Several recent results on thermodynamics have been obtained using the tools of quantum information theory and resource theories. So far, the resource theories utilised to describe thermodynamics have assumed the existence of an infinite thermal reservoir, by declaring that thermal states at some background temperature come for free. Here, we propose a resource theory of quantum thermodynamics without a background temperature, so that no states at all come for free. We apply this resource theory to the case of many non-interacting systems, and show that all quantum states are classified by their entropy and average energy, even arbitrarily far away from equilibrium. This implies that thermodynamics takes place in a two-dimensional convex set that we call the energy-entropy diagram. The answers to many resource-theoretic questions about thermodynamics can be read off from this diagram, such as the efficiency of a heat engine consisting of finite reservoirs, or the rate of conversion between two states. This allows us to consider a resource theory which puts work and heat on an equal footing, and serves as a model for other resource theories.
Thermodynamics has recently been extended to small scales with resource theories that model heat exchanges. Real physical systems exchange diverse quantities: heat, particles, angular momentum, etc. We generalize thermodynamic resource theories to exchanges of observables other than heat, to baths other than heat baths, and to free energies other than the Helmholtz free energy. These generalizations are illustrated with "grand-potential" theories that model movements of heat and particles. Free operations include unitaries that conserve energy and particle number. From this conservation law an…
Thermodynamics, which describes vast systems, has been reconciled with small scales, relevant to single-molecule experiments, in resource theories. Resource theories have been used to model exchanges of energy and information. Recently, particle exchanges were modeled; and an umbrella family of thermodynamic resource theories was proposed to model diverse baths, interactions, and free energies. This paper motivates and details the family's structure and prospective applications. How to model electrochemical, gravitational, magnetic, and other thermodynamic systems is explained. Szilard's engin…
Entanglement has recently been recognized as an energy resource which can outperform classical resources if decoherence is relatively low. Multi-atom entangled states can mutate irreversibly to so called bound entangled (BE) states under noise. Resource value of BE states in information applications has been under critical study and a few cases where they can be useful have been identified. We explore the energetic value of typical BE states. Maximal work extraction is determined in terms of ergotropy. Since the BE states are non-thermal, extracting heat from them is less obvious. We compare s…
Driving Quantum Heat Engines Beyond Classical Limits through Multilevel Coherence
Institute for Quantum Science and Engineering, Texas A&M University（德克萨斯农工大学量子科学与工程研究所）；Okinawa Institute of Science and Technology Graduate University（冲绳科学技术大学院大学）；Baylor University（贝勒大学）；Princeton University（普林斯顿大学）
The heat engine, a machine that extracts useful work from thermal sources, is one of the basic theoretical constructs and fundamental applications of classical thermodynamics. The classical description of a heat engine does not include coherence in its microscopic degrees of freedom. By contrast, a quantum heat engine might possess coherence between its internal states. Although the Carnot efficiency cannot be surpassed, and coherence can be performance degrading in certain conditions, it was recently predicted that even when using only thermal resources, internal coherence can enable a quantu…
Explaining the influence of strong coupling in the dynamics of open quantum systems is one of the most challenging issues in the rapidly growing field of quantum thermodynamics. By using a particular definition of heat, we develop a new approach to study thermodynamics in the strong coupling regime, which takes into account quantum resources as coherence and entanglement. We apply the method to calculate the time-dependent thermodynamic properties of a system and an environment interacting via the generalized amplitude-damping channel (GADC). The results indicate that the transient imbalance b…
We show that non-Markovian effects of the reservoirs can be used as a resource to extract work from an Otto cycle. The state transformation under non-Markovian dynamics is achieved via a two-step process, namely an isothermal process using a Markovian reservoir followed by an adiabatic process. From second law of thermodynamics, we show that the maximum amount of extractable work from the state prepared under the non-Markovian dynamics quantifies a lower bound of non-Markovianity. We illustrate our ideas with an explicit example of non-Markovian evolution.
