The CS molecule is known to be absorbed onto dust in the cold and dense conditions, causing it to get significantly depleted in the central region of cores. This study is aimed to investigate the depletion of the CS molecule using the optically thin C$^{34}$S molecular line observations. We mapped five prestellar cores, L1544, L1552, L1689B, L694-2, and L1197 using two molecular lines, C$^{34}$S $(J=2-1)$ and N$_2$H$^+$ $(J=1-0)$ with the NRO 45-m telescope, doubling the number of cores where the CS depletion was probed using C$^{34}$S. In most of our targets, the distribution of C$^{34}$S emission shows features that suggest that the CS molecule is generally depleted in the center of the prestellar cores. The radial profile of the CS abundance with respect to H$_2$ directly measured from the CS emission and the Herschel dust emission indicates that the CS molecule is depleted by a factor of $\sim$3 toward the central regions of the cores with respect to their outer regions. The degree of the depletion is found to be even more enhanced by an order of magnitude when the contaminating effect introduced by the presence of CS molecules in the surrounding envelope that lie along the line-of-sight is removed. Except for L1197 which is classified as relatively the least evolved core in our targets based on its observed physical parameters, we found that the remaining four prestellar cores are suffering from significant CS depletion at their central region regardless of the relative difference in their evolutionary status.
Models of prestellar cores often assume that the cores are isolated from their environment - material outside the core boundary plays no role in the subsequent evolution. This is unlikely to be the case in reality, where cores are located within hierarchically substructured molecular clouds. We investigate the dynamical and chemical evolution of prestellar cores, modelled as Bonnor-Ebert spheres, and show that the density of the ambient medium has a large impact on the resulting chemical properties of the cores. Models embedded in high-density, low-temperature surroundings have greatly enhance…
Disentangling the different stages of the star-formation process, in particular in the high-mass regime, is a challenge in astrophysics. Chemical clocks could help alleviating this problem, but their evolution strongly depends on many parameters, leading to degeneracy in the interpretation of the observational data. One of these uncertainties is the degree of CO depletion. We present here the first self-consistent magneto-hydrodynamic simulations of high-mass star-forming regions at different scales, fully coupled with a non-equilibrium chemical network, which includes C-N-O bearing molecules.…
Unveiling Central ortho-H2D+ Depletion at Sub-kau Scales in Prestellar Core G205.46-14.56M3: The First Interferometric Evidence and Implications for Deuterium Chemistry
Direct observational measurements of the magnetic field strength in prestellar cores typically find supercritical mass-to-flux ratios, suggesting that the magnetic field is insufficient to prevent gravitational collapse. These measurements suffer from significant uncertainties; an alternative approach is to utilise the sensitivity of prestellar chemistry to the evolutionary history, and indirectly constrain the degree of magnetic support. We combine non-ideal magnetohydrodynamic simulations of prestellar cores with time-dependent chemistry and radiative transfer modelling, producing synthetic …
High-mass analogues of low-mass prestellar cores are searched for to constrain the models of high-mass star formation. Several high-mass cores, at various evolutionary stages, have been recently identified towards the massive star-forming region W43-MM1 and amongst them a high-mass prestellar core candidate. We aim to characterise the chemistry in this high-mass prestellar core candidate, referred to as W43-MM1 core #6, and its environment. Using ALMA high-spatial resolution data of W43-MM1, we have studied the molecular content of core #6 and a neighbouring high-mass protostellar core, referr…
Context: The $^{15}$N fractionation has been observed to show large variations among astrophysical sources, depending both on the type of target and on the molecular tracer used. These variations cannot be reproduced by the current chemical models. Aims: Until now, the $^{14}$N/$^{15}$N ratio in N$_2$H$^+$ has been accurately measured in only one prestellar source, L1544, where strong levels of fractionation, with depletion in $^{15}$N, are found ($^{14}$N/$^{15}$N$\: \approx 1000$). In this paper we extend the sample to three more bona fide prestellar cores, in order to understand if the anti…
