Quantifying the degree of irreversibility of an open system dynamics represents a problem of both fundamental and applied relevance. Even though a well-known framework exists for thermal baths, the results give diverging results in the limit of zero temperature and are also not readily extended to nonequilibrium reservoirs, such as dephasing baths. Aimed at filling this gap, in this paper we introduce a phase-space-entropy production framework for quantifying the irreversibility of spin systems undergoing Lindblad dynamics. The theory is based on the spin Husimi-Q function and its corresponding phase-space entropy, known as Wehrl entropy. Unlike the von Neumann entropy production rate, we show that in our framework, the Wehrl entropy roduction rate remains valid at any temperature and is also readily extended to arbitrary nonequilibrium baths. As an application, we discuss the irreversibility associated with the interaction of a two-level system with a single-photon pulse, a problem which cannot be treated using the conventional approach.
In the theory of open quantum systems interaction is a fundamental concepts in the review of the dynamics of open quantum systems. Correlation, both classical and quantum one, is generated due to interaction between system and environment. Here, we recall the quantity which well known as total entropy production. Appearance of total entropy production is due to the entanglement production between system an environment. In this work, we discuss about the role of the total entropy production for detecting non-Markovianity. By utilizing the relation between total entropy production and total corr…
Unified entropy production in finite quantum systems
Independent Researcher（独立研究者）；Department of Information and Communication Engineering, Graduate School of Information Science and Technology, The University of Tokyo（东京大学信息理工学系研究科信息通信工程学系）
Entropy production is a key quantity characterizing nonequilibrium systems. However, it can often be difficult to compute in practice, as it requires detailed information about the system and the dynamics it undergoes. This becomes even more difficult in the quantum domain, and if one is interested in generic nonequilibrium reservoirs, for which the standard thermal recipes no longer apply. In this paper, we derive an upper bound for the entropy production in terms of the entropy flux for a class of systems for which the flux is given in terms of a system's observable. Since currents are often…
Thermodynamic irreversibility is well characterized by the entropy production arising from non-equilibrium quantum processes. We show that the entropy production of a quantum system undergoing open-system dynamics can be formally split into a term that only depends on population unbalances, and one that is underpinned by quantum coherences. The population unbalances are found to contribute to both an entropy flux and an entropy production rate. The decoherence, on the other hand, contributes only to the entropy production rate. This allows us to identify a genuine quantum contribution to the e…
We examine the conjecture that entropy production in subsystems of a given system can be used as a dynamical criterion for quantum chaos in the latter. Numerical results are presented for finite dimensional spin systems as also for the quantum baker's map. Of especial importance is the power spectrum of the entropy production which gets progressively more and more broad-banded as the degree of correlation in the Hamiltonian matrix is made to decrease.
The irreversible motion of an open quantum system can be represented through an ensemble of state vectors following a stochastic dynamics with piecewise deterministic paths. It is shown that this representation leads to a natural definition of the rate of quantum entropy production. The entropy production rate is expressed in terms of the von Neumann entropy and of the numbers of quantum jumps corresponding to the various decay channels of the open system. The proof of the positivity and of the convexity of the entropy production rate is given. Monte Carlo simulations of the stochastic dynamic…
Fluctuation theorems allow one to make generalised statements about the behaviour of thermodynamic quantities in systems that are driven far from thermal equilibrium. In this article we use Crooks' fluctuation theorem to understand the entropy production of a continuously measured, zero-temperature quantum system; namely an optical cavity measured via homodyne detection. At zero temperature, if one uses the classical definition of inverse temperature $β$, then the entropy production becomes divergent. Our analysis shows that the entropy production can be well defined at zero temperature by con…
Local approach to entropy production in the nonequilibrium dynamics of open quantum systems
University of Freiburg（弗赖堡大学）；Institute of Physics, University of Freiburg（弗赖堡大学物理研究所）；EUCOR Centre for Quantum Science and Quantum Computing, University of Freiburg（弗赖堡大学EUCOR量子科学与量子计算中心）
We explore the notion of generated entropy in open quantum systems. We focus on the study of the discrete-time quantum walk on the line, from the entropy production perspective. We argue that the evolution of the coin can be modeled as an open two-level system that exchanges energy with the lattice at some effective temperature that depends on the initial state. The entropy balance shows that there is a positive entropy production during the evolution, in accordance with the second law of thermodynamics.