Conventional statistical mechanics describes large systems and averages over many particles or over many trials. But work, heat, and entropy impact the small scales that experimentalists can increasingly control, e.g., in single-molecule experiments. The statistical mechanics of small scales has been quantified with two toolkits developed in quantum information theory: resource theories and one-shot information theory. The field has boomed recently, but the theorems amassed have hardly impacted experiments. Can thermodynamic resource theories be realized experimentally? Via what steps can we s…
As a model of so-called quantum battery (QB), quantum degrees of freedom as energy storage, we study a charging protocol of a many-body QB consisting of $N$ two-level systems (TLSs) using quantum heat engines (QHEs). We focus on the collective enhancement effects in the charging performance of QBs in comparison to the individual charging. It is a challenging goal of QBs to achieve large collective enhancements in the charging power and the capacity while keeping the experimental feasibility, the stability, and the cheapness of the required control and resources. We show that our model actually…
The power and efficiency of many-body heat engines can be boosted by performing cooperative non-adiabatic operations in contrast to the commonly used adiabatic implementations. Here, the key property relies on the fact that non-adiabaticity is required in order to allow for cooperative effects, that can use the thermodynamic resources only present in the collective non-passive state of a many-body system. In particular, we consider the efficiency of an Otto cycle, which increases with the number of copies used and reaches a many-body bound, which we discuss analytically.
We study the modification of the second law of thermodynamics for a quantum system interacting with a reservoir regarding quantum coherence. The whole system is isolated so that neither energy nor information is lost. It is discovered that the coherence of the reservoir can serves as a useful resource allowing the system extract more energy from the reservoir; among the coherence measures, only is the relative entropy of coherence feasible to quantitatively characterize energy exchange. We demonstrate that a thermodynamic cycle between two coherent reservoirs can output more work than its clas…
Uncovering whether strong system-bath coupling can be an advantageous operation resource for energy conversion can facilitate the development of efficient quantum heat engines (QHEs). Yet, a consensus on this ongoing debate is still lacking owing to challenges arising from treating strong couplings. Here we conclude the debate for optimal linear cyclic QHEs operated under a small temperature difference by revealing the detrimental role of strong system-bath coupling in their optimal operations. We analytically demonstrate that both the efficiency at maximum power and maximum efficiency of stro…
At the heart of quantum thermodynamics lies a fundamental question about what is genuine "quantum" in quantum heat engines and how to seek this quantumness, so that thermodynamical tasks could be performed more efficiently compared with classical protocols. Here, using the concept of $P$-representability, we define a function called classicality, which quantifies the degree of non-classicality of bosonic modes. This function allows us to explore the role of non-classicality in quantum heat engines and design optimal protocols for work extraction. For two specific cycles, a quantum Otto and a g…
It is shown how information contained in the pairwise correlations (in general, partial) between atoms of a gas can be used to completely convert heat taken from a thermostat into mechanical work in a process of relaxation of the system to its thermal equilibrium state. Both classical correlations and quantum correlations (entanglement) are considered. The amount of heat converted into work is proportional to the entropy defect of the initial state of the system. For fully correlated particles, in the case of entanglement the amount of work obtained per particle is twice as large as in the cas…
We study a quantum Otto engine embedding a working substance composed by a two-level system interacting with a harmonic mode. The physical properties of the substance are described by a generalized quantum Rabi model arising in superconducting circuits realizations. We show that light-matter quantum correlations reduction during the hot bath stage and compression stage act as a resource for enhanced work extraction and efficiency respectively. Also, we demonstrate that the anharmonic spectrum of the working subtance has a direct impact on the transition from heat engine into refrigerator as th…
The information-carrying capacity of a memory is known to be a thermodynamic resource facilitating the conversion of heat to work. Szilard's engine explicates this connection through a toy example involving an energy-degenerate two-state memory. We devise a formalism to quantify the thermodynamic value of memory in general quantum systems with nontrivial energy landscapes. Calling this the thermal information capacity, we show that it converges to the non-equilibrium Helmholtz free energy in the thermodynamic limit. We compute the capacity exactly for a general two-state (qubit) memory away fr…