Aims. To constrain the physical processes that lead to the birth of high-mass stars it is mandatory to study the very first stages of their formation. We search for high-mass analogs of low-mass prestellar cores in W43-MM1. Methods. We conducted a 1.3 mm ALMA mosaic of the complete W43-MM1 cloud, which has revealed numerous cores with ~ 2000 au FWHM sizes. We investigated the nature of cores located at the tip of the main filament, where the clustering is minimum. We used the continuum emission to measure the core masses and the $^{13}$CS(5-4) line emission to estimate their turbulence level. …
We utilize the more than 100 gravitationally-bound dense cores formed in our three-dimensional, turbulent MHD simulations reported in Chen & Ostriker (2015) to analyze structural, kinematic, and magnetic properties of prestellar cores. Our statistical results disagree with the classical theory of star formation, in which cores evolve to be oblate with magnetic field parallel to the minor axes. Instead, we find that cores are generally triaxial, although the core-scale magnetic field is still preferentially most parallel to the core's minor axis and most perpendicular to the major axis. The int…
Studying the physical and chemical properties of cold and dense molecular clouds is crucial for the understanding of how stars form. Under the typical conditions of infrared dark clouds, CO is removed from the gas phase and trapped on to the surface of dust grains by the so-called depletion process. This suggests that the CO depletion factor ($f_{\rm D}$) can be a useful chemical indicator for identifying cold and dense regions (i.e., prestellar cores). We have used the 1.3 mm continuum and C$^{18}$O(2-1) data observed at the resolution of $\sim$5000 au in the ALMA Survey of 70 $μ$m Dark High-…
The first hydrostatic core, also called the first Larson core, is one of the first steps in low-mass star formation, as predicted by theory. With recent and future high performance telescopes, details of these first phases become accessible, and observations may confirm theory and even bring new challenges for theoreticians. In this context, we study from a theoretical point of view the chemical and physical evolution of the collapse of prestellar cores until the formation of the first Larson core, in order to better characterize this early phase in the star formation process. We couple a stat…
The study of prestellar cores is critical as they set the initial conditions in star formation and determine the final mass of the stellar object. To date, several hypotheses are describing their gravitational collapse. We perform detailed line analysis and modelling of H$_{2}$D$^{+}$ 110 -111 and N$_{2}$H$^{+}$ 4-3 emission at 372 GHz, using 2'x2' maps (JCMT). Our goal is to test the most prominent dynamical models by comparing the modelled gas kinematics and spatial distribution (H$_{2}$D$^{+}$ and N$_{2}$H$^{+}$) with observations towards four prestellar (L1544, L183, L694-2, L1517B) and on…
We present a detailed study of the Orion B clouds (d~400 pc), imaged with the PACS/SPIRE cameras at 70-500 $μ$m by the Herschel Gould Belt survey (HGBS). We release new high-res. maps of column density and dust temperature. In the filamentary sub-regions NGC2023/2024, NGC2068/2071, and L1622, 1768 starless dense cores were identified, ~28-45% of which are self-gravitating prestellar cores. A total of 76 protostellar dense cores were also found. The typical lifetime of the prestellar cores was found to be $t_{\rm pre}=1.7_{-0.6}^{+0.8}$ Myr. The prestellar core mass function (CMF) peaks at ~0.5…
We present a study of chemistry toward 294 dense cores in 12 molecular clumps using the data obtained from the ALMA Survey of 70 $μ\rm m$ dark High-mass clumps in Early Stages (ASHES). We identified 97 protostellar cores and 197 prestellar core candidates based on the detection of outflows and molecular transitions of high upper energy levels ($E_{u}/k > 45$ K). The detection rate of the N$_{2}$D$^{+}$ emission toward the protostellar cores is 38%, which is higher than 9% for the prestellar cores, indicating that N$_{2}$D$^{+}$ does not exclusively trace prestellar cores. The detection rates o…
The mass function of clumps observed in molecular clouds raises interesting theoretical issues, especially in its relation to the stellar initial mass function. We propose a statistical model of the mass function of prestellar cores (CMF), formed in self-gravitating isothermal clouds at a given stage of their evolution. The latter is characterized by the mass-density probability distribution function ($ρ$-PDF), which is a power-law with slope $q$. The variety of MCs is divided in ensembles according to the PDF slope and each ensemble is represented by a single spherical cloud. The cores are co…
