Recent theoretical, numerical, and observational work have suggested that when a growing planet opens a gap in its disk the flow of gas into the gap is dominated by gas falling vertically from a height of at least one gas scale height. Our primary objective is to include, for the first time, the chemical impact that accreting gas above the midplane will have on the resulting C/O. We compute the accretion of gas onto planetary cores beginning at different disk radii and track the chemical composition of the gas and small icy grains to predict the resulting carbon-to-oxygen ratio (C/O) in their atmospheres. In our model, all of the planets which began their evolution inward of 60 AU open a gap in the gas disk, and hence are chemically affected by the vertically accreting gas. Two important conclusions follow from this vertical flow: (1) more oxygen rich icy dust grains become available for accretion onto the planetary atmosphere. (2) The chemical composition of the gas dominates the final C/O of planets in the inner ($<$ 20 AU) part of the disk. This implies that with the launch of the James Webb Space Telescope we can trace the disk material that sets the chemical composition of exoplanetary atmospheres.
Turbulent vertical transport driven by double-diffusive shear instabilities is identified as likely important in hot exoplanet atmospheres. In hot Jupiter atmospheres, the resulting vertical mixing appears sufficient to alleviate the nightside cold trap, thus facilitating the maintenance of nocturnal clouds on these planets. The strong level of vertical mixing expected near hot Jupiter thermal photospheres will impact their atmospheric chemistry and even their vertical structures where cloud radiative feedback proves important.
We investigate the abiotic production of oxygen and its photochemical byproduct ozone through water vapor photolysis in moist atmospheres of temperate terrestrial exoplanets. The amount of water vapor available for photolysis in the middle atmosphere of a planet can be limited by an atmospheric cold-trap, the formation of which largely depends on the amount of non-condensable gases. We study this effect using a photochemical model coupled to a 1D radiative-convective equilibrium model in atmospheres with N2, CO2 and H2O as the main constituents. We find that in atmospheres with a low N2 invent…
Detection of life on other planets requires identification of biosignatures, i.e., observable planetary properties that robustly indicate the presence of a biosphere. One of the most widely accepted biosignatures for an Earth-like planet is an atmosphere where oxygen is a major constituent. Here we show that lifeless habitable zone terrestrial planets around any star type may develop oxygen-dominated atmospheres as a result of water photolysis, because the cold trap mechanism that protects H2O on Earth is ineffective when the atmospheric inventory of non-condensing gases (e.g., N2, Ar) is low.…
Oxygen is a constituent of many of the most abundant molecules detected in exoplanetary atmospheres and a key ingredient for tracking how and where a planet formed. In particular, the OI 777.4 nm triplet is used to probe airglow and aurora on the Earth and the oxygen abundance in stellar atmospheres, but has not been detected in an exoplanet atmosphere before. We present a definite ground-based detection of the neutral oxygen 777.4 nm triplet lines in the transmission spectrum of the ultra-hot Jupiter KELT-9b, the hottest known giant planet. The synthetic spectrum computed employing novel non-…
Recent observations of several planet-hosting M dwarfs show that most have FUV/NUV flux ratios 1000 times greater than that of the Sun. Here we show that the atmospheric oxygen contents (O2 and O3) of potentially habitable planets in this type of UV environment could be 2~3 orders of magnitude greater than those of their counterparts around Sun-like stars as a result of decreased photolysis of O3, H2O2, and HO2. Thus detectable levels of atmospheric oxygen, in combination with the existence of H2O and CO2, may not be the most promising biosignatures on planets around stars with high FUV/NUV ra…
Atmospheric chemistry models have shown molecular oxygen can build up in CO2-dominated atmospheres on potentially habitable exoplanets without an input of life. Existing models typically assume a surface pressure of 1 bar. Here we present model scenarios of CO2-dominated atmospheres with the surface pressure ranging from 0.1 to 10 bars, while keeping the surface temperature at 288 K. We use a one-dimensional photochemistry model to calculate the abundance of O2 and other key species, for outgassing rates ranging from a Venus-like volcanic activity up to 20x Earth-like activity. The model maint…
