We report high quality single crystalline growth of SmBi using flux method. The compound crystallizes in the simple rock salt structure with space group Fm3m. The cubic structure of the single crystal was confirmed by Laue diffraction pattern. The magnetic susceptibility measurements reveal sharp antiferromagnetic order with Neel temperature of 9 K. The core level photoemission spectroscopy study of Sm 3d has been performed using monochromatic Al Kalpha source. We observe multiple features in the experimental spectra due to fonal state effect - a signature of hybridization between Sm 4f - Bi 6p states. Intense satellite features are also observed presumably due to mixed valency arising from Kondo coupling. No signature of surface-bulk difference is observed in the Sm 3d core level spectra.
Realization of semimetals with non-trivial topologies such as Dirac and Weyl semimetals, have provided a boost in the study of these quantum materials. Presence of electron correlation makes the system even more exotic due to enhanced scattering of charge carriers, Kondo screening etc. Here, we studied the electronic properties of single crystalline, SmBi employing varied state of the art bulk measurements. Magnetization data reveals two magnetic transitions; an antiferromagnetic order with a Neel temperature of ~ 9 K and a second magnetic transition at a lower temperature (= 7 K). The electri…
Temperature-dependent angle-resolved photoemission spectroscopy (ARPES) was carried out on single-crystalline EuB6 samples. By measuring ARPES spectra in an extended Brillouin zone, a B 2p hole pocket centered at the X point is clearly observed, thus proving the semimetallic nature of EuB6. Below the Curie temperature TC, ARPES spectra show two B 2p bands of which separation is due to an exchange interaction between local Eu 4f and itinerant B 2p electrons. The exchange splitting becomes smaller as the temperature increases and disappears well above TC. Additionally, a diffuse structure near t…
We present an investigation on electronic structure of 1T-TiTe2 material via high-resolution angle-resolved photoemission spectroscopy (ARPES), utilizing tunable photon energy excitations. The typical semimetal-like electronic structure is observed and examined, where multiple hole pockets related to Te 5p bands and one electron pockets related to Ti 3d band are populated. The obtained results reveals i) a pronounced three-dimensional (3D) electronic structure of 1T-TiTe2 with typical semi-metallic features, for both the Ti 3d and the Te 5p states; ii) multiple Fermi surface (FS) sheets and co…
We present a combined study from angle-resolved photoemission and density-functional theory calculations of the temperature-dependent electronic structure in the excitonic insulator candidate Ta$_2$NiSe$_5$. Our experimental measurements unambiguously establish the normal state as a semimetal with a significant band overlap of $>$100~meV. Our temperature-dependent measurements indicate how these low-energy states hybridise when cooling through the well-known 327~K phase transition in this system. From our calculations and polarisation-dependent photoemission measurements, we demonstrate the im…
Co$_3$Sn$_2$S$_2$ is a magnetic Weyl semimetal, in which ferromagnetic ordering at 177K is predicted to stabilize Weyl points. We perform temperature and spatial dependent angle--resolved photoemission spectroscopy measurements through the Curie temperature ($T_c$), which show large band shifts and renormalization concomitant with the onset of magnetism. We argue that Co$_3$Sn$_2$S$_2$ evolves from a Mott ferromagnet below $T_c$ to a correlated metallic state above $T_c$. To understand the magnetism, we derive a tight-binding model of Co-$3d_{x^2-y^2}$ orbitals on the kagome lattice. At the fi…
We reveal an ultrafast purely electronic phase transition in \TNS, which is a plausible excitonic insulator, after excited by an ultrafast infrared laser pulse. Specifically, the order parameter of the strong electron-hole binding shrinks with enhancing the pump pulse, and above a critical pump fluence, a photo-excited semimetallic state is experimentally identified with the absence of ultrafast structural transition. In addition, the bare valence and conduction bands and also the effective exciton binding energy in \TNS~are determined. These findings and detailed analysis suggest a bare noneq…
Electronic band structures in solids stem from a periodic potential reflecting the structure of either the crystal lattice or an electronic order. In the stoichiometric ruthenate Ca$_3$Ru$_2$O$_7$, numerous Fermi surface sensitive probes indicate a low-temperature electronic reconstruction. Yet, the causality and the reconstructed band structure remain unsolved. Here, we show by angle-resolved photoemission spectroscopy, how in Ca$_3$Ru$_2$O$_7$ a $C_2$-symmetric massive Dirac semimetal is realized through a Brillouin-zone preserving electronic reconstruction. This Dirac semimetal emerges in a…