We develop analytic approximations to the density evolution of prestellar cores, based on the results of hydrodynamical simulations. We use these approximations as input for a time-dependent gas-grain chemical code to investigate the effects of differing modes of collapse on the molecular abundances in the core. We confirm that our method can provide reasonable agreement with an exact numerical solution of both the hydrodynamics and chemistry while being significantly less computationally expensive, allowing a large grid of models varying multiple input parameters to be run. We present results…
We investigate differences in the molecular abundances between magnetically super- and sub-critical prestellar cores, performing three-dimensional non-ideal magnetohydrodynamical (MHD) simulations with varying densities and magnetic field strengths, and post-processing the results with a time-dependent gas-grain chemical code. Most molecular species show significantly more central depletion in subcritical models, due to the longer duration of collapse. However, the directly observable quantities - the molecule to hydrogen column density ratios - are generally too similar for observational data…
Hot corino chemistry and warm carbon chain chemistry (WCCC) are driven by gas-grain interactions in star-forming cores: radical-radical recombination reactions to form complex organic molecules (COMs) in the ice mantle, sublimation of CH$_4$ and COMs, and their subsequent gas-phase reactions. These chemical features are expected to depend on the composition of ice mantle which is set in the prestellar phase. We calculated the gas-grain chemical reaction network considering a layered ice-mantle structure in star-forming cores, to investigate how the hot corino chemistry and WCCC depend on the p…
We present a new method for assessing the intrinsic 3D shape of prestellar cores from molecular column densities. We have employed hydrodynamic simulations of contracting, isothermal cores considering three intrinsic geometries: spherical, cylindrical/filamentary and disk-like. We have coupled our hydrodynamic simulations with non-equilibrium chemistry. We find that a) when cores are observed very elongated (i.e. for aspect ratios $\le$ 0.15) the intrinsic 3D geometry can be probed by their 2D molecular emission maps, since these exhibit significant qualitative morphological differences betwee…
Complex organic molecules (COMs) are detected in many regions of the interstellar medium, including prestellar cores. However, their formation mechanisms in cold (~10 K) cores remain to this date poorly understood. The formyl radical HCO is an important candidate precursor for several O-bearing terrestrial COMs in cores, as an abundant building block of many of these molecules. Several chemical routes have been proposed to account for its formation, both on grain surfaces, as an incompletely hydrogenated product of H addition to frozen-out CO molecules, or in the gas phase, either the product …
We present Herschel SPIRE and PACS maps of the Cepheus Flare clouds L1157, L1172, L1228, L1241, and L1251, observed by the Herschel Gould Belt Survey (HGBS) of nearby star-forming molecular clouds. Through modified blackbody fits to the SPIRE and PACS data, we determine typical cloud column densities of 0.5-1.0 $\times$ 10$^{21}$ cm$^{-2}$ and typical cloud temperatures of 14-15 K. Using the getsources identification algorithm, we extract 832 dense cores from the SPIRE and PACS data at 160-500 $μ$m. From placement in a mass vs. size diagram, we consider 303 to be candidate prestellar cores, an…
The Herschel Gould Belt survey mapped the nearby (d < 500 pc) star-forming regions to understand better how the prestellar phase influences the star formation process. Here we report a complete census of dense cores in a 15 deg2 area of the Serpens star-forming region located between d=420 pc and 484 pc. The PACS and SPIRE cameras imaged this cloud from 70micron to 500micron. With the multi-wavelength source extraction algorithm getsources, we extract 833 sources, of which 709 are starless cores and 124 are candidate proto-stellar cores. We obtain temperatures and masses for all the sample, cl…
We develop a detailed chemical network relevant to the conditions characteristic of prestellar core collapse. We solve the system of time-dependent differential equations to calculate the equilibrium abundances of molecules and dust grains, with a size distribution given by size-bins for these latter. These abundances are used to compute the different non-ideal magneto-hydrodynamics resistivities (ambipolar, Ohmic and Hall), needed to carry out simulations of protostellar collapse. For the first time in this context, we take into account the evaporation of the grains, the thermal ionisation of…
