Recently, multifold fermions characterized by band crossings with multifold degeneracy and Fermi surfaces with nontrivial Chern numbers have been discovered experimentally in AlPt[arXiv:1812.03310] and XSi(X=Rh,Co)[arXiv:1812.04466][arXiv:1901.03358][arXiv:1809.01312]. In this work, we largely expand the family of multifold fermion materials by pointing out that several well-studied noncentrosymmetric superconductors are indeed multifold fermion metals. Importantly, their normal state topological properties, which have been ignored in previous studies, play an important role in the superconducting properties. Taking Li$_2$Pd$_3$B and Li$_2$Pt$_3$B as examples, we found a large number of unconventional degenerate points, such as double spin-1, spin-3/2, Weyl and double Weyl topological band crossing points near the Fermi energy, which result in finite Chern numbers on Fermi surfaces. Long Fermi arc states in Li$_2$Pd$_3$B, originating from the nontrivial band topology were found. Importantly, it has been shown experimentally that Li$_2$Pd$_3$B and Li$_2$Pt$_3$B are fully gapped and gapless superconductors, respectively. By analyzing the possible pairing symmetries, we suggest that Li$_2$Pd$_3$B can be a DIII class topological superconductor with Majorana surface states, even though the spin-orbit coupling in Li$_2$Pd$_3$B is negligible. Interestingly, Li$_2$Pt$_3$B, being gapless, is likely to be a nodal topological superconductor with dispersionless surface Majorana modes. We further identified that several noncentrosymmetric superconductors, such as Mo$_3$Al$_2$C, PdBiSe, Y$_2$C$_3$ and La$_2$C$_3$, are multifold fermion superconductors whose normal state topological properties have been ignored in previous experimental and theoretical studies.
We study three-dimensional time-reversal-invariant topological superconductivity in noncentrosymmetric materials such as RhSi, CoSi, and AlPt which host coupled multifold nodes energetically split by the spin-orbit coupling at the same time-reversal-invariant momentum (TRIM). The topological superconductivity arises from the $s_{+} \oplus s_{-}$ gap function, which is $\boldsymbol{k}$ independent, but with opposite signs for the two nodes split at the same TRIM. We consider various electron-electron interactions in the tight-binding model for RhSi and find that the topological superconducting …
We show that the chiral multifold fermions present a dual Haldane sphere problem in momentum space. Owing to the Berry monopole at the degenerate point, a dual Landau level emerges in the trace of quantum metric, with which a quantized geometric invariant is defined through a surface integration. We further demonstrate potential manifestations in the measurable, physical observables. With a lower bound derived for the finite spread of Wannier functions, anomalous phase coherence is identified accordingly for the flat band superconductivity. We briefly comment on the stability of these results …
Unconventional Superconductivity in the Chiral Topological Semimetal Ag2Pd3S
Indian Institute of Science Education and Research Bhopal（印度科学教育研究所博帕尔分校）；Indian Institute of Technology, Kanpur（坎普尔印度理工学院）；McMaster University（麦克马斯特大学）；Technion-Israel Institute of Technology（以色列理工学院）
We explore a spin-fermion model with fermion-spin-quadrupolar interaction. In a nematic phase, this interaction reduces to a four-fermion interaction that is a basis of superconductivity. When the coupling constant is positive the superconductivity is p-wave with spin-parallel paired fermions. When it is negative the superconductivity is p-wave and fermions are spin-antiparallel paired. For a system with zero chemical potential, even a very small coupling can bind fermions into bound state that leads to the superconductivity. When the chemical potential is non-zero the system possesses quantum…
This review discusses the heavy-fermion superconductivity in Ce- and U-based compounds crystallizing in the body-centered tetragonal ThCr2Si2 structure. Special attention will be paid to the theoretical background of these systems which are located close to a magnetic instability.
