Biomolecular sensing at the interface between chiral metasurfaces and hyperbolic metamaterials
Giovanna Palermo, Giuseppe E. Lio, Marco Esposito, Loredana Ricciardi, Mariachiara Manoccio, Vittorianna Tasco, Adriana Passaseo, Antonio De Luca, Giuseppe Strangi
In recent years significant efforts have been made to design and fabricate functional nanomaterials for biomedical applications based on the control of light matter interaction at the nanometer scale. Among many other artificial materials, hyperbolic dispersion metamaterials allow to access unprecedented physical effects and mechanisms due to the extreme anisotropy of their optical constants. The unbound isofrequency surface of hyperbolic metamaterials (HMMs) enable the possibility to support a virtually infinite density of states and ultra-high confinement of electromagnetic fields, allowing perfect absorption of light and extreme sensing properties. Optical sensor technology based on plasmonic metamaterials offers significant opportunities in the field of clinical diagnostics, particularly for the detection of low-molecular-weight biomolecules in highly diluted solutions. In this context, we present a computational effort to engineer a biosensing platform based on hyperbolic metamaterials, supporting highly confined bulk plasmon modes integrated with out-of-plane chiral metasurfaces. The role of the helicoidal chiral metasurface is manifold: i) as a diffractive element to increase the momentum of the incoming light to excite the plasmon sensing modes with linearly and circularly polarized light; ii) as out-of-plane extended sensing surface to capture target analytes away from the substrate thereby the diffusion limit; iii) as a plamonic chiral nanostructure with enhanced sensing performance over circularly polarized reflectance light.
The metasurface concept has emerged as an advantageous reconfigurable antenna architecture for beam forming and wavefront shaping, with applications that include satellite and terrestrial communications, radar, imaging, and wireless power transfer. The metasurface antenna consists of an array of metamaterial elements distributed over an electrically large structure, each subwavelength in dimension and with subwavelength separation between elements. In the antenna configuration we consider here, the metasurface is excited by the fields from an attached waveguide. Each metamaterial element can b…
We consider the design and modeling of metasurfaces that couple energy from guided waves to propagating wavefronts. This is a first step towards a comprehensive, multiscale modeling platform for metasurface antennas-large arrays of metamaterial elements embedded in a waveguide structure that radiates into free-space--in which the detailed electromagnetic responses of metamaterial elements are replaced by polarizable dipoles. We present two methods to extract the effective polarizability of a metamaterial element embedded in a one- or two-dimensional waveguide. The first method invokes surface …
Metasurface antenna arrays, formed by tiling multiple metasurface subapertures, offer an alternative architecture to electrically large beamsteering arrays often used in radar and communications. The advantages offered by metasurfaces are enabled by the use of passive, tunable radiating elements. While these metamaterial elements do not exhibit the full range of phase tuning as can be obtained with phase shifters, they can be engineered to provide a similar level of performance with much lower power requirements and circuit complexity. Due to the limited phase and magnitude control, however, l…
Metasurfaces, the two-dimensional counterpart of metamaterials, have caught great attention thanks to their powerful control over electromagnetic waves. Recent times have seen the emergence of a variety of metasurfaces exhibiting not only countless functionalities, but also a reconfigurable or even programmable response. Reconfigurability, however, entails the integration of tuning and control circuits within the metasurface structure and, as this new paradigm moves forward, new reliability challenges may arise. This paper examines, for the first time, the reliability problem in programmable m…
In this paper, we present a Bound states in the continuum (BIC) metamaterial in heterogeneous structures based on the universal coupled mode theory. We find the more general physical parameters to represent BIC, which are the resonant frequencies and corresponding phases of metamaterial structures. Therefore, BIC metamaterial comes from the equal value of the resonant frequencies and phases of metamaterial structures which are not only for homogeneous structures. Meanwhile if slightly vary one of metamaterial structure's resonant frequency and phase by varying geometry, we can obtain the quasi…
The unusual viscoelastic properties of silica aerogel plates are efficiently used to design subwavelength perfect sound absorbers. We theoretically, numerically and experimentally report a perfect absorbing metamaterial panel made of periodically arranged resonant building blocks consisting of a slit loaded by a clamped aerogel plate backed by a closed cavity. The impedance matching condition is analyzed using the Argand diagram of the reflection coefficient, i.e., the trajectory of the reflection coefficient as a function of frequency in the complex plane. The lack or excess of losses in the …
Tunable dielectric meta-surface nanostructures offer incredible performance in optical application due to their extraordinary tunability of the polarization and engineering the dispersion of light with low loss in infrared range. In this article, we designed and experimentally measured the tunability of all-dielectric subwavelength silicon nanoparticles with the help of the temperature-based refractive index of the liquid crystal in the telecom regime. The proposed structure composed of high dielectric nanodisk surrounded by nematic liquid crystal (NLC) is simulated with numerical software, as…