The impacts of quantum coherence on nonequilibrium thermodynamics become observable by dividing the heat and work into the conventional diagonal part and the other part relaying on the superpositions and the time derivative of Hamiltonian. Specializing to exactly-solvable dynamics of Larmor precession, we build a quantum Otto heat engine employing magnetic-driven atomic rotations. The coherence induced by the population transition guarantees the positive work output when the control protocol is time dependent. The time-dependent control of a quantum heat engine implements the correspondence be…
We propose employing a quantum heat engine as a sensitive probe for thermal baths. In particular, we study a single-atom Otto engine operating in an open thermodynamic cycle. Owing to its cyclic nature, the engine is capable of translating small temperature differences between two baths into a macroscopic oscillation in a flywheel. We present analytical and numerical modeling of the quantum dynamics of the engine and estimate it to be capable of detecting temperature differences as small as 2 $μ$K. This sensitivity can be further improved by utilizing quantum resources such as squeezing of the…
We investigate the Unruh quantum Otto heat engine with level degeneracy. An effectively two level system, where the ground state is non-degenerate and the excited state is $n$-fold degenerate, is acting as the working substance, and the vacuum of massless free scalar field serves as a thermal bath via the Unruh effect. We calculate the heat and work at each step of the Unruh quantum Otto cycle and study the features of the heat engine. The efficiency of the heat engine depends only on the excited energy values of the two level system, not on its level degeneracy. However, the degeneracy acts a…
A heat engine operating in the one-shot finite-size regime, where systems composed of a small number of quantum particles interact with hot and cold baths and are restricted to one-shot measurements, delivers fluctuating work. Further, engines with lesser fluctuation produce a lesser amount of deterministic work. Hence, the heat-to-work conversion efficiency stays well below the Carnot efficiency. Here we overcome this limitation and attain Carnot efficiency in the one-shot finite-size regime, where the engines allow the working systems to simultaneously interact with two baths via the semi-lo…
We investigate energy transfer by the radiation from a cavity quantum electrodynamics (QED) system in the context of quantum thermodynamics. We propose a method of decomposing it into work and heat within the framework of quantum master equations. We find that the work and heat correspond respectively to the coherent and incoherent parts of the radiation. In the derivation of the method, it is crucial to investigate the dynamics of the system that receives the radiation from the cavity.
In miniaturising electrical devices down to nanoscales, heat transfer has turned into a serious obstacle but also potential resource for future developments, both for conventional and quantum computing architectures. Controlling heat transport in superconducting circuits has thus received increasing attention in engineering microwave environments for circuit quantum electrodynamics (cQED) and circuit quantum thermodynamics experiments (cQTD). While theoretical proposals for cQTD devices are numerous, the experimental situation is much less advanced. There exist only relatively few experimental…
Quantum thermodynamics can be cast as a resource theory by considering free access to a heat bath, thereby viewing the Gibbs state at a fixed temperature as a free state and hence any other state as a resource. Here, we consider a multipartite scenario where several parties attempt at extracting work locally, each having access to a local heat bath (possibly with a different temperature), assisted with an energy-preserving global unitary. As a specific model, we analyze a collection of harmonic oscillators or a multimode bosonic system. Focusing on the Gaussian paradigm, we construct a reasona…
The optimal efficiency of quantum (or classical) heat engines whose heat baths are $n$-particle systems is given by the information geometry and the strong large deviation. We give the optimal work extraction process as a concrete energy-preserving unitary time evolution among the heat baths and the work storage. We show that our optimal work extraction turns the disordered energy of the heat baths to the ordered energy of the work storage, by evaluating the ratio of the entropy difference to the energy difference in the heat baths and the work storage, respectively. By comparing the statistic…
We propose and analyze the theoretical model for a two-stroke quantum heat engine with one of the heat baths replaced by a non-selective quantum measurement. We show that the engine's invariant reference state depends on whether the cycle is monitored or unmonitored via diagnostic measurements to determine the engine's work output. We explore in detail the average work output and fluctuations of the proposed heat engine for the monitored and unmonitored cases. We also identify unitary work strokes for which the invariant states can support coherences in the energy basis leading to differing pr…
