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arXiv 1808.06976math-phcond-mat.stat-mechmath.MP
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热力学相空间中的重参数化和度量结构

Reparametrizations and metric structures in thermodynamic phase space

Viridiana Pineda-Reyes, Lenin F. Escamilla-Herrera, Christine Gruber, Francisco Nettel, Hernando Quevedo

摘要:

我们调查的后果重新参数化的几何描述的热力学分析的热力学相空间的影响。热力学相空间的接触结构和黎曼结构与Boltzmann-Gibbs统计力学中的热力学平衡和统计涨落有关。这种分析的物理动机依赖于这样一种可能性,即控制原始变量的一组可微函数,而不是直接控制确定相应物理储层状态的密集参数。同样,我们考虑一组可微函数的广泛的变量占的可能性,没有直接访问的原始变量。我们发现,热力学相空间上的重新参数化的效果可以被编码,在几何方面,在其接触和黎曼结构。特别是,我们挑出一个秩2张量,进入几何上包括这种reparametrizations的信息的度量的定义。我们注意到,即使这些几何结构被重新参数化修改,平衡态热力学空间上的度规结构仍然保持不变。

英文摘要:

We investigate the consequences of reparametrizations in the geometric description of thermodynamics analyzing the effects on the thermodynamic phase space. It is known that the contact and Riemannian structures of the thermodynamic phase space are related to thermodynamic equilibrium and statistical fluctuations in the Boltzmann-Gibbs statistical mechanics. The physical motivation for this analysis rests upon the possibility of having, instead of a direct control of the intensive parameters determining the state of the corresponding physical reservoirs, the control of a set of differentiable functions of the original variables. Likewise, we consider a set of differentiable functions of the extensive variables accounting for the possibility of not having direct access to the original variables. We find that the effect of reparametrizations on the thermodynamic phase space can be codified, in geometrical terms, in its contact and Riemannian structures. In particular, we single out a rank-two tensor that enters in the definition of the metric which geometrically comprises the information about such reparametrizations. We notice that even if these geometric structures are modified by the reparametrizations, the metric structure on the thermodynamic space of equilibrium states is preserved.

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