We consider a theory of quantum thermodynamics with multiple conserved quantities (or charges). To this end, we generalize the seminal results of Sparaciari et al. [PRA 96:052112, 2017] to the case of multiple, in general non-commuting charges, for which we formulate a resource theory of thermodynamics of asymptotically many non-interacting systems. To every state we associate the vector of its expected charge values and its entropy, forming the phase diagram of the system. Our fundamental result is the Asymptotic Equivalence Theorem (AET), which allows us to identify the equivalence classes of states under asymptotic approximately charge-conserving unitaries with the points of the phase diagram.
Using the phase diagram of a system and its bath, we analyze the first and the second laws of thermodynamics. In particular, we show that to attain the second law, an asymptotically large bath is necessary. In the case that the bath is composed of several identical copies of the same elementary bath, we quantify exactly how large the bath has to be to permit a specified work transformation of a given system, in terms of the number of copies of the elementary bath systems per work system (bath rate). If the bath is relatively small, we show that the analysis requires an extended phase diagram exhibiting negative entropies. This corresponds to the purely quantum effect that at the end of the process, system and bath are entangled, thus permitting classically impossible transformations. For a large bath, system and bath may be left uncorrelated and we show that the optimal bath rate, as a function of how tightly the second law is attained, can be expressed in terms of the heat capacity of the bath.
Our approach solves a problem from earlier investigations about how to store the different charges under optimal work extraction protocols in physically separate batteries.
Modified logarithmic Sobolev inequality for 1D non-commuting Hamiltonians
University of Cambridge（剑桥大学）；Universität Tübingen（蒂宾根大学）；Universidad Complutense de Madrid（马德里康普顿斯大学）；Instituto de Ciencias Matemáticas (ICMAT)（数学科学研究所）；Instituto de Física Teórica UAM/CSIC（UAM/CSIC理论物理研究所）
Modern quantum experiments provide examples of transport with non-commuting quantities, offering a tool to understand the interplay between thermal and quantum effects. Here we set forth a theory for non-Abelian transport in the linear response regime. Our key insight is to use generalized Gibbs ensembles with non-commuting charges as the basic building blocks and strict charge-preserving unitaries in a collisional setup. The linear response framework is then built using a collisional model between two reservoirs. We show that the transport coefficients obey Onsager reciprocity. Moreover, we f…
Several recent results on thermodynamics have been obtained using the tools of quantum information theory and resource theories. So far, the resource theories utilised to describe thermodynamics have assumed the existence of an infinite thermal reservoir, by declaring that thermal states at some background temperature come for free. Here, we propose a resource theory of quantum thermodynamics without a background temperature, so that no states at all come for free. We apply this resource theory to the case of many non-interacting systems, and show that all quantum states are classified by thei…
We construct a dynamical decoupling protocol for accurately generating local and global symmetries in general many-body systems. Multiple commuting and non-commuting symmetries can be created by means of a self-similar-in-time ("polyfractal") drive. The result is an effective Floquet Hamiltonian that remains local and avoids heating over exponentially long times. This approach can be used to realize a wide variety of quantum models, and non-equilibrium quantum phases.
