The quantum critical Antiferromagnetic (AFM) fluctuation spectra measured by inelastic neutron scattering recently in two heavy fermion superconductors are used together with their other measured properties to calculate their D-wave superconducting transition temperatures $T_{\rm c}$. To this end, the linearized Eliashberg equations for D-wave superconductivity induced by AFM fluctuations are solved in models of fermions with various levels of nesting. The results for the ratio of $T_{\rm c}$ to the characteristic spin-fluctuation energy are well parametrized by a dimensionless coupling constant and the AFM correlation length. Comparing the results with experiments suggests that one may reasonably conclude that superconductivity in these compounds is indeed caused by AFM fluctuations. This conclusion is strengthened by a calculation with the same parameters of the measured coefficient of the normal state quantum-critical resistivity $\propto T^{3/2}$ characteristic of {\it gaussian} AFM quantum-critical fluctuations. The calculations give details of the superconducting coupling as a function of the correlation length and the integrated fluctuation spectra useful in other compounds.
We report superconductivity in novel iron-based compounds Ca10(PtnAs8)(Fe2-xPtxAs2)5 with n = 3 and 4. Both compounds crystallize in triclinic structures (space group P-1), in which Fe2As2 layers alternate with PtnAs8 spacer layers. Superconductivity with a transition temperature of 38 K is observed in the n = 4 compound with a Pt content of x ~ 0.36 in the Fe2As2 layers. The compound with n = 3 exhibits superconductivity at 13 K.
Crystal structure and physical properties of the novel BiS2-based layered superconductors are briefly reviewed. Superconductivity in the BiS2-based layered compounds is induced by electron doping into the BiS2 conduction layers. The superconducting properties seem to correlate with the crystal structure. Possible strategies for increasing transition temperature in this family are discussed.
This review discusses the heavy-fermion superconductivity in Ce- and U-based compounds crystallizing in the body-centered tetragonal ThCr2Si2 structure. Special attention will be paid to the theoretical background of these systems which are located close to a magnetic instability.
We investigate the superconductivity of carbon compounds with a sodalite structure, which are similar to hydrogen compounds showing the high-temperature superconductivity. A systematic analysis by first-principles calculations is carried out, including examination of mechanical and dynamic instabilities under external pressure $P$. These instabilities are classified on the phase diagram for the effective doping charge versus the lattice constant of the system. We also present the superconducting transition temperature $T_{\rm c}$ as a function of $P$ for many carbon compounds and a pure carbon…
We give a brief review of superconductivity at ambient pressure in elements, alloys, and simple three-dimensional compounds. Historically these were the first superconducting materials studied, and based on the experimental knowledge gained from them the BCS theory of superconductivity was developed in 1957. Extended to include the effect of phonon retardation, the theory is believed to describe the subset of superconducting materials known as `conventional superconductors', where superconductivity is caused by the electron-phonon interaction. These include the elements, alloys and simple comp…
Superconductivity in the Infinite Layer Compound CaCuO2
研究了电场效应掺杂的无限层状化合物CaCuO_2的超导电性。有人认为，在超导CuO 2层，旁边的绝缘Al 2 O 3覆盖层，铜离子的氧的配位是金字塔形的，而不是正方形平面。这一观点源于现有的NEXAFS和HRETM结果的分析，以及化学方面的考虑，并且主要针对空穴掺杂但也针对电子掺杂区域的相位图进行讨论。
Polycrystalline samples of F-substituted LnOBiS2 (Ln = La, Ce, Pr, Nd, Yb) compounds were synthesized by solid-state reaction. The samples were characterized by x-ray diffraction measurements and found to have the ZrCuSiAs crystal structure. Electrical resistivity and magnetic susceptibility measurements were performed on all of the samples and specific heat measurements were made on those with Ln = La, Ce, and Yb. All of these compounds exhibit superconductivity in the range 1.9 K - 5.4 K, which has not previously been reported for the compounds based on Ce, Pr, and Yb. The YbO0.5F0.5BiS2 com…
