Some of the oldest and most important applications of thermodynamics are operations of refrigeration as well as production of useful energy. Part of the efforts to understand and develop thermodynamics in the quantum regime have been focusing on harnessing quantum effects to such operations. In this review we present the recent developments regarding the role of quantum coherences in the performances of thermal machines --the devices realising the above thermodynamic operations. While this is known to be an intricate subject, in part because being largely model-dependent, the review of the recent results allow us to identify some general tendencies and to suggest some future directions.
We calculate exactly the quantum mechanical, temporal second-order coherence function for a single-mode, degenerate parametric amplifier for a system in the Gaussian state, viz., a displaced-squeezed thermal state. The calculation involves first the generation of the Gaussian state and subsequent measurements of two photons a time $τ\geq 0$ apart. The generation of the Gaussian state by the parametric amplifier insures that the temporal second-order coherence function depends only on $τ$.
The characterization and control of quantum effects in the performance of thermodynamic tasks may open new avenues for small thermal machines working in the nanoscale. We study the impact of coherence in the energy basis in the operation of a small thermal machine which can act either as a heat engine or as a refrigerator. We show that input coherence may enhance the machine performance and allow it to operate in otherwise forbidden regimes. Moreover, our results also indicate that, in some cases, coherence may also be detrimental, rendering optimization of particular models a crucial task for…
We present a model for an autonomous quantum thermal machine comprised of two qubits capable of manipulating and even amplifying the local coherence in a non-degenerate external system. The machine uses only thermal resources, namely, contact with two heat baths at different temperatures, and the external system has a non-zero initial amount of coherence. The method we propose allows for an interconversion between energy, both work and heat, and coherence in an autonomous configuration working in out-of-equilibrium conditions. This model raises interesting questions about the role of fundament…
Coherent control of self-contained quantum systems offers the possibility to fabricate smallest thermal transistors. The steady coherence created by the delocalization of electronic excited states arouses nonlinear heat transports in non-equilibrium environment. Applying this result to a three-level quantum system, we show that quantum coherence gives rise to negative differential thermal resistances, making the thermal transistor suitable for thermal amplification. The results show that quantum coherence facilitates efficient thermal signal processing and can open a new field in the applicati…
Quantum coherence associated with the superpositions of two different sets of eigenbasis vectors has been regarded as essential in thermodynamics. It is found that coherent factors can be determined by writing observables as an expansion in the basis vectors of the systemic density operator and Hamiltonian. We reveal the roles of coherence in finite-time thermodynamic processes, such as the spin precession and the spontaneous emission of a photon. Results show that the work in the spin precession and the heat in the spontaneous emission process are mainly generated by coherence.
Coherence-induced deep thermalization transition in random permutation quantum dynamics
National University of Singapore（新加坡国立大学）；The University of Texas at Austin（德克萨斯大学奥斯汀分校）；Centre for Quantum Technologies, National University of Singapore（新加坡国立大学量子技术中心）
We consider finite sized atomic systems with varying number of particles which have dipolar interactions among them and also under the collective driving and dissipative effect of thermal photon environment. Focusing on the simple case of two atoms, we investigate the impact of different parameters of the model on the coherence contained in the system. We observe that even though the system is initialized in a completely incoherent state, it evolves to a state with a finite amount of coherence and preserve that coherence in the long-time limit in the presence of thermal photons. We propose a n…
The dynamics of coherence in a two-qubit Heisenberg XXX model with magnetic field in the presence of the intrinsic decoherence is investigated. We discuss the influence of dipole parameter, spin distance, magnetic field and initial state parameter on coherence of the long time limit situation. Then, we discuss how decoherence changes with time with the initial state parameter and the decoherence parameter.
Quantum coherence, the ability of a quantum system to be in a superposition of orthogonal quantum states, is a distinct feature of the quantum mechanics, thus marking a deviation from classical physics. Coherence finds its applications in quantum sensing and metrology, quantum thermodynamics and computation. A particularly interesting is the possibility to observe coherence arising in counter-intuitive way from thermal energy that is without implementation of intricate protocols involving coherent driving sequences. In this manuscript, we investigate quantum coherence emerging in a hybrid syst…
We analyze the coherence properties of a cold or a thermal neutron by utilizing the Wigner quasidistribution function. We look in particular at a recent experiment performed by Badurek {\em et al.}, in which a polarized neutron crosses a magnetic field that is orthogonal to its spin, producing highly non-classical states. The quantal coherence is extremely sensitive to the field fluctuation at high neutron momenta. A "decoherence parameter" is introduced in order to get quantitative estimates of the losses of coherence.
