We describe a mechanism by which the longitudinal thermal conductivity $κ_{xx}$, measured in an in-plane magnetic field, oscillates as a function of field angle in layered nodal superconductors. These oscillations occur when the spin-orbit splitting at the nodes is larger than the nodal scattering rate, and are complementary to vortex-induced oscillations identified previously. In sufficiently anisotropic materials, the spin-orbit mechanism may be dominant. As a particular application, we focus on the cuprate high-temperature superconductor YBa$_2$Cu$_3$O$_{6+x}$. This material belongs to the class of Rashba bilayers, in which individual CuO$_2$ layers lack inversion symmetry although the crystal itself is globally centrosymmetric. We show that spin-orbit coupling endows $κ_{xx}/T$ with a characteristic dependence on magnetic field angle that should be easily detected experimentally, and argue that for underdoped samples the spin-orbit contribution is larger than the vortex contribution. A key advantage of the magneto-thermal conductivity is that it is a bulk probe of spin-orbit physics, and therefore not sensitive to inversion breaking at surfaces.
Here we consider the universal heat conduction and the angular dependent thermal conductivity in the vortex state for a few nodal superconductors. We present the thermal conductivity as a function of impurity concentration and the angular dependent thermal conductivity in a few nodal superconductors. This provides further insight in the gap symmetry of superconductivity in Sr$_2$RuO$_4$ and UPd$_2$Al$_3$.
There are now many nodal superconductors in heavy fermion (HF) systems, charge conjugated organic metals, high Tc cuprates and ruthenates. On the other hand only few of them have a well established gap function. We present here a study of the angular dependent thermal conductivity in the vortex state of some of the nodal superconductors. We hope it will help to identify the nodal directions in the gap function of UPd_2Al_3, UNi_2Al_3, UBe_13 and URu_2Si_2.
Motivated by Sr2RuO4, we consider a chiral superconductor where the gap is strongly suppressed along certain momentum directions. We evaluate the thermal Hall conductivity in the gapless regime, i.e., at temperature small compared with the impurity band width γ, taking the simplest model of isotropic impurity scattering. We find that, under favorable circumstances, this thermal Hall conductivity can be quite significant, and is smaller than the diagonal component (the universal thermal conductivity) only by a factor of 1/ ln(2 Δ_M/γ), where Δ_M is the maximum gap.
The bulk microwave conductivity of a dirty d-wave superconductor is known to depend sensitively on the range of the disorder potential: long-range scattering enhances the conductivity, while short- range scattering has no effect. Here we show that the three-terminal electrical conductance of a normal-metal-d-wave superconductor-normal-metal junction has a dual behavior: short-range scattering suppresses the conductance, while long-range scattering has no effect.
How to determine the symmetry of the superconducting order parameter is one of the important issues in novel superconductors, which include charge conjugated organic superconductors. We have proposed that the angular dependence of the thermal conductivity in a planar magnetic field provides a new window to look at the symmetry of the order parameter. After a brief summary of the quasiclassical approach we describe how the symmetry of the superconducting order parameter in Sr$_2$RuO$_4$, CeCoIn$_5$ and $κ$-(ET)$_2$Cu(NCS)$_2$ is determined. Also in some of experiments the phononic thermal condu…
We apply a semi-classical method to the problem of field angle-dependent oscillations of the density of states and thermal conductivity for nodal superconductors and apply our results to the superconductor PrOs$_4$Sb$_{12}$. The oscillatory contributions to the thermal conductivity for all possible point node configurations for a superconductor with $T_h$ symmetry are calculated. It is found that experimental results are best accounted for by nodes in the off-axis directions $[\pm \sinϕ_0, 0, \pm\cosϕ_0]$, which are associated with the time-reversal breaking, triplet paired phase $D_2(E)$.
