Among the many physical properties, the amorphous state manifests itself in the most spectacular way in heat transport. Anomalously low thermal conductivity, its low-temperature dependence as a function of temperature, the presence of a plateau of thermal conductivity, all are definitely different when compared with the ordered state of crystals. For this reason, the microscopic mechanisms from which these surprising behaviors may emerge have been the subject of intensive theoretical research and even more extensive experimental research. These investigations have led to the detection of a huge range of disordered materials with somewhat similar properties, which have become a rich base for various physical interpretations. In this chapter we present the last 50 years of the history of experimental research together with the key theoretical physics scenarios
By using very general arguments, we show that the entropy loss conjecture at the glass transition violates the second law of thermodynamics and must be rejected.
A major challenge in the modeling of ionically conducting glasses is to understand how the large variety of possible chemical compositions and specific structural properties influence ionic transport quantities. Here we revisit and extend a theoretical approach for alkali borophosphate glasses, where changes of conductivity activation energies with the borate to phosphate mixing ratio are related to modifications of the ionic site energy landscape. The landscape modifications are caused by varying amounts of different units forming the glassy network, which lead to spatial redistributions of t…
We report new inelastic Raman and neutron scattering spectra for glasses with different degrees of fragility; the data are compared for each sample to obtain the Raman coupling function $C(ω)$. The study indicates a general linear behaviour of the $C(ω)$ near the Boson peak maximum, and evidence a correlation between vibrational and relaxational properties, already observed in recent publications.
By connecting realistic spin glass models at low temperature to the highly disordered model at zero temperature, we argue that ordinary Edwards-Anderson spin glasses below eight dimensions have at most a single pair of physically relevant pure states at nonzero low temperature. Less likely scenarios that evade this conclusion are also discussed.
Within the wide class of disordered materials, spin glasses occupy a special place because of their conceptually simple definition of randomly interacting spins. Their modelling has triggered spectacular developments of out-of-equilibrium statistical physics, as well analytically as numerically, opening the way to a new vision of glasses in general. "Real" spin glasses are disordered magnetic materials which can be very diverse from the chemist's point of view, but all share a number of common properties, laying down the definition of generic spin glass behaviour. This paper aims at giving to …
Aging phenomena have been studied in very different materials like polymers, supercooled liquids or disordered orientational crystals. We recall here the main features of aging in spin glasses, and use this example of magnetic systems as a guideline for the description of the others. A particular attention is put on the sensitivity of aging to the cooling rate and to temperature variations. This allows us to point out differences between temperature specific processes, yielding ``rejuvenation and memory effects'' as known in spin glasses, and domain growth processes, giving cumulative contribu…
At very low temperatures, the tunnelling theory for amorphous solids predicts a thermal conductivity $κ\propto T^p$, with $p = 2$. We have studied the effect of the Nuclear Quadrupole moment on the thermal conductivity of glasses at very low temperatures. We developed a theory that couples the tunnelling motion to the nuclear quadrupoles moment in order to evaluate the thermal conductivity. Our result suggests a cross over between two different regimes at the temperature close to the nuclear quadrupoles energy. Below this temperature we have shown that the thermal conductivity is larger than t…
Non-Arrhenius behaviour and fast increase of the ionic conductivity is observed for a number of potassium silicate glasses $(1-x)SiO_2-xK_2O$ with potassium oxide concentration larger than a certain value $x=x_c=0.14$. Recovering of Arrhenius behaviour is provided by the annealing that enhances densification. Conductivity furthermore obeys a percolation law with the same critical concentration $x_c$. These various results are the manifestation of the floppy or rigid nature of the network and can be analyzed with constraint theory. They underscore the key role played by network rigidity for the…
In this chapter, we discuss avalanches in glasses and disordered systems, and the macroscopic dynamical behavior that they mediate. We briefly review three classes of systems where avalanches are observed: depinning transition of disordered interfaces, yielding of amorphous materials, and the jamming transition. Without extensive formalism, we discuss results gleaned from theoretical approaches -- mean-field theory, scaling and exponent relations, the renormalization group, and a few results from replica theory. We focus both on the remarkably sophisticated physics of avalanches and on relativ…
The paper contains a rigorous proof of the absence of quasi-long-range order in the random-field O(N) model for strong disorder in the space of an arbitrary dimensionality. This result implies that quasi-long-range order inherent to the Bragg glass phase of the vortex system in disordered superconductors is absent as the disorder or external magnetic field is strong.