The unitary generation of coherence from an incoherent thermal state is investigated. We consider a completely controllable Hamiltonian allowing to generate all possible unitary transformations. Optimizing the unitary control to achieve maximum coherence leads to a micro-canonical energy distribution on the diagonal energy representation. We demonstrate such a control scenario starting from a Hamiltonian utilizing optimal control theory for unitary targets. Generating coherence from an incoherent initial state always costs external work. By constraining the amount of work invested by the contr…
In the general framework of open quantum systems, we assess the impact of the pulse area on single and double quantum coherence (1QC and 2QC) signals extracted from fluorescence emitted by dilute thermal gases. We show that 1QC and 2QC signals are periodic functions of the pulse area, with distinctive features which reflect the particles' interactions via photon exchange, the polarizations of the laser pulses, and the observation direction.
In the long-time limit, an open quantum system coupled to a dissipative environment is believed to lose its coherence without driving or measurement. Counterintuitively, we provide a necessary condition on trapping the coherence of a two-level system entirely with a thermal bath. Based on a time-local master equation, it is found that the residue coherence survives even under a high-temperature bath as long as the long-time Lamb shift is exactly negative to the system transition frequency. This condition is generally met in the strong and even ultrastrong coupling regime that could be relaxed …
It is shown that quantum coherence is conserved in a principal system in the case that the system is coupled to a fast dissipating environment [arXiv:0709.0562]. The phenomenon is called the quantum wipe effect. Here, this effect is reviewed and the analytical proof for a model system consisting of a one-qubit system coupled to a fast dissipating environment is extended to an environment at a thermal equilibrium.
We discuss the role of quantum coherence in the energy fluctuations of open quantum systems. To this aim, we introduce a protocol, to which we refer to as the end-point-measurement scheme, allowing to define the statistics of energy changes as a function of energy measurements performed only after the evolution of the initial state. At the price of an additional uncertainty on the initial energies, this approach prevents the loss of initial quantum coherences and enables the estimation of their effects on energy fluctuations. We demonstrate our findings by running an experiment on the IBM Quan…
The introduction of the quantum analogue of a Carnot engine based on a bath comprising of particles with a small amount of coherence initiated an active line of research on the harnessing of different quantum resources for the enhancement of thermal machines beyond the standard reversible limit, with an emphasis on non-thermal baths containing quantum coherence. In our work, we investigate the impact of coherence on the thermodynamic tasks of a collision model which is composed of a system interacting, in the continuous time limit, with a series of coherent ancillas of two baths at different t…
A novel thermal light interferometer was recently introduced in V. Tamma and J. Seiler, New J. Phys. 18, 032002 (2016). Here, two classically correlated beams, obtained by beam splitting a thermal light beam, propagate through two unbalanced Mach-Zehnder interferometers. Remarkably, second-order interference between the long and the short paths in the two interferometers was predicted independently of how far, in principle, the length difference between the long and short paths is beyond the coherence length of the source. This phenomenon seems to contradict our common understanding of second …
The effects of an impurity plaquette on the thermal quantum correlations measurement by the concurrence, on the quantum coherence quantified by the recently proposed $l_{1}$-norm of coherence and on the quantum teleportation in a Ising-$XXZ$ diamond chain are discussed. Such an impurity is formed by the XXZ interaction between the interstitial Heisenberg dimers and the nearest-neighbor Ising coupling between the nodal and interstitial spins. All the interaction parameters are different from those of the rest of the chain. By tailoring them, the quantum entanglement and quantum coherence can be…
Thermal operations are an operational model of non-equilibrium quantum thermodynamics. In the absence of coherence between energy levels, exact state transition conditions under thermal operations are known in terms of a mathematical relation called thermo-majorization. But incorporating coherence has turned out to be challenging, even under the relatively tractable model wherein all Gibbs state-preserving quantum channels are included. Here we find a mathematical generalization of thermal operations at low temperatures, "cooling maps", for which we derive the necessary and sufficient state tr…