Charge density waves and superconductivity in the electron-positive fermion gas using a simple intuitive model. Part II: Collective modes, effective interactions, superconductivity, and transport
We find new mechanism of superconductivity beyond the spin-fluctuation theory, the standard model for unconventional superconductivity in the weak coupling approach, where Kondo fluctuations result in multi-gap superconductivity around an antiferromagnetic quantum critical point of the slave-fermion theory. Fingerprints of the hybridization mechanism are two kinds of resonance modes in not only spin but also charge fluctuations, originating from $d-wave$ pairing of conduction electrons and spinless holons, respectively, thus differentiated from the spin-fluctuation mechanism. We show that the …
For two-dimensional single-valley quadratic band crossing systems with weak repulsive electron-electron interactions, we show that upon introducing a chemical potential, particle-hole order is suppressed and superconductivity becomes the leading instability. In contrast to the two-valley case realized in bilayer graphene, the single-valley quadratic band touching is protected by crystal symmetries, and the different symmetries and number of fermion flavors can lead to distinct phase instabilities. Our results are obtained using a weak-coupling Wilsonian renormalization group procedure on a low…
The quantum critical Antiferromagnetic (AFM) fluctuation spectra measured by inelastic neutron scattering recently in two heavy fermion superconductors are used together with their other measured properties to calculate their D-wave superconducting transition temperatures $T_{\rm c}$. To this end, the linearized Eliashberg equations for D-wave superconductivity induced by AFM fluctuations are solved in models of fermions with various levels of nesting. The results for the ratio of $T_{\rm c}$ to the characteristic spin-fluctuation energy are well parametrized by a dimensionless coupling consta…
We discuss the mechanisms of unconventional superconductivity and superfluidity in 3D and 2D fermionic systems with purely repulsive interaction at low densities. We construct phase diagrams of these systems and find the areas of the superconducting state in free space, as well as on the lattice in the framework of the Fermi-gas model with hard-core repulsion, the Hubbard model, the Shubin-Vonsovsky model, and the $t-J$ model. We demonstrate that the critical superconducting temperature can be greatly increased in the spin-polarized case or in a two-band situation already at low densities. The…
Topological crystalline metals/semimetals (TCMs) have stimulated a great research interest, which broaden the classification of topological phases and provide a valuable platform to explore topological superconductivity. Here, we report the discovery of superconductivity and topological features in Pb-intercalated transition-metal dichalcogenide Pb$_{1/3}$TaS$_2$. Systematic measurements indicate that Pb$_{1/3}$TaS$_2$ is a quasi-two-dimensional (q-2D) type-II superconductor ({\em T}$_c \approx$ 2.8 K) with a significantly enhanced anisotropy of upper critical field ($γ_{H_{c2}}$ = $H_{c2}^{ab…
As a half-metal is spin-polarized at its Fermi level by definition, it was conventionally thought to have little proximity effect to an s-wave superconductor. Here we show that, with interface spin-orbit coupling, $p_x +ip_y$ superconductivity without spin degeneracy is induced on the half-metal, and we give an estimate of its bulk energy gap. Therefore a single-band half-metal can give us a topological superconductor with a single chiral Majorana edge state. Our band calculation shows that two atomic layers of VTe or CrO$_2$ is a single-band half-metal for a wide range ($\sim$0.1eV) of Fermi …
To explore whether a flat-band system can accommodate superconductivity, we consider repulsively interacting fermions on the diamond chain, a simplest quasi-one-dimensional system that contains a flat band. Exact diagonalization and the density-matrix renormalization group (DMRG) are used to show that we have a significant binding energy of a Cooper pair with a long-tailed pair-pair correlation in real space when the total band filling is slightly below $1/3$, where the dispersive band interacts with the flat band that is empty but close to $E_F$. Pairs selectively formed across the outer site…
Cooper's one pair problem is investigated for a 2D lattice in the background of both passive and active Fermi sea in a weakly correlated environment. Boson exchange mechanisms involving excitons as well as phonons are invoked for pairing in the s- wave channel. The important quantities calculated are pairing energy and coherence length as functions of bosonic energy, attracted coupling constant and band filling factor. Comparison of our theoretical results with those from experiments on overdoped cuprate superconductors and other type of theoretical calculations show electronic mechanism to be…
We describe boundary effects in superconducting systems with Fulde-Ferrell-Larkin-Ovchinnikov (FFLO) superconducting instability, using Bogoliubov-de-Gennes and Ginzburg-Landau (GL) formalisms. First, we show that in dimensions larger than one the standard GL functional formalism for FFLO superconductors is unbounded from below. This is demonstrated by finding solutions with zero Laplacian terms near boundaries. We generalize the GL formalism for these systems by retaining higher order terms. Next, we demonstrate that a cuboid sample of a superconductor with imbalanced fermions at a mean-field…
