Magnetic coercivity is often viewed to be lower in alloys with negligible (or zero) values of the anisotropy constant. However, this explains little about the dramatic drop in coercivity in FeNi alloys at a non-zero anisotropy value. Here, we develop a theoretical and computational tool to investigate the fundamental interplay between material constants that govern coercivity in bulk magnetic alloys. The two distinguishing features of our coercivity tool are that: (a) we introduce a large localized disturbance, such as a spike-like magnetic domain, that provides a nucleation barrier for magnetization reversal; and (b) we account for magneto-elastic energy -- however small -- in addition to the anisotropy and magnetostatic energy terms. We apply this coercivity tool to show that the interactions between local instabilities and material constants, such as anisotropy and magnetostriction constants, are key factors that govern magnetic coercivity in bulk alloys. Using our model, we show that coercivity is minimum at the permalloy composition (Fe-21.5Ni-78.5) at which the alloy's anisotropy constant is not zero. We systematically vary the values of the anisotropy and magnetostriction constants, around the permalloy composition, and identify new combinations of material constants at which coercivity is small. More broadly, our coercivity tool provides a theoretical framework to potentially discover novel magnetic materials with low coercivity.
We present a strategy for the design of ferromagnetic materials with exceptionally low magnetic hysteresis, quantified by coercivity. In this strategy, we use a micromagnetic algorithm that we have developed in previous research and which has been validated by its success in solving the "Permalloy Problem" -- the well-known difficulty of predicting the composition 78.5% Ni of lowest coercivity in the Fe-Ni system -- and by the insight, it provides into the "Coercivity Paradox" of W. F. Brown. Unexpectedly, the design strategy predicts that cubic materials with large saturation magnetization $m…
Coercivity weighted Langevin magnetisation; A new approach to interpret superparamagnetic and nonsuperparamagnetic behaviour in single domain magnetic nanoparticles
In conventional FORC (First Order Reversal Curve) analysis of a magnetic system, reversible and low-coercivity irreversible materials are treated as being qualitatively different: the FORC distribution shows low-coercivity materials but completely hides reversible (zero-coercivity) ones. This distinction is artificial -- as the coercivity approaches zero, the physical properties of an irreversible material change smoothly into those of a reversible material. We have developed a method (called FORC+, implemented in free software at http://MagVis.org) for displaying the reversible properties of …
Soft magnetic materials (SMMs) serve in electrical applications and sustainable energy supply, allowing magnetic flux variation in response to changes in applied magnetic field, at low energy loss1. The electrification of transport, households and manufacturing leads to an increase in energy consumption due to hysteresis losses2. Therefore, minimizing coercivity, which scales these losses, is crucial3. Yet, meeting this target alone is not enough: SMMs in electrical engines must withstand severe mechanical loads, i.e., the alloys need high strength and ductility4. This is a fundamental design …
Nanoparticles with their specific properties newly have drawn a great deal of attention of researchers [1-3]Yttrium iron Garnet magnetic nanoparticles (YIG-NPs) are promising materials with novel applications in microwave, spintronics, magnonics, and magneto-optical devices. However, achieving stable and remarkable magnetic YIG-NPs has been remaining as a great challenge. In this paper, synthesized YIG-NPs by modifying co-precipitation (MCP) method is reported. Structural and magnetic properties of final products are compared to those of the materials prepared by citrate-nitrate (CN) method. S…
The Nd permanent magnet (Nd$_{2}$Fe$_{14}$B) is an indispensable material used in modern energy conversion devices. The realization of high coercivity at finite temperatures is a burning issue. One of the important ingredients for controlling the coercive force is the surface property of magnetic grains. It has been reported by first-principles studies that the Nd atoms in the first (001) surface layer facing the vacuum have in-plane anisotropy perpendicular to the $c$ axis, which may decrease the coercivity. Focusing on the surface anisotropy effect on the coercivity, we examine the coercivit…
