Atmospheric chemistry models have shown molecular oxygen can build up in CO2-dominated atmospheres on potentially habitable exoplanets without an input of life. Existing models typically assume a surface pressure of 1 bar. Here we present model scenarios of CO2-dominated atmospheres with the surface pressure ranging from 0.1 to 10 bars, while keeping the surface temperature at 288 K. We use a one-dimensional photochemistry model to calculate the abundance of O2 and other key species, for outgassing rates ranging from a Venus-like volcanic activity up to 20x Earth-like activity. The model maintains the redox balance of the atmosphere and the ocean, and includes the pressure dependency of outgassing on the surface pressure. Our calculations show that the surface pressure is a controlling parameter in the photochemical stability and oxygen buildup of CO2-dominated atmospheres. The mixing ratio of O2 monotonically decreases as the surface pressure increases at the very high outgassing rates, whereas it increases as the surface pressure increases at the lower-than-Earth outgassing rates. Abiotic O2 can only build up to the detectable level, defined as 1e-3 in volume mixing ratio, in 10-bar atmospheres with the Venus-like volcanic activity rate and the reduced outgassing rate of H2 due to the high surface pressure. Our results support the search for biological activities and habitability via atmospheric O2 on terrestrial planets in the habitable zone of Sun-like stars.
UV radiation can induce photochemical processes in exoplanet atmospheres and produce haze particles. Recent observations suggest that haze and/or cloud layers could be present in the upper atmospheres of exoplanets. Haze particles play an important role in planetary atmospheres and may provide a source of organic material to the surface which may impact the origin or evolution of life. However, very little information is known about photochemical processes in cool, high-metallicity exoplanetary atmospheres. Previously, we investigated haze formation and particle size distribution in laboratory…
We investigate the impact of photochemical hazes and disequilibrium gases on the thermal structure of hot-Jupiters, using a detailed 1-D radiative-convective model. We find that the inclusion of photochemical hazes results in major heating of the upper and cooling of the lower atmosphere. Sulphur containing species, such as SH, S$_2$ and S$_3$ provide significant opacity in the middle atmosphere and lead to local heating near 1 mbar, while OH, CH, NH, and CN radicals produced by the photochemistry affect the thermal structure near 1 $μ$bar. Furthermore we show that the modifications on the the…
Refractive indices of photochemical haze analogs for Solar System and exoplanet applications : a cross-laboratory comparative study between the PAMPRE and COSmIC experimental set-ups
Spectral slopes in optical transmission spectra of exoplanetary atmospheres encapsulate information on the properties of exotic clouds. The slope is usually attributed to the Rayleigh scattering caused by tiny aerosol particles, whereas recent retrieval studies have suggested that the slopes are often steeper than the canonical Rayleigh slopes. Here, we propose that photochemical haze formed in vigorously mixing atmospheres can explain such super-Rayleigh slopes. We first analytically show that the spectral slope can be steepened by the vertical opacity gradient in which atmospheric opacity in…
Photochemical Production of CS2 in Temperate-to-Warm Gas Giant Exoplanet Atmospheres
University of Chicago（芝加哥大学）；Arizona State University（亚利桑那州立大学）；University of California, Santa Cruz（加州大学圣克鲁兹分校）；Carnegie Institution for Science（卡内基科学机构）
Photochemical CS$_2$ Gas Detected on a 20-Myr-old Exoplanet
University of California Los Angeles（加州大学洛杉矶分校）；Arizona State University（亚利桑那州立大学）；Tsinghua University（清华大学）；Imperial College London（伦敦帝国理工学院）；Osaka University（大阪大学）；Institute for Astronomy, University of Hawai‘i at Mānoa（夏威夷大学马诺阿分校天体物理研究所）；NASA Ames Research Center（美国宇航局艾姆斯研究中心）；University of Kansas（堪萨斯大学）
利用JWST/NIRSpec透射光谱，在年轻行星V1298 Tau e的大气中以>8σ置信度探测到CS$_2$，表明强紫外辐射下H/He主导大气中硫光化学的复杂性。
About 2.5 billion years ago, microbes learned to harness plentiful solar energy to reduce CO$_2$ with H$_2$O, extracting energy and producing O$_2$ as waste. O$_2$ production from this metabolic process was so vigorous that it saturated its photochemical sinks, permitting it to reach "runaway" conditions and rapidly accumulate in the atmosphere despite its reactivity. Here we argue that O$_2$ may not be unique: diverse gases produced by life may experience a "runaway" effect similar to O$_2$. This runaway occurs because the ability of an atmosphere to photochemically cleanse itself of trace ga…
Hydrocarbon complexity and photochemical shielding of prebiotic feedstock molecules in exoplanet atmospheres