The structure of the superconducting order parameter in the iron-pnictide superconductor BaFe$_2$(As$_{0.67}$P$_{0.33}$)$_2$ ($T_c=31$\,K) with line nodes is studied by the angle-resolved thermal conductivity measurements in a magnetic field rotated within the basal plane. We find that the thermal conductivity displays distinct fourfold oscillations with minima when the field is directed at $\pm45^\circ$ with respect to the tetragonal a-axis. We discuss possible gap structures that can account for the data, and conclude that the observed results are most consistent with the closed nodal loops …
Fermi liquid theory is remarkably successful in describing the transport and optical properties of metals; at frequencies higher than the scattering rate, the optical conductivity adopts the well-known power law behavior $σ_1(ω) \propto ω^{-2}$. We have observed an unusual non-Fermi liquid response $σ_1(ω) \propto ω^{-1\pm 0.2}$ in the ground states of several cuprate and iron-based materials which undergo electronic or magnetic phase transitions resulting in dramatically reduced or nodal Fermi surfaces. The identification of an inverse (or fractional) power-law behavior in the residual optica…
The angle dependence at different temperatures of the longitudinal thermal conductivity $κ_{xx}(θ)$ in the presence of a planar magnetic field is presented. In order to study the influence of the gap symmetry on the thermal transport angular scans were measured up to a few Kelvin below the critical temperature $T_c$. We found that the four-fold oscillation of $κ_{xx}(θ)$ vanishes at $T > 20 $K and transforms into a one-fold oscillation with maximum conductivity for a field of 8 T applied parallel to the heat current. Nevertheless, the results indicate that the d-wave pairing symmetry is the ma…
In hole-doped high-Tc superconductors, thermal conductivity increases drastically just below Tc, which has been considered as a hallmark of a nodal gap. In contrast, such a coherence peak in thermal conductivity is not visible in electron-doped compounds, which may indicate a full-gap state such as a (d+is)-wave state. To settle this problem, we study the thermal conductivity in the Hubbard model using the fluctuation-exchange (FLEX) approximation, which predicts that the nodal d-wave state is realized in both hole-doped and electron-doped compounds. The contrasting behavior of thermal conduct…
Although the superconductivity in UPt_3 is one of the most well studied, there are still lingering questions about the nodal directions in the B and C phase in the presence of a magnetic field. Limiting ourselves to the low temperature regime (T<<Delta(0)), we study the magnetothermal conductivity with in semiclassical approximation using Volovik's approach. The angular dependence of the magnetothermal conductivity for an arbitrary field direction should clarify the nodal structure in UPt_3.
We comment on the recent work [N. Harrison, \textit{et al.} Phys. Rev. B {\bf 92}, 224505 (2015)] which attempts to explain the sign reversal and quantum oscillations of the Hall coefficient observed in cuprates from a single nodal diamond-shaped electron pocket with concave arc segments. Given the importance of this work, it calls for a closer scrutiny. Their conclusion of sign reversal of the Hall coefficient depends on a non-generic rounding of the sharp vertices. Moreover, their demonstration of quantum oscillation in the Hall coefficient from a single pocket is unconvincing. We maintain t…
In the last few years the gap symmetries of many new superconductors,including Sr$_2$RuO$_4$, CeCoIn$_5$, $κ$-(ET)$_{2}$Cu(NCS)$_{2}$, YNi$_{2}$B$_{2}$C and PrOs$_{4}$Sb$_{12}$, have been identified via angle-dependent magnetothermal conductivity measurements. However, a controversy still persists as to the nature of the superconductivity in Sr$_2$RuO$_4$. For PrOs$_{4}$Sb$_{12}$, spin-triplet superconductivity has recently been proposed. Here, we also propose g-wave superconductivity for UPd$_2$Al$_3$ (i.e., $Δ({\bf k})=Δ\cos(2χ), χ= ck_{z}$) based on recent thermal conductivity data.
We have measured the complex conductivity of a BSCCO(2212) thin film between 0.2 and 1.0 THz. We find the conductivity in the superconducting state to be well described as the sum of contributions from quasiparticles, the condensate, and order parameter fluctuations which draw 30% of the spectral weight from the condensate. An analysis based on this decomposition yields a quasiparticle scattering rate on the order of k_(B)*T/(hbar) for temperatures below Tc.
In contrast to multigap superconductors (e.g. MgB$_{2}$), the low-temperature properties of nodal superconductors are dominated by nodal excitations. Here we extend for a variety of nodal superocnductors the earlier work by Simon and Lee and Kübert and Hirschfeld. The scaling relations seen in the thermodynamics and the thermal conductivity will provide an unequivocal test of nodal superconductivity.
