The performance of endoreversible thermal machines operating at finite power constitutes one of the main challenges of nonequilibrium classical and quantum thermodynamics, engineering and others. We introduce the idea of adjusting the interaction time asymmetry in order to optimize the engine performance. We consider one of the simplest thermal machines, composed of a quantum dot interacting sequentially with two different reservoirs of heat and particles. Distinct optimization protocols are analyzed in the framework of stochastic thermodynamics. Results reveal that asymmetric interaction times play a fundamental role in enhancing the power output and that maximizations can provide an increase larger than 25\% the symmetric case. As an extra advantage, efficiencies at maximum power are slightly greater than the endoreversible Curzon-Ahlborn efficiency for a broad range of reservoir temperatures.
We consider the optimization of the work output and fluctuations of a finite-time quantum Otto heat engine cycle consisting of compression and expansion work strokes of unequal duration. The asymmetry of the cycle is characterized by a parameter $r_u$ giving the ratio of the times for the compression and expansion work strokes. For such an asymmetric quantum Otto engine cycle, with working substance chosen as a harmonic oscillator or a two-level system, we find that the optimal values of $r_u$ maximising the work output and the reliability (defined as the ratio of average work output to its st…
Discrete-spin systems with maximally random nearest-neighbor interactions that can be symmetric or asymmetric, ferromagnetic or antiferromagnetic, including off-diagonal disorder, are studied, for the number of states $q=3,4$ in $d$ dimensions. We use renormalization-group theory that is exact for hierarchical lattices and approximate (Migdal-Kadanoff) for hypercubic lattices. For all d>1 and all non-infinite temperatures, the system eventually renormalizes to a random single state, thus signaling qxq degenerate ordering. Note that this is the maximally degenerate ordering. For high-temperatur…
An engine producing a finite power at the ideal (Carnot) efficiency is a dream engine, which is not prohibited by the thermodynamic second law. Some years ago, a two-terminal heat engine with {\em asymmetric} Onsager coefficients in the linear response regime was suggested by Benenti, Saito, and Casati [Phys. Rev. Lett. {\bf 106}, 230602 (2011)], as a prototypical system to make such a dream come true with non-divergent system parameter values. However, such a system has never been realized in spite of many trials. Here, we introduce an exactly solvable two-terminal Brownian heat engine with t…
Recent experimental breakthroughs produced the first nano heat engines that have the potential to harness quantum resources. An instrumental question is how their performance measures up against the efficiency of classical engines. For single ion engines undergoing quantum Otto cycles it has been found that the efficiency at maximal power is given by the Curzon-Ahlborn efficiency. This is rather remarkable as the Curzon-Alhbron efficiency was originally derived for endoreversible Carnot cycles. Here, we analyze two examples of endoreversible Otto engines within the same conceptual framework as…
We have studied the single particle heat engine and refrigerator driven by time asymmetric protocol of finite duration. Our system consists of a particle in a harmonic trap with time-periodic strength that drives the particle cyclically between two baths. Each cycle consists of two isothermal steps at different temperatures and two adiabatic steps connecting them. The system works in irreversible mode of operation even in the quasistatic regime. This is indicated by finite entropy production even in the large cycle time limit. Consequently, Carnot efficiency for heat engine or Carnot Co-effici…
Despite its idealizations, thermodynamics has proven its power as a predictive theory for practical applications. In particular, the Curzon-Ahlborn efficiency provides a benchmark for any real engine operating at maximal power. Here we further develop the analysis of endoreversible Otto engines. For a generic class of working mediums, whose internal energy is proportional to some power of the temperature, we find that no engine can achieve the Carnot efficiency at finite power. However, we also find that for the specific example of photonic engines the efficiency at maximal power is larger tha…
In a stochastic heat engine driven by a cyclic non-equilibrium protocol, fluctuations in work and heat give rise to a fluctuating efficiency. Using computer simulations and tools from large deviation theory, we have examined these fluctuations in detail for a model two-state engine. We find in general that the form of efficiency probability distributions is similar to those described by Verley et al. [2014 Nat Comm, 5 4721], in particular featuring a local minimum in the long-time limit. In contrast to the time-symmetric engine protocols studied previously, however, this minimum need not occur…
The construction of efficient thermal engines operating at finite times constitutes a fundamental and timely topic in nonequilibrium thermodynamics. We introduce a strategy for optimizing the performance of Brownian engines, based on a collisional approach for unequal interaction times between the system and thermal reservoirs. General (and exact) expressions for thermodynamic properties and their optimized values are obtained, irrespective of the driving forces, asymmetry, the temperatures of reservoirs and protocol to be maximized. Distinct routes for the engine optimization, including maxim…