We present a systematic design method for a cylindrical conformal array of rectangular waveguide-fed metasurfaces. The conformal metasurface consists of multiple curved rectangular waveguides loaded with metamaterial elements\textemdash electrically small irises\textemdash inserted into the upper conducting walls of the waveguides. Each element radiates energy into free space to contribute to an overall radiation pattern. Thus, the geometry or electrical configuration of each of the individual metamaterial elements needs to be tailored to generate a desired pattern. In general, due to difficul…
Advances in graphene plasmonics offer numerous opportunities for enabling the design and manufacture of a variety of nanoelectronics and other exciting optical devices. However, due to the limitation of material properties, its operating frequency cannot drop to the microwave range. In this work, a new concept of microwave equivalent graphene based on the ultrathin monolayer plasmonic metasurface is proposed and demonstrated. Based on this concept, elliptical and hyperbolic dispersion can be theoretically obtained by stacking the equivalent graphene metasurfaces periodically. As proofs of the …
We develop a fast, accurate, and robust technique to model the electromagnetic response of a two-dimensional (2D) waveguide-fed metasurface aperture. The geometry under consideration consists of a parallel-plate waveguide with an array of subwavelength, complementary metamaterial elements patterned into one of the conducting surfaces. To determine the radiated field, we model each radiating element as a polarizable dipole, and account for mutual interactions among elements via guided and radiated fields by applying a coupled dipole framework. Using full-wave simulations of parallel-plate waveg…
We present the design, fabrication, and experimental characterization of a two-dimensional, dynamically tuned, metasurface aperture, emphasizing its potential performance in computational imaging applications. The dynamic metasurface aperture (DMA) consists of an irregular, planar cavity that feeds a multitude of tunable metamaterial elements, all fabricated in a compact, multilayer printed circuit board process. The design considerations for the metamaterial element as a tunable radiator, the associated biasing circuitry, as well as cavity parameters are examined and discussed. A sensing matr…
Elastic and acoustic metamaterials can sculpt dispersion of waves through resonances. In turn, resonances can give rise to negative effective properties, usually localized around the resonance frequencies, which support band gaps at subwavelength frequencies (i.e., below the Bragg-scattering limit). However, the band gaps width correlates strongly with the resonators' mass and volume, which limits their functionality in applications. Trampoline phenomena have been numerically and experimentally shown to broaden the operational frequency ranges of two-dimensional, pillar-based metamaterials thr…
We present the design of a phased, modulated, power distribution network for metasurface array antennas. The specific metasurface array design comprises a series of waveguides, each feeding a sub-array of dynamically tunable metamaterial elements that radiate at microwave (X-band) frequencies. To remain a one-port device, the composite array requires a power divider that can excite each branch waveguide with equal power. Further, the power divider must also apply a prescribed phase shift to each branch waveguide to mitigate metasurface-specific grating lobes. The presented design features holl…
Controlling the electromagnetic properties of materials beyond those achievable with natural substances has become a reality with the advent of metamaterials, artificially designed materials offering a wide range of unusual physical phenomena. The extreme properties that metamaterials provide can protect optical and electromagnetic systems from surrounding ordinary materials and substances - a feature never explicitly used yet. Wireless energy transfer, i.e., the transmission of electromagnetic energy without physical connectors, demands reliable and stable solutions for charging high-power sy…
Invisibility or unhearability cloaks have been made possible by using metamaterials making light or sound flow around obstacle without the trace of reflections or shadows. Metamaterials are known for being flexible building units that can mimic a host of unusual and extreme material responses, which are essential when engineering artificial material properties to realize a coordinate transforming cloak. Bending and stretching the coordinate grid in space requires stringent material parameters, therefore, small inaccuracies and inevitable material losses become sources for unwanted scattering t…
In this paper, we describe the manifestation of localized states through coherent and incoherent analyses of a diffuse elastic wavefield inside a two-dimensional metamaterial made of a collection of vertical long beams glued to a thin plate. We demonstrate that localized states arise due to multi-wave interactions at the beam-plate attachment when the beams acts as coupled resonators for both compressional and flexural resonances on the metasurface. Due to the low-quality factor compressional resonance of the beams, inside the main bandgap the modal density of the systel drops to near a high-q…
Metasurfaces, the two-dimensional counterpart of metamaterials, have caught great attention thanks to their powerful capabilities on manipulation of electromagnetic waves. Recent times have seen the emergence of a variety of metasurfaces exhibiting not only countless functionalities, but also a reconfigurable response. Additionally, digital or coding metasurfaces have revolutionized the field by describing the device as a matrix of discrete building block states, thus drawing clear parallelisms with information theory and opening new ways to model, compose, and (re)program advanced metasurface…