A characteristic feature of the copper oxide high-temperature superconductors is the dichotomy between the electronic excitations along the nodal (diagonal) and antinodal (parallel to the Cu-O bonds) directions in momentum space, generally assumed to be linked to the "d-wave" symmetry of the superconducting state. Angle-resolved photoemission measurements in the superconducting state have revealed a quasiparticle spectrum with a d-wave gap structure that exhibits a maximum along the antinodal direction and vanishes along the nodal direction. Subsequent measurements have shown that, at low dopi…
The phonon contribution to the thermal conductivity at low temperature in superconductors with line nodes is calculated assuming that scattering by both nodal quasiparticles and the sample boundaries is significant. It is determined that, within the regime in which the quasiparticles are in the universal limit and the phonon attenuation is in the hydrodynamic limit, there exists a wide temperature range over which the phonon thermal conductivity varies as $T^2$. This behaviour comes from the fact that transverse phonons propagating along certain directions do not interact with nodal quasiparti…
High resolution measurements of superfluid density and broadband quasiparticle conductivity have been used to probe the low energy excitation spectrum of nodal quasiparticles in underdoped YBCO. Penetration depth is measured to temperatures as low as 0.05 K. Microwave conductivity is measured from 0.1 to 20 GHz and is a direct probe of zero-energy quasiparticles. The data are compared with predictions for a number of theoretical scenarios that compete with or otherwise modify pure d-wave superconductivity, in particular commensurate and incommensurate spin and charge density waves; d + i s and…
We measured the low-temperature thermal conductivity of a new layered superconductor with quasi-one-dimensional characteristics, the ternary telluride Ta$_4$Pd$_3$Te$_{16}$ with transition temperature $T_c \approx$ 4.3 K. The significant residual linear term of thermal conductivity in zero magnetic field and its rapid field dependence provide evidences for nodes in the superconducting gap. By measuring resistivity under pressures, we reveal a superconducting dome in the temperature-pressure phase diagram. The existence of gap nodes and superconducting dome suggests unconventional superconducti…
The thermal fluctuations contribution to magnetization and magneto-conductivity of type II layered superconductor is calculated in the framework of Lawrence-Doniach model. For numerous high temperature cuprate superconductors, it was discovered that the magnetization dependence on temperature in wide range of fields exhibits an intersection point at a temperature slightly below $T_{c}$. We notice a similar intersection point of the magneto-conductivity curves at the approximate same temperature. The phenomenon is explained by strong (non-gaussian) thermal fluctuations with interactions treated…
We report on the detailed analysis of the infrared (IR) conductivity of two prototypical high-$T_{c}$ systems YBa$_{2}$Cu$_{3}$O$_{y}$ and La$_{2-x}$Sr$%_{x}$CuO$_{4}$ throughout the complex phase diagram of these compounds. Our focus in this work is to thoroughly document the electromagnetic response of the nodal metal state which is initiated with only few holes doped in parent antiferromagnetic systems and extends up to the pseudogap boundary in the phase diagram. The key signature of the nodal metal is the two-component conductivity: the Drude mode at low energies followed by a resonance i…
Topological semimetals with superconducting properties provide an emergent platform to explore the properties of topological superconductors. We report magnetization, and magneto-transport measurements on high quality single crystals of transition metal dichalcogenide SnTaS2. It is a nodal line semimetal with superconducting transition below Tc = 2.9 K. Moderate anisotropy (3.1) is observed in upper critical fields along H||c and H||ab plane. In the normal state we observe large magneto-resistance and weak anti-localization effect that provide unambiguous confirmation of topological features i…
This course has a dual purpose. First we review the successes of the weak-coupling BCS theory in describing new classes of superconductors discovered since 1979. They include the heavy-fermion superconductors, high-Tc cuprate superconductors, organic superconductors, Sr2RuO4, etc. Second, we present the quasiclassical approximation introduced by Volovik, which we extend to describe the thermodynamics and the thermal conductivity of the vortex state in nodal superconductors. This approach provides the most powerful tool to identify the symmetry of the energy gap function Delta(k) in these new s…
In light of recent experimental evidence of density wave order in the cuprates, we consider a phenomenological model of a d-wave superconductor with coexisting charge, spin or pair density wave order of various form and wave vector. We study the evolution of the nodal structure of the quasiparticle energy spectrum as a function of the amplitude of the coexisting order and perform diagrammatic linear response calculations of the low-temperature (universal-limit) thermal conductivity. The work described herein expands upon our past studies, which focused on a particular unit-cell-doubling charge…
We analyse the behavior of the thermal conductivity, $κ(H)$, in the vortex state of a quasi-two-dimensional d-wave superconductor when both the heat current and the applied magnetic field are in the basal plane. At low temperature the effect of the field is accounted for in a semiclassical approximation, via a Doppler shift in the spectrum of the nodal quasiparticles. In that regime $κ(H)$ exhibits twofold oscillations as a function of the angle between the direction of the field in the plane and the direction of the heat current, in agreement with experiment.