We present results from one-dimensional atmospheric simulations investigating the effect of varying the carbon-to-oxygen (C/O) ratio on the thermal structure, chemical composition and transmission and emission spectra, for irradiated hydrogen-dominated atmospheres. We find that each of these properties of the atmosphere are strongly dependent on the individual abundances (relative to hydrogen) of carbon and oxygen. We confirm previous findings that different chemical equilibrium compositions result from different sets of element abundances but with the same C/O ratio. We investigate the effect…
Thermochemical models have been used in the past to constrain the deep oxygen abundance in the gas and ice giant planets from tropospheric CO spectroscopic measurements. Knowing the oxygen abundance of these planets is a key to better understand their formation. These models have widely used dry and/or moist adiabats to extrapolate temperatures from the measured values in the upper troposphere down to the level where the thermochemical equilibrium between H$_2$O and CO is established. The mean molecular mass gradient produced by the condensation of H$_2$O stabilizes the atmosphere against conv…
Earth's modern atmosphere is highly oxygenated and is a remotely detectable signal of its surface biosphere. However, the lifespan of oxygen-based biosignatures in Earth's atmosphere remains uncertain, particularly for the distant future. Here we use a combined biogeochemistry and climate model to examine the likely timescale of oxygen-rich atmospheric conditions on Earth. Using a stochastic approach, we find that the mean future lifespan of Earth's atmosphere with oxygen levels more than 1% of the present atmospheric level is 1.08+-0.14 billion years. The model projects that a deoxygenation o…
Aerosols appear to be ubiquitous in close-in gas giant atmospheres, and disequilibrium chemistry likely impacts the emergent spectra of these planets. Lofted aerosols and disequilibrium chemistry are caused by vigorous vertical transport in these heavily irradiated atmospheres. Here we numerically and analytically investigate how vertical transport should change over the parameter space of spin-synchronized gas giants. In order to understand how tracer transport depends on planetary parameters, we develop an analytic theory to predict vertical velocities and mixing rates ($K_\mathrm{zz}$) and …
Oxygen isotope fractionation in the Martian atmosphere induced by CO$_2$ photolysis and O$_3$ formation
Earth-Life Science Institute, Institute of Science Tokyo（地球生命研究所，东京科学大学）；Department of Earth and Space Sciences, University of Washington（华盛顿大学地球与空间科学系）；Department of Geophysics, Graduate School of Science, Tohoku University（东北大学理学研究科地球物理学科）；Department of Complexity Science and Engineering, Graduate School of Frontier Sciences, The University of Tokyo（东京大学前沿科学研究生院复杂科学与工程系）；Instituto de Astrofísica de Andalucía, CSIC（安达卢西亚天体物理研究所，西班牙国家科学研究委员会）；Research Center for Advanced Science and Technology, The University of Tokyo（东京大学先进科学技术研究中心）；Department of Earth and Planetary Sciences, School of Science, Institute of Science Tokyo（东京科学大学理学院地球行星科学系）；Faculty of Environment and Information Studies, Keio University（庆应义塾大学环境信息学部）
The escape of hot O and C atoms from the present martian atmosphere during low and high solar activity conditions has been studied with a Monte-Carlo model. The model includes the initial energy distribution of hot atoms, elastic, inelastic, and quenching collisions between the suprathermal atoms and the ambient cooler neutral atmosphere, and applies energy dependent total and differential cross sections for the determination of the collision probability and the scattering angles. The results yield a total loss rate of hot oxygen of $2.3-2.9\times 10^{25}\,{\rm s}^{-1}$ during low and high sol…
Most chemistry and cloud formation models for planetary atmospheres adopt a one-dimensional (1D) diffusion approach to approximate the global-mean vertical tracer transport. The physical underpinning of the key parameter in this framework, eddy diffusivity $K_{zz}$, is usually obscure. Here we analytically and numerically investigate vertical tracer transport in a 3D stratified atmosphere and predict $K_{zz}$ as a function of the large-scale circulation strength, horizontal mixing due to eddies and waves and local tracer sources and sinks. We find that $K_{zz}$ increases with tracer chemical l…