Since the discovery of superconductivity in a high-entropy alloy (HEA) Ti-Zr-Nb-Hf-Ta in 2014, the community of superconductor science has explored new HEA superconductors to find the merit of the HEA states on superconducting properties. Since 2018, we have developed HEA-type compounds as superconductors or thermoelectric materials. As well known, compounds like intermetallic compounds or layered compounds are composed of multi crystallographic sites. In a HEA-type compounds, one or more sites are alloyed and total mixing entropy satisfies with the criterion of HEA. Herein, we summarize the s…
We have studied the half-Heusler compound TbPdBi through resistivity, magnetization, Hall effect and heat capacity measurements. A semimetal behavior is observed in its normal state transport properties, which is characterized by a large negative magnetoresistance below 100 K. Notably, we find the coexistence of superconductivity and antiferromagnetism in this compound. The superconducting transition appears at 1.7 K, while the antiferromagnetic phase transition takes place at 5.5 K. The upper critical field $H_{c2}$ shows an unusual linear temperature dependence, implying unconventional super…
The structural misfit compound (PbSe)1.16(TiSe2)2 is reported. It is a superconductor with a Tc of 2.3 K. (PbSe)1.16(TiSe2)2 derives from a parent compound, TiSe2, which shows a charge density wave transition and no superconductivity. The crystal structure, characterized by high resolution electron microscopy and powder x-ray diffraction, consists of two layers of 1T-TiSe2 alternating with a double layer of (100) PbSe. Transport measurements suggest that the superconductivity is induced by charge transfer from the PbSe layers to the TiSe2 layers.
The out-of-plane intercalate phonons of superconducting YbC6 have been measured with inelastic x-ray scattering. Model fits to this data, and previously measured out-of-plane intercalate phonons in graphite intercalation compounds (GICs), reveal surprising trends with the superconducting transition temperature. These trends suggest that superconducting GICs should be viewed as electron-doped graphite.
The field of superconductivity in the class of materials known as graphite intercalation compounds has a history dating back to the 1960s. This paper recontextualizes the field in light of the discovery of superconductivity in CaC6 and YbC6 in 2005. In what follows, we outline the crystal structure and electronic structure of these and related compounds. We go on to experiments addressing the superconducting energy gap, lattice dynamics, pressure dependence, and how this relates to theoretical studies. The bulk of the evidence strongly supports a BCS superconducting state. However, important q…
The iron-based superconductors had a significant impact on condensed matter physics. They have a common structural motif of a two-dimensional square iron lattice and exhibit fruitful physical properties as a strongly correlated electron system. During the extensive investigations, quasi-one-dimensional iron-based spin-ladder compounds attracted much attention as a platform for studying the interplay between magnetic and orbital ordering. In these compounds, BaFe2S3 and BaFe2Se3 were found to exhibit superconductivity under high pressure, having a different crystal and magnetic structure at low…
We discovered a novel annealing method for Fe-chalcogenide superconductors. It was found that sulfur annealing deintercalated excess Fe via formation of FeS2. Due to its specifics, sulfur annealing is applicable when preparing Fe-chalcogenide-based wires or cables.
We found superconductivity in CaSb$_2$ with the transition temperature of 1.7 K by means of electrical-resistivity, magnetic-susceptibility, and specific-heat measurements. This material crystallizes in a nonsymmorphic structure and is predicted to have multiple Dirac nodal lines in the bulk electronic band structure protected by symmetry even in the presence of spin-orbit coupling. We discuss a possible topological superconductivity for the quasi-2-dimensional band originating mainly from one of the antimony sites.