Inverse magnetostriction is the effect by which magnetization can be changed upon application of stress/strain. A strain modulation may be created electrically by exciting interdigitated transducers to generate surface acoustic waves (SAWs). Hence SAWs appear as a possible route towards induction-free undulatory magnetic data manipulation. Here we demonstrate experimentally on an out-of-plane magnetostrictive layer a reduction of the coercive field of up to 60$\%$ by a SAW, over millimetric distances. A simple model shows that this spectacular effect can be partly explained by the periodic low…
Additive manufacturing (AM) offers an unprecedented opportunity for the quick production of complex shaped parts directly from a powder precursor. But its application to functional materials in general and magnetic materials in particular is still at the very beginning. Here we present the first attempt to computationally study the microstructure evolution and magnetic properties of magnetic materials (e.g. Fe-Ni alloys) processed by selective laser melting (SLM). SLM process induced thermal history and thus the residual stress distribution in Fe-Ni alloys are calculated by finite element anal…
Giant Exfoliation Induced Magnetic Coercivity in Fe$_3$GaTe$_2$
National High Magnetic Field Laboratory（国家强磁场实验室）；Florida State University（佛罗里达州立大学）；The University of Edinburgh（爱丁堡大学）；Argonne National Laboratory（阿贡国家实验室）；Donostia International Physics Center (DIPC)（圣塞巴斯蒂安国际物理中心）；Baylor University（贝勒大学）
Permanent magnet materials require a high uniaxial magneto-crystalline anisotropy. Exchange coupling between small crystallites with easy-plane anisotropy induces an effective uniaxial anisotropy if arranged accordingly. Nanostructuring of materials with easy-plane anisotropy is an alternative way to create hard-magnetic materials. The coercivity increases with decreasing feature size. The resulting coercive field is about 12 percent of the anisotropy field for a crystal size of 3.4 times the Bloch parameter.
Compositionally complex materials (CCMs) present a potential paradigm shift in the design of magnetic materials. These alloys exhibit long-range structural order coupled with limited or no chemical order. As a result, extreme local environments exist with a large opposing magnetic energy term, which can manifest large changes in the magnetic behavior. In the current work, the magnetic properties of (Cr, Mn, Fe, Ni) alloys are presented. These materials were prepared by room-temperature combinatorial sputtering, resulting in a range of compositions with a single BCC structural phase and no chem…
High coercivity magnets are an important resource for renewable energy, electric vehicles and memory technologies. Most hard magnetic materials incorporate rare-earths such as neodymium and samarium, but the concerns about the environmental impact and supply stability of these materials is prompting research into alternatives. Here, we present a hybrid bilayer of cobalt and the nano-carbon molecule C60 which exhibits significantly enhanced coercivity with minimal reduction in magnetisation. We demonstrate how this anisotropy enhancing effect cannot be described by existing models of molecule-m…
The development of permanent magnets containing less or no rare-earth elements is linked to profound knowledge of the coercivity mechanism. Prerequisites for a promising permanent magnet material are a high spontaneous magnetization and a sufficiently high magnetic anisotropy. In addition to the intrinsic magnetic properties the microstructure of the magnet plays a significant role in establishing coercivity. The influence of the microstructure on coercivity, remanence, and energy density product can be understood by {using} micromagnetic simulations. With advances in computer hardware and num…
We aim at combining high coercivity magnetic nanowires in a polymer matrix in a view to fabricate rare--earth free bonded magnets. In particular, our aim is to fabricate anisotropic materials by aligning the wires in the polymer matrix. We have explored the different parameters of the fabrication process in order to produce a material with the best possible magnetic properties. We show that the choice of a proper solvent allows obtaining stable nanowire suspensions. The length and the type of the polymer chains play also an important role. Smaller chains ($M_w < 10000$) provide better magnetiz…
