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arXiv 2112.03356astro-ph.GAastro-ph.IM
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在ISM中扩展硫代乙酰胺(CH3CSNH2)的亚毫米波光谱学和天文学搜索

Expanding the submillimeter wave spectroscopy and astronomical search for thioacetamide (CH3CSNH2) in the ISM

A. Remijan, C. Xue, L. Margulès, A. Belloche, R. A. Motiyenko, J. Carder, C. Codella, N. Balucani, C. L. Brogan, C. Ceccarelli, T. R. Hunter, A. Maris, S. Melan… 展开作者

A. Remijan, C. Xue, L. Margulès, A. Belloche, R. A. Motiyenko, J. Carder, C. Codella, N. Balucani, C. L. Brogan, C. Ceccarelli, T. R. Hunter, A. Maris, S. Melandri, M. Siebert, B. A. McGuire

摘要:

硫代乙酰胺(CH 3CSNH 2)是乙酰胺(CH 3CONH 2)的硫类似物,它是一个可行的候选者,可以在天文环境中搜索,特别是在已经发现其他含硫分子的区域,如果可能的话,也可以检测到CH 3CONH 2。如果被发现,它不仅将继续扩大天文环境中分子复杂性的观点,而且有助于更好地阐明这些类型物种在这些环境中的可能形成途径。研究了CH 3CSNH 2分子在650 GHz范围内的转动光谱。使用新改进的CH 3CSNH 2光谱,以及化学相关物质CH 3CONH 2的额外光谱数据,搜索了各种天文来源,包括来自以下大型调查的数据:与绿岸望远镜(GBT)进行的PRIMOS;与ALMA进行的探索分子复杂性(EMoCA);和天体化学调查在IRAM(ASAI)进行了与研究所射电天文学毫米(IRAM)30米望远镜。从Vt=0状态到330 GHz的范围内,总共分配了1428个跃迁,其中最大值J=47和Ka=20,并且在400 - 660 GHz的范围内,J=95和Ka=20。我们还分配了321个从Vt=1状态到330 GHz的跃迁,最大值J=35,Ka=9。最终拟合基于包括40个参数的ρ轴方法(RAM)哈密顿模型。根据所有新的光谱数据,对CH 3CSNH 2进行了天文搜索。没有过渡的CH 3CSNH 2被检测到对我们的调查中所包含的任何来源。使用适当的望远镜和物理参数为每个天文来源,上限的柱密度被发现为CH 3CSNH 2对每个源。

英文摘要:

Thioacetamide (CH3CSNH2) is the sulfur analog to acetamide (CH3CONH2) and it is a viable candidate to search for in astronomical environments specifically toward regions where other S-bearing molecules have been found and, if possible, that also contain a detection of CH3CONH2. If detected, it would not only continue to expand the view of molecular complexity in astronomical environments, but also help to better elucidate the possible formation pathways of these types of species in these environments. The rotational spectrum of CH3CSNH2 was investigated up to 650 GHz. Using the newly refined spectrum of CH3CSNH2, as well as additional spectroscopic data on the chemically related species CH3CONH2, a variety of astronomical sources were searched including data from the following large surveys: The PRIMOS conducted with the Green Bank Telescope (GBT); Exploring molecular complexity with ALMA (EMoCA) conducted with ALMA; and Astrochemical Surveys at IRAM (ASAI) conducted with the Institut de Radioastronomie Millimetrique (IRAM) 30m Telescope. A total of 1428 transitions from the vt=0 state with maximum values J=47 and Ka=20 in the range up to 330 GHz, and J=95 and Ka=20 in the range from 400 - 660 GHz were assigned. We also assigned 321 transitions from the vt=1 state with the maximum values J=35 and Ka=9 up to 330 GHz. The final fit is based on the rho-axis-method (RAM) Hamiltonian model that includes 40 parameters. An astronomical search for CH3CSNH2 was conducted based on all the new spectroscopic data. No transitions of CH3CSNH2 were detected toward any of the sources contained in our survey. Using the appropriate telescope and physical parameters for each astronomical source, upper limits to the column densities were found for CH3CSNH2 toward each source.

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