We develop a martingale theory to describe fluctuations of entropy production for open quantum systems in nonequilbrium steady states. Using the formalism of quantum jump trajectories, we identify a decomposition of entropy production into an exponential martingale and a purely quantum term, both obeying integral fluctuation theorems. An important consequence of this approach is the derivation of a set of genuine universal results for stopping-time and infimum statistics of stochastic entropy production. Finally we complement the general formalism with numerical simulations of a qubit system.
The author calls attention to previous work with related results, which has escaped scrutiny before the publication of the article "Nonlinear quantum evolution with maximal entropy production", Phys.Rev.A63, 022105 (2001).
We consider open quantum systems weakly coupled to a heat reservoir and driven by arbitrary time-dependent parameters. We derive exact microscopic expressions for the nonequilibrium entropy production and entropy production rate, valid arbitrarily far from equilibrium. By using the two-point energy measurement statistics for system and reservoir, we further obtain a quantum generalization of the integrated fluctuation theorem put forward by Seifert [PRL 95, 040602 (2005)].
The second law of nonequilibrium thermodynamics within the open system paradigm (a small system coupled to one or multiple baths) is derived. This is done by showing positivity of entropy production for arbitrary Hamiltonian dynamics for a large class of initial states. Using the recently introduced notion of observational entropy, shortcomings of previous approaches are overcome. I apologize that the actual abstract of the manuscript is longer than the arXiv guidelines allow and therefore not displayed here.
We study the entropy production of an open quantum system surrounded by a complex environment consisting of several heat baths at different temperatures. The detailed balance is elaborated in view of the distinguishable channels provided by the couplings to different heat baths, and a refined entropy production rate is derived accordingly. It is demonstrated that the entropy production rates can characterize the quantum statistical property of the baths: the bosonic and fermionic baths display different behaviors in the high-temperature limit while they have the same asymptotic behavior at low…
We analyze a specific role of probability density gradients in the theory of irreversible transport processes. The classic Fisher information and information entropy production concepts are found to be intrinsically entangled with the very notion of the Markovian diffusion process and that of the related (local) momentum conservation law.
The nonadiabatic entropy production is a useful tool for the thermodynamic analysis of continuously dissipating, nonequilibrium steady states. For open quantum systems, two seemingly distinct definitions for the nonadiabatic entropy production have appeared in the literature, one based on the quantum relative entropy and the other based on quantum trajectories. We show that these two formulations are equivalent. Furthermore, this equivalence leads us to a proof of the monotonicity of the quantum relative entropy under a special class of completely-positive, trace-preserving quantum maps, which…
Bridging the second law of thermodynamics and microscopic reversible dynamics has been a longstanding problem in statistical physics. We here address this problem on the basis of quantum many-body physics, and discuss how the entropy production saturates in isolated quantum systems under unitary dynamics. First, we rigorously prove the saturation of the entropy production in the long time regime, where a total system can be in a pure state. Second, we discuss the non-negativity of the entropy production at saturation, implying the second law of thermodynamics. This is based on the eigenstate t…
The physics of driven-dissipative transitions is currently a topic of great interest, particularly in quantum optical systems. These transitions occur in systems kept out of equilibrium and are therefore characterized by a finite entropy production rate. However, very little is known about how the entropy production behaves around criticality and all of it is restricted to classical systems. Using quantum phase-space methods, we put forth a framework that allows for the complete characterization of the entropy production in driven-dissipative transitions. Our framework is tailored specifically…
We explore a recently introduced quantum thermodynamic entropy $S^Q_{univ}$ of a pure state of a composite system-environment computational "universe" with a simple system $\mathcal{S}$ coupled to a constant temperature bath $\mathcal{E}$. The principal focus is "excess entropy production" in which the quantum entropy change is greater than expected from the classical entropy-free energy relationship. We analyze this in terms of quantum spreading of time dependent states, and its interplay with the idea of a microcanonical shell. The entropy takes a basis-dependent Shannon information definiti…
By using entropy and entropy production, we calculate the steady flux of some phenomena. The method we use is a competition method, $S_S/τ+σ={\it maximum}$, where $S_S$ is system entropy, $σ$ is entropy production and $τ$ is microscopic interaction time. System entropy is calculated from the equilibrium state by studying the flux fluctuations. The phenomena we study include ionic conduction, atomic diffusion, thermal conduction and viscosity of a dilute gas.
For quantum systems with externally time-varied Hamiltonians a definition of operators of system's energy change rate (work per unit time) and entropy production observables is suggested and discussed in the context of rigorous statistical equalities (generalized fluctuation-dissipation relations) under the Jordan-symmetrized chronological operator ordering rule.