We analyze the behavior of the thermal conductivity in quasi-two dimensional superconductors with line nodes. Motivated by measurements of the anisotropy between the interplane and intraplane thermal transport in CeIrIn_5 we show that a simple model of the open Fermi surface with vertical line nodes is insufficient to describe the data. We propose two possible extensions of the model taking into account a) additional modulation of the gap along the axial direction of the open Fermi surface; and b) dependence of the interplane tunneling on the direction of the in-plane momentum. We discuss the …
For high-Tc superconductors, clarifying the role and origin of the pseudogap is essential for understanding the pairing mechanism. Among the various models describing the pseudogap, the preformed Cooper pair model is a potential candidate. Therefore, we present experimental evidence for the preformed Cooper pair model by studying the pseudogap spectrum observed in the optical conductivity of a Ca10(Pt4As8)(Fe2As2)5 (Tc = 34.6 K) single crystal. We observed a clear pseudogap structure in the optical conductivity and observed its temperature dependence. In the superconducting (SC) state, one SC …
Since 1979, many new classes of superconductors have been discovered, including heavy-fermion compounds, organic conductors, high-Tc cuprates, and Sr2RuO4. Most of these superconductors are unconventional and/or nodal. Therefore it is of central importance to determine the symmetry of the order parameter in each of these superconductors. In particular, the angular-controlled thermal conductivity in the vortex state provides a unique means of investigating the nodal structure of the superconducting energy gap when high-quality single crystals in the extremely clean limit are available. Using th…
We consider a quasi two-dimensional superconductor with line nodes in an in-plane magnetic field, and compute the dependence of the specific heat, $C$, and the in-plane heat conductivity, $κ$, on the angle between the field and the nodal direction in the vortex state. We use a variation of the microscopic Brandt-Pesch-Tewordt method that accounts for the scattering of quasiparticles off vortices, and analyze the signature of the nodes in $C$ and $κ$. At low to moderate fields the specific heat anisotropy changes sign with increasing temperature. Comparison with measurements of $C$ and $κ$ in C…
We propose a model of nodal order parameters for the superconducting A and B - phase of skutterudite PrOs_4Sb_{12} and discuss the associated angular dependent magnetothermal conductivity at low temperatures. The model for the hybrid gap functions \De(k) containing an s- and g- wave parts is consistent with recent thermal conductivity experiments in PrOs_4Sb_12. In particular the model accounts for the data on polar an azimuthal field angle dependence of κ_zz(θ,ϕ). The low temperature behaviour of thermodynamic properties in zero field is also presented. We show that the effect of impurity sca…
Over the past two decades, unconventional superconductivity with gap symmetry other than s-wave has been found in several classes of materials, including heavy fermion (HF), high-T_c, and organic superconductors. Unconventional superconductivity is characterized by anisotropic superconducting gap functions, which may have zeros (nodes) along certain directions in the Brillouin zone. The nodal structure is closely related to the pairing interaction, and it is widely believed that the presence of nodes is a signature of magnetic or some other exotic, rather than conventional phonon-mediated, pai…
The interplay between magnetism and superconductivity has been a central issue in unconventional superconductors. While the dynamic magnetism could be the source of electron pairing, the static magnetism is generally believed to compete with superconductivity. In this sense, the observation of Q phase, the coupled spin-density wave order and superconductivity, in the heavy-fermion superconductor CeCoIn5 is very puzzling. Whether this Q phase origins from the novel Fulde-Ferrel-Larkin-Ovchinnikov state is under hot debate. Here we report the resistivity and thermal conductivity study of a newly…
We have recently proposed the s+g wave model for superconducting borocarbides. In spite of a substantial s-wave component, this order parameter exhibits the H^1/2 dependent specific heat and a thermal conductivity linear in H in the vortex state. This is characteristic for nodal superconductors when T, Γ<< Δwhere Γis the quasiparticle scattering rate and Δthe maximum superconducting gap. Here we investigate the thermal conductivity parallel to the c- and a- axis in a magnetic field tilted by θfrom the c- axis and rotating within the a-b plane.
The in-plane thermal conductivity of iron-based superconductor RbFe$_2$As$_2$ single crystal ($T_c \approx$ 2.1 K) was measured down to 100 mK. In zero field, the observation of a significant residual linear term $κ_0/T$ = 0.65 mW K$^{-2}$ cm$^{-1}$ provides clear evidence for nodal superdonducting gap. The field dependence of $κ_0/T$ is similar to that of its sister compound CsFe$_2$As$_2$ with comparable residual resistivity $ρ_0$, and lies between the dirty and clean KFe$_2$As$_2$. These results suggest that the (K,Rb,Cs)Fe$_2$As$_2$ serial superconductors have a common nodal gap structure.