Deterministic quantum computation with one qubit (DQC1) is iconic in highlighting that exponential quantum speedup may be achieved with negligible entanglement. Its discovery catalyzed heated study of general quantum resources, and various conjectures regarding their role in DQC1's performance advantage. Coherence and discord are prominent candidates, respectively characterizing non-classicality within localized and correlated systems. Here we realize DQC1 within a superconducting system, engineered such that the dynamics of coherence and discord can be tracked throughout its execution. We exp…
We propose a quantum Stirling heat engine with an ensemble of harmonic oscillators as the working medium. We show that the efficiency of the harmonic oscillator quantum Stirling heat engine (HO-QSHE) at a given frequency can be maximized at a specific ratio of the temperatures of the thermal reservoirs. In the low temperature or equivalently high frequency limit of the harmonic oscillators, the efficiency of the HO-QSHE approaches the Carnot efficiency. Further, we analyse quantum Stirling heat engine with an ensemble of particle in box quantum systems as the working medium. Here both work and…
How may we quantify the value of physical resources, such as entangled quantum states, heat baths or lasers? Existing resource theories give us partial answers; however, these rely on idealizations, like perfectly independent copies of states or exact knowledge of a quantum state. Here we introduce the general tool of currencies to quantify realistic descriptions of resources, applicable in experimental settings when we do not have perfect control over a physical system, when only the neighbourhood of a state or some of its properties are known, or when there is no obvious way to decompose a g…
We present the general theory of a quantum heat machine based on an $N$-level system (working medium) whose $N-1$ excited levels are degenerate, a prerequisite for steady-state interlevel coherence. Our goal is to find out: To what extent is coherence in the working medium an asset for heat machines? The performance bounds of such a machine are common to (reciprocating) cycles that consist of consecutive strokes and continuous cycles wherein the periodically driven system is constantly coupled to cold and hot heat baths. Intriguingly, we find that the machine's performance strongly depends on …
We address the detailed study of the energy current and its components, heat and work, in the boundary-driven 1D XXZ quantum model. We carry out the investigation by considering two different approaches present in the literature. First, we take the repeated interaction scheme and derive the expressions for the currents of heat and work, exchanged between system and baths. Then, we perform the derivation of the energy current by means of a Lindblad master equation together with a continuity equation, another approach which is recurrently used. A comparison between the obtained expressions allow…
The question of whether quantum coherence is a resource beneficial or detrimental to the performance of quantum heat engines has been thoroughly studied but remains undecided. To isolate the contribution of coherence, we analyze the performance of a purely coherence-driven quantum heat engine, a device that does not include any heat flow during the thermodynamic cycle. The engine is powered by the coherence of a multiqubit system, where each qubit is charged via interaction with a coherence bath using the Jaynes-Cummings model. We demonstrate that optimal coherence charging and hence extractab…
When a quantum system is subject to a thermal gradient it may sustain a steady non-equilibrium heat current, by entering into a so-called non equilibrium steady state (NESS). Here we show that NESS constitute a thermodynamic resource that can be exploited to fuel a quantum heat engine. This adds to the list of recently reported sources available at the nano-scale, such as coherence, entanglement and quantum measurements. We elucidate this concept by showing analytic and numerical studies of a two-qubits quantum battery that is alternatively charged by a thermal gradient and discharged by appli…
We analyze an autonomous thermoelectric engine composed of two superconducting qubits coupled to separate heat baths and connected by a Josephson junction. Work and heat are process quantities and not observables of the engine quantum system, but their rates can be derived from the steady state expectation value of appropriate system observables and their fluctuations are given by correlation functions determined with the GKLS master equation and quantum regression theorem. The correlation functions also reveal a cyclical, dynamical transfer of energy - the strokes of the engine - hiding under…