We have studied the nonlinear conductivity of two-dimensional Coulomb glasses. We have used a Monte Carlo algorithm to simulate the dynamic of the system under an applied electric field $E$. We found that in the nonlinear regime the site occupancy in the Coulomb gap follows a Fermi-Dirac distribution with an effective temperature $T_{\rm eff}$, higher than the phonon bath temperature $T$. The value of the effective temperature is compatible with that obtained for slow modes from the generalized fluctuation-dissipation theorem. The nonlinear conductivity for a given electric field and $T$ is fa…
Positional disorder has been introduced into the atomic structure of certain crystalline lattices, and the orientationally-averaged structure factor S(k) and pair-correlation function g(r) of these disordered lattices have been studied. Analytical expressions for S(k) and g(r) for Gaussian positional disorder in 2D and 3D are confirmed with precise numerical simulations. These analytic results also have a bearing on the unsolved Gauss circle problem in mathematics. As the positional disorder increases, high-k peaks in S(k) are destroyed first, eventually leaving a single peak, that with the lo…
We present here a calculation of the configuration averaged optical conductivity of random binary alloys CuAu and AgAu. Our formulation is based on the augmented space formalism proposed by Mookerjee [J. Phys. C : Solid State Phys. {\bf 6} 1340 (1973)] and the optical conductivity is obtained directly through a recursive procedure suggested by Viswanath and Müller ["The user friendly recursion method", Troisieme Cycle de la Physique, en Suisse Romande (1993)].
The thermal conductivity of some orientational glasses of protonated C2H5OH and deuterated C2D5OD ethanol, cyclic substances (cyclohexanol C6H11OH, cyanocyclohexane C6H11CN, cyclohexene C6H10), and freon 112 (CFCl2)2 have been analyzed in the temperature interval 2-130 K. The investigated substances demonstrate new effects concerned with the physics of disordered systems. Universal temperature dependences of the thermal conductivity of molecular orientational glasses have been revealed. At low temperatures, the thermal conductivity exhibits a universal behavior that can be described by the sof…
A numerical study of the energy relaxation and conductivity of the Coulomb glass is presented. The role of many-electron transitions is studied by two complementary methods: a kinetic Monte Carlo algorithm and a master equation in configuration space method. A calculation of the transition rate for two-electron transitions is presented, and the proper extension of this to multi-electron transitions is discussed. It is shown that two-electron transitions are important in bypassing energy barriers which effectively block sequential one-electron transitions. The effect of two-electron transitions…
The spin glasses are disordered and frustrated magnetic systems. They show aging phenomena which are also a characteristic feature of structural glasses, polymers, dielectrics, colloids, etc. Under a strong enough magnetic field variation, spin glasses can be "rejuvenated", in the same way as glasses under a high enough stress. But spin glasses also display non-trivial "rejuvenation and memory" effects when they are submitted to temperature variations. Comparable phenomena have recently been identified in some polymers and gels, although less sharply pronounced. We propose to describe aging ph…
The out-of-equilibrium excess conductance of electron-glasses typically relaxes with a logarithmic time-dependence. Here it is shown that the log(t) relaxation of a weakly-disordered amorphous indium-oxide films crosses-over asymptotically to an exponential dependence. This allows assigning a well-defined relaxation-time t' for a given system-disorder (characterized by the Ioffe-Regel parameter). Near the metal-insulator transition, t' obeys the scaling relation with the same critical disorder where the zero-temperature conductivity of this system vanishes. The latter defines the position of t…
The field-dependent ion transport in thin samples of different glasses is characterised by means of nonlinear conductivity spectroscopy. AC electric fields with strengths up to 77 kV/cm are applied to the samples, and the Fourier components of the current spectra are analysed. In the dc conductivity regime and in the transition region to the dispersive conductivity, higher harmonics in the current spectra are detected, which provide information about higher--order conductivity coefficients. Our method ensures that these higher--order conductivity coefficients are exclusively governed by field-…
