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arXiv 1908.01631cond-mat.str-el
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CaTi1-xRuxO3中杂质自旋与量子顺电涨落耦合的证据

Evidence of the impurity spin coupling with quantum paraelectric fluctuations in CaTi1-xRuxO3

Ivica M. Bradarić, Feodor V. Kusmartsev

摘要:

量子顺电是一种长程铁电/反铁电有序被量子涨落抑制的材料,即晶格的零点运动即使在T = 0 K时也能防止软极性声子模式的凝聚。最突出的量子顺电材料是SrTiO 3、KTaO 3和CaTiO 3。在这里,我们专注于赝立方钙钛矿CaTi 1-xRuxO 3系统的特殊性能。也就是说,只要任何浓度的Ru或Ti被引入到纯化合物中,在低温下就会发生与浓度无关的类铁磁转变。我们提出的自旋极化的CaTi 1-xRuxO 3的基态诱导的耦合的磁矩的Ru杂质与量子顺电涨落在主体化合物CaTiO 3的实验证据。

英文摘要:

Quantum paraelectrics are materials in which a long-range ferroelectric/antiferroelectric order is suppressed by quantum fluctuations, i.e. zero-point motion of the lattice prevents condensation of the soft polar phonon mode even at T = 0 K. The most prominent quantum paraelectric materials are SrTiO3, KTaO3, and CaTiO3. Here we focus on peculiar properties of the pseudo-cubic perovskite CaTi1-xRuxO3 system. Namely, as soon as any concentration of either Ru or Ti is introduced into the pure compounds, a concentration-independent ferromagnetic-like transition occurs at low temperatures. We present the experimental evidence of the spin-polarized ground state of CaTi1-xRuxO3 induced by coupling of magnetic moments of Ru impurities with quantum paraelectric fluctuations in the host compound CaTiO3.

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