We study the superconductivity in the three-dimensional multiband d-p model, in which a Cu$_2$O$_3$-ladder layer and a CuO$_2$-chain layer are alternately stacked, as a model of the superconducting spin-chain ladder cuprate. $p_z$-Wave-like triplet superconductivity is found to be the most stable, and its dependence on interlayer coupling can explain the superconducting transition temperature dependence on pressure in real superconducting spin-chain ladder cuprates. The superconductivity may be enhanced if hole transfer from the chain layer to the ladder layer can be promoted beyond the typica…
CeNi0.8Bi2 is very recent entrant in superconductivity kitchen [1], and the same seeks reproduction from other groups. We report synthesis, structural details and superconductivity in CeNi0.8Bi2 compound. The CeNi0.8Bi2 compound is synthesized by solid state reaction route via vacuum encapsulation of high purity mixed Ce, Ni, Bi and subsequent heating of the same at 500 0C for 10 hours followed by annealing at 750 0C for 20 hours. As synthesized compounds are dark grey in color and do crystallize in tetragonal structure with space group P4/nmm. The lattice parameters are a = 3.61 Å and c = 10.…
We report superconductivity in polycrystalline samples of the 1038-type compounds (Ca$_{1-x}$RE$_x$)$_{10}$(FeAs)$_{10}$(Pt$_3$As$_8$) up to T$_c$ = 35 K with RE = Y, La-Nd, Sm, Gd-Lu. The critical temperatures are independent of the trivalent rare earth element used, yielding an universal T$_c$($x$) phase diagram for electron doping in all these systems. The absence of superconductivity in Eu$^{2+}$ doped samples, as well as the close resemblance of (Ca$_{1-x}$RE$_x$)$_{10}$(FeAs)$_{10}$(Pt$_3$As$_8$) to the 1048 compound substantiate that the electron doping scenario in the RE-1038 and 1048 …
Systematical doping studies have been carried out to search for the possible superconductivity in the transition metal doped Zr$_5$Ge$_3$ system. Superconductivity up to 5.7K is discovered in the Ru-doped Zr$_5$Ge$_{2.5}$Ru$_{0.5}$ sample. Interestingly, with the same Ru-doping, superconductivity is only induced with doping at the Ge site, but remains absent down to 1.8K with doping at the Zr site or interstitial site. Both magnetic and transport studies have revealed the bulk superconductivity nature for Ru-doped Zr$_5$Ge$_{2.5}$Ru$_{0.5}$ sample. The high upper critical field, enhanced elect…
Kamihara and coworkers' report of superconductivity at Tc = 26 K in fluorine-doped LaFeAsO inspired a worldwide effort to understand the nature of the superconductivity in this new class of compounds. These iron pnictide and chalcogenide (FePn/Ch) superconductors have Fe electrons at the Fermi surface, plus an unusual Fermiology that can change rapidly with doping, which lead to normal and superconducting state properties very different from those in standard electron-phonon coupled 'conventional' superconductors. Clearly superconductivity and magnetism/magnetic fluctuations are intimately rel…
A series of SmFeAsO1-xFx samples were sintered in quartz tubes filled with air of different pressures. The effects of the sintering atmosphere on the superconductivity were systematically investigated. The SmFeAsO1-xFx system maintains a transition temperature (Tc) near 50 K until the concentration of oxygen in quartz tubes increases to a certain threshold, after which Tc decreases dramatically. Fluorine losses, whether due to vaporization, reactions with starting materials, and reactions with oxygen, proved to be detrimental to the superconductivity of this material. The deleterious effects o…
On the basis of the model that was successfully applied to KC8, RbC8, and CsC8 in 1982, we have calculated the superconducting transition temperature Tc for CaC6 and YbC6 to find that the same model reproduces the observed Tc in those compounds as well, indicating that it is a standard model for superconductivity in the graphite intercalation compounds with Tc ranging over three orders of magnitude. Further enhancement of Tc well beyond 10 K is also predicted. The present method for calculating Tc from first principles is compared with that in the density functional theory for superconductors,…
Superconductivity in the Intercalated Graphite Compounds C6Yb and C6Ca
本文报道了在等结构石墨层间化合物C_6Yb和C_6Ca中发现的超导电性，其转变温度分别为6.5K和11.5K。这些化合物的结构表征表明，它们是六方层状系统在同一类的其他石墨插层。如果我们假设所有的外层s-电子都从嵌入物转移到石墨片上，那么这些化合物中的电荷转移与其他超导石墨嵌入物如C8 K 1，2相当。然而，C6 Yb和C6 Ca的超导转变温度高达两个数量级。有趣的是，超导上临界场的研究和电阻率测量表明，这些化合物是显着更各向同性比纯石墨。这是出乎意料的，因为引入插层剂的效果是使石墨层进一步分开。
Phonon density of states, anharmonicity, electron-phonon coupling and possible multigap superconductivity in the clathrate superconductors Ba8Si46 and Ba24Si100: Why is Tc different in these two compounds?