Large Hubbard U limit of the Kane-Mele model on a zigzag ribbon of honeycomb lattice near half-filling is studied via a renormalized mean-field theory. The ground state exhibits time-reversal symmetry (TRS) breaking d + i d'-wave superconductivity. At large spin-orbit coupling, the Z2 phase with non-trivial spin Chern number in the pure Kane-Mele model is persistent into the TRS broken state (called spin-Chern phase), and has two pairs of counter-propagating helical Majorana modes at the edges. As the spin-orbit coupling is reduced, the system undergoes a topological quantum phase transition f…
The heavy fermion CeMIn5 family with M = Co, Rh, Ir provide a prototypical example of strange superconductors with unconventional d-wave pairing and strange metal normal state, emerged near an antiferromagnetic quantum critical point. The microscopic origin of strange superconductor and its link to antiferromagnetic quantum criticality and strange metal state are still open issues. We propose a microscopic mechanism for strange superconductor, based on the coexistence and competition between the Kondo correlation and the quasi-2d short-ranged antiferromagnetic resonating-valence-bond spin-liqu…
Based on specific heat and magnetoresistance measurements, we report that a "heavy" electronic state exists below $T \approx$ 20 K in KNi$_2$Se$_2$, with an increased carrier mobility and enhanced effective electronic band mass, $m$* = 6$m_b$ to 18$m_b$. This "heavy" state evolves into superconductivity at $T_c$ = 0.80(1) K. These properties resemble that of a many-body heavy-fermion state, which derives from the hybridization between localized magnetic states and conduction electrons. Yet, no evidence for localized magnetism or magnetic order is found in KNi$_2$Se$_2$ from magnetization measu…
Since the discovery of the cuprate high-temperature superconductivity in 1986, a universal phase diagram has been constructed experimentally and numerous theoretical models have been proposed. However, there remains no consensus on the underlying physics thus far. Here, we theoretically investigate the phase diagram of hole-doped cuprates based on an itinerant-localized dual fermion model, with the charge carriers doped on the oxygen sites and localized holes on the copper $d_{x^{2}-y^{2}}$ orbitals. We analytically demonstrate that the puzzling anomalous normal state or the strange metal coul…
Spin-orbit coupled superconductors are potentially interesting candidates for realizing topological and potentially non-Abelian states with Majorana Fermions. We argue that time-reversal broken spin-orbit coupled superconductors generically can be characterized as having sub-gap states that are bound to localized non-magnetic impurities. Such bound states, which are referred to as Shiba states, can be detected as sharp resonances in the tunneling spectrum of the spin-orbit coupled superconductors. The Shiba state resonance can be tuned using a gate-voltage or a magnetic field from being at the…
Charge density waves and superconductivity in the electron-positive fermion gas using a simple intuitive model. Part I: The model, instabilities, and phase diagram
We study a model of a two-dimensional repulsive Fermi gas with Rashba spin-orbit coupling $α_R$, and investigate the superconducting instability using renormalization group approach. We find that in general superconductivity is enhanced as the dimensionless ratio 1/2mα_R^2/E_F$ increases, resulting in unconventional superconducting states which break time reversal symmetry.
We discuss a physical mechanism of a non-BCS nature which can stabilize a superconducting state in a {\it strongly repulsive} electronic system. By considering the two-dimensional Hubbard model with spatially modulated electron hoppings, we demonstrate how kinetic-energy frustration can lead to robust d-wave superconductivity at {\it arbitrarily} large on-site repulsion. This phenomenon should be observable in experiments using fermionic atoms, e.g. ${}^{40}K$, in specially prepared optical lattices.
Near a quantum-critical point in a metal strong fermion-fermion interaction mediated by a soft collective boson gives rise to incoherent, non-Fermi liquid behavior. It also often gives rise to superconductivity which masks the non-Fermi liquid behavior. We analyze the interplay between superconductivity and fermionic incoherence for a set of quantum-critical models with effective dynamical interaction between low-energy fermions. We argue that superconductivity always develops above a quantum-critical point, no matter how strong the fermionic self-energy is. We argue that superconductivity sho…
Heavy fermions have served as prototype examples of strongly-correlated electron systems. The occurrence of unconventional superconductivity in close proximity to the electronic instabilities associated with various degrees of freedom points to an intricate relationship between superconductivity and other electronic states, which is unique but also shares some common features with high temperature superconductivity. The magnetic order in heavy fermion compounds can be continuously suppressed by tuning external parameters to a quantum critical point, and the role of quantum criticality in deter…