We deploy and demonstrate the capabilities of the magnetic field model developed by Ewertowski & Basu (2013) by fitting observed polarimetry data of the prestellar core FeSt 1-457. The analytic hourglass magnetic field function derived directly from Maxwell's equations yields a central-to-surface magnetic field strength ratio in the equatorial plane, as well as magnetic field directions with relative magnitudes throughout the core. This fit emerges from a comparison of a single plane of the model with the polarization map that results from the integrated properties of the magnetic field and du…
Observations of prestellar cores in star-forming filaments show two distinct morphologies. While molecular line measurements often show broad cores, submillimeter continuum observations predominantly display pinched cores compared to the bulk of the filament gas. In order to explain how different morphologies arise, we use the gravitational instability model where prestellar cores form by growing density perturbations. The radial extent at each position is set by the local line-mass. We show that the ratio of core radius to filament radius is determined by the initial line-mass of the filament…
We present a catalogue of dense cores in a $\sim 4^\circ\times2^\circ$ field of the Taurus star-forming region, inclusive of the L1495 cloud, derived from Herschel SPIRE and PACS observations in the 70 $μ$m, 160 $μ$m, 250 $μ$m, 350 $μ$m, and 500 $μ$m continuum bands. Estimates of mean dust temperature and total mass are derived using modified blackbody fits to the spectral energy distributions. We detect 525 starless cores of which $\sim10$-20% are gravitationally bound and therefore presumably prestellar. Our census of unbound objects is $\sim85$% complete for $M>0.015\,M_\odot$ in low densit…
Recent observations indicate that organic molecules are prevalent towards starless and prestellar cores. Deuteration of these molecules has not been well-studied during the starless phase. Published observations of singly-deuterated methanol, CH$_2$DOH, have only been observed in a couple of well-studied, dense and evolved prestellar cores (e.g. L1544, L183). Since the formation of gas-phase methanol during this cold phase is believed to occur via desorption from the icy grain surfaces, observations of CH$_2$DOH may be useful as a probe of the deuterium fraction in the ice mantles of dust grai…
We aim to reveal the physical properties and chemical composition of the cores in the California molecular cloud (CMC), so as to better understand the initial conditions of star formation. We made a high-resolution column density map (18.2") with Herschel data, and extracted a complete sample of the cores in the CMC with the \textsl{fellwalker} algorithm. We performed new single-pointing observations of molecular lines near 90 GHz with the IRAM 30m telescope along the main filament of the CMC. In addition, we also performed a numerical modeling of chemical evolution for the cores under the phy…
Ambipolar diffusion likely plays a pivotal role in the formation and evolution of dense cores in weakly-ionized molecular clouds. Linear analyses show that the evolutionary times and fragmentation scales are significantly greater than the hydrodynamic (Jeans) values even for clouds with mildly supercritical mass-to-flux ratio. We utilize values of fragmentation scales and growth times that correspond to typical ionization fractions within a molecular cloud, and apply to the context of the observed estimated lifetime of prestellar cores as well as the observed number of such embedded cores form…
Observational studies reveal that complex organic molecules (COMs) can be found in various objects associated with different star formation stages. The identification of COMs in prestellar cores, i.e., cold environments in which thermally induced chemistry can be excluded and radiolysis is limited by cosmic rays and cosmic ray induced UV-photons, is particularly important as this stage sets up the initial chemical composition from which ultimately stars and planets evolve. Recent laboratory results demonstrate that molecules as complex as glycolaldehyde and ethylene glycol are efficiently form…
Given the low ionization fraction of molecular clouds, ambipolar diffusion is thought to be an integral process in star formation. However, chemical and radiative-transfer effects, observational challenges, and the fact that the ion-neutral drift velocity is inherently very small render a definite detection of ambipolar diffusion extremely non-trivial. Here, we study the ion-neutral drift velocity in a suite of chemodynamical, non-ideal magnetohydrodynamic (MHD), two-dimensional axisymmetric simulations of prestellar cores where we alter the temperature, cosmic-ray ionization rate, visual exti…