GJ1214b is a warm sub-Neptune transiting in front of a nearby M dwarf star. Recent observations indicate the presence of high and thick clouds or haze whose presence requires strong atmospheric mixing. In order to understand the transport and distribution of such clouds/haze, we study the atmospheric circulation and the vertical mixing of GJ1214b with a 3D General Circulation Model for cloud-free hydrogen-dominated atmospheres (metallicity of 1, 10 and 100 times the solar value) and for a water-dominated atmosphere. We analyze the effect of the atmospheric metallicity on the thermal structure …
The search for habitable exoplanets in the Universe is actively ongoing in the field of astronomy. The biggest future milestone is to determine whether life exists on such habitable exoplanets. In that context, oxygen in the atmosphere has been considered strong evidence for the presence of photosynthetic organisms. In this paper, we show that a previously unconsidered photochemical mechanism by titanium(IV) oxide (titania) can produce abiotic oxygen from liquid water under near ultraviolet (NUV) lights on the surface of exoplanets. Titania works as a photocatalyst to dissociate liquid water i…
Close-in exoplanets with highly eccentric orbits are subject to large variations in incoming stellar flux between periapse and apoapse. These variations may lead to large swings in atmospheric temperature, which in turn may cause changes in the chemistry of the atmosphere from higher CO abundances at periapse to higher CH4 abundances at apoapse. Here we examine chemical timescales for CO<->CH4 interconversion compared to orbital timescales and vertical mixing timescales for the highly eccentric exoplanets HAT-P-2b and CoRoT-10b. As exoplanet atmospheres cool, the chemical timescales for CO<->C…
Vertical Temperature Structure in Io's Atmosphere from ALMA SO$_2$ Observations
California Institute of Technology（加州理工学院）；University of California, Berkeley（加州大学伯克利分校）；New York University（纽约大学）；American Museum of Natural History（美国自然历史博物馆）；Observatoire de Paris, Université PSL, CNRS, Sorbonne Université, Université Paris Cité（巴黎天文台，巴黎文理研究大学，法国国家科学研究中心，索邦大学，巴黎西岱大学）；National Radio Astronomy Observatory（美国国家射电天文台）
[Abridged] Combining a time-dependent astrochemical model with a model of planet formation and migration, we compute the carbon-to-oxygen ratio (C/O) of a range of planetary embryos starting their formation in the inner solar system (1-3 AU). The volatile and ice abundance of relevant carbon and oxygen bearing molecular species are determined through a complex chemical kinetic code which includes both gas and grain surface chemistry. This is combined with a model for the abundance of the refractory dust grains to compute the total carbon and oxygen abundance in the protoplanetary disk availabl…
Recently, Nadir and Occultation for Mars Discovery (NOMAD) ultraviolet and visible spectrometer instrument on board the European Space Agency's ExoMars Trace Gas Orbiter (TGO) simultaneously measured the limb emission intensities for both [OI] 2972 and 5577 Å (green) emissions in the dayside of Martian upper atmosphere. We aim to explore the photochemistry of all these forbidden atomic oxygen emissions ([OI] 2972, 5577, 6300, 6464 Å) in the Martian daylight upper atmosphere and suitable conditions for the simultaneous detection of these emissions lines in the dayside visible spectra. A photoch…
Neptune remains a mysterious world that deserves further exploration and is a high-priority objective for a future planetary mission in order to better understand the formation and evolution of ice giant planets. We have developed a coupled ion-neutral 1D photochemical model of Neptune's atmosphere to study the origin and evolution of the hydrocarbons and the oxygen species. The up-to-date chemical scheme is derived from one used for Titan's atmosphere, which led to good agreements with the Cassini-CIRS observations for oxygen species and the main hydrocarbons. The main results we obtain are t…
