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arXiv 1601.01995cond-mat.str-elcond-mat.mtrl-sci
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La $_{0.5}$ Ba $_{0.5}$ CoO $_3$中相互作用铁磁和小反铁磁团簇的共存

Coexistence of interacting-ferromagnetic and small-antiferromagnetic clusters in La$_{0.5}$Ba$_{0.5}$CoO$_3$

Devendra Kumar, A Banerjee

摘要:

我们报告详细的直流磁化,线性和非线性交流磁化率测量的空穴掺杂无序钴酸盐La $_{0.5}$ Ba $_{0.5}$ CoO $_3$。我们的结果表明,该系统的磁有序状态由共存的非铁磁相和分散的铁磁团簇。在居里温度为201.5(5)~K时,铁磁团簇可能开始磁有序化。非铁磁相主要由尺寸小于铁磁团簇的反铁磁团簇组成。在居里温度以下,系统表现出场冷和零场冷磁化的不可逆性以及交流磁化率峰值的频率依赖性。这些动力学特征表明,朝着可能的共存的自旋玻璃相沿铁磁团簇类似于La $_{1-x}$ Sr $_{x}$ CoO $_3$(x $\geq$ 0.18),但没有场发散的交流磁化率和零场冷却存储器的第三谐波明确排除了任何这种可能性。我们认为,自旋玻璃相在La $_{1-x}$ Sr $_{x}$ CoO $_3$(x $\geq$ 0.18)是与存在不相称的反铁磁有序的非铁磁相,这是不存在的La $_{0.5}$ Ba $_{0.5}$ CoO $_3$。我们的分析表明,La $_{0.5}$ Ba $_{0.5}$ CoO $_3$中观察到的动力学特征可能是由于铁磁团簇的渐进热阻塞,这一点进一步被Wohlfarth的超顺磁性模型所证实。交流磁化率峰的频率依赖性服从Vogel-Fulcher定律,并具有$τ_0\approx10^{-9}$ s。这与H-T空间中AT线的存在一起表明这些铁磁团簇之间存在显著的团簇间相互作用。

英文摘要:

We report detailed dc magnetization, linear and non-linear ac susceptibility measurements on the hole doped disordered cobaltite La$_{0.5}$Ba$_{0.5}$CoO$_3$. Our results show that the magnetically ordered state of the system consists of coexisting non-ferromagnetic phases along with percolating ferromagnetic-clusters. The percolating ferromagnetic-clusters possibly start a magnetic ordering at the Curie temperature of 201.5(5)~K. The non-ferromagnetic phases mainly consist of antiferromagnetic-clusters with size smaller than the ferromagnetic-clusters. Below Curie temperature the system exhibits an irreversibility in the field cooled and zero field cooled magnetization and frequency dependence in the peak of ac susceptibility. These dynamical features indicate towards the possible coexistence of spin-glass phase along with ferromagnetic-clusters similar to La$_{1-x}$Sr$_{x}$CoO$_3$ (x$\geq$0.18), but the absence of field divergence in third harmonic of ac susceptibility and zero field cooled memory clearly rule out any such possibility. We argue that the spin-glass phase in La$_{1-x}$Sr$_{x}$CoO$_3$ (x$\geq$0.18) is associated with the presence of incommensurate antiferromagnetic ordering in non-ferromagnetic phases which is absent in La$_{0.5}$Ba$_{0.5}$CoO$_3$. Our analysis show that the observed dynamical features in La$_{0.5}$Ba$_{0.5}$CoO$_3$ are possibly due to progressive thermal blocking of ferromagnetic-clusters which is further confirmed by the Wohlfarth's model of superparamagnetism. The frequency dependence of the peak of ac susceptibility obeys the Vogel-Fulcher law with $τ_0\approx10^{-9}$s. This together with the existence of an AT line in H-T space indicates the presence of significant inter-cluster interaction among these ferromagnetic-clusters.

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