Oxygen $K$-edge X-ray absorption spectroscopy measurements were conducted on T*-type La$_{1-x/2}$Eu$_{1-x/2}$Sr$_x$CuO$_4$ (LESCO) to estimate the hole density ($n_{\rm h}$) and investigate the oxidation annealing effect on $n_{\rm h}$. A drastic increase in $n_{\rm h}$ due to annealing was found. The increase in $n_{\rm h}$ cannot be explained solely by the oxygen gain due to annealing, suggesting that delocalized holes are introduced into the CuO$_2$ plane. A phase diagram of LESCO was redrawn against $n_{\rm h}$.
Inelastic neutron scattering has been used to study the in-plane Cu-O bond-stretching mode in oxygen doped La$_{1.94}$Sr$_{0.06}$CuO$_{4.035}$ ($T_c = 38\,\text{K}$) and La$_2$CuO$_{4+δ}$ ($T_c = 43\,\text{K}$). Similar to results from optimally doped La$_{1.85}$Sr$_{0.15}$CuO$_4$ ($T_c = 35\,\text{K}$), we observe anomalous features in the dispersion of this half-breathing mode in the form of a softening halfway through the Brillouin Zone. Considering the differences in electronic structure and local environment between the oxygen- and strontium-doped compounds with similar $T_\text{c}$, we r…
While recent experiments have found that at optimum doping for the highest critical temperature in HgBa$_2$CuO$_{4+y}$ (Hg1201) the oxygen interstitials (O-i) are not homogeneously distributed but form one-dimensional atomic wires, there are no available information of its electronic structure considering self-organized O-i atomic wires. Here we report the calculated electronic structure of HgBa$_2$CuO$_{4+y}$ where oxygen interstitials form atomic wires along (1,0,0) crystal direction in the Hg layer. We find that at optimum doping for superconductivity the chemical potential is tuned near an…
Novel nanoscale probes are opening new venues for understanding unconventional electronic and magnetic functionalities driven by multiscale lattice complexity in doped high temperature superconducting perovskites. In this work we focus on the multiscale texture at supramolecular level of atomic oxygen interstitials (O-i) stripes in HgBa$_2$CuO$_{4+y}$ at optimal doping for the highest superconducting critical temperature $T_C$=94K. We report compelling evidence for the nematic phase of oxygen-interstitial O-i atomic wires with fractal-like spatial distribution over multiple scales by using sca…
The superconducting properties of high-\tc\ materials are functions of carriers concentration, which is controlled by the concentration of defects including heterovalent cations, interstitial oxygen ions, and oxygen vacancies. Here we combine low-temperature thermal treatment of La$_{2-x}$Sr$_{x}$CuO$_{4}$ epitaxial thin films and confocal Raman spectroscopy to control and investigate oxygen vacancies. We demonstrate that the apical site is the most favorable position to accommodate oxygen vacancies under low-temperature annealing conditions. Additionally we show that in high-quality films of …
Magneto-elastic coupling between copper spin configurations and oxygen octahedra in La(2-x)Sr(x)CuO(4). Untwinning, Raman (phonon) spectrum, and neutron response
Electron-doped and hole-doped superconducting cuprates exhibit a symmetric phase diagram as a function of doping. This symmetry is however only approximate. Indeed, electron-doped cuprates become superconductors only after a specific annealing process: This annealing affects the oxygen content by only a tiny amount, but has a dramatic impact on the electronic properties of the sample. Here we report the occurrence of superconductivity in oxygen-deficient Nd$_{2-x}$Ce$_x$CuO$_4$ thin films grown in an oxygen-free environment, after annealing in pure argon flow. As verified by x-ray diffraction,…
We performed neutron powder diffraction measurements on the as-sintered (AS) and oxygen-reduced (OR) La$_{1.8}$Eu$_{0.2}$CuO$_{4+α-δ}$ (LECO). The structural parameters for oxygens in AS and OR samples refined by the Rietveld analysis are almost identical to those of the reference system, Pr$_{2}$CuO$_{4+α-δ}$. Thus, the two systems are comparable in terms of the structural changes in oxygens due to the annealing, although superconductivity appears only in LECO.