Lava planets have non-global, condensible atmospheres similar to icy bodies within the solar system. Because they depend on interior dynamics, studying the atmospheres of lava planets can lead to understanding unique geological processes driven by their extreme environment. Models of lava planet atmospheres have thus far focused on either radiative transfer or hydrodynamics. In this study, we couple the two processes by introducing ultraviolet and infrared radiation to a turbulent boundary layer model. We also test the effect of different vertical temperature profiles on atmospheric dynamics. …
Molecular oxygen (O2) paired with a reducing gas is regarded as a promising biosignature pair for the atmospheric characterization of terrestrial exoplanets. In circumstances when O2 may not be detectable in a planetary atmosphere (e.g., at mid-IR wavelengths) it has been suggested that ozone (O3), the photochemical product of O2, could be used as a proxy to infer the presence of O2. However, O3 production has a nonlinear dependence on O2 and is strongly influenced by the UV spectrum of the host star. To evaluate the reliability of O3 as a proxy for O2, we used Atmos, a 1D coupled climate/phot…
In Zhang $\&$ Showman (2018, hereafter Paper I), we developed an analytical theory of 1D eddy diffusivity $K_{zz}$ for global-mean vertical tracer transport in a 3D atmosphere. We also presented 2D numerical simulations on fast-rotating planets to validate our theory. On a slowly rotating planet such as Venus or a tidally locked planet (not necessarily a slow-rotator) such as a hot Jupiter, the tracer distribution could exhibit significant longitudinal inhomogeneity and tracer transport is intrinsically 3D. Here we study the global-mean vertical tracer transport on tidally locked planets using…
We present a comprehensive photochemistry model for exploration of the chemical composition of terrestrial exoplanet atmospheres. The photochemistry model is designed from the ground up to have the capacity to treat all types of terrestrial planet atmospheres, ranging from oxidizing through reducing, which makes the code suitable for applications for the wide range of anticipated terrestrial exoplanet compositions. The one-dimensional chemical transport model treats up to 800 chemical reactions, photochemical processes, dry and wet deposition, surface emission and thermal escape of O, H, C, N …
The Ice Giants Uranus and Neptune have hydrogen-based atmospheres with several constituents that condense in their cold upper atmospheres. A small number of bright cloud systems observed in both planets are good candidates for moist convective storms, but their observed properties (size, temporal scales and cycles of activity) differ from moist convective storms in the Gas Giants. These clouds and storms are possibly due to methane condensation and observations also suggest deeper clouds of hydrogen sulfide (H$_2$S) at depths of a few bars. Even deeper, thermochemical models predict clouds of …
Titan's atmosphere is a natural laboratory for exploring the photochemical synthesis of organic molecules. Significant recent advances in the study of the atmosphere of Titan include: (a) detection of C$_3$ molecules: C$_3$H$_6$, CH$_2$CCH$_2$, c-C$_3$H$_2$, and (b) retrieval of C$_6$H$_6$, which is formed primarily via C$_3$ chemistry, from Cassini-UVIS data. The detection of $c$-C$_3$H$_2$ is of particular significance since ring molecules are of great astrobiological importance. Using the Caltech/JPL KINETICS code, along with the best available photochemical rate coefficients and parameteri…
Chemical disequilibrium in exoplanetary atmospheres (detectable with remote spectroscopy) can indicate life. The modern Earth's atmosphere-ocean system has a much larger chemical disequilibrium than other solar system planets with atmospheres because of oxygenic photosynthesis. However, no analysis exists comparing disequilibrium on lifeless, prebiotic planets to disequilibrium on worlds with primitive chemotrophic biospheres that live off chemicals and not light. Here, we use a photochemical-microbial ecosystem model to calculate the atmosphere-ocean disequilibria of Earth with no life and wi…
The Role of Intrinsic Temperature and Vertical Mixing in Characterizing Sub-Neptune Atmospheres
The Pennsylvania State University（宾夕法尼亚州立大学）；Southeastern Universities Research Association（东南部大学研究协会）；NASA Goddard Space Flight Center（美国宇航局戈达德太空飞行中心）；NASA Ames Research Center（美国宇航局艾姆斯研究中心）；University of Washington（华盛顿大学）；Arizona State University（亚利桑那州立大学）