Many versions of Thermodynamic Uncertainty Relations (TUR) have recently been discovered, which impose lower bounds on relative fluctuations of integrated currents in irreversible dissipative processes, and suggest that there may be fundamental limitations on the precision of small scale machines and heat engines. In this work we rigorously demonstrate that TUR can be evaded by using dynamic protocols that are asymmetric under time-reversal. We illustrate our results using a model heat engine using two-level systems, and also discuss heuristically the fundamental connections between TUR and ti…
Understanding the connections between information and thermodynamics has been among the most visible applications of stochastic thermodynamics. While recent theoretical advances have established that the second law of thermodynamics sets limits on information-to-energy conversion, it is currently unclear to what extent real systems can achieve the predicted theoretical limits. Using a simple model of an information engine that has recently been experimentally implemented, we explore the limits of information-to-energy conversion when an information engine's benefit is limited to output energy …
Ideal heat engine cycles at maximal efficiency -- the ideal gas and beyond
University of Maryland, College Park（马里兰大学帕克分校）；University of Maryland, Baltimore County（马里兰大学巴尔的摩郡分校）；Quantum Science Institute, University of Maryland, Baltimore County（马里兰大学巴尔的摩郡分校量子科学研究所）；National Quantum Laboratory（国家量子实验室）
We study a two-level system controlled in a discrete feedback loop, modeling both the system and the controller in terms of stochastic Markov processes. We find that the extracted work, which is known to be bounded from above by the mutual information acquired during measurement, has to be compensated by an additional energy supply during the measurement process itself, which is bounded by the same mutual information from below. Our results confirm that the total cost of operating an information engine is in full agreement with the conventional second law of thermodynamics. We also consider th…
Thermodynamics places a limit on the efficiency of heat engines, but not on their output power or on how the power and efficiency change with the engine's cycle time. In this manuscript, we develop a geometrical description of the power and efficiency as a function of the cycle time, applicable to an important class of heat engine models. This geometrical description is used to design engine protocols that attain both the maximal power and maximal efficiency at the fast driving limit. Furthermore, using this method we also prove that no protocol can exactly attain the Carnot efficiency at non-…
A dynamical model of a highly efficient heat engine is proposed, where an applied temperature difference maintains the motion of particles around the circuit consisting of two asymmetric narrow channels, in one of which the current flows against the applied thermodynamic forces. Numerical simulations and linear-response analysis suggest that, in the absence of frictional losses, the Carnot efficiency can be achieved in the thermodynamic limit.
We present a quantum Otto engine model consisting of two isochoric and two adiabatic strokes, where the adiabatic expansion or compression is realized by adiabatically changing the shape of the potential. Here we show that such an adiabatic deformation may alter operation mode and enhance machine performance by increasing output work and efficiency, even with the advantage of decreasing work fluctuations. If the heat engine operates under maximal power by optimizing the control parameter, the efficiency shows certain universal behavior.
We study spectral gaps of the one-dimensional totally asymmetric simple exclusion process (TASEP) with open boundaries in the maximal current phase. Earlier results for the model with periodic boundaries suggest that the gaps contributing to the universal KPZ regime may be understood as points on an infinite genus Riemann surface built from a parametric representation of the cumulant generating function of the current. We perform explicit analytic continuations from the known large deviations of the current for open TASEP, and confirm the results for the gaps by an exact Bethe ansatz calculati…
We derive the general relations between the maximum power, maximum efficiency and minimum dissipation for the irreversible heat engine in nonlinear response regime. In this context, we use the minimally nonlinear irreversible model and obtain the lower and upper bounds of the above relations for the asymmetric dissipation limits. These relations can be simplified further when the system possesses the time-reversal symmetry or anti-symmetry. We find that our results are the generalization of various such relations obtained earlier for different heat engines.
We consider the totally asymmetric simple exclusion process with open boundaries, at the edge of the maximal current phase. Using analytic continuations from the known stationary eigenvalue, we obtain exact expressions for the spectral gaps in the limit of large system size. The underlying Riemann surface,generated by modified Lambert functions, interpolates between the one for periodic TASEP and the one for open TASEP in the maximal current phase.
We discuss the efficiency of a heat engine operating in a nonequilibrium steady state maintained by two heat reservoirs. Within the general framework of linear irreversible thermodynamics we derive a universal upper bound on the efficiency of the engine operating at arbitrary fixed power. Furthermore, we show that a slight decrease of the power below its maximal value can lead to a significant gain in efficiency. The presented analysis yields the exact expression for this gain and the corresponding upper bound.