Under a general framework, shortcuts to adiabatic processes are shown to be possible in classical systems. We then study the distribution function of the work done on a small system initially prepared at thermal equilibrium. It is found that the work fluctuations can be significantly reduced via shortcuts to adiabatic processes. For example, in the classical case probabilities of having very large or almost zero work values are suppressed. In the quantum case negative work may be totally removed from the otherwise non-positive-definite work values. We also apply our findings to a micro Otto-cy…
Interactions of quantum systems with their environment play a crucial role in resource-theoretic approaches to thermodynamics in the microscopic regime. Here, we analyze the possible state transitions in the presence of "small" heat baths of bounded dimension and energy. We show that for operations on quantum systems with fully degenerate Hamiltonian (noisy operations), all possible state transitions can be realized exactly with a bath that is of the same size as the system or smaller, which proves a quantum version of Horn's lemma as conjectured by Bengtsson and Zyczkowski. On the other hand,…
Thermal machines perform useful tasks--such as producing work, cooling, or heating--by exchanging energy, and possibly additional conserved quantities such as particles, with reservoirs. Here we consider thermal machines that perform more than one useful task simultaneously, terming these "hybrid thermal machines". We outline their restrictions imposed by the laws of thermodynamics and we quantify their performance in terms of efficiencies. To illustrate their full potential, reservoirs that feature multiple conserved quantities, described by generalized Gibbs ensembles, are considered. A mini…
We use a near quantum limited detector to experimentally track individual quantum state trajectories of a driven qubit formed by the hybridization of a waveguide cavity and a transmon circuit. For each measured quantum coherent trajectory, we separately identify energy changes of the qubit as heat and work, and verify the first law of thermodynamics for an open quantum system. We further establish the consistency of these results by comparison with the master equation approach and the two-projective-measurement scheme, both for open and closed dynamics, with the help of a quantum feedback loop…
We review theoretical approaches to analyzing efficiency of steady state heat to work conversion which is crucial in the timely problem of optimizing efficiency of small-scale heat engines and refrigerators. A rather abstract perspective of non-equilibrium statistical mechanics and dynamical system's theory is taken to view at this very practical problem. Several recently discovered general mechanisms of optimizing the figure of merit of thermoelectric efficiency are discussed, also in connection to breaking time-reversal symmetry of the microscopic equations of motion. Applications of these t…
We analyze work extraction from an autonomous (self-contained) heat-powered optomechanical setup. The initial state of the quantized mechanical oscillator plays a key role. As the initial mean amplitude of the oscillator decreases, the resulting efficiency increases. In contrast to laser-powered self-induced oscillations, work extraction from a broadband heat bath does not require coherence or phase-locking: an initial phase-averaged coherent state of the oscillator still yields work, as opposed to an initial Fock-state.
Heat engines used to output useful work have important practical significance, which, in general, operate between heat baths of infinite size and constant temperature. In this paper we study the efficiency of a heat engine operating between two finite-size heat sources with initial temperature differences. The total output work of such heat engine is limited due to the finite heat capacity of the sources. We investigate the effects of different heat capacity characteristics of the sources on the heat engine's efficiency at maximum work (EMW) in the quasi-static limit. In addition, we study the…
Various engine types are thermodynamically equivalent in the quantum limit of small 'engine action'. Our previous derivation of the equivalence is restricted to Markovian heat baths and to implicit classical work repository (e.g., laser light in the semi-classical approximation). In this paper all the components, baths, batteries, and engine, are explicitly taken into account. To neatly treat non-Markovian dynamics we use mediating particles that function as a heat exchanger. We find that on top of the previously observed equivalence there is a higher degree of equivalence that cannot be achie…
Quantum physics revolutionized classical disciplines of mechanics, statistical physics, and electrodynamics. One branch of scientific knowledge however seems untouched: thermodynamics. Major motivation behind thermodynamics is to develop efficient heat engines. Technology has a trend to miniaturize engines, reaching to quantum regimes. Development of quantum heat engines (QHEs) requires emerging field of quantum thermodynamics. Studies of QHEs debate whether quantum coherence can be used as a resource. We explore an alternative where it can function as an effective catalyst. We propose a QHE w…