Evidence of disequilibrium chemistry due to vertical mixing in the atmospheres of many T and Y-dwarfs has been inferred due to enhanced mixing ratios of CO and reduced NH$_3$. Atmospheric models of planets and brown dwarfs typically parameterize this vertical mixing phenomenon with the vertical eddy diffusion coefficient, $K_{\rm zz}$. While $K_{\rm zz}$ can perhaps be approximated in the convective regions in the atmosphere with mixing length theory, in radiative regions the strength of vertical mixing is uncertain by many orders of magnitude. With a new grid of self-consistent 1D model atmos…
We study roles of the thermosphere and exosphere on the Martian ionospheric structure and ion escape rates in the process of the solar wind-Mars interaction. We employ a four-species multifluid MHD (MF-MHD) model to simulate the Martian ionosphere and magnetosphere. The $cold$ thermosphere background is taken from the Mars Global Ionosphere Thermosphere Model (M-GITM) and the $hot$ oxygen exosphere is adopted from the Mars exosphere Monte Carlo model - Adaptive Mesh Particle Simulator (AMPS). A total of four cases with the combination of 1D (globally averaged) and 3D thermospheres and exospher…
The surprising discovery by the Rosetta spacecraft of molecular oxygen (O$_2$) in the coma of comet 67P/Churyumov-Gerasimenko (Bieler et al. 2015) challenged our understanding of the inventory of this volatile species on and inside bodies from the Kuiper Belt. That discovery motivated our search for oxygen in the atmosphere of Kuiper Belt planet Pluto, because O$_2$ is volatile even at Pluto's surface temperatures. During the New Horizons flyby of Pluto in July 2015, the spacecraft probed the composition of Pluto's atmosphere using a variety of observations, including an ultraviolet solar occu…
High-resolution spectra of Pluto in the 1.66 um region, recorded with the VLT/CRIRES instrument in 2008 (2 spectra) and 2012 (5 spectra), are analyzed to constrain the spatial and vertical distribution of methane in Pluto's atmosphere and to search for mid-term (4 year) variability. A sensitivity study to model assumptions (temperature structure, surface pressure, Pluto's radius) is performed. Results indicate that (i) no variation of the CH4 atmospheric content (column-density or mixing ratio) with Pluto rotational phase is present in excess of 20 % (ii) CH4 column densities show at most marg…
Condensation clouds in substellar atmospheres have been widely inferred from spectra and photometric variability. Up until now, their horizontally averaged vertical distribution and mean particle size have been largely characterized using models, one of which is the eddy diffusion-sedimentation model from Ackerman & Marley (2001) that relies on a sedimentation efficiency parameter, $f_{\rm sed}$, to determine the vertical extent of clouds in the atmosphere. However, the physical processes controlling the vertical structure of clouds in substellar atmospheres are not well understood. In this wo…
Life has had a dramatic impact on the composition of Earth's atmosphere over time, which suggests that statistical studies of other inhabited planets' atmospheres could reveal how they co-evolve with life. While many evolutionary pathways are possible for inhabited worlds, a possible starting hypothesis is that most of them evolve similarly to Earth, which we propose could lead to a positive "age-oxygen correlation" between the ages of inhabited planets and the fraction which have oxygen-rich atmospheres. We demonstrate that next-generation space observatories currently under consideration cou…
The search for life on planets outside our solar system will use spectroscopic identification of atmospheric biosignatures. The most robust remotely-detectable potential biosignature is considered to be the detection of oxygen (O_2) or ozone (O_3) simultaneous to methane (CH_4) at levels indicating fluxes from the planetary surface in excess of those that could be produced abiotically. Here, we use an altitude-dependent photochemical model with the enhanced lower boundary conditions necessary to carefully explore abiotic O_2 and O_3 production on lifeless planets with a wide variety of volcani…
Oxygen is a promising exoplanet biosignature due to the evolutionary advantage conferred by harnessing starlight for photosynthesis, and the apparent low likelihood of maintaining oxygen-rich atmospheres without life. Hypothetical scenarios have been proposed for non-biological oxygen accumulation on planets around late M-dwarfs, where the extended pre-main sequence may favor abiotic O$_2$ accumulation. In contrast, abiotic oxygen accumulation on planets around F, G, and K-type stars is seemingly less likely, provided they possess substantial non-condensable gas inventories. The comparative ro…