We study analytically M-spin-flip stable states in disordered short-ranged Ising models (spin glasses and ferromagnets) in all dimensions and for all M. Our approach is primarily dynamical and is based on the convergence of a zero-temperature dynamical process with flips of lattice animals up to size M and starting from a deep quench, to a metastable limit. The results (rigorous and nonrigorous, in infinite and finite volumes) concern many aspects of metastable states: their numbers, basins of attraction, energy densities, overlaps, remanent magnetizations and relations to thermodynamic states…
Results of DC and frequency dependent conductivity in the quantum limit, i.e. hw > kT, for a broad range of dopant concentrations in nominally uncompensated, crystalline phosphorous doped silicon and amorphous niobium-silicon alloys are reported. These materials fall under the general category of disordered insulating systems, which are referred to as electron glasses. Using microwave resonant cavities and quasi-optical millimeter wave spectroscopy we are able to study the frequency dependent response on the insulating side of the metal-insulator transition. We identify a quantum critical regi…
We examine the dynamics of driven classical Wigner solids interacting with quenched disorder from charged impurities. For strong disorder, the initial motion is plastic -- in the form of crossing winding channels. For increasing drive, the disordered Wigner glass can reorder to a moving Wigner smectic -- with the electrons moving in non-crossing 1D channels. These different dynamic phases can be related to the conduction noise and I(V) curves. For strong disorder, we show criticality in the voltage onset just above depinning. We also obtain the dynamic phase diagram for driven Wigner solids an…
Structural glasses formed by quenching a melt are known to host a population of low-energy quasilocalized (nonphononic) excitations whose frequencies $ω$ follow a universal $\sim\!ω^4$ distribution as $ω\!\to\!0$, independently of the glass formation history, the interparticle interaction potential or spatial dimension. Here, we show that the universal quartic law of nonphononic excitations also holds in disordered crystals featuring finite long-range order, which is absent in their glassy counterparts. We thus establish that the degree of universality of the quartic law extends beyond structu…
We develop a real space renormalisation group analysis of disordered models of glasses, in particular of the spin models at the origin of the Random First Order Transition theory. We find three fixed points respectively associated to the liquid state, to the critical behavior and to the glass state. The latter two are zero-temperature ones; this provides a natural explanation of the growth of effective activation energy scale and the concomitant huge increase of relaxation time approaching the glass transition. The lower critical dimension depends on the nature of the interacting degrees of fr…
In equilibrium, disorder conspires with topological defects to redefine the ordered states of matter in systems as diverse as crystals, superconductors and liquid crystals. Far from equilibrium, however, the consequences of quenched disorder on active condensed matter remain virtually uncharted. Here, we reveal a state of strongly disordered active matter with no counterparts in equilibrium: a dynamical vortex glass. Combining high-content microfluidic experiments and theory, we show how colloidal flocks collectively cruise through disorder without relaxing the topological singularities of the…
We argue that the intrinsic glassy degrees of freedom in amorphous solids giving rise to the thermal conductivity plateau and the ``boson peak'' in the heat capacity at moderately low temperatures are directly connected to those motions giving rise to the two-level like excitations seen at still lower temperatures. These degrees of freedom can be thought of as strongly anharmonic transitions between the local minima of the glassy energy landscape that are accompanied by ripplon-like domain wall motions of the glassy mosaic structure predicted to occur at $T_g$ by the random first order transit…
For small tension the response of a solid to an applied stress is given by Hooke's law. Outside this linear regime the relation between stress and strain is no longer universal and at present there is no satisfactory insight on how to connect for disordered materials the stress-strain relation to the microscopic properties of the system. Here we use atomistic computer simulations to establish this connection for the case of silicate glasses containing modifiers. By probing how in the highly non-linear regime the stress-strain curve depends on composition, we are able to identify the microscopi…
We put forward a fundamental relationship between the normalized spectral density of excess current noise and the imaginary part of complex conductivity.