Ti2O3 exhibits a unique metal-insulator transition (MIT) at approximately 450 K over a wide temperature range of ~ 150 K. This broad MIT accompanied by lattice deformation differs from the sharp MITs observed in most other transition-metal oxides. A long-standing issue is determining the role of electron-electron correlation in the electronic structure and MIT of Ti2O3. However, the lack of information about the band structure of Ti2O3 has hindered investigating the origin of its unusual physical properties. Here, we report the electronic band structure of insulating Ti2O3 films with slight ho…
Staged emergence of anomalous Hall transport in a correlated uranium Weyl semimetal
Idaho National Laboratory（爱达荷国家实验室）；Uppsala University（乌普萨拉大学）；Lawrence Berkeley National Laboratory（劳伦斯伯克利国家实验室）；Harvard University（哈佛大学）；Institute of Low Temperature and Structure Research, Polish Academy of Sciences（波兰科学院低温与结构研究所）
Uncovering surface states of the Dirac semimetal BaMg2Bi2
Technische Universität Berlin（柏林工业大学）；Fritz Haber Institut der Max Planck Gesellshaft（马克斯·普朗克学会弗里茨·哈伯研究所）；University of Agder（阿格德尔大学）；Gdansk University of Technology（格但斯克理工大学）；Aarhus University（奥胡斯大学）；Synchrotron SOLEIL（SOLEIL同步辐射中心）；Stanford University（斯坦福大学）；CNR-SPIN（意大利国家研究委员会自旋科学研究所）
We demonstrate that a theoretical framework fully incorporating intra-atomic correlations and multiplet structure of the localized 4f states is required in order to capture the essential physics of rare-earth semiconductors and semimetals. We focus in particular on the rare-earth semimetal erbium arsenide (ErAs), for which effective one-electron approaches fail to provide a consistent picture of both high and low-energy electronic states. We treat the many-body states of the Er 4f shell within an atomic approximation in the framework of dynamical mean-field theory. Our results for the magnetic…
The electronic structure of Sb(110) is studied by angle-resolved photoemission spectroscopy and first-principle calculations, revealing several electronic surface states in the projected bulk band gaps around the Fermi energy. The dispersion of the states can be interpreted in terms of a strong spin-orbit splitting. The bulk band structure of Sb has the characteristics of a strong topological insulator with a Z2 invariant nu0=1. This puts constraints on the existence of metallic surface states and the expected topology of the surface Fermi contour. However, bulk Sb is a semimetal, not an insul…
Weyl semimetals harbor unusual surface states known as Fermi arcs, which are essentially disjoint segments of a two dimensional Fermi surface. We describe a prescription for obtaining Fermi arcs of arbitrary shape and connectivity by stacking alternate two dimensional electron and hole Fermi surfaces and adding suitable interlayer coupling. Using this prescription, we compute the local density of states -- a quantity directly relevant to scanning tunneling microscopy -- on a Weyl semimetal surface in the presence of a point scatterer and present results for a particular model that is expected …
One of central issues in iron-based superconductors is the role of structural change to the superconducting transition temperature (T_c). It was found in FeSe that the lattice strain leads to a drastic increase in T_c, accompanied by suppression of nematic order. By angle-resolved photoemission spectroscopy on tensile- or compressive-strained and strain-free FeSe, we experimentally show that the in-plane strain causes a marked change in the energy overlap (DeltaE_{h-e}) between the hole and electron pockets in the normal state. The change in DeltaE_{h-e} modifies the Fermi-surface volume, lead…
Eu2Ir2O7, a candidate Weyl semimetal, shows an insulator-to-metal transition as a function of Bi substitution at the Eu site. In this work, we investigate the (Eu_1-xBi_x)2Ir2O7 series via Hard X-ray Photoemission Spectroscopy (HAXPES), where substitution of larger Bi3+ for Eu3+ is reported to result in an anomalous lattice contraction (20 %) for low Bi doping (3.5 %). Using HAXPES, we confirm that all the cations retain their nominal valence state throughout the series. The asymmetric nature of Bi core-level spectra for compositions in the metallic region indicates that Bi contributes to the …
Cr1+dTe2 is a self-intercalated transition metal dichalcogenide that hosts tunable electronic filling and magnetism in its semimetallic band structure. Recent angle-resolved photoemission spectroscopy (ARPES) studies have unveiled a systematic shift in this semimetallic band structure relative to the chemical potential with increased Cr doping. This report presents the temperature and magnetic field dependence of the longitudinal thermopower Sxx for different Cr1+dTe2 compositions. We show that as doping increases, the sign of Sxx changes from positive to negative at the critical doping level …