The atmospheric C/O ratio of exoplanets is widely used to constrain their formation. To guarantee that the C/O ratio provides robust information, we need to accurately quantify the amount of C and O in exoplanetary atmospheres. In the case of O, water and carbon monoxide are generally studied as the two key carriers. However, oxygen is a very reactive element and does not bind with carbon; depending on the temperature, it also binds to refractory elements. Estimating the amount of oxygen bound to refractory elements is therefore critical for unbiased estimates of the C/O ratio. In this work, w…
Ganymede's atmosphere is produced by charged particle sputtering and sublimation of its icy surface. Previous far-ultraviolet observations of the O{\small I\,}1356-Å and O{\small I\,}1304-Å oxygen emissions were used to infer sputtered molecular oxygen (O$_2$) as an atmospheric constituent, but an expected sublimated water (H$_2$O) component remained undetected. Here we present an analysis of high-sensitivity spectra and spectral images acquired by the Hubble Space Telescope revealing H$_2$O in Ganymede's atmosphere. The relative intensity of the oxygen emissions requires contributions from di…
Since its discovery in the aurorae of Jupiter ~30 years ago, the H$_{3}^{+}$ ion has served as an invaluable probe of giant planet upper atmospheres. However, the vast majority of monitoring of planetary H$_{3}^{+}$ radiation has followed from observations that rely on deriving parameters from column-integrated paths through the emitting layer. Here, we investigate the effects of density and temperature gradients along such paths on the measured H$_{3}^{+}$ spectrum and its resulting interpretation. In a non-isothermal atmosphere, H$_{3}^{+}$ column densities retrieved from such observations a…
To understand the role that planet formation history has on the observable atmospheric carbon-to-oxygen ratio (C/O) we have produced a population of astrochemically evolving protoplanetary disks. Based on the parameters used in a pre-computed population of growing planets their combination allows us to trace the molecular abundances of the gas that is being collected into planetary atmospheres. We include atmospheric pollution of incoming (icy) planetesimals as well as the effect of refractory carbon erosion noted to exist in our own solar system. We find that the carbon and oxygen content of …
Gravity waves are primarily generated in the lower atmosphere, and can reach thermospheric heights in the course of their propagation. This paper reviews the recent progress in understanding the role of gravity waves in vertical coupling during sudden stratospheric warmings. Modeling of gravity wave effects is briefly reviewed, and the recent developments in the field are presented. Then, the impact of these waves on the general circulation of the upper atmosphere is outlined. Finally, the role of gravity waves in vertical coupling between the lower and the upper atmosphere is discussed in the…
We have developed 1-D photochemical and thermochemical kinetics and diffusion models for the transiting exoplanets HD 189733b and HD 209458b to study the effects of disequilibrium chemistry on the atmospheric composition of "hot Jupiters." Here we investigate the coupled chemistry of neutral carbon, hydrogen, oxygen, and nitrogen species, and we compare the model results with existing transit and eclipse observations. We find that the vertical profiles of molecular constituents are significantly affected by transport-induced quenching and photochemistry, particularly on cooler HD 189733b; howe…
Motivated by recent spectroscopic observations suggesting that atmospheres of some extrasolar giant-planets are carbon-rich, i.e. carbon/oxygen ratio (C/O) $\ge$ 1, we find that the whole set of compositional data for Jupiter is consistent with the hypothesis that it be a carbon-rich giant planet. We show that the formation of Jupiter in the cold outer part of an oxygen-depleted disk (C/O $\sim$1) reproduces the measured Jovian elemental abundances at least as well as the hitherto canonical model of Jupiter formed in a disk of solar composition (C/O = 0.54). The resulting O abundance in Jupite…