Metamaterials and metasurfaces operating in the visible and near-infrared (NIR) offer a promising route towards next-generation photodetectors and devices for solar energy harvesting. While numerous metamaterials and metasurfaces using metals and semiconductors have been demonstrated, semimetals-based metasurfaces in the vis-NIR range are notably missing. Here, we experimentally demonstrate a broadband metasurface superabsorber based on large area, semimetallic, van der Waals PtSe2 thin films in agreement with electromagnetic simulations. Our results show that PtSe2 is an ultrathin and scalabl…
Over almost five decades of development and improvement, Magnetic Resonance Imaging (MRI) has become a rich and powerful, non-invasive technique in medical imaging, yet not reaching its physical limits. Technical and physiological restrictions constrain physically feasible developments. A common solution to improve imaging speed and resolution is to use higher field strengths, which also has subtle and potentially harmful implications. However, patient safety is to be considered utterly important at all stages of research and clinical routine. Here we show that dynamic metamaterials are a prom…
Metamaterials and metasurfaces have given possibilities for manipulating electromagnetic (EM) waves that in the past would have seemed impossible. The majority of metasurface designs are suitable for a particular frequency and angle of incidence. One long-sought objective is the design of programmable metasurfaces to dynamically manipulate a variety of incoming EM frequencies and angles. In order to do this, a large-scale mesh of networked chips are required below the metasurface, which apart from adapting electrical impedance properties, also communicate with each other, thus relaying informa…
Chua's mem-components are ideal for creating adaptive metasurfaces for manipulating EM waves given that they hold their state without external biases. In this paper, we propose a generic adaptive reactive element that is in fact a memcapacitor/meminductor. This element makes use of a polymer that demonstrates reversible trans-cis photochemical isomerization, thus making it possible to change the distance between two conductive plates by up to 25%. Furthermore, a design methodology for utilizing these devices is presented.
Auxiliary nanostructures introduce additional flexibility into optomechanical manipulation schemes. Metamaterials and metasurfaces capable to control electromagnetic interactions at the near-field regions are especially beneficial for achieving improved spatial localization of particles, reducing laser powers required for trapping, and for tailoring directivity of optical forces. Here, optical forces acting on small particles situated next to anisotropic substrates, are investigated. A special class of hyperbolic metasurfaces is considered in details and is shown to be beneficial for achieving…
Fingerprint spectral response of several materials with terahertz electromagnetic radiation indicates that terahertz technology is an effective tool for sensing applications. However, sensing few nanometer thin-film of dielectrics with much longer terahertz waves (1 THz = 0.3 mm) is challenging. Here, we demonstrate a quasi-bound state in the continuum (BIC) resonance for sensing of nanometer scale thin analyte deposited on a flexible metasurface. The large sensitivity originates from strong local field confinement of the quasi-BIC Fano resonance state and extremely low absorption loss of a lo…
Metasurfaces, the two-dimensional analogues of metamaterials, are ideal platforms for sensing molecular chirality at the nanoscale, e.g. of inclusions of natural optically active molecules, as they offer large accessible areas (they are essentially surfaces) and can accommodate the necessary strong resonances for coupling the probing radiation with the chiral inclusions. Here, we examine theoretically achiral isotropic metasurfaces, and we treat them as polarizable surfaces that support resonant electric and magnetic currents, which are coupled via the chiral inclusions. We derive analytically…
Monitoring and controlling the state of polarization of electromagnetic waves is of significant interest for various basic and practical applications such as linear position sensing and medical imaging. Here, we propose the first conformal digital metamaterial absorber to detect the polarization state of THz incident waves. The proposed polarimeter is capable of characterizing four independent polarization states of (TE, TM, $\pm {45^\circ}$ linear, and RCP/LCP) by observing the reflectivity of the structure with respect to the x- and y-direction. Besides, the proposed structure displays a str…
The Rashba effect, i.e., the splitting of electronic spin-polarized bands in the momentum space of a crystal with broken inversion symmetry, has enabled the realization of spin-orbitronic devices, in which spins are manipulated by spin-orbit coupling. In optics, where the helicity of light polarization represents the spin degree of freedom for spin-momentum coupling, the optical Rashba effect is manifested by the splitting of optical states with opposite chirality in the momentum space. Previous realizations of the optical Rashba effect relied on passive devices determining either the propagat…
Metamaterials have recently established a new paradigm for enhanced light absorption in state-of-the-art photodetectors. Here, we demonstrate broadband, highly efficient, polarization-insensitive, and gate-tunable photodetection at room temperature in a novel metadevice based on gold/graphene Sierpinski carpet plasmonic fractals. We observed an unprecedented internal quantum efficiency up to 100% from the near-infrared to the visible range with an upper bound of optical detectivity of $10^{11}$ Jones and a gain up to $10^{6}$, which is a fingerprint of multiple hot carriers photogenerated in g…