At the mean-field level, on fully connected lattices, several disordered spin models have been shown to belong to the universality class of "structural glasses", with a "random first-order transition" (RFOT) characterized by a discontinuous jump of the order parameter and no latent heat. However, their behavior in finite dimensions is often drastically different, displaying either no glassiness at all or a conventional spin-glass transition. We clarify the physical reasons for this phenomenon and stress the unusual fragility of the RFOT to short-range fluctuations, associated e.g. with the mer…
The specific heat Cp and other properties of glasses (ranging from amorphous solids to disordered crystals) at low temperatures, are well known to be markedly different from those in fully-ordered crystals. For decades, this qualitative, and even quantitative, universal behavior of glasses has been thoroughly studied. However, a clear understanding of its origin and microscopic nature, needless to say a closed theory, is still lacking. To shed light on this matter, I review the situation in this work, mainly by compiling and discussing measured low-temperature Cp data of many glasses and disor…
Toyota Central R&D Labs, Inc.（丰田中央研发实验室股份有限公司）；Nagoya University（名古屋大学）
Glass transitions are widely observed in various types of soft matter systems. However, the physical mechanism of these transitions remains {elusive}, despite years of ambitious research. In particular, an important unanswered question is whether the glass transition is accompanied by a divergence of the correlation lengths of the characteristic static structures. In this study, we develop a deep-neural-network-based method that is used to extract the characteristic local meso-structures solely from instantaneous {particle} configurations without any {information} about the dynamics. We first …
Recently, Bauke and Mertens conjectured that the local statistics of energies in random spin systems with discrete spin space should in most circumstances be the same as in the random energy model. Here we give necessary conditions for this hypothesis to be true, which we show to hold in wide classes of examples: short range spin glasses and mean field spin glasses of the SK type. We also show that, under certain conditions, the conjecture holds even if energy levels that grow moderately with the volume of the system are considered.
The translational symmetry of solids gives rise to the existence of low-frequency phonons. In ordered systems, some phonons characterized by different wavevectors are degenerate, i.e. they share the same frequency $ω$; in finite-size systems, phonons form a discrete set of bands with $n_q(ω)$-fold degeneracy. Here we focus on understanding how this degeneracy is lifted in the presence of disorder, and its physical implications. Using standard degenerate perturbation theory and simple statistical considerations, we predict the dependence of the disorder-induced frequency width of phonon bands t…
An important prediction of Mode-Coupling-Theory (MCT) is the relationship between the power- law decay exponents in the β regime. In the original structural glass context this relationship follows from the MCT equations that are obtained making rather uncontrolled approximations and λ has to be treated like a tunable parameter. It is known that a certain class of mean-field spin-glass models is exactly described by MCT equations. In this context, the physical meaning of the so called parameter exponent λ has recently been unveiled, giving a method to compute it exactly in a static framework. I…
We evaluate the electron-electron interaction corrections to the electronic thermal conductivity in a disordered conductor in the diffusive regime. We use a diagrammatic many-body method analogous to that of Altshuler and Aronov for the electrical conductivity. We derive results in one, two and three dimensions for both the singlet and triplet channels, and in all cases find that the Wiedemann-Franz law is violated.