Since the early days of Dirac flux quantization, magnetic monopoles have been sought after as a potential corollary of quantized electric charge. As opposed to magnetic monopoles embedded into the theory of electromagnetism, Weyl crystals exhibit Berry flux monopoles in reciprocal parameter space. As a function of crystal momentum, such monopoles locate at the degeneracy point of the Weyl cone. Here, we report momentum-resolved spectroscopic signatures of Berry flux monopoles in TaAs as a paradigmatic Weyl semimetal. We have probed the orbital and spin angular momentum (OAM and SAM) of the Wey…
We report an experimental study of the magnetic order and electronic structure and transport of the layered pnictide EuMnSb$_2$, performed using neutron diffraction, angle-resolved photoemission spectroscopy (ARPES), and magnetotransport measurements. We find that the Eu and Mn sublattices display antiferromagnetic (AFM) order below $T_\mathrm{N}^\mathrm{Eu} = 21(1)$ K and $T_\mathrm{N}^\mathrm{Mn} = 350(2)$ K respectively. The former can be described by an A-type AFM structure with the Eu spins aligned along the $c$ axis (an in-plane direction), whereas the latter has a C-type AFM structure w…
Using soft x-ray angle-resolved photoemission spectroscopy we probed the bulk electronic structure of Td MoTe2. We found that on-site Coulomb interaction leads to a Lifshitz transition, which is essential for a precise description of the electronic structure. A hybrid Weyl semimetal state with a pair of energy bands touching at both type-I and type-II Weyl nodes is indicated by comparing the experimental data with theoretical calculations. Unveiling the importance of Coulomb interaction opens up a new route to comprehend the unique properties of MoTe2, and is significant for understanding the …
Pyrite-type PdSb$_2$ with a nonsymmorphic cubic structure has been predicted to host six-fold-degenerate exotic fermions beyond the Dirac and Weyl fermions. Though magnetotransport measurements on PdSb$_2$ suggest its topologically nontrivial character, direct spectroscpic study of its band structure remains absent. Here, by utilizing high-resolution angle-resolved photoemission spectroscopy, we present a systematic study on its bulk and surface electronic structure. Through careful comparison with first-principles calculations, we verify the existence of six-fold fermions in PdSb$_2$, which a…
Magnetic topological materials are a class of compounds with the underlying interplay of nontrivial band topology and magnetic spin configuration. Extensive interests have been aroused due to their application potential involved with an array of exotic quantum states. With angle-resolved photoemission spectroscopy and first-principles calculations, here we study the electronic properties of two magnetic Weyl semimetal candidates PrAlSi and SmAlSi. Though the two compounds harbor distinct magnetic ground states (ferromagnetic and antiferromagnetic for PrAlSi and SmAlSi, respectively) and 4$f$ s…
While recent advances in band theory and sample growth have expanded the series of extremely large magnetoresistance (XMR) semimetals in transition metal dipnictides $TmPn_2$ ($Tm$ = Ta, Nb; $Pn$ = P, As, Sb), the experimental study on their electronic structure and the origin of XMR is still absent. Here, using angle-resolved photoemission spectroscopy combined with first-principles calculations and magnetotransport measurements, we performed a comprehensive investigation on MoAs$_2$, which is isostructural to the $TmPn_2$ family and also exhibits quadratic XMR. We resolve a clear band struct…
The three dimensional (3D) Dirac semimetal, which has been predicted theoretically, is a new electronic state of matter. It can be viewed as 3D generalization of graphene, with a unique electronic structure in which conduction and valence band energies touch each other only at isolated points in momentum space (i.e. the 3D Dirac points), and thus it cannot be classified either as a metal or a semiconductor. In contrast to graphene, the Dirac points of such a semimetal are not gapped by the spin-orbit interaction and the crossing of the linear dispersions is protected by crystal symmetry. In co…
Strong spin-orbit coupling fosters exotic electronic states such as topological insulators and superconductors, but the combination of strong spin-orbit and strong electron-electron interactions is just beginning to be understood. Central to this emerging area are the 5d transition metal iridium oxides. Here, in the pyrochlore iridate Pr2Ir2O7, we identify a nontrivial state with a single point Fermi node protected by cubic and time-reversal symmetries, using a combination of angle-resolved photoemission spectroscopy and first principles calculations. Owing to its quadratic dispersion, the uni…
