Thermoelectric effects in metals are typically small due to the nearly-perfect particle-hole (PH) symmetry around their Fermi surface [1, 2]. Despite being initially considered paradoxical [3], thermophase effects [4-8] and linear thermoelectricity [9] in superconducting systems were identified only when PH symmetry is explicitly broken [10-14]. Here, we experimentally demonstrate that a superconducting tunnel junction can develop a very large bipolar thermoelectric effect in the presence of a nonlinear thermal gradient thanks to spontaneous PH symmetry breaking [15]. Our junctions show a maximum thermovoltage of $\pm150\; μ$ V at $\pm650$ mK, directly proportional to the superconducting gap. Notably, the corresponding Seebeck coefficient of $\pm300\; μ$V/K is roughly $10^5$ times larger than the one expected for a normal metal at the same temperature [16, 17]. Moreover, by integrating our junctions into a Josephson interferometer, we realize a bipolar thermoelectric Josephson engine (BTJE) [18] with phase-coherent thermopower control [19]. When connected to a generic load, the BTJE generates a phase-tunable electric power up to about 140 mW/m$^2$ at subKelvin temperatures. In addition, our device implements the prototype for a persistent thermoelectric memory cell, written or erased by current injection [20]. We expect that our findings will trigger thermoelectricity in PH symmetric systems, and will lead to a number of groundbreaking applications in superconducting electronics [21], cutting-edge quantum technologies [22-24] and sensing [25].
Not so long ago, thermoelectricity in superconductors was believed to be possible only by breaking explicitly the particle-hole symmetry. Recently, it has been theoretically predicted that a superconducting tunnel junction can develop bipolar thermoelectric phenomena in the presence of a large thermal gradient owing to non-equilibrium spontaneous PH symmetry breaking. The experimental realization of the first thermoelectric Josephson engine then followed. Here, we give a more extended discussion and focus on the impact of the Josephson contribution on thermoelectricity modulating the Cooper pa…
Superconducting tunnel junctions constitute the units of superconducting quantum circuits and are massively used both for quantum sensing and quantum computation. In previous works, we predicted the existence of a nonlinear thermoelectric effect in a electron-hole symmetric system, namely, a thermally biased tunnel junction between two different superconductors, where the Josephson effect is suppressed. In this paper we investigate the impact of the phase-coherent contributions on the thermoelectric effect, by tuning the size of the Josephson coupling changing the flux of a direct-current Supe…
We investigate the noise current in a thermally biased tunnel junction between two superconductors with different zero-temperature gaps. When the Josephson effect is suppressed, this structure can support a nonlinear thermoelectric effect due to the spontaneous breaking of electron-hole symmetry, as we recently theoretically predicted. We discuss the possibly relevant role played by the noise in the junction. While a moderate noise contribution assists the generation of the thermoelectric signal, further unveiling the spontaneous nature of the electron-hole symmetry breaking, a large noise con…
The thermoelectric effects in semiconducting single-walled carbon nanotubes (SWCNTs) are investigated based on the linear response theory combined with the thermal Green's function method. It is shown that the electronic states near the lowest conduction band minimum and the highest valence band maximum can be effectively described in terms of one-dimensional (1D) Dirac electrons to which a theoretical scheme is developed to describe the thermoelectric responses making it possible to study the effects of inter-band impurity scattering and in-gap states. Using the proposed scheme, the bipolar t…
The thermoelectric performance of a topological Josephson nonlocal heat engine is thoroughly investigated. The nonlocal response is obtained by using a normal metal probe coupled with only one of the proximized helical edges in the middle of the junction. In this configuration, we investigate how the flux bias and the phase bias trigger the nonlocal thermoelectric effects under the application of a thermal difference between the superconducting terminals. Possible experimental nonidealities such as asymmetric proximized superconducting gaps are considered showing how the nonlocal response can …
It is known that Josephson junction (JJ) hosting scattering centers with energy-dependent scattering amplitudes which breaks the $ω\rightarrow-ω$ symmetry (where $ω$ is the excitation energy of electron about the Fermi level) exhibits finite thermoelectric response. In contrast, here we show that even in a ballistic JJ this symmetry is broken and it leads to a non-zero thermoelectric response when the junction length is of the order of coherence length of the superconductor and the corresponding thermoelectric coefficient confirms to the universal sinusoidal dependence on $ϕ_{12}$, where $ϕ_{1…
We demonstrate that thermoelectric signal as well as dc Josephson current may be severely enhanced in multi-terminal superconducting hybrid nanostructures exposed to a temperature gradient. At temperatures $T$ strongly exceeding the Thouless energy of our device both the supercurrent and the thermo-induced voltage are dominated by the contribution from non-equilibrium low energy quasiparticles and are predicted to decay slowly (algebraically rather than exponentially) with increasing $T$. We also predict a non-trivial current-phase relation and a transition to a $π$-junction state controlled b…
We discuss the phase dependent nonlocal thermoelectric effect in a topological Josephson junction in contact with a normal-metal probe. We show that, due to the helical nature of topological edge states, nonlocal thermoelectricity is generated by a purely Andreev interferometric mechanism. This response can be tuned by imposing a Josephson phase difference, through the application of a dissipationless current between the two superconductors, even without the need of applying an external magnetic field. We discuss in detail the origin of this effect and we provide also a realistic estimation of…
We consider a Josephson junction hosting a Kramers pair of helical edge states of a quantum spin Hall bar in contact with a normal-metal probe. In this hybrid system, the orbital phase induced by a small magnetic field threading the junction known as Doppler shift (DS), combines with the conventional Josephson phase difference and originates an effect akin to a Zeeman field in the spectrum. As a consequence, when a temperature bias is applied to the superconducting terminals, a thermoelectric current is established in the normal probe. We argue that this purely non-local thermoelectric effect …
Thermocurrent flowing through a single-molecule device contains valuable information about the quantum properties of the molecular structure and, in particular, on its electronic and phononic excitation spectra, and entropy. Furthermore, accessing the thermoelectric heat-to-charge conversion efficiency experimentally can help to select suitable molecules for future energy conversion devices, which - predicted by theoretical studies - could reach unprecedented efficiencies. However, one of the major challenges in quantifying thermocurrents in nanoscale devices is to determine the exact temperat…
In the linear regime, thermo-electric effects between two conductors are possible only in the presence of an explicit breaking of the electron-hole symmetry. We consider a tunnel junction between two electrodes and show that this condition is no longer required outside the linear regime. In particular, we demonstrate that a thermally-biased junction can display an absolute negative conductance (ANC), and hence thermo-electric power, at a small but finite voltage bias, provided that the density of states of one of the electrodes is gapped and the other is monotonically decreasing. We consider a…
This paper reviews recent developments in quantum transport and it presents recent efforts to explore the contribution of topological insulator boundary states to thermoelectricity in Bi$_2$Te$_3$ thin films. Although Bi$_2$Te$_3$ has been used as a thermoelectric material for many years, it is only recently that thin films of this material have been synthesized as 3D topological insulators with interesting physics and potential applications related to topologically protected surface states. A major bottleneck in Bi$_2$Te$_3$ thin films has been eliminating its bulk conductivity while increasi…
In the last 60 years conventional solid and electrolyte gating allowed sizable modulations of the surface carrier concentration in metallic superconductors resulting in tuning their conductivity and changing their critical temperature. Recent conventional gating experiments on superconducting metal nano-structures showed full suppression of the critical current without variations of the normal state resistance and the critical temperature. These results still miss a microscopic explanation. In this article, we show a complete set of gating experiments on Ti-based superconducting Dayem bridges …