Exploiting the relative entropy of coherence, we isolate the coherent contribution in the energetics of a driven non-equilibrium quantum system. We prove that a division of the irreversible work can be made into a coherent and incoherent part, which provides an operational criterion for quantifying the coherent contribution in a generic non-equilibrium transformation on a closed quantum system. We then study such a contribution in two physical models of a driven qubit and kicked rotor. In addition, we also show that coherence generation is connected to the non-adiabaticity of a processes, for …
We discuss the role of quantum coherence in the energy fluctuations of open quantum systems. To this aim, we introduce an operational protocol, to which we refer to as the end-point-measurement scheme, allowing to define the statistics of energy changes as a function of energy measurements performed only after its evolution. At the price of an additional uncertainty on the value of the initial energies, this approach prevents the loss of initial quantum coherences and enables the estimation of their effects on energy fluctuations. We illustrate our findings using a three-level quantum system i…
We consider a quantum engine driven by repeated weak interactions with a heat bath of identical three-level atoms. This model was first introduced by Scully et al. [Science, 2003], who showed that coherence between the energy-degenerate ground states serves as a thermodynamic resource that allows operation of a thermal cycle with a coherence-dependent thermalisation temperature. We consider a similar engine out of the quasistatic limit and find that the ground-state coherence also determines the rate of thermalisation, therefore increasing the output power and the engine efficiency only when t…
Both ghost imaging (GI) and ghost imaging via compressive sampling (GICS) can nonlocally image an object. We report the influence of spatial transverse coherence property of a thermal source on GI and GICS and show that, using the same acquisition numbers, the signal-to-noise ratio (SNR) of images recovered by GI will be reduced while the quality of reconstructed images will be enhanced for GICS as the spatial transverse coherence lengths located on the object plane are decreased. Differences between GI and GICS, methods to further improve the quality and image extraction efficiency of GICS, a…
The quantum coherence of the two-site XYZ model with Dzyaloshinsky-Moriya (DM) interactions in an external inhomogenous magnetic field is studied. The DM interaction, the magnetic field and the measurement basis can be along different directions, and we examine the quantum coherence at finite temperature. With respect to the spin-spin interaction parameter, we find that the quantum coherence decreases when the direction of measurement basis is the same as that of the spin-spin interaction. When the spin-lattice interaction is varied, the coherence always increases irrespective of the relation …
We report observation of a counter-intuitive phenomenon in multi-path correlation interferometry with thermal light. The intensity correlation between the outputs of two unbalanced Mach-Zehnder interferometers (UMZI) with two classically correlated beams of thermal light at the input exhibits genuine second-order interference with the visibility of $1/3$. Surprisingly, the second-order interference does not degrade at all no matter how much the path length difference in each UMZI is increased beyond the coherence length of the thermal light. Moreover, the second-order interference is dependent…
We calculate the quantum mechanical, temporal second-order coherence function for a single-mode, degenerate parametric amplifier for a system in the Gaussian state, viz., a displaced-squeezed thermal state. The calculation involves first the dynamical generation at time $t$ of the Gaussian state from an initial thermal state and subsequent measurements of two photons a time $τ\geq 0$ apart. The generation of the Gaussian state by the parametric amplifier ensures that the temporal second-order coherence function depends only on $τ$, via $τ/t$, for given Gaussian state parameters, Gaussian state…
We consider a finite-time quantum Otto heat engine that consists of two isochoric (thermal-contact) process, where the system is alternatively coupled to a hot squeezed and a cold thermal reservoir, and two unitary driven strokes, where the system is isolated from these two baths and its von Neumann entropy keeps constant. Both quantum inner friction and coherence are generated along the driven stroke and coherence cannot be fully erased after the finite-time hot isochore. Using full counting statistics, we present the probability distribution functions of heat injection and total work per cyc…
To control and utilize quantum features in small scale for practical applications such as quantum transport, it is crucial to gain deep understanding of quantum characteristics of states such as coherence. Here by introducing a technique that simplifies solving the dynamical equation, we study the dynamics of coherence in a system of qubits interacting with each other through a common bath at non zero temperature. Our results demonstrate that depending on initial state, environment temperature affect coherence and excitation transfer in different ways. We show that when initial state is incohe…