In this paper we study entropy production and transport of heat and matter in an 1D bipartite fermionic chain. Moreover, we input a phenomenological dephasing noise in order to show its effect on the dynamics of the system. Specially, it is shown the importance of such noise in the emergence of the entropy production. For the fluxes, analytical solutions are obtained using both Boltzmann and Fermi-Dirac distribuition. Finally, we show that a particular fluctuation theorem for energy and matter exchange is obeyed even in the presence of such noise.
A quantum statistical expression for the entropy of a nonequilibrium system is defined so as to be consistent with Gibbs' relation, and is shown to corresponds to dynamical variable by introducing analogous to the Heisenberg picture in quantum mechanics. The general relation between system-reservoir interactions and an entropy change operator in an open quantum system, relying just on the framework of statistical mechanics and the definition of von Neumann entropy. By using this formula, we can obtain the correct entropy production in the linear response framework. The present derivation of en…
Linear, irreversible thermodynamics predicts that the entropy production rate can become negative. We demonstrate this prediction for metals under AC-driving whose conductivity is well-described by the Drude-Sommerfeld model. We then show that these negative rates are fully compatible with stochastic thermodynamics, namely, that the entropy production does fulfill a fluctuation theorem. The analysis is concluded with the observation that the stochastic entropy production as defined by the surprisal or ignorance of the Shannon information does not agree with the phenomenological approach.
For open systems described by the quantum master equation (QME), we investigate the excess entropy production under quasistatic operations between nonequilibrium steady states. The average entropy production is composed of the time integral of the instantaneous steady entropy production rate and the excess entropy production. We propose to define average entropy production rate using the average energy and particle currents, which are calculated by using the full counting statistics with QME. The excess entropy production is given by a line integral in the control parameter space and its integ…
We evaluate entropy production in a photovoltaic cell that is modeled by four electronic levels resonantly coupled to thermally populated field modes at different temperatures. We use a formalism recently proposed, the so-called multiple parallel worlds, to consistently address the nonlinearity of entropy in terms of density matrix. Our result shows that entropy production is the difference between two flows: a semiclassical flow that linearly depends on occupational probabilities, and another flow that depends nonlinearly on quantum coherence and has no semiclassical analog. We show that entr…
An operator equality on the entropy production for general quantum Markovian master equations is derived without resorting quantum stochastic trajectory and priori quantum definition of entropy production. We find that, the equality can be still interpreted as a consequence of time-reversal asymmetry of the nonequilibrium processes of the systems. In contrast with the classical case, however, the first order expansion of the equality does not directly related to the mean entropy production, which arises from noncommute property of operators in quantum physics.
We present a scheme to evaluate thermodynamic variables for a system coupled to a heat bath under a time-dependent external force using the quasi-static Helmholtz energy from the numerically "exact" hierarchical equations of motion (HEOM). We computed the entropy produced by a spin system strongly coupled to a non-Markovian heat bath for various temperatures. We showed that when changes to the external perturbation occurred sufficiently slowly, the system always reached thermal equilibrium. Thus, we calculated the Boltzmann entropy and the von Neumann entropy for an isothermal process, as well…
We examine the dynamics of entanglement entropy of all parts in an open system consisting of a two-level dimer interacting with an environment of oscillators. The dimer-environment interaction is almost energy conserving. We find the precise link between decoherence and production of entanglement entropy. We show that not all environment oscillators carry significant entanglement entropy and we identify the oscillator frequency regions which contribute to the production of entanglement entropy. Our results hold for arbitrary strengths of the dimer-environment interaction, and they are mathemat…
Interplay between Standard Quantum Detailed Balance and Thermodynamically Consistent Entropy Production
The University of Tokyo（东京大学）；RIKEN Hakubi Research Team, Pioneering Research Institute (PRI), RIKEN（理化学研究所前沿研究机构（PRI）Hakubi研究团队）；Universal Biology Institute, The University of Tokyo（东京大学全球生物学研究院）；Center for Gravitational Physics and Quantum Information, Yukawa Institute for Theoretical Physics, Kyoto University（京都大学汤川理论物理研究所引力物理与量子信息研究中心）；Department of Physics, Graduate School of Science, The University of Tokyo（东京大学理学研究科物理学系）
We derive, for a bistochastic strictly contractive quantum channel on a matrix algebra, a relation between the contraction rate and the rate of entropy production. We also sketch some applications of our result to the statistical physics of irreversible processes and to quantum information processing.