Center for Space and Habitability, University of Bern（伯尔尼大学太空与宜居性中心）；Centre for Exoplanet Science, University of Edinburgh（爱丁堡大学系外行星科学中心）；Department of Earth and Planetary Sciences, University of California Riverside（加州大学河滨分校地球与行星科学系）；Institute of Astronomy & Astrophysics, Academia Sinica（中央研究院天文及天文物理研究所）
Photochemical hazes are suspected to obscure molecular features, such as water, from detection in the transmission spectra of exoplanets with atmospheric temperatures < 800 K. The opacities of laboratory produced organic compounds (tholins) from Khare et al. (1984) have become a standard for modeling haze in exoplanet atmospheres. However, these tholins were grown in an oxygen-free, Titan-like environment that is very different from typical assumptions for exoplanets, where C/O~0.5. This work presents the 0.13-10 micron complex refractive indices derived from laboratory transmission measuremen…
Assessing the Impact of Varying HSO Cross Sections on Photochemical Models: Implications for the Spectral Characterization of Terrestrial Exoplanets
Institute of Astrophysics and Space Sciences, Universidade do Porto（波尔图大学天体物理与空间科学研究所）；Departamento de Física e Astronomia, Faculdade de Ciências, Universidade do Porto（波尔图大学理学院物理与天文系）；Bard College（巴德学院）；Department of Earth and Planetary Sciences, University of California, Riverside（加州大学河滨分校地球与行星科学系）；Blue Marble Space Institute of Science（蓝大理石空间科学研究所）；University of Arizona, Lunar and Planetary Laboratory/Department of Planetary Sciences（亚利桑那大学月球与行星实验室/行星科学系）
Three dimensional temporal evolution of photochemical haze in exoplanet atmospheres I. Description and test application to HD 189733b
Center for Space and Habitability, University of Bern（伯尔尼大学太空与宜居性中心）；University of Chicago（芝加哥大学）；National Astronomical Observatory of Japan（日本国立天文台）；University of California, Santa Cruz（加州大学圣克鲁兹分校）
Photochemistry is expected to change the chemical composition of the upper atmospheres of irradiated exoplanets through the dissociation of species, such as methane and ammonia, and the association of others, such as hydrogen cyanide. Although primarily the high altitude day side should be affected by photochemistry, it is still unclear how dynamical processes transport photochemical species throughout the atmosphere, and how these chemical disequilibrium effects scale with different parameters. In this work we investigate the influence of photochemistry in a two-dimensional context, by synthe…
Photochemistry induced by stellar UV flux should produce haze particles in exoplanet atmospheres. Recent observations indicate that haze and/or cloud layers exist in the atmospheres of exoplanets. However, photochemical processes in exoplanetary atmospheres remain largely unknown. We performed laboratory experiments with the PHAZER chamber to simulate haze formation in a range of exoplanet atmospheres (hydrogen-rich, water-rich, and carbon dioxide-rich at 300, 400, and 600 K), and observed the gas phase compositional change (the destruction of the initial gas and the formation of new gas speci…
Photochemical hazes have been frequently used to interpret exoplanet transmission spectra that show an upward slope towards shorter wavelengths and weak molecular features. While previous studies have only considered spherical haze particles, photochemical hazes composed of hydrocarbon aggregate particles are common throughout the solar system. We use an aerosol microphysics model to investigate the effect of aggregate photochemical haze particles on transmission spectra of warm exoplanets. We find that the wavelength dependence of the optical depth of aggregate particle hazes is flatter than …
Exoplanets orbiting M-dwarfs within habitable zones are exposed to stellar environments more extreme than that terrestrial planets experience in our Solar System, which can significantly impact the atmospheres of the exoplanets and affect their habitability and sustainability. This study provides the first prediction of hot oxygen corona structure and the associated photochemical loss from a 1 bar CO2-dominated atmosphere of a Venus-like rocky exoplanet, where dissociative recombination of O2+ ions is assumed to be the major source reaction for the escape of neutral O atoms and formation of th…
Terrestrial exoplanets orbiting M-dwarf stars are promising targets for transmission spectroscopy with existing or near-future instrumentation. The atmospheric composition of such rocky planets remains an open question, especially given the high X-ray and ultraviolet flux from their host M dwarfs that can drive atmospheric escape. The 1.3 $R_\oplus$ exoplanet GJ 486b ($T_{\rm{eq}} \sim$ 700 K), orbiting an M3.5 star, is expected to have one of the strongest transmission spectroscopy signals among known terrestrial exoplanets. We observed three transits of GJ 486b using three different high-res…