Thermodynamics has recently been extended to small scales with resource theories that model heat exchanges. Real physical systems exchange diverse quantities: heat, particles, angular momentum, etc. We generalize thermodynamic resource theories to exchanges of observables other than heat, to baths other than heat baths, and to free energies other than the Helmholtz free energy. These generalizations are illustrated with "grand-potential" theories that model movements of heat and particles. Free operations include unitaries that conserve energy and particle number. From this conservation law an…
The mixing time of Markovian dissipative evolutions of open quantum many-body systems can be bounded using optimal constants of certain quantum functional inequalities, such as the modified logarithmic Sobolev constant. For classical spin systems, the positivity of such constants follows from a mixing condition for the Gibbs measure, via quasi-factorization results for the entropy. Inspired by the classical case, we present a strategy to derive the positivity of the modified logarithmic Sobolev constant associated to the dynamics of certain quantum systems from some clustering conditions on th…
Thermodynamics, which describes vast systems, has been reconciled with small scales, relevant to single-molecule experiments, in resource theories. Resource theories have been used to model exchanges of energy and information. Recently, particle exchanges were modeled; and an umbrella family of thermodynamic resource theories was proposed to model diverse baths, interactions, and free energies. This paper motivates and details the family's structure and prospective applications. How to model electrochemical, gravitational, magnetic, and other thermodynamic systems is explained. Szilard's engin…
Thermal channels -- the free processes allowed in the resource theory of quantum thermodynamics -- are generalised to thermal instruments, which we interpret as implementing thermodynamically free quantum measurements; a Maxwellian demon using such measurements never violates the second law of thermodynamics. Further properties of thermal instruments are investigated and, in particular, it is shown that they only measure observables commuting with the Hamiltonian, and they thermalise the measured system when performing a complete measurement, the latter of which indicates a thermodynamically i…
Entanglement has recently been recognized as an energy resource which can outperform classical resources if decoherence is relatively low. Multi-atom entangled states can mutate irreversibly to so called bound entangled (BE) states under noise. Resource value of BE states in information applications has been under critical study and a few cases where they can be useful have been identified. We explore the energetic value of typical BE states. Maximal work extraction is determined in terms of ergotropy. Since the BE states are non-thermal, extracting heat from them is less obvious. We compare s…
Identifying an accurate model for the dynamics of a quantum system is a vexing problem that underlies a range of problems in experimental physics and quantum information theory. Recently, a method called quantum Hamiltonian learning has been proposed by the present authors that uses quantum simulation as a resource for modeling an unknown quantum system. This approach can, under certain circumstances, allow such models to be efficiently identified. A major caveat of that work is the assumption of that all elements of the protocol are noise-free. Here, we show that quantum Hamiltonian learning …
Quantum thermodynamics can be understood as a resource theory, whereby thermal states are free and the only allowed operations are unitary transformations commuting with the total Hamiltonian of the system. Previous literature on the subject has just focused on transformations between different state resources, overlooking the fact that quantum operations which do not commute with the total energy also constitute a potentially valuable resource. In this Letter, given a number of non-thermal quantum channels, we study the problem of how to integrate them in a thermal engine so as to distill a m…
Driving Quantum Heat Engines Beyond Classical Limits through Multilevel Coherence
Institute for Quantum Science and Engineering, Texas A&M University（德克萨斯农工大学量子科学与工程研究所）；Okinawa Institute of Science and Technology Graduate University（冲绳科学技术大学院大学）；Baylor University（贝勒大学）；Princeton University（普林斯顿大学）
We study the fidelity approach to quantum phase transitions (QPTs) and apply it to general thermal phase transitions (PTs). We analyze two particular cases: the Stoner-Hubbard itinerant electron model of magnetism and the BCS theory of superconductivity. In both cases we show that the sudden drop of the mixed state fidelity marks the line of the phase transition. We conduct a detailed analysis of the general case of systems given by mutually commuting Hamiltonians, where the non-analyticity of the fidelity is directly related to the non-analyticity of the relevant response functions (susceptib…
Expressive equivalence of classical and quantum restricted Boltzmann machines
Computation-Based Science and Technology Research Center, The Cyprus Institute（计算科学与技术研究中心、塞浦路斯研究所）；European Organisation for Nuclear Research (CERN)（欧洲核子研究中心）
Derandomized shallow shadows: Efficient Pauli learning with bounded-depth circuits
Harvard University（哈佛大学）；Harvard-Smithsonian Center for Astrophysics（哈佛-史密森尼天体物理中心）；University of Maryland（马里兰大学）；Joint Quantum Institute（联合量子研究所）；Joint Center for Quantum Information and Computer Science（量子信息与计算机科学联合中心）；National Institute of Standards and Technology（美国国家标准与技术研究院）；University of Innsbruck（因斯布鲁克大学）