The infrared behaviour of a non-mean field spin-glass system is analysed, and the critical exponent related to the divergence of the correlation length is computed at two loops within the epsilon-expansion technique with two independent methods. Both methods yield the same result confirming that the infrared behaviour of the theory if well-defined and the underlying ideas of the Renormalization Group hold also in such non-mean field disordered model. By pushing such calculation to high orders in epsilon, a consistent and predictive non-mean field theory for such disordered system could be esta…
Raman scattering, IR reflectance and modulated DSC measurements are performed on specifically prepared dry (AgI)x(AgPO3)1-x glasses over a wide range of compositions 0 < x < 0.60. A reversibility window is observed in the 0.095< x < 0.378 range, which fixes the elastically rigid but unstressed regime also known as the Intermediate Phase. Glass compositions at x < 0.095 are stressed-rigid, while those at x > 0.378 elastically flexible. Raman optical elasticity power-laws, trends in the nature of the glass transition endotherms corroborate the three elastic phase assignments. Ionic conductivitie…
We present computational data on the thermal conductivity of nonlinear waves in disordered chains. Disorder induces Anderson localization for linear waves and results in a vanishing conductivity. Cubic nonlinearity restores normal conductivity, but with a strongly temperature-dependent conductivity $κ(T)$. We find indications for an asymptotic low-temperature $κ\sim T^4$ and intermediate temperature $κ\sim T^2$ laws. These findings are in accord with theoretical studies of wave packet spreading, where a regime of strong chaos is found to be intermediate, followed by an asymptotic regime of wea…
Disorder has been long considered as a formidable foe of theoretical physicists in their attempts to understand system's behavior. Here, we review recently accumulated data and propose that from the point of view of calculating thermodynamic properties, the problem of disorder may not be as severe as has been hitherto assumed. We particularly emphasize that contrary to the long-held view, collective excitations do not decay in disordered systems. We subsequently discuss recent experimental, theoretical and modelling results related to collective excitations in disordered media, and show how th…
We study the thermal conductivity, at fixed positive temperature, of a disordered lattice of harmonic oscillators, weakly coupled to each other through anharmonic potentials. The interaction is controlled by a small parameter $ε> 0$. We rigorously show, in two slightly different setups, that the conductivity has a non-perturbative origin. This means that it decays to zero faster than any polynomial in $ε$ as $ε\rightarrow 0$. It is then argued that this result extends to a disordered chain studied by Dhar and Lebowitz, and to a classical spins chain recently investigated by Oganesyan, Pal and …
Exploring structural order in disordered systems including liquids and glasses is an intriguing but challenging issue in condensed matter physics. Here we construct a new parameter based on the angular distribution function of particles and show that this new orientational order has significantly higher correlation with dynamic heterogeneity compared to a translational parameter based on the radial distribution functions in colloidal glasses. The gradual development of orientational and translational order in supercooled liquids shows that the higher correlation between orientational order and…
We study the probability distribution function of the ground-state energies of the disordered one-dimensional Ising spin chain with power-law interactions using a combination of parallel tempering Monte Carlo and branch, cut, and price algorithms. By tuning the exponent of the power-law interactions we are able to scan several universality classes. Our results suggest that mean-field models have a non-Gaussian limiting distribution of the ground-state energies, whereas non-mean-field models have a Gaussian limiting distribution. We compare the results of the disordered one-dimensional Ising ch…
In crystals, molecules thermally vibrate around the periodic lattice sites. Vibrational motions are well understood in terms of phonons, which carry heat and control heat transport. The situation is notably different in disordered solids, where vibrational excitations are not phonons and can be even localized. Recent numerical work has established the concept of elastic heterogeneity: disordered solids show inhomogeneous local mechanical response. Clearly, the heterogeneous nature of elastic properties strongly influences vibrational and thermal properties, and it is expected to be the origin …
The electrical {\em dc}-conductivity of disordered, non-interacting electrons is calculated in the asymptotic limit of high lattice dimensions $d\to \infty$. To go beyond the lowest-order contribution in the expansion parameter $1/d$ of the single bubble diagram, vertex corrections are calculated from an asymptotic expression for the two-particle vertex. A mean-field approximation for the dc-conductivity containing the leading high-dimensional vertex corrections is proposed which is free of spurious non-analyticities, i.e. the conductivity is non-negative and shows no unphysical behavior in $d…
We report on a novel non-linear electric field effect in the conductivity of disordered conductors. We find that an electric field gives rise to dephasing in the particle-hole channel, which depresses the interference effects due to disorder and interaction and leads to a non-linear conductivity. This non-linear effect introduces a field dependent temperature scale $T_E$ and provides a microscopic mechanism for electric field scaling at the metal-insulator transition. We also study the magnetic field dependence of the non-linear conductivity and suggest possible ways to experimentally verify o…
We present ac conductivity spectra of tellurite glasses at several temperatures. For the first time, we report oscillatory modulations at frequencies around MHz. This effect is more pronounced the lower the temperature, and washes out when approaching the glass transition temperature $T_g$. We show, by using a minimal model, how this modulation may be attributed to the fractal structure of the glass at intermediate mesoscopic length scales.