An exoplanet's structure and composition are first-order controls of the planet's habitability. We explore which aspects of bulk terrestrial planet composition and interior structure affect the chief observables of an exoplanet: its mass and radius. We apply these perturbations to the Earth, the planet we know best. Using the mineral physics toolkit BurnMan to self-consistently calculate mass-radius models, we find that core radius, presence of light elements in the core and an upper-mantle consisting of low-pressure silicates have the largest effect on the final calculated mass at a given rad…
We are on the verge of characterizing the atmospheres of terrestrial exoplanets in the habitable zones of M dwarf stars. Due to their large planet-to-star radius ratios and higher frequency of transits, terrestrial exoplanets orbiting M dwarf stars are favorable for transmission spectroscopy. In this work, we quantify the effect that water clouds have on the amplitude of water vapor transmission spectral features of terrestrial exoplanets orbiting M dwarf stars. To do so, we make synthetic transmission spectra from general circulation model (GCM) experiments of tidally locked planets. We impro…
We use thermodynamic calculations to model atmospheric chemistry on terrestrial exoplanets that are hot enough for chemical equilibira between the atmosphere and lithosphere, as on Venus. The results of our calculations place constraints on abundances of spectroscopically observable gases, the surface temperature and pressure, and the mineralogy of the surface. These results will be useful in planning future observations of the atmospheres of terrestrial-sized exoplanets by current and proposed space observatories such as the Hubble Space Telescope (HST), Spitzer, James Webb Space Telescope (J…
Terrestrial exoplanets likely form initial atmospheres through outgassing during and after accretion, although there is currently no first-principles understanding of how to connect a planet's bulk composition to its early atmospheric properties. Important insights into this connection can be gained by assaying meteorites, representative samples of planetary building blocks. We perform laboratory outgassing experiments that use a mass spectrometer to measure the abundances of volatiles released when meteorite samples are heated to 1200 $^{\circ}$C. We find that outgassing from three carbonaceo…
Data from Kepler's first 136 days of operation are analyzed to determine the distribution of exoplanets with respect to radius, period, and host-star spectral type. The analysis is extrapolated to estimate the percentage of terrestrial, habitable-zone exoplanets. The Kepler census is assumed to be complete for bright stars (magnitude <14.0) having transiting planets >0.5 Earth radius and periods <42 days. It is also assumed that the size distribution of planets is independent of orbital period, and that there are no hidden biases in the data. Six significant statistical results are found: ther…
Exoplanet surveys around M dwarfs have detected a growing number of exoplanets with Earth-like insolation. It is expected that some of those planets are rocky planets with the potential for temperate climates favourable to surface liquid water. However, various models predict that terrestrial planets orbiting in the classical habitable zone around M dwarfs have no water or too much water, suggesting that habitable planets around M dwarfs might be rare. Here we present the results of an updated planetary population synthesis model, which includes the effects of water enrichment in the primordia…
Hurricanes are one of the most extreme storm systems that occur on Earth, characterized by strong rainfall and fast winds. The terrestrial exoplanets that will be characterized with future infrared space telescopes orbit M dwarf stars. As a result, the best observable terrestrial exoplanets have vastly different climates than Earth, with a large dayside-to-nightside irradiation contrast and relatively slow rotation. Hurricanes may affect future observations of terrestrial exoplanets because they enhance the vertical transport of water vapor and could influence ocean heat transport. In this wor…
Sulfur gases are common components in the volcanic and biological emission on Earth, and are expected to be important input gases for atmospheres on terrestrial exoplanets. We study the atmospheric composition and the spectra of terrestrial exoplanets with sulfur compounds (i.e., H2S and SO2) emitted from their surfaces. We use a comprehensive one-dimensional photochemistry model and radiative transfer model to investigate the sulfur chemistry in atmospheres ranging from reducing to oxidizing. The most important finding is that both H2S and SO2 are chemically short-lived in virtually all types…