We study the optimization of the performance of arbitrary periodically driven thermal machines. Within the assumption of fast modulation of the driving parameters, we derive the optimal cycle that universally maximizes the extracted power of heat engines, the cooling power of refrigerators, and in general any linear combination of the heat currents. We denote this optimal solution as ``generalized Otto cycle'' since it shares the basic structure with the standard Otto cycle, but it is characterized by a greater number of fast strokes. We bound this number in terms of the dimension of the Hilbe…
Quantum thermodynamics can be cast as a resource theory by considering free access to a heat bath, thereby viewing the Gibbs state at a fixed temperature as a free state and hence any other state as a resource. Here, we consider a multipartite scenario where several parties attempt at extracting work locally, each having access to a local heat bath (possibly with a different temperature), assisted with an energy-preserving global unitary. As a specific model, we analyze a collection of harmonic oscillators or a multimode bosonic system. Focusing on the Gaussian paradigm, we construct a reasona…
The heat engine, a machine that extracts useful work from thermal sources, is one of the basic theoretical constructs and fundamental applications of classical thermodynamics. The classical description of a heat engine does not include coherence in its microscopic degrees of freedom. By contrast, a quantum heat engine might possess coherence between its internal states. Although the Carnot efficiency cannot be surpassed, and coherence can be performance degrading in certain conditions, it was recently predicted that even when using only thermal resources, internal coherence can enable a quantu…
Geometric phases and holonomies (their non-commuting generalizations) are a promising resource for the realization of high-fidelity quantum operations in noisy devices, due to their intrinsic fault-tolerance against noise and experimental imperfections. Despite their conceptual appeal and proven fault-tolerance, for a long time their practical use in quantum computing was limited to proof of principle demonstrations. Only in 2012 Sjöqvist et al. formulated a strategy to generate non-Abelian (i.e. holonomic) quantum gates through non-adiabatic transformation. Successful experimental demonstrati…
The power and efficiency of many-body heat engines can be boosted by performing cooperative non-adiabatic operations in contrast to the commonly used adiabatic implementations. Here, the key property relies on the fact that non-adiabaticity is required in order to allow for cooperative effects, that can use the thermodynamic resources only present in the collective non-passive state of a many-body system. In particular, we consider the efficiency of an Otto cycle, which increases with the number of copies used and reaches a many-body bound, which we discuss analytically.
Magic Gate Teleportation: Structure, Useful Resource States, and Simpler Feedforward
Yale Quantum Institute & Department of Applied Physics, Yale University（耶鲁大学应用物理系及耶鲁量子研究所）；Pritzker School of Molecular Engineering, University of Chicago（芝加哥大学普里茨克分子工程学院）
A heat engine operating in the one-shot finite-size regime, where systems composed of a small number of quantum particles interact with hot and cold baths and are restricted to one-shot measurements, delivers fluctuating work. Further, engines with lesser fluctuation produce a lesser amount of deterministic work. Hence, the heat-to-work conversion efficiency stays well below the Carnot efficiency. Here we overcome this limitation and attain Carnot efficiency in the one-shot finite-size regime, where the engines allow the working systems to simultaneously interact with two baths via the semi-lo…
Explaining the influence of strong coupling in the dynamics of open quantum systems is one of the most challenging issues in the rapidly growing field of quantum thermodynamics. By using a particular definition of heat, we develop a new approach to study thermodynamics in the strong coupling regime, which takes into account quantum resources as coherence and entanglement. We apply the method to calculate the time-dependent thermodynamic properties of a system and an environment interacting via the generalized amplitude-damping channel (GADC). The results indicate that the transient imbalance b…
At the heart of quantum thermodynamics lies a fundamental question about what is genuine "quantum" in quantum heat engines and how to seek this quantumness, so that thermodynamical tasks could be performed more efficiently compared with classical protocols. Here, using the concept of $P$-representability, we define a function called classicality, which quantifies the degree of non-classicality of bosonic modes. This function allows us to explore the role of non-classicality in quantum heat engines and design optimal protocols for work extraction. For two specific cycles, a quantum Otto and a g…
Collective thermalization, work reliability, and resource bounds in a population-inverted Dicke Otto engine
Instituto de Física, Universidade Federal de Goiás（戈亚斯联邦大学物理研究所）；Department of Physics, Zhejiang Normal University（浙江师范大学物理学院）；Department of Fundamental Sciences, Hainan Bielefeld University of Applied Sciences（海南比勒费尔德应用科学大学基础科学系）
We show that non-Markovian effects of the reservoirs can be used as a resource to extract work from an Otto cycle. The state transformation under non-Markovian dynamics is achieved via a two-step process, namely an isothermal process using a Markovian reservoir followed by an adiabatic process. From second law of thermodynamics, we show that the maximum amount of extractable work from the state prepared under the non-Markovian dynamics quantifies a lower bound of non-Markovianity. We illustrate our ideas with an explicit example of non-Markovian evolution.