We use single crystal $^{63}$Cu NMR techniques to revisit the early $^{63}$Cu NQR signature of charge order observed for La$_{1.875}$Ba$_{0.125}$CuO$_{4}$ ($T_{\text{c}} =4$~K) [A. W. Hunt et al., Phys. Rev. Lett. {\bf 82}, 4300 (1999)]. We show that the growth of spin correlations is accelerated below $\sim 80$~K, where the inverse Laplace transform (ILT) T$_{1}$ analysis of the $^{139}$La NMR spin-lattice relaxation curve recently uncovered emergence of the slow components in the lattice and/or charge fluctuations [P. M. Singer et al., {\bf 101}, 174508 (2020)]. From the accurate measurement…
In this article, we studied the role of oxygen in Pr$_{2}$CuO$_{4\pmδ}$ thin films fabricated by polymer assisted deposition method. The magnetoresistance and Hall resistivity of Pr$_{2}$CuO$_{4\pmδ}$ samples were systematically investigated. It is found that with decreasing the oxygen content, the low-temperature Hall coefficient ($R_H$) and magnetoresistance change from negative to positive, similar to those with the increase of Ce-doped concentration in R$_{2-x}$Ce$_{x}$CuO$_{4}$ (R= La, Nd, Pr, Sm, Eu). In addition, $T_c$ versus $R_H$ for both Pr$_{1-x}$LaCe$_{x}$CuO$_{4}$ and Pr$_{2}$CuO$…
The oxygen dopants are essential in tuning electronic properties of Bi$_2$Sr$_2$Ca$_{n-1}$Cu$_n$O$_{2n+4+δ}$ superconductors. Here we apply the technique of scanning tunneling microscopy and spectroscopy to study the influence of oxygen dopants in an optimally doped Bi$_2$Sr$_{2-x}$La$_x$CuO$_{6+δ}$ and an overdoped Bi$_{2-y}$Pb$_y$Sr$_2$CuO$_{6+δ}$. In both samples, we find that interstitial oxygen atoms on the SrO layers dominate over the other two forms of oxygen dopants, oxygen vacancies on the SrO layers and interstitial oxygen atoms on the BiO layers. The hole doping is estimated from th…
Bulk crystals of electron-doped cuprates with the T'-type structure require both Ce substitutions and reduction annealing for the emergence of superconductivity while the reduction annealing alone can induce superconductivity in thin films of the T'-type cuprates. In order to reveal low-energy electronic states which are responsible for the superconductivity, we have conducted angle-resolved photoemission spectroscopy measurements on thin films of the superconducting Ce-free T'-type cuprate Pr$_2$CuO$_4$. The results indicate that the overall band structure and the Fermi surface area of the su…
An intact CuO$_2$ plane is widely believed to be a prerequisite for the high-$T_c$ superconductivity in cuprate superconductors. However, an exception may exist in the superconducting Ba$_2$CuO$_{3+δ}$ materials where CuO chains play a more important role. From first-principles density functional theory calculations, we have studied the electronic and magnetic structures of Ba$_2$CuO$_{3+δ}$. The stoichiometric Ba$_2$CuO$_3$ and Ba$_2$CuO$_4$ contain quasi-one-dimensional CuO chains and intact two-dimensional CuO$_2$ planes, respectively. In comparison with the nonmagnetic metal Ba$_2$CuO$_4$,…
For both electron- and hole-doped cuprates, superconductivity appears in the vicinity of suppressed broken symmetry order, suggesting that quantum criticality plays a vital role in the physics of these systems. A confounding factor in identifying the role of quantum criticality in the electron-doped systems is the competing influence of chemical doping and oxygen stoichiometry. Using high quality thin films of Pr$_{2}$CuO$_{4\pmδ}$, we tune superconductivity and uncover the influence of quantum criticality without Ce substitution. We observe magnetic quantum oscillations that are consistent wi…