In heavy fermion systems, higher-rank multipole operators are active thanks to the strong spin-orbit interaction (SOI), and the role of diverse multipole fluctuations on the pairing mechanism attracts a lot of attention. Here, we study a mechanism of superconductivity in heavy fermion systems, by focusing on the impact of vertex corrections (VCs) for the pairing interaction going beyond the Migdal approximation. In heavy fermion systems, strong interference between multipole fluctuations cause significant VCs, that represent many-body effects beyond mean-field-type approximations. Especially, …
Superconductivity in strongly correlated electron systems frequently emerges in proximity to another broken symmetry. In heavy-electron superconductors, the nearby ordered state most commonly is magnetism, and the so-called Ce115 heavy-electron compounds have been particularly instructive for revealing new relationships between magnetism and superconductivity. From measurements of the resistive and bulk transitions to superconductivity in these materials, we find that the resistive transition appears at a temperature considerably higher than the bulk transition when superconductivity and magne…
To identify the microscopic mechanism of heavy-fermion Cooper pairing is an unresolved challenge in quantum matter studies; it may also relate closely to finding the pairing mechanism of high temperature superconductivity. Magnetically mediated Cooper pairing has long been the conjectured basis of heavy-fermion superconductivity but no direct verification of this hypothesis was achievable. Here, we use a novel approach based on precision measurements of the heavy-fermion band structure using quasiparticle interference (QPI) imaging, to reveal quantitatively the momentum-space (k-space) structu…
Motivated by a scarcity of simple and analytically tractable models of superconductivity from strong repulsive interactions, we introduce a simple tight-binding lattice model of fermions with repulsive interactions that exhibits unconventional superconductivity (beyond BCS theory). The model resembles an idealized conductor-dielectric-conductor trilayer. The Cooper pair consists of electrons on opposite sides of the dielectric, which mediates the attraction. In the strong coupling limit, we use degenerate perturbation theory to show that the model reduces to a superconducting hard-core Bose-Hu…
Inspired by the recent experimental evidence of antiferromagnetism and superconductivity coexistence in heavy fermion CeRhIn$_5$, we propose a fully microscopic approach based on the idea of real space pairing within the Anderson-Kondo lattice model. We present an overall phase diagram incorporating the emergence of a quantum critical point, where Kondo insulating (KI), antiferromagnetic (AF) and superconducting (SC) phases meet. We also obtain the Kondo insulating state with totally compensated magnetic moments as the parental state for the emerging SC phases. Furthermore, the coexistent (AF+…
We use the spin-fermion model to describe the CuO$_2$ planes of the high-Tc superconductors. Using a large wavelength approach, we show that the ferromagnetic component of the Cu spin fluctuations couple to the oxygen holes producing a pairing interaction that leads to a superconducting gap whose symmetry is determined by the anisotropy of the Kondo interaction. We calculate Tc as a function of the hole concentration in a mean-field approximation and our numerical results are in good agreement with the experiments.
Heavy fermion superconductivity: X-boson treatment
我们用X玻色子方法研究了重费米子超导性，在$ U = \infty $极限下，扩展了周期性Anderson模型，在局域$ f $ -电子之间存在最近邻吸引相互作用，我们表明，较高的杂化参数值意味着与超导临界温度最大值相关的较低的杂化参数值$ T_{c} $，这表明能带之间的真实电荷转移倾向于使库珀配对不稳定。此外，我们表明，超导性被限制在附近的职业范围内，在费米能级$ ρ_{f} (μ) $的$ f $ -带态密度有足够高的值，虽然超导性被发现的配置，系统目前的中间价和重费米子的行为，实验观察到。最后，随着总占有率的提高和杂交参数$ V $的增加，存在绝缘体-超导体转变，这与存在无法通过从玻色子方法获得的杂交间隙有关。
Superconductivity in lanthanide- and actinide-based heavy-fermion metals can have different microscopic origins. Among others, Cooper pair formation based on fluctuations of the valence, of the quadrupole moment or of the spin of the localized 4f/5f shell have been proposed. Spin-fluctuation mediated superconductivity in CeCu2Si2 was demonstrated by inelastic neutron scattering to exist in the vicinity of a spin-density-wave quantum critical point. The isostructural HF compound YbRh2Si2 which is prototypical for a Kondo-breakdown quantum critical point has so far not shown any sign of supercon…
Point contact conductance measurements on topological $Bi_2Te_2Se$ and $Bi_2Se_3$ films reveal a signature of superconductivity below 2-3 K. In particular, critical current dips and a robust zero bias conductance peak are observed. The latter suggests the presence of zero energy bound states which could be assigned to Majorana Fermions in an unconventional topological superconductor. We attribute these novel observations to proximity induced local superconductivity in the films by small amounts of superconducting Bi inclusions or segregation to the surface, and provide supportive evidence for …
In superconductors, electrons bound into Cooper pairs conduct a dissipationless current. The strength of the Cooper pairs scales with the value of the critical transition temperature (Tc). In cuprate high-Tc superconductors, however, the pairing mechanism is still unexplained. Here we unveil why in the cuprates the Cooper pairs are so strongly bound to work out the extraordinary high Tc. From one-to-one correspondence between numerical simulation on a microscopic cuprate model and a simple two-component fermion model, we show that hidden fermions emerge from the strong electron correlation and…