We consider the problem of keeping an arbitrary state $ρ_s$ out of thermal equilibrium. We find that counter-acting thermalisation using only a resource system which is in a stationary state at the initial time and a system-resource interaction that preserves the global energy is possible if and only if the target state $ρ_s$ is block-diagonal in the eigenbasis of the system's Hamiltonian $H_s.$ As a consequence, we compute the extra work the operator must provide by tuning the resource-system interaction to overcome this constraint. This quantity, which is interpreted as the work needed to pr…
One of the principal objectives of quantum thermodynamics is to explore quantum effects and their potential beneficial role in thermodynamic tasks like work extraction or refrigeration. So far, even though several papers have already shown that quantum effect could indeed bring quantum advantages, a global and deeper understanding is still lacking. Here, we extend previous models of autonomous machines to include quantum batteries made of arbitrary systems of discrete spectrum. We establish their actual efficiency, which allows us to derive an efficiency upper bound, called maximal achievable …
Quantum correlations and coherence generated between two free spinless particles in the lattice, interacting with a common quantum phonon bath, are studied. The reduced density matrix is solved using the Markov approach. We show that the bath induces correlations between the particles. The coherence induced by the bath is studied, calculating off-diagonal elements of the density matrix, spatiotemporal dispersion, purity and quantum mutual information. We find a characteristic time-scale pointing out when this coherence is maximum. In addition, a Wigner-like distribution in the phase-space (lat…
The dynamical behavior of quantum coherence of a displaced squeezed thermal state in contact with an external bath is discussed in the present work. We use a Fano-Anderson type of Hamiltonian to model the environment and solve the quantum Langevin equation. From the solution of the quantum Langevin equation we obtain the Green's functions which are used to calculate the expectation value of the quadrature operators which are in turn used to construct the covariance matrix. We use a relative entropy based measure to calculate the quantum coherence of the mode. The single mode squeezed thermal s…
We show that certain coherences, termed as heat-exchange coherences, which contribute to the thermalization process of a quantum probe in a repeated interactions scheme, can modify the spectral response of the probe system. We suggest to use the power spectrum as a way to experimentally assess the apparent temperature of non-thermal atomic clusters carrying such coherences and also prove that it is useful to measure the corresponding thermalization time of the probe, assuming some information is provided on the nature of the bath. We explore this idea in two examples in which the probe is assu…
Recent experiments at the nanoscales confirm that thermal rectifiers, the thermal equivalent of electrical diodes, can operate in the quantum regime. We present a thorough investigation of the effect of different particle exchange statistics, coherence, and collective interactions on the quantum heat transport of rectifiers with two-terminal junctions. Using a collision model approach to describe the open system dynamics, we obtain a general expression of the nonlinear heat flow that fundamentally deviates from the Landauer formula whenever quantum statistical or coherence asymmetries are pres…
The entropy production in dissipative processes is the essence of the arrow of time and the second law of thermodynamics. For dissipation of quantum systems, it was recently shown that the entropy production contains indeed two contributions: a classical one and a quantum one. Here we show that for degenerate (or near-degenerate) quantum systems there are additional quantum contributions which, remarkably, can become negative. Furthermore, such negative contributions are related to significant changes in the ongoing thermodynamics. This includes phenomena such as generation of coherences betwe…
The formation of diatomic molecules with rotational and vibrational coherence is demonstrated experimentally in free-to-bound two-photon femtosecond photoassociation of hot atoms. In a thermal gas at a temperature of 1000 K, pairs of magnesium atoms, colliding in their electronic ground state, are excited into coherent superpositions of bound rovibrational levels in an electronically excited state. The rovibrational coherence is probed by a time-delayed third photon, resulting in quantum beats in the UV fluorescence. A comprehensive theoretical model based on ab initio calculations rationalize…
