arXivDaily arXiv每日学术速递 周一至周五更新
arXiv 2008.01838cond-mat.mtrl-sci
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用原子探针层析成像技术估算蒸发场和Specific Heats

Estimating Evaporation Fields and Specific Heats Through Atom Probe Tomography

Andrew P. Proudian, Jeramy D. Zimmerman

摘要:

尽管在重建和数据分析过程中的重要性,在原子探针层析成像(APT)文献中的蒸发场值的估计是稀疏的。这项工作描述了一个简单的方法来估计的零势垒蒸发场($F_E$),使用测量的电压与激光脉冲能量的恒定蒸发率。该估计值取决于样品的曲率半径及其比热($C_p$)。如果对固定蒸发速率的测量电压与基础温度进行类似测量,则可以直接提取材料的$C_p$,仅留下样品曲率半径作为输入参数。该方法适用于提取$F_E$从以前公布的电压与激光脉冲能量数据集的CdTe($18.07 \pm 0.87~\mathrm{V~nm^{-1}}$);此外,使用公布的电压与基准温度扫描的CdTe允许提取的比热($11.27 \pm 2.54~\mathrm{J~K^{-1}mol^{-1}}$在$23.1~\mathrm{K}$)与文献($11.14~\mathrm{J~K^{-1}mol^{-1}}$在$22.17~\mathrm{K}$)良好的一致性。然后将该方法应用于先前未表征的材料三[2-苯基吡啶-C2,N]铱(III)($\mathrm{Ir(ppy)_3}$),得到$F_E = 7.49 \pm 0.96~\mathrm{V~nm^{-1}}$和$C_p = 173 \pm 27~\mathrm{J~K^{-1} mol^{-1}}$ ;该$F_E$远低于迄今为止用APT表征的大多数材料。

英文摘要:

Estimations of evaporation field values in atom probe tomography (APT) literature are sparse despite their importance in the reconstruction and data analysis process. This work describes a straightforward method for estimating the zero-barrier evaporation field ($F_E$) that uses the measured voltage vs. laser pulse energy for a constant evaporation rate. This estimate depends on the sample radius of curvature and its specific heat ($C_p$). If a similar measurement is made of the measured voltage vs. base temperature for a fixed evaporation rate, direct extraction of the material's $C_p$ can be made, leaving only the sample radius of curvature as an input parameter. The method is applied to extract $F_E$ from a previously published voltage vs. laser pulse energy dataset for CdTe ($18.07 \pm 0.87~\mathrm{V~nm^{-1}}$); furthermore, using the published voltage vs. base-temperature sweep of CdTe permits extraction of a specific heat ($11.27 \pm 2.54~\mathrm{J~K^{-1}mol^{-1}}$ at $23.1~\mathrm{K}$) in good agreement with the literature ($11.14~\mathrm{J~K^{-1}mol^{-1}}$ at $22.17~\mathrm{K}$). The method is then applied to the previously uncharacterized material tris[2-phenylpyridinato-C2,N]iridium(III) ($\mathrm{Ir(ppy)_3}$), yielding $F_E = 7.49 \pm 0.96~\mathrm{V~nm^{-1}}$ and $C_p = 173 \pm 27~\mathrm{J~K^{-1} mol^{-1}}$; this $F_E$ is much lower than most materials characterized with APT to date.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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