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arXiv 2203.00149cond-mat.softphysics.bio-ph
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通过长程分子相互作用理解布朗但非高斯扩散

Understanding Brownian yet non-Gaussian diffusion via long-range molecular interactions

Francisco E. Alban Chacón, Erick A. Lamilla Rubio, Manuel S. Alvarez Alvarado

AI总结:

本文提出包含分子相互作用的综合数学模型,基于Gennes界面理论和朗之万动力学,证明弱相互作用流体中长程作用导致拉普拉斯位移分布,相变解释高扩散性及向高斯分布演化,理论与实验数据定性定量相符。

摘要:

近年来,在生物和软物质物理学领域的胶体悬浮液实验中,报告了粒子位移呈现正态扩散且具有拉普拉斯概率分布(即布朗但非高斯扩散)的现象。为了对这一行为进行建模,人们提出了不同的随机模型,这些模型都引入了新的随机元素,以涵盖我们对介质信息的缺乏。尽管这些模型在实际中有效,但由于其自身性质,深入理解在布朗但非高斯扩散中介质如何与自身及布朗粒子相互作用,超出了它们的研究目的和范围。因此,本文提出了一个包含分子相互作用的综合数学模型来解释布朗但非高斯扩散。基于Gennes的界面理论和朗之万动力学,研究表明,在弱相互作用流体中以及零黏度的微观体系下,长程相互作用会导致粒子位移呈现拉普拉斯概率分布。此外,研究表明,相变能够解释高扩散性,并导致这种拉普拉斯分布通过时间间隔内的转移概率向高斯分布演化,正如实验中所观察到的那样。为了验证这些模型预测,本文使用了Wang等人关于磷脂双层上胶体珠布朗运动的实验数据,并与理论结果进行了比较。这种比较表明,所提出的模型不仅能够定性地解释布朗但非高斯扩散,而且能够定量地解释。

英文摘要:

In the last years, a few experiments in the fields of biological and soft matter physics in colloidal suspensions have reported normal diffusion with a Laplacian probability distribution in the particles displacements (i.e., Brownian yet non Gaussian diffusion). To model this behavior different stochastic models had been proposed, with all of them introducing new random elements that incorporate our lack of information about the media. Although these models work in practice, due to their own nature a thorough understanding of how the media interacts with itself and with the Brownian particle in Brownian yet non Gaussian diffusion is outside of their aim and scope. For this reason, a comprehensive mathematical model to explain Brownian yet non Gaussian diffusion that includes molecular interactions is proposed in this paper. Based on the theory of interfaces by Gennes and Langevin dynamics, it is shown that long-range interactions in a weakly interacting fluid and in a microscopic regime of zero viscosity leads to a Laplacian probability distribution in the particles displacements. Further, it is shown that a phase transition can explain a high diffusivity and causes this Laplacian distribution to evolve towards a Gaussian via a transition probability in the interval of time as it was observed in experiments. To validate these model predictions, the experimental data of the Brownian motion of colloidal beads on phospholipid bilayer by Wang et al. is used and compared with the results of the theory. This comparison suggests that the proposed model not only is able to explain qualitatively the Brownian yet non-Gaussian diffusion, but also quantitatively.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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