at% in all single crystals. The single crystals showed superconducting transition temperature with zero resistivity within 1.2-4.2 K. The superconducting transition temperature, superconducting anisotropy, electronic specific heat coefficient, and Debye temperature of the crystals were not correlated with the mixed entropy at the RE-site. Except for the electronic specific heat coefficient, the variation of these parameters as a function of mixed entropy showed different trends for equivalent and non-equivalent RE element compositions. Thus, the configuration of RE elements influences the superconducting properties of REOBiS$_2$ single crystals, alluding to a method of modulating transition temperatures.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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