We report the appearance of superconductivity under hydrostatic pressure (0.35 to 2.5GPa) in Sr0.5RE0.5FBiS2 with RE = Ce, Nd, Pr and Sm. The studied compounds, synthesized by solid state reaction route, are crystallized in tetragonal P4/nmm space group. At ambient pressure though the RE = Ce exhibit the onset of superconductivity below 2.5K, the Nd, Pr and Sm samples are not superconducting down to 2K. With application of hydrostatic pressure (up to 2.5GPa), superconducting transition temperature is increased to around 10K for all the studied samples. The magneto-transport measurements are ca…
We report superconductivity at 1.4K in the ternary SrPt$_{10}$P$_4$ with a complex new structure. SrPt$_{10}$P$_4$ crystallizes in a monoclinic space-group C2/c (\#15) with lattice parameters a= 22.9151(9)$Å$, b= 13.1664(5)$Å$, c=13.4131(5)$Å$, and $β$= 90.0270(5)${^\circ}$. Bulk superconductivity in the samples has been demonstrated through resistivity, ac susceptibility, and heat capacity measurements. High pressure measurements have shown that the superconducting T$_C$ is systematically suppressed upon application of pressure, with a dT$_C$/dP coefficient of -0.016 K/GPa.
By interpreting various experimental data for the new high temperature FeAs type superconductors in terms of lattice mediated multi gap superconductivity, it is shown that these systems strongly resemble MgB2, however, with the distinction that local polaronic lattice effects exist. This fact establishes a connection to cuprate high temperature superconductors where polaron formation is essential for the pseudogap phase and the unconventional isotope effects observed there. However, similar to MgB2 and in contrast to cuprates the two superconducting gaps in the Fe-As based materials are isotro…
We study the newly discovered Pt phosphides $A$Pt$_3$P ($A$=Sr, Ca, La) [ T. Takayama et al. Phys. Rev. Lett. 108, 237001 (2012)] using first-principles calculations and Migdal-Eliashberg theory. Given the remarkable agreement with the experiment, we exclude the charge-density wave scenario proposed by previous first-principles calculations, and give conclusive answers concerning the superconducting state in these materials. The pairing increases from La to Ca and Sr due to changes in the electron-phonon matrix elements and low-frequency phonons. Although we find that all three compounds are w…
We report the discovery of superconductivity in pressurized CeRhGe3, until now the only remaining non-superconducting member of the isostructural family of non-centrosymmetric heavy-fermion compounds CeTX3 (T = Co, Rh, Ir and X = Si, Ge). Superconductivity appears in CeRhGe3 at a pressure of 19.6 GPa and the transition temperature Tc reaches a maximum value of 1.3 K at 21.5 GPa. This finding provides an opportunity to establish systematic correlations between superconductivity and materials properties within this family. Though ambient-pressure unit-cell volumes and critical pressures for supe…
The niobium rich selenide compound Nb5Se4 was synthesized at ambient pressure by high-temperature solid-state reaction in a sealed Ta tube. Resistivity and heat capacity measurements reveal that this compound is superconducting, with a T_c = 1.85K. The electronic contribution to the specific heat γ and the Debye temperature are found to be 18.1 mJ/mol/K^2 and 298 K respectively. The calculated electron-phonon coupling constant λ_ep = 0.5 and the ΔC_p/γTc = 1.42 ratio imply that Nb5Se4 is a weak coupling BCS superconductor. The upper critical field and coherence length are found to be 1.44 T an…
Owing to the specific topological states in nodal-line semimetals, novel topological superconductivity is expected to emerge in these systems. In this letter, by combination of the first-principles calculations and resistivity, susceptibility and specific heat measurements, we demonstrate that La$_3$Pt$_3$Bi$_4$ is a topologically nontrivial nodal-ring semimetal protected by the gliding-mirror symmetry even in the presence of spin-orbit coupling. Meanwhile, we discover bulk superconductivity with a transition temperature of $\sim$1.1 K, and an upper critical field of $\sim$0.41 T. These findin…
Polycrystalline samples of four intermetallic compounds: MV$_2$Al$_{20}$ (M = Sc, Y, La, and Lu) were synthesized using an arc-melting technique. The crystal structures were analyzed by means of powder x-ray diffraction and Rietveld analysis, and the physical properties were studied by means of heat capacity, electrical resistivity and magnetic susceptibility measurements down to 0.4 K. For ScV$_2$Al$_{20}$, LuV$_2$Al$_{20}$, and YV$_2$Al$_{20}$, superconductivity was observed with critical temperatures T$_c$ = 1.00 K, 0.57 K, and 0.60 K, respectively. Superconductivity for the Lu compound is …