Exoplanet discoveries over recent years have shown that terrestrial planets are exceptionally common. Many of these planets are in compact systems that result in complex orbital dynamics. A key step toward determining the surface conditions of these planets is understanding the latitudinally dependent flux incident at the top of the atmosphere as a function of orbital phase. The two main properties of a planet that influence the time-dependent nature of the flux are the obliquity and orbital eccentricity of the planet. We derive the criterion for which the flux variation due to obliquity is eq…
We present a comprehensive photochemistry model for exploration of the chemical composition of terrestrial exoplanet atmospheres. The photochemistry model is designed from the ground up to have the capacity to treat all types of terrestrial planet atmospheres, ranging from oxidizing through reducing, which makes the code suitable for applications for the wide range of anticipated terrestrial exoplanet compositions. The one-dimensional chemical transport model treats up to 800 chemical reactions, photochemical processes, dry and wet deposition, surface emission and thermal escape of O, H, C, N …
In order to recognize a habitable exoplanet from future observed spectra, we present new model reflected spectra and geometric albedo for modern and prebiotic (3.9 Ga) Earth-like exoplanets orbiting within the habitable zone of stars of spectral types F, G, K and M. We compute this for various atmospheric and surface compositions of the planets. Molecules that are potential biosignatures and act as greenhouse agents are incorporated in our model atmosphere. Various combinations of solid and liquid materials such as ocean, coast, land consisting of trees, grass, sand or rocks determine the surf…
A Fast, Parallelized, GPU-Accelerated Photochemical Model, XODIAC, with Built-in Equilibrium Chemistry and Multiple Chemical Networks for Exoplanetary Atmospheres
The investigation of planets around other stars began with the study of gas giants, but is now extending to the discovery and characterization of super-Earths and terrestrial planets. Motivated by this observational tide, we survey the basic dynamical principles governing the atmospheric circulation of terrestrial exoplanets, and discuss the interaction of their circulation with the hydrological cycle and global-scale climate feedbacks. Terrestrial exoplanets occupy a wide range of physical and dynamical conditions, only a small fraction of which have yet been explored in detail. Our approach …
Astrophysical observations reveal a large diversity of radii and masses of exoplanets. It is important to characterize the interiors of exoplanets to understand planetary diversity and further determine how unique, or not, Earth is. Assessing interior structure is challenging because there are few data and large uncertainties. Thus, for a given exoplanet a range of interior structure models can satisfy available data. Typically, interior models aim to constrain the radial structure and composition of the core and mantle, and additionally ice, ocean, and gas layer if appropriate. Constraining t…
The discovery and characterization of Earth-sized planets that are in, or near, a tidally-locked state are of crucial importance to understanding terrestrial planet evolution, and for which Venus is a clear analog. Exoplanetary science lies at the threshold of characterizing hundreds of terrestrial planetary atmospheres, thereby providing a statistical sample far greater than the limited inventory of terrestrial planetary atmospheres within the Solar System. However, the model-based approach for characterizing exoplanet atmospheres relies on Solar System data, resulting in our limited inventor…
Using an idealised general circulation model, we investigate the atmospheric circulation of Earth-like terrestrial planets in a variety of orbital configurations. We relax the common assumption of the planet being tidally-locked, and look at the role atmospheric dynamics can have in the observed thermal phase curve when the substellar point is non-stationary. In slowly rotating planets, a moving forcing can induce strong jets in the upper troposphere, both prograde and retrograde, sensitive to the speed and direction of the diurnal forcing. We find that, consistent with previous shallow water …
Exoplanet interior modelling usually makes the assumption that the elemental abundances of a planet are identical to those of its host star. Host stellar abundances are good proxies of planetary abundances, but only for refractory elements. This is particularly true for terrestrial planets, as evidenced by the relative differences in bulk chemical composition between the Sun and the Earth and other inner solar system bodies. The elemental abundances of a planet host star must therefore be devolatilised in order to correctly represent the bulk chemical composition of its terrestrial planets. Fu…