Layered copper oxides have highest superconducting transition temperatures at ambient pressure. Its mechanism remains a grand challenge in condensed matter physics. The essential physics lying in 2-dimensional copper-oxygen layers is well described by a single band Hubbard model or its strong coupling limit t-J model in 2-dimensional square lattice. Recently discovered high temperature superconductor Ba$_2$CuO$_{3+δ}$ with $δ\sim 0.2$ has different crystal structure with large portion of in-plane oxygen vacancies. We observe that an oxygen vacancy breaks the bond of its two neighboring copper …
Measurements of the $^{17}$O nuclear magnetic resonance (NMR) quadrupolar spectrum of apical oxygen in HgBa$_{2}$CuO$_{4+δ}$ were performed over a range of magnetic fields from 6.4 to 30\,T in the superconducting state. Oxygen isotope exchanged single crystals were investigated with doping corresponding to superconducting transition temperatures from 74\,K underdoped, to 78\,K overdoped. The apical oxygen site was chosen since its NMR spectrum has narrow quadrupolar satellites that are well separated from any other resonance. Non-vortex contributions to the spectra can be deconvolved in the ti…
The oxygen isotope ($^{16}$O/$^{18}$O) effect (OIE) on the pseudogap (charge-stripe ordering) temperature $T^{\ast}$ is investigated for the cuprate superconductor La$_{2-x}$Sr$_{x}$CuO$_{4}$ as a function of doping $x$ by means of x-ray absorption near edge structure (XANES) studies. A strong $x$ dependent and sign reversed OIE on $T^{\ast}$ is observed. The OIE exponent $α_{T^{\ast}}$ systematically decreases from $α_{T^{\ast}} = - 0.6(1.3)$ for $x = 0.15$ to $α_{T^{\ast}} = - 4.4(1.1)$ for $x = 0.06$, corresponding to increasing $T^{\ast}$ and decreasing superconducting transition temperatu…
We investigated Ce-substitution and reduction annealing effects on the electronic states at copper sites by Cu ${K}$-edge x-ray absorption near-edge structure measurements in Pr$_{2-x}$Ce$_x$CuO$_{4+α-δ}$ (PCCO) with varying $x$ and $δ$ (the amount of oxygen loss during annealing) values. Absorption near-edge spectra were modified by Ce-substitution and reduction annealing in a similar manner with increasing $x$ and $δ$. Considering electron doping by Ce-substitution, this similarity indicates an increase of electron number at the copper sites due to annealing $n_{\rm AN}$. Thus, the total num…
Physical origin of the buckling in CuO$_2$: Electron-phonon coupling and Raman spectra
理论上表明，CuO $_{2}$平面在某些铜酸盐体系中的屈曲可以用横跨平面的电场来解释，该电场起源于平面上方和下方原子的不同价态。该场还导致氧原子的拉曼活性异相振动（$B_{1g}$模式）与CuO $_{2}$平面中的两个氧之间的电子电荷转移的强耦合。因此，电场可以从$B_{1g}$声子的Fano型线形推导出。利用从电子-声子耦合估计的电场，计算了屈曲的振幅，发现与结构数据吻合得很好。直接的实验支持提出的想法是在研究中获得的YBa $_{2}$ Cu $_{3}$ O $_{6+x}$和Bi $_{2}$ Sr $_{2}$（Ca $_{1-x}$ Y $_{x}$）Cu $_{2}$ O $_{8}$与不同的氧和钇掺杂，包括反铁磁样品。在后一种化合物中，通过Y部分取代Ca的对称性破缺导致电子-声子耦合增强一个数量级。
The presence of charge and spin stripe order in the La2CuO4-based family of superconductors continues to lead to new insight on the unusual ground state properties of high Tc cuprates. Soon after the discovery of charge stripe order at T(charge)=65K in Nd3+ co-doped LSCO ($T_{c}\simeq6$~K) [Tranquada et al., Nature {\bf 375} (1995) 561], Hunt et al. demonstrated that La$_{1.48}$Nd$_{0.4}$Sr$_{0.12}$CuO$_4$ and superconducting LSCO with x~1/8 (Tc ~ 30K) share nearly identical NMR anomalies near $T_{charge}$ of the former [Phys. Rev. Lett. {\bf 82} (1999) 4300]. Their inevitable conclusion that …
LCAO model for 3D Fermi surface of high-T_c cuprate Tl_2Ba_2CuO_{6+delta}
在LCAO近似的框架下，导出了Cu~4s，Cu~3d $_{x^2-y^2}$，O~ 2 p $_x$和O~ 2 p $_y$态上${\rm Tl_{2}Ba_{2}CuO_{6+δ}}$的三维费米面的简单解析公式.这一分析结果可用于拟合极角磁阻振荡等三维FS的实验数据。该模型考虑了相邻\cuo层Cu~4s轨道之间的有效铜-铜跳跃幅度\tss。与实验数据的可接受的对应关系给出了一个提示，即\tss振幅在相干3D FS的形成中占主导地位，而其他氧-氧和铜-氧振幅则可以忽略不计。对于跳跃参数的绝对测定，一个简单的电子实验与场效应晶体管型微结构的建议。薄超导层是施加AC电流的分层结构的源极-漏极沟道。
