arXivDaily arXiv每日学术速递 周一至周五更新
arXiv 2006.07930cond-mat.mtrl-sci
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电子关联驱动的应变无序VO2薄膜的金属-绝缘体转变

Electron Correlation driven Metal-Insulator transition in Strained and Disordered VO2 films

Alessandro D'Elia, Cesare Grazioli, Albano Cossaro, Bowen Li, Chongwen Zou, Javad Rezvani, Nicola Pinto, Augusto Marcelli, Marcello Coreno

摘要:

VO 2中的金属-绝缘体转变(MIT)的特征在于晶格、电子和轨道自由度之间的复杂相互作用。在这篇文章中,我们研究了轨道层次的应变调制和对VO 2金属相宏观性质的影响,如费米能级(FL)布居和金属性,即,材料屏蔽电场的能力,通过温度依赖的X射线吸收近边结构(XANES)和共振光电子能谱(ResPES)。我们证明了应变VO 2中的MIT是填充控制型的,因此它是由电子相关效应产生的。此外,我们发现,MIT在纳米结构(NS)无序VO 2,其中的结构相变淬火,是由电子相关驱动。因此,对相关性的微调可以导致对过渡特征的精确控制和调谐。

英文摘要:

The Metal-Insulator transition (MIT) in VO2 is characterized by the complex interplay among lattice, electronic and orbital degrees of freedom. In this contribution we investigated the strain-modulation of the orbital hierarchy and the influence over macroscopic properties of the metallic phase of VO2 such as Fermi Level (FL) population and metallicity, i.e., the material ability to screen an electric field, by means of temperature-dependent X-ray Absorption Near Edge Structure (XANES) and Resonant Photoemission spectroscopy (ResPES). We demonstrate that the MIT in strained VO2 is of the Filling Control type, hence it is generated by electron correlation effects. In addition, we show that the MIT in Nanostructured (NS) disordered VO2, where the structural phase transition is quenched, is driven by electron correlation. Therefore a fine tuning of the correlation could lead to a precise control and tuning of the transition features.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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