A key factor in determining the potential habitability of synchronously rotating planets is the strength of the atmospheric boundary layer inversion between the dark side surface and the free atmosphere. Here we analyse data obtained from polar night measurements at the South Pole and Alert Canada, which are the closest analogues on Earth to conditions on the dark sides of synchronously rotating exoplanets without and with a maritime influence, respectively. On Earth, such inversions rarely exceed 30 K in strength, because of the effect of turbulent mixing induced by phenomena such as so-calle…
A space telescope capable of high-contrast imaging has been recognized as the avenue toward finding terrestrial planets around nearby Sun-like stars and characterizing their potential habitability. It is thus essential to quantify the capability of reflected light spectroscopy obtained through direct imaging for terrestrial exoplanets, and existing work focused on planetary analogs of modern Earth. Here we go beyond Earth analogs and use a Bayesian retrieval algorithm, ExoReL$^\Re$, to determine what we could learn about terrestrial exoplanets from their reflected light spectra. Recognizing th…
Exomoons orbiting terrestrial or super-terrestrial exoplanets have not yet been discovered; their possible existence and properties are therefore still an unresolved question. Here we explore the collisional formation of exomoons through giant planetary impacts. We make use of smooth particle hydrodynamical (SPH) collision simulations and survey a large phase-space of terrestrial/super-terrestrial planetary collisions. We characterize the properties of such collisions, finding one rare case in which an exomoon forms through a graze&capture scenario, in addition to a few graze&merge or hit&run …
Following the discovery of the first exoplanet candidate transiting a white dwarf (WD), a "white dwarf opportunity" for characterizing the atmospheres of terrestrial exoplanets around WDs is emerging. Large planet-to-star size ratios and hence large transit depths make transiting WD exoplanets favorable targets for transmission spectroscopy - conclusive detection of spectral features on an Earth-like planet transiting a close-by WD can be achieved within a medium James Webb Space Telescope (JWST) program. Despite the apparently promising opportunity, however, the post-main sequence (MS) evolut…
Robust atmospheric and radiative transfer modeling will be required to properly interpret reflected light and thermal emission spectra of terrestrial exoplanets. This will help break observational degeneracies between the numerous atmospheric, planetary, and stellar factors that drive planetary climate. Here we simulate the climates of Earth-like worlds around the Sun with increasingly slow rotation periods, from Earth-like to fully Sun-synchronous, using the ROCKE-3D general circulation model. We then provide these results as input to the Spectral Planet Model (SPM), which employs the SMART r…
Characterizing habitable exoplanets and/or their moons is of paramount importance. Here we show the results of our magnetic field topological modeling which demonstrate that terrestrial exoplanet-exomoon coupled magnetospheres work together to protect the early atmospheres of both the exoplanet and the exomoon. When exomoon magnetospheres are within the exoplanet's magnetospheric cavity, the exomoon magnetosphere acts like a protective magnetic bubble providing an additional magnetopause confronting the stellar winds when the moon is on the dayside. In addition, magnetic reconnection would cre…
Terrestrial Exoplanet Internal Structure Constraints Enabled by Comprehensive Host Star Characterization Reveal that Terrestrial Planets in Mean-motion Resonances are Water Rich
The recent detections of temperate terrestrial planets orbiting nearby stars and the promise of characterizing their atmospheres motivates a need to understand how the diversity of possible planetary parameters affects the climate of terrestrial planets. In this work, we investigate the atmospheric circulation and climate of terrestrial exoplanets orbiting both Sun-like and M-dwarf stars over a wide swath of possible planetary parameters, including the planetary rotation period, surface pressure, incident stellar flux, surface gravity, planetary radius, and cloud particle size. We do so using …
Atmospheric studies of spectroscopically accessible terrestrial exoplanets lay the groundwork for comparative planetology between these worlds and the Solar System terrestrial planets. LHS 3844b is a highly-irradiated terrestrial exoplanet (R=1.303+/-0.022R_Earth) orbiting a mid-M dwarf 15 parsecs away. Work based on near-infrared Spitzer phase curves ruled out atmospheres with surface pressures >/=10 bars on this planet. We present 13 transit observations of LHS 3844b taken with the Magellan Clay telescope and the LDSS3C multi-object spectrograph covering 620-1020 nm. We analyze each of the 1…