We investigate the Unruh quantum Otto heat engine with level degeneracy. An effectively two level system, where the ground state is non-degenerate and the excited state is $n$-fold degenerate, is acting as the working substance, and the vacuum of massless free scalar field serves as a thermal bath via the Unruh effect. We calculate the heat and work at each step of the Unruh quantum Otto cycle and study the features of the heat engine. The efficiency of the heat engine depends only on the excited energy values of the two level system, not on its level degeneracy. However, the degeneracy acts a…
Conventional statistical mechanics describes large systems and averages over many particles or over many trials. But work, heat, and entropy impact the small scales that experimentalists can increasingly control, e.g., in single-molecule experiments. The statistical mechanics of small scales has been quantified with two toolkits developed in quantum information theory: resource theories and one-shot information theory. The field has boomed recently, but the theorems amassed have hardly impacted experiments. Can thermodynamic resource theories be realized experimentally? Via what steps can we s…
We propose employing a quantum heat engine as a sensitive probe for thermal baths. In particular, we study a single-atom Otto engine operating in an open thermodynamic cycle. Owing to its cyclic nature, the engine is capable of translating small temperature differences between two baths into a macroscopic oscillation in a flywheel. We present analytical and numerical modeling of the quantum dynamics of the engine and estimate it to be capable of detecting temperature differences as small as 2 $μ$K. This sensitivity can be further improved by utilizing quantum resources such as squeezing of the…
A major limitations for many heat engines is that their functioning demands on-line control, and/or an external fitting between environmental parameters (e.g. temperatures of thermal baths) and internal parameters of the engine. We study a model for an adaptive heat engine, where---due to feedback from the functional part---the engine's structure adapts to given thermal baths. Hence no on-line control and no external fitting are needed. The engine can employ unknown resources, it can also adapt to results of its own functioning that makes the bath temperatures closer. We determine thermodynami…
Standard quantum master equation techniques such as the Redfield or Lindblad equations are perturbative to second order in the microscopic system-reservoir coupling parameter $λ$. As a result, characteristics of dissipative systems, which are beyond second order in $λ$, are not captured by such tools. Moreover, if the leading order in the studied effect is higher-than-quadratic in $λ$, a second-order description fundamentally fails, even at weak coupling. Here, using the reaction coordinate (RC) quantum master equation framework, we are able to investigate and classify higher-than-second order…
The performance of variational quantum algorithms relies on the success of using quantum and classical computing resources in tandem. Here, we study how these quantum and classical components interrelate. In particular, we focus on algorithms for solving the combinatorial optimization problem MaxCut, and study how the structure of the classical optimization landscape relates to the quantum circuit used to evaluate the MaxCut objective function. In order to analytically characterize the impact of quantum features on the critical points of the landscape, we consider a family of quantum circuit a…
Uncovering whether strong system-bath coupling can be an advantageous operation resource for energy conversion can facilitate the development of efficient quantum heat engines (QHEs). Yet, a consensus on this ongoing debate is still lacking owing to challenges arising from treating strong couplings. Here we conclude the debate for optimal linear cyclic QHEs operated under a small temperature difference by revealing the detrimental role of strong system-bath coupling in their optimal operations. We analytically demonstrate that both the efficiency at maximum power and maximum efficiency of stro…
We study the modification of the second law of thermodynamics for a quantum system interacting with a reservoir regarding quantum coherence. The whole system is isolated so that neither energy nor information is lost. It is discovered that the coherence of the reservoir can serves as a useful resource allowing the system extract more energy from the reservoir; among the coherence measures, only is the relative entropy of coherence feasible to quantitatively characterize energy exchange. We demonstrate that a thermodynamic cycle between two coherent reservoirs can output more work than its clas…