A mean-field treatment is presented of a square lattice two-orbital-model for ${\rm BiS_2}$ taking into account intra- and inter-orbital superconductivity. A rich phase diagram involving both types of superconductivity is presented as a function of the ratio between the couplings of electrons in the same and different orbitals (${\rm η= V_{XX}/V_{XY}}$) and electron doping $x$. With the help of a quantity we call orbital-mixing ratio, denoted as $R(ϕ)$, the phase diagram is analyzed using a simple and intuitive picture based on how $R(ϕ)$ varies as electron doping increases. The predictive pow…
The recent discovery of superconductivity in heavy Fermion compound UTe2, a candidate topological and triplet-paired superconductor, has aroused widespread interest. However, to date, there is no consensus on whether the stoichiometric sample of UTe2 is superconducting or not due to lack of reliable evidence to distinguish the difference between the nominal and real compositions of samples. Here, we are the first to clarify that the stoichiometric UT2 is non-superconducting at ambient pressure and under hydrostatic pressure up to 6 GPa, however we find that it can be compressed into supercondu…
The half-Heusler compounds YPdBi and TbPdBi, while having similar band structure, exhibit different magnetic properties. YPdBi is a diamagnet, while TbPdBi shows antiferromagnetic order below 5.5 K. Both are superconductors with T${_c}\approx$1 K for YPdBi and T${_c}\approx$1.75 K for TbPdBi. Such a contrast in properties between these two compounds opens a question about the effects of band structure or magnetic correlations on superconductivity. Using the combination of a tunnel diode oscillator (TDO) and a commercial dilution refrigerator, we measured temperature dependent magnetic penetrat…
Recently, Bi-based compounds have attracted attentions because of the strong spin-orbit coupling (SOC). In this work, we figured out the role of SOC in ABi$_{3}$ (A=Sr and Ba) by theoretical investigation of the band structures, phonon properties, and electron-phonon coupling. Without SOC, strong Fermi surface nesting leads to phonon instabilities in ABi$_{3}$. SOC suppresses the nesting and stabilizes the structure. Moreover, without SOC the calculation largely underestimates the superconducting transition temperatures ($T_{c}$), while with SOC the calculated $T_{c}$ are very close to those d…
On the basis of microscopic theory it is demonstrated how the coupling between the electrons by means of magnetization fluctuations in ferromagnetic metal with orthorhombic symmetry gives rise equal spin pairing superconducting state with general form of the order parameter dictated by symmetry. The strong upturn of the upper critical field along $b$-direction above 5 Tesla in UCoGe is explained by the increase of pairing interaction caused by the suppression of the Curie temperature by magnetic field parallel to b-axis. It is proposed that similar phenomenon at much higher field must take pla…
We study the superconducting properties of the non-centrosymmetric compound LaNiC$_2$ by measuring the London penetration depth $Δλ(T)$, the specific heat $C(T,B)$ and the electrical resistivity $ρ(T,B)$. Both $Δλ(T)$ and the electronic specific heat $C_e(T)$ exhibit exponential behavior at low temperatures and can be described in terms of a phenomenological two-gap BCS model. The residual Sommerfeld coefficient in the superconducting state, $γ_0(B)$, shows a fast increase at low fields and then an eventual saturation with increasing magnetic field. A pronounced upturn curvature is observed in…
EXAFS studies at the As K edge as a function of temperature have been carried out in SmFeAsO$_{1-x}$F$_x$ ($x$ = 0 and 0.2) compounds to understand the role of local structural distortions superconductivity observed in F doped compound. A significant correlation between thermal variation of local structural parameters like anion height and superconducting onset is found in the fluorinated compound. Such a variation in anion height is absent in non-superconducting compound. Increase in Fe-As bond distance just below superconducting onset temperature indicates a similarity in distortions observe…