We use a parametric down-conversion source pumped by a short coherence-length continuous-wave (CW) diode laser to perform two-photon interferometry in an intermediate regime between the more familiar Franson-type experiments with a long coherence-length pump laser, and the short pulsed pump "time-bin" experiments pioneered by Gisin's group. The use of a time-bin-like Mach-Zehnder interferometer in the CW pumping beam induces coherence between certain two-photon amplitudes, while the CW nature of the experiment prevents the elimination of remaining incoherent ones. The experimental results high…
We study the limitations on coherence evolutions under the constraints of thermodynamic laws, and focus on the optimal thermal operations (TO) reaching the bounds. For qubit case, we find a thermal operation involving only a single-mode reservoir (STO) which maintains the maximum coherence allowed by general TO. For higher dimensions, we derive general bounds on coherence merging under TO, and find STO to reach the bounds. By applying the bound to a two-qubit system, we prove that erasing correlations while preserving the marginal states is not free in the resource theory of thermodynamics. Du…
Utilizing quantum coherence monotone, we reexamine the thermal nature of the Unruh effect of an accelerating detector. We consider an UDW detector coupling to a n-dimensional conformal field in Minkowski spacetime, whose response spectrum generally exhibits an intermediate statistics of (1+1) anyon field. We find that the thermal nature of the Unruh effect guaranteed by KMS condition is characterized by a vanishing asymptotic quantum coherence. We show that the time-evolution of coherence monotone can distinguish the different thermalizing ways of the detector, which depends on the scaling dim…
The interplay between quantum-mechanical properties, such as coherence, and classical notions, such as energy, is a subtle topic at the forefront of quantum thermodynamics. The traditional Carnot argument limits the conversion of heat to work; here we critically assess the problem of converting coherence to work. Through a careful account of all resources involved in the thermodynamic transformations within a fully quantum-mechanical treatment, we show that there exist thermal machines extracting work from coherence arbitrarily well. Such machines only need to act on individual copies of a sta…
Here, we study a minimal model, the three-level V system coupled to two heat baths, and investigate the role of quantum coherences in heat transport in both the transient regime and in the nonequilibrium steady-state. In our model, energy is exchanged between the baths through two parallel pathways, which can be made distinct through the nondegeneracy of excited levels (energy splitting $Δ$) and a control parameter $α$, which adjusts the strength of one of the arms. Using a nonsecular quantum master equation of Redfield form, we succeed in deriving closed-form expressions for the quantum coher…
A quantum framework, according quantum theories of electromagnetic (EM)radiation to matter response, leads to a handy scheme addressed to examine both physical and chemical processes. Fundamental quantum effects such asentanglement, coherence, de-coherence and re-coherence yield a fully quantum physical presentation applicable to chemical processes. A photonic basis-set obtains including all possibilities accessible to a system in abstract space; electronuclear (EN) base states put in resonance by photon fields are the ground where quantum states, q-states, would show time evolution. At labora…
The total correlations in a bipartite quantum system are measured by the quantum mutual information $\mathcal{I}$, which consists of quantum discord and classical correlation. However, recent results in quantum information shows that coherence, which is a part of total correlation, is more general and more fundamental than discord. The role of coherence in quantum resource theories is worthwhile to investigate. We first study the relation between quantum discord and coherence by reducing the difference between them. And then, we consider the dynamics of quantum discord, classical correlations …
Manifestations of dipole-dipole interactions in dilute thermal gases are difficult to sense because of strong inhomogeneous broadening. Recent experiments reported signatures of such interactions in fluorescence detection-based measurements of multiple quantum coherence (MQC) signals, with many characteristic features hitherto unexplained. We develop an original open quantum systems theory of MQC in dilute thermal gases, which allows us to resolve this conundrum. Our theory accounts for the vector character of the atomic dipoles as well as for driving laser pulses of arbitrary strength, includ…
We investigate attractor quantum neural networks (aQNNs) within the framework of coherence theory. We show that: i) aQNNs are associated to non-coherence-generating quantum channels; ii) the depth of the network is given by the decohering power of the corresponding quantum map; and iii) the attractor associated to an arbitrary input state is the one minimizing their relative entropy. Further, we examine faulty aQNNs described by noisy quantum channels, derive their physical implementation and analyze under which conditions their performance can be enhanced by using entanglement or coherence as…