We present the results of chemical modeling of complex organic molecules (COMs) under conditions typical for prestellar cores. We utilize an advanced gas-grain astrochemical model with updated gas-phase chemistry, with a multilayer approach to ice-surface chemistry and an up-to-date treatment of reactive desorption based on recent experiments of Minissale et al. (2016). With the chemical model, radial profiles of molecules including COMs are calculated for the case of the prototypical prestellar core L1544 at the timescales when the modeled depletion factor of CO becomes equal to that observed…
The quantity of NH3 produced on grain surfaces in the prestellar core is thought to be one of the determining factors regarding the chemical complexity achievable at later stages of stellar birth. In order to investigate how this quantity might be influenced by the gas-grain cycling of molecular material within the cloud, we employ a modified rates gas-grain chemical code and follow the time-dependent chemistry of NH3 as the system evolves. Our models incorporate an updated version of the most recent UDfA network of reaction rate coefficients, desorption from the grains through standard therma…
Probing the ion-neutral drift velocity towards the L1544 prestellar core: Detection of ambipolar diffusion using N$_2$D$^+$ and para-NH$_2$D
Institute for Advanced Study, Kyushu University（九州大学高等研究院）；Department of Earth and Planetary Sciences, Faculty of Science, Kyushu University（九州大学理学部地球行星科学系）；National Astronomical Observatory of Japan（日本国立天文台）；Max-Planck-Institut für Extraterrestrische Physik（马克斯·普朗克地外物理研究所）；Kaghoshima University（鹿儿岛大学）；Faculty of Science and Engineering, Kyushu Sangyo University（九州产业大学理工学部）；Institut de Radioastronomie Millimétrique (IRAM)（毫米波射电天文学研究所）
High degrees of deuterium fractionation are commonly found in cold prestellar cores and in the envelopes around young protostars. As it brings strong constraints to chemical models, deuterium chemistry is often used to infer core history or molecule formation pathways. Whereas a large number of observations is available regarding interstellar deuterated stable molecules, relatively little is known about the deuteration of hydride radicals, as their fundamental rotational transitions are at high frequencies where the atmosphere is mostly opaque. Nitrogen hydride radicals are important species i…
Context. The deuterium fraction in low-mass prestellar cores is a good diagnostic indicator of the initial phases of star formations, and it is also a fundamental quantity to infer the ionisation degree in these objects. Aims. With the analysis of multiple transitions of $\rm N_2H^+$, $\rm N_2D^+$, $\rm HC^{18}O^+$ and $\rm DCO^+$ we are able to determine the molecular column density maps and the deuterium fraction in $\rm N_2H^+$ and $\rm HCO^+$ toward the prototypical prestellar core L1544. This is the preliminary step to derive the ionisation degree in the source. Methods. We use a non-loca…
Short version: We apply a new synergetic radiative transfer method: the derived 1D density profiles are both consistent with a cut through the Herschel PACS/SPIRE and JCMT SCUBA-2 continuum maps of L1689B and with a derived local interstellar radiation field. Choosing an appropriate cut along the filament major axis, we minimize the impact of the filament emission on the modeling. For the bulk of the core (5000-20000 au) an isothermal sphere model with a temperature of around 10 K provides the best fits. We show that the power law index of the density profile, as well as the constant temperatu…
We have performed survey-type observations in 1 mm continuum and molecular lines toward dense cores (32 prestellar + 7 protostellar) with an average density of $\gtrsim$10$^5$ cm$^{-3}$ in the Taurus molecular clouds using the Atacama Large Millimeter/submillimeter Array-Atacama Compact Array (ALMA-ACA) stand-alone mode with an angular resolution of 6.$''$5 ($\sim$900 au). The primary purpose of this study is to investigate the innermost part of dense cores toward understanding the initial condition of star formation. In the protostellar cores, contributions from protostellar disks dominate th…
HCCNC and HNC3 are less commonly found isomers of cyanoacetylene, HC3N, a molecule that is widely found in diverse astronomical sources. We want to know if HNC3 is present in sources other than the dark cloud TMC-1 and how its abundance is relative to that of related molecules. We used the ASAI unbiased spectral survey at IRAM 30m towards the prototypical prestellar core L1544 to search for HNC3 and HCCNC which are by-product of the HC3NH+ recombination, previously detected in this source. We performed a combined analysis of published HNC3 microwave rest frequencies with thus far unpublished m…