Oxygenated False Positive Biosignatures in Mars-like Exoplanet Atmospheres
Southeastern Universities Research Association（东南大学研究协会）；NASA Goddard Space Flight Center（美国国家航空航天局戈达德太空飞行中心）；Mary W. Jackson NASA Headquarters（玛丽·W·杰克逊 NASA 总部）；Johns Hopkins University（约翰斯·霍普金斯大学）；Johns Hopkins Applied Physics Laboratory（约翰斯·霍普金斯大学应用物理实验室）
Nearby M dwarf systems currently offer the most favorable opportunities for spectroscopic investigations of terrestrial exoplanet atmospheres. The LTT~1445 system is a hierarchical triple of M dwarfs with two known planets orbiting the primary star, LTT~1445A. We observe four transits of the terrestrial world LTT~1445Ab ($R=1.3$ R$_\oplus$, $M=2.9$ M$_\oplus$) at low resolution with Magellan II/LDSS3C. We use the combined flux of the LTT~1445BC pair as a comparison star, marking the first time that an M dwarf is used to remove telluric variability from time-series observations of another M dwa…
It has been suggested that the recently discovered exoplanet GJ581d might be able to support liquid water due to its relatively low mass and orbital distance. However, GJ581d receives 35% less stellar energy than Mars and is probably locked in tidal resonance, with extremely low insolation at the poles and possibly a permanent night side. Under such conditions, it is unknown whether any habitable climate on the planet would be able to withstand global glaciation and / or atmospheric collapse. Here we present three-dimensional climate simulations that demonstrate GJ581d will have a stable atmos…
Surveys reveal that terrestrial- to Neptune-sized planets (1 $< R <$ 4 R$_{\rm{Earth}}$) are the most common type of planets in our galaxy. Detecting and characterizing such small planets around nearby stars holds the key to understanding the diversity of exoplanets and will ultimately address the ubiquitousness of life in the universe. The following fundamental questions will drive research in the next decade and beyond: (1) how common are terrestrial to Neptune-sized planets within a few AU of their host star, as a function of stellar mass? (2) How does planet composition depend on planet ma…
We investigate the abiotic production of oxygen and its photochemical byproduct ozone through water vapor photolysis in moist atmospheres of temperate terrestrial exoplanets. The amount of water vapor available for photolysis in the middle atmosphere of a planet can be limited by an atmospheric cold-trap, the formation of which largely depends on the amount of non-condensable gases. We study this effect using a photochemical model coupled to a 1D radiative-convective equilibrium model in atmospheres with N2, CO2 and H2O as the main constituents. We find that in atmospheres with a low N2 invent…
Terrestrial exoplanets are on the verge of joining the ranks of astronomically accessible objects. Interpreting their observable characteristics, and informing decisions on instrument design and use, will hinge on the ability to model these planets successfully across a vast range of configurations and climate forcings. A hierarchical approach that addresses fundamental behaviors as well as more complex, specific, situations is crucial to this endeavor and is presented here. Incorporating Earth-centric knowledge, and continued cross-disciplinary work will be critical, but ultimately the astrop…
Upper atmosphere dynamics and drivers of volatiles loss from terrestrial-type (exo)planets
Austrian Academy of Sciences（奥地利科学院）；University of Bern（伯尔尼大学）；NASA Goddard Institute for Space Studies（美国宇航局戈达德太空研究所）；Uppsala University（乌普萨拉大学）；Institut de Recherche en Astrophysique et Planétologie, Université de Toulouse/CNRS/CNES（天体物理与行星学研究 institute，图卢兹大学/CNRS/CNES）；Center for Space Research and Technology, Academy of Athens（雅典科学院空间研究与技术中心）；INAF-Osservatorio Astrofisico di Catania（意大利国家天体物理研究所卡塔尼亚天文台）；Florida Institute of Technology（佛罗里达理工学院）；International Space Science Institute（国际空间科学研究所）；Swedish Institute of Space Physics（瑞典空间物理研究所）；Res
Most exoplanets detected so far have atmospheric T significantly higher than 300K. Often close to their star, they receive an intense UV photons flux that triggers important photodissociation processes. The T dependency of VUV absorption cross sections are poorly known, leading to an undefined uncertainty in atmospheric models. Similarly, data measured at low T similar to that of the high atmosphere of Mars, Venus, and Titan are often lacking. Our aim is to quantify the T dependency of the abs. cross section of important molecules in planetary atmospheres. We want to provide both high-resoluti…