The paper describes the capability of magnetic softening of a coarse grained bulk material by a severe deformation technique. Connecting the microstructure with magnetic properties, the coercive field decreases dramatically for grains smaller than the magnetic exchange length. This makes the investigation of soft magnetic properties of severely drawn pearlitic wires very interesting. With the help of the starting two phase microstructure, it is possible to substantially refine the material, which allows the investigation of magnetic properties for nanocrystalline bulk material. Compared to the…
The recent discovery of magnetic van der Waals materials has triggered a wealth of investigations in materials science, and now offers genuinely new prospects for both fundamental and applied research. Although the catalogue of van der Waals ferromagnets is rapidly expanding, most of them have a Curie temperature below 300 K, a notable disadvantage for potential applications. Combining element-selective x-ray magnetic imaging and magnetic force microscopy, we resolve at room temperature the magnetic domains and domains walls in micron-sized flakes of the CrTe$_2$ van der Waals ferromagnet. Flu…
Magnetic isotropic NdFeB powder is processed by the following additive manufacturing methods: (i) stereolithography (SLA), (ii) fused filament fabrication (FFF), and (iii) selective laser sintering (SLS). For the first time, a stereolithography based method is used to 3D print hard magnetic materials. FFF and SLA use a polymer matrix material as binder, SLS sinters the powder directly. All methods use the same hard magnetic NdFeB powder material. Complex magnets with small feature sizes in a superior surface quality can be printed with SLA. The magnetic properties for the processed samples are…
We propose a solution to the longstanding permalloy problem$-$why the particular composition of permalloy, Fe$_{21.5}$Ni$_{78.5}$, achieves a dramatic drop in hysteresis, while its material constants show no obvious signal of this behavior. We use our recently developed coercivity tool to show that a delicate balance between local instabilities and magnetic material constants are necessary to explain the dramatic drop of hysteresis at 78.5% Ni. Our findings are in agreement with the permalloy experiments and, more broadly, provide theoretical guidance for the discovery of novel low hysteresis …
Despite the composition close to glassy forming alloys, face centered cubic (FCC) Co81.8Si9.1B9.1, designed based on Co9B atomic cluster (polyhedral), are synthesized as singlephase ribbons successfully. These ribbons, with grain sizes of ca. 92 nm, show supreme ductility and strong orientation along (111), which couples with shape anisotropy leading to high magnetocrystalline anisotropy comparable to Co rich Co-Pt nanoscale thin films, with a coercivity of 430 Oe and squareness of 0.82 at room temperature. The stability and magnetic behaviors of the phase are discussed based on experimental e…
La$_{0.7}$Sr$_{0.3}$MnO$_3$ polycrystalline samples have been prepared using different synthesis routes. X-ray Diffraction (XRD) confirms that the samples are of single phase with R$\bar{3}$c space group. The surface morphology and particle size has been measured using Field Emission Scanning Electron Microscopy (FESEM). Magnetic measurement shows that the magnetization in the materials are affected by low crystallite size which destroys the spin ordering due to strain at grain boundaries and in turn also lead to reduction in magnetization as well as an enhanced coercivity in the material.
Machine learning was utilized to efficiently boost the development of soft magnetic materials. The design process includes building a database composed of published experimental results, applying machine learning methods on the database, identifying the trends of magnetic properties in soft magnetic materials, and accelerating the design of next-generation soft magnetic nanocrystalline materials through the use of numerical optimization. Machine learning regression models were trained to predict magnetic saturation ($B_S$), coercivity ($H_C$) and magnetostriction ($λ$), with a stochastic optim…
Interplay between Exchange Interaction and Magnetic Shape Anisotropy of ferromagnetic nanoparticles in a non-magnetic matrix for rare-earth-free permanent magnets