Some aspects of how sound waves travel through disordered solids are still unclear. Recent work has characterized a feature of disordered solids which seems to influence vibrational excitations at the mesoscales, local elastic heterogeneity. Sound waves propagation has been demonstrated to be strongly affected by inhomogeneous mechanical features of the materials which add to the standard anharmonic couplings, amounting to extremely complex transport properties at finite temperatures. Here, we address these issues for the case of a simple atomic glass former, by Molecular Dynamics computer sim…
We present a unified understanding of the experimentally observed minimal dc conductivity in weakly disordered graphene. Firstly, based on linear response theory, we reveal that randomness or disorder inevitably induces momentum dependent corrections to the electron self-energy function, which naturally yields a sample-dependent minimal conductivity. Taking the long-ranged Gaussian and Coulomb potentials as examples, we derive the momentum dependent self-energy function within the Born approximation, and further validate it via numerical simulations using the large-scale Lanczos algorithm. The…
We reinvestigate the behavior of the conductivity of several disordered quantum lattice models at infinite temperature using exact diagonalization. Contrary to the conclusion drawn in a recent investigation of similar quantities in identical systems, we find evidence of a localized regime for strong random fields. We estimate the location of the critical field for the many-body localization transition for the random-field XXZ spin chain, and compare our findings with recent investigations in related systems.
A disordered array of metal grains with large and random intergrain conductances is studied within the one-loop accuracy renormalization group approach. While at low level of disorder the dependence of conductivity on log T is nonuniversal (it depends on details of the array's geometry), for strong disorder this dependence is described by a universal nonlinear function, which depends only on the array's dimensionality. In two dimensions this function is found numerically. The dimensional crossover in granular films is discussed.
Mean-field theory of non-interacting disordered electron systems is widely and successfully used to describe equilibrium properties of alloys in the whole range of disorder strengths. It, however, fails to take into account effects of quantum coherence and localizing back-scattering effects when applied to transport phenomena. We present an approximate scheme extending the mean-field theory for one-electron properties in that it offers a formula for the two-particle vertex and the electrical conductivity non-perturbatively including the leading-order vertex corrections in a way that the approx…
This lecture deals with glassy dynamics and aging in disordered systems. Special emphasis is put on dynamic mean field theory. In the first part I present some of the systems of interest, in particular spin-glasses, supercooled liquids and glasses, drift, creep and pinning of a particle in a random potential, neural networks, graph partitioning as an example of combinatorial optimisation, the K-sat problem and the minority game as a model for the behaviour of agents on markets. The second part deals with the dynamics of the spherical p-spin-glass with long ranged interactions. This model is a …
The amorphous solids can be theoretically modeled by anharmonic disordered lattices. However, most of theoretical studies on thermal conductivity in anharmonic disordered lattices only focus on the potentials of hard-type (HT) anharmonicity. Here we study the thermal conductivity $κ$ of one-dimensional (1D) disordered lattices with both hard- and soft-type (ST) anharmonic on-site potentials. It is found, via both direct molecular dynamic simulations and theoretical method, that the anharmonicity dependence of $κ$ in the HT model is nonmonotonous, while in the ST model is monotonously increased…