The question of whether quantum coherence is a resource beneficial or detrimental to the performance of quantum heat engines has been thoroughly studied but remains undecided. To isolate the contribution of coherence, we analyze the performance of a purely coherence-driven quantum heat engine, a device that does not include any heat flow during the thermodynamic cycle. The engine is powered by the coherence of a multiqubit system, where each qubit is charged via interaction with a coherence bath using the Jaynes-Cummings model. We demonstrate that optimal coherence charging and hence extractab…
When a quantum system is subject to a thermal gradient it may sustain a steady non-equilibrium heat current, by entering into a so-called non equilibrium steady state (NESS). Here we show that NESS constitute a thermodynamic resource that can be exploited to fuel a quantum heat engine. This adds to the list of recently reported sources available at the nano-scale, such as coherence, entanglement and quantum measurements. We elucidate this concept by showing analytic and numerical studies of a two-qubits quantum battery that is alternatively charged by a thermal gradient and discharged by appli…
Interactions of quantum systems with their environment play a crucial role in resource-theoretic approaches to thermodynamics in the microscopic regime. Here, we analyze the possible state transitions in the presence of "small" heat baths of bounded dimension and energy. We show that for operations on quantum systems with fully degenerate Hamiltonian (noisy operations), all possible state transitions can be realized exactly with a bath that is of the same size as the system or smaller, which proves a quantum version of Horn's lemma as conjectured by Bengtsson and Zyczkowski. On the other hand,…
The information-carrying capacity of a memory is known to be a thermodynamic resource facilitating the conversion of heat to work. Szilard's engine explicates this connection through a toy example involving an energy-degenerate two-state memory. We devise a formalism to quantify the thermodynamic value of memory in general quantum systems with nontrivial energy landscapes. Calling this the thermal information capacity, we show that it converges to the non-equilibrium Helmholtz free energy in the thermodynamic limit. We compute the capacity exactly for a general two-state (qubit) memory away fr…
Quantum physics revolutionized classical disciplines of mechanics, statistical physics, and electrodynamics. One branch of scientific knowledge however seems untouched: thermodynamics. Major motivation behind thermodynamics is to develop efficient heat engines. Technology has a trend to miniaturize engines, reaching to quantum regimes. Development of quantum heat engines (QHEs) requires emerging field of quantum thermodynamics. Studies of QHEs debate whether quantum coherence can be used as a resource. We explore an alternative where it can function as an effective catalyst. We propose a QHE w…
Resource theories are a generic approach used to manage any valuable resource, such as entanglement, purity, and asymmetry. Such frameworks are characterized by two main elements: a set of predefined (free) operations and states, that one assumes to be easily obtained at no cost. Given these ground rules, one can ask: what is achievable by using such free operations and states? This usually results in a set of state transition conditions, that tell us if a particular state $ ρ$ may evolve into another state $ ρ' $ via the usage of free operations and states. We shall see in this chapter that t…
Temperature uncertainty of a quantum system in canonical ensemble is inversely determined by its energy fluctuation, which is known as the temperature-energy uncertainty relation. No such uncertainty relation was discovered for a non-equilibrium open quantum system. In this article, we derive a universal temperature uncertainty relation for general non-equilibrium processes. We find that it is the fluctuation of heat, which is defined as the change in bath energy, determines the temperature uncertainty in non-equilibrium case. Specifically, the heat is divided into trajectory heat and backacti…
Markovian heat engine boosted by quantum coherence
Centre for Bioinformatics and Photonics—CIBioFi（生物信息学与光子学中心）；Departamento de Física, Universidad del Valle（国立谷大学物理系）；Department of Physics, University of Oslo（奥斯陆大学物理系）
Universal Statistics of Charges Exchanges in Non-Abelian Quantum Transport
Instituto de Física Teórica (IFT), UAM-CSIC（理论物理研究所 (IFT)，马德里自治大学-西班牙国家科学研究委员会）；Institute for Cross-Disciplinary Physics and Complex Systems (IFISC), UIB-CSIC（交叉物理学与复杂系统研究所 (IFISC)，巴利阿里群岛大学-西班牙国家科学研究委员会）
Pure quantum states play a central role in applications of quantum information, both as initial states for many algorithms and as resources for quantum error correction. Preparation of highly pure states that satisfy the threshold for quantum error correction remains a challenge, not only for ensemble implementations like NMR or ESR but also for other technologies. Heat-Bath Algorithmic Cooling is a method to increase the purity of set of qubits coupled to a bath. We investigated the achievable polarization by analyzing the state when no more entropy can be extracted. In particular we give an …