Transverse thermoelectric generation using magnetic materials is essential to develop active thermal engineering technologies, for which the improvements of not only the thermoelectric output but also applicability and versatility are required. In this study, using combinatorial material science and lock-in thermography technique, we have systematically investigated the transverse thermoelectric performance of Sm-Co-based alloy films. The high-throughput material investigation revealed the best Sm-Co-based alloys with the large anomalous Nernst effect (ANE) as well as the anomalous Ettingshaus…
The exchange interaction between nanostructured components is an effective way to enhance the magnetic properties of materials. This effect is used in exchange-coupled magnetic composites, which properties are governed by synergetic impact of constituent phases. Texturing is one of the problems that needs to be solved in order for such composites to be used in industry. In this work, we performed experimental and micromagnetic investigation of the exchange-bias properties in Co/Co3O4 nanocomposites based on nanorods array. Specifically, we investigated how the resulting properties will change …
Half-metallic fully compensated ferrimagnets (HM-FCFMs), a special class of half-metals exhibiting zero magnetization at absolute zero, are promising candidates for next-generation spintronics applications. For over 25 years, theoretical studies have been conducted to realize HM-FCFM materials for practical applications. Herein, we experimentally demonstrate a NiAs-type hexagonal-structured (CrFe)S compound that could serve as an HM-FCFM material. It has a half-metallic nature, with 100% spin-polarized Fermi surfaces and zero magnetization. Further, the magnetization shows a linear behavior as…
Giant Magnetocrystalline Anisotropy in Honeycomb Iridate NiIrO3 with Large Coercive Field Exceeding 17 T
School of Chemistry, Sun Yat-Sen University（中山大学化学学院）；School of Chemistry and Environment, Jiaying University（嘉应学院化学与环境学院）；School of Physics, Sun Yat-Sen University（中山大学物理学院）；School of Physics, Huazhong University of Science and Technology（华中科技大学物理学院）；Institute of Physics, Chinese Academy of Sciences（中国科学院物理研究所）；School of Chemistry and Chemical Engineering, Hainan University（海南大学化学化工学院）
This paper describes the open Novamag database that has been developed for the design of novel Rare-Earth free/lean permanent magnets. The database software technologies, its friendly graphical user interface, advanced search tools and available data are explained in detail. Following the philosophy and standards of Materials Genome Initiative, it contains significant results of novel magnetic phases with high magnetocrystalline anisotropy obtained by three computational high-throughput screening approaches based on a crystal structure prediction method using an Adaptive Genetic Algorithm, tet…
Modelling magnetic material properties with uncertainty-aware neural networks
University of Cambridge（剑桥大学）；ETH Zurich（苏黎世联邦理工学院）；University of Tokyo（东京大学）；National Institute for Materials Science（国家材料科学研究所）；Max Planck Institute for Intelligent Systems（智能系统马克斯·普朗克研究所）
Two dimensional (2D) van der Waals (vdW) materials have demonstrated fascinating optical, electrical and thickness-dependent characteristics. These have been explored by numerous authors but reports on magnetic properties and spintronic applications of 2D vdW materials are scarce by comparison. By performing anomalous Hall effect transport measurements, we have characterised the thickness dependent magnetic properties of single crystalline vdW Fe3GeTe2. The nanoflakes of this vdW metallic material exhibit a single hard magnetic phase with a near square-shaped magnetic loop, large coercivity (u…
Magnetic systems exhibiting exchange bias effect are being considered as materials for applications in data storage devices, sensors and biomedicine. As the size of new mag- netic devices is being continuously reduced, the influence of thermally induced instabilities in magnetic order has to be taken into account during their fabrication process. In this study we show the influence of superparamagnetism on magnetic properties of exchange-biased [CoO/Co/Pd]10 multilayer. We find that the process of progressive thermal blocking of the superparamagnetic clusters causes an unusually fast rise of t…
Magnetic properties of amorphous Co$_x$Nb$_{100-x}$ alloys produced by mechanical alloying
从元素粉末开始通过机械合金化制备三种非晶Co $_x$ Nb $_{100-x}$合金，Co $_{25}$ Nb $_{75}$、Co $_{57}$ Nb $_{43}$和Co $_{80}$ Nb $_{20}$。用交变梯度磁力仪（AGFM）测定了它们的磁性能，并由磁滞回线得到了它们的剩磁、饱和磁场和矫顽磁场。合金具有相对高的饱和磁场，其随着成分变得富含Co而降低。矫顽力和回复磁化强度在57%at.Co附近达到最佳值，使得{ \em a}-Co $_{57}$ Nb $_{43}$成为三种合金中最硬的磁性材料。进一步添加Co产生软合金。
