arXivDaily arXiv每日学术速递 周一至周五更新
arXiv 2006.03152cond-mat.mtrl-sci
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Al8- xFe23Ge12 .5+x(0<=x<=3)体系中铁磁态与反铁磁态的竞争

Competition between ferromagnetic and antiferromagnetic states in Al8.5-xFe23Ge12.5+x (0<=x<=3)

Jiro Kitagawa, Genta Yakabe, Akinori Nakayama, Terukazu Nishizaki, Masami Tsubota

摘要:

用X射线衍射、金相、磁化强度和电阻率等测试方法研究了多晶Al 7 + xFe 23 Ge 14-x型正交晶系Al 8.5-xFe 23 Ge 12.5 +x(0<=x<=3)化合物。晶格参数显示各向异性的x依赖性,反映了较低的对称性,而复杂的晶体结构。在x=0的样品中,铁磁(FM)转变发生在居里温度TC为255 K,这是系统地减少与增加x和消失在x=2.5的反铁磁(AFM)基态实现。Neel温度TN似乎出现在x>=1处,并随着x的增加而增加到x=3处的143 K。在x(1<=x<=2)的中间范围内,在TC以下发生FM到AFM的相变。在AFM阶段,电阻率ρ显示出费米表面不稳定性,其特征在于ρ的向上翻转低于约TN。FM和AFM态之间的竞争归因于Fe-Fe键长的各向异性x依赖性。

英文摘要:

Polycrystalline Al7+xFe23Ge14-x-type orthorhombic Al8.5-xFe23Ge12.5+x (0<=x<=3) compounds were studied by X-ray diffraction measurement, metallographic examination, and magnetization and electrical resistivity measurements. The lattice parameters show anisotropic x dependences, reflecting a lower symmetry of rather complex crystal structure. In the x=0 sample, a ferromagnetic (FM) transition occurs at the Curie temperature TC of 255 K, which is systematically reduced with increasing x and disappears at x=2.5 where an antiferromagnetic (AFM) ground state is realized. The Neel temperature TN seems to appear at x>=1, and grows to 143 K at x=3 with the increment of x. In the intermediate range of x (1<=x<=2), a FM to AFM phase transition occurs below TC. In the AFM phase, the electrical resistivity rho shows a Fermi surface instability characterized by the upturn of rho below approximately TN. The competition between the FM and AFM states would be ascribed to the anisotropic x dependences of Fe-Fe bond lengths.

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