The second law and beyond in microscopic quantum setups
Raam Uzdin
备注：
As a chapter of: F. Binder, L. A. Correa, C. Gogolin, J. Anders, and G. Adesso (eds.), "Thermodynamics in the quantum regime - Recent Progress and Outlook", (Springer International Publishing). v1 does not include references to other book chapters
The Clausius inequality (CI) is one of the most versatile forms of the second law. Although it was originally conceived for macroscopic steam engines, it is also applicable to quantum single particle machines. Moreover, the CI is the main connecting thread between classical microscopic thermodynamics and nanoscopic quantum thermodynamics. In this chapter, we study three different approaches for obtaining the CI. Each approach shows different aspects of the CI. The goals of this chapter are: (i) To show the exact assumptions made in various derivations of the CI. (ii) To elucidate the structure of the second law and its origin. (iii) To discuss the possibilities each approach offers for finding additional second-law like inequalities. (iv) To pose challenges related to the second law in nanoscopic setups. In particular, we introduce and briefly discuss the notions of exotic heat machines (X machines), and "lazy demons".
We investigate the role of the environment in a quantum erasure setup in the cavity quantum electrodynamics domain. Two slightly different schemes are analyzed. We show that the effects of the environment vary when a scheme is exchanged for another. This can be used to estimate the macroscopic parameters related to the system-environment microscopic correlations.
The microscopic basis of Newton's law of cooling and its modification when the difference in temperature between the system and the surroundings is very large is discussed. When the system of interest is interacting with a small bath, the effect of the dynamical evolution of the bath variables is important to find out its dynamical feedback on the system. As in the usual system-bath approach, however, the bath is finally considered to be in thermal equilibrium and thereby provides an effective generalization of the Born-Markov master equation. It is shown that the cooling at early time is fast…
Recently implemented quantum devices such as quantum processors and quantum simulators combine highly complicated quantum dynamics with high-resolution measurements. We present a passivity deformation methodology that sets thermodynamic constraints on the evolution of such quantum devices. This framework enhances the thermodynamic predictive power by simultaneously resolving four of the cardinal deficiencies of the second law in microscopic setups: i) It yields tight bounds even when the environment is microscopic; ii) The ultra-cold catastrophe is resolved; iii) It enables to integrate conser…
The principle of microscopic reversibility lies at the core of fluctuation theorems, which have extended our understanding of the second law of thermodynamics to the statistical level. In the quantum regime, however, this elementary principle should be amended as the system energy cannot be sharply determined at a given quantum phase space point. In this Letter, we propose and experimentally test a quantum generalization of the microscopic reversibility when a quantum system interacts with a heat bath through energy-preserving unitary dynamics. Quantum effects can be identified by noting that …
A microscopic derivation of the master equation for the Jaynes-Cummings model with cavity losses is given, taking into account the terms in the dissipator which vary with frequencies of the order of the vacuum Rabi frequency. Our approach allows to single out physical contexts wherein the usual phenomenological dissipator turns out to be fully justified and constitutes an extension of our previous analysis [Scala M. {\em et al.} 2007 Phys. Rev. A {\bf 75}, 013811], where a microscopic derivation was given in the framework of the Rotating Wave Approximation.
The setting of Moessbauer nuclei embedded in thin-film cavities has facilitated an aspiring platform for x-ray quantum optics as shown in several recent experiments. Here, we generalize the theoretical model of this platform that we developed earlier [Phys. Rev. A 88, 043828 (2013)]. The theory description is extended to cover multiple nuclear ensembles and multiple modes in the cavity. While the extensions separately do not lead to qualitatively new features, their combination gives rise to cooperative effects between the different nuclear ensembles and distinct spectral signatures in the obs…
In order to examine whether or not the quantum phase transition of Dicke type exists in realistic systems, we revisit the model setup of the superconducting circuit QED from a microscopic many-body perspective based on the BCS theory with pseudo-spin presentation. By deriving the Dicke model with the correct charging terms from the minimum coupling principle, it is shown that the circuit QED system can exhibit superradiant quantum phase transition in the limit N\rightarrow\infty. The critical point could be reached at easiness by adjusting the extra parameters, the ratio of Josephson capacitan…
The main thread that links classical thermodynamics and the thermodynamics of small quantum systems is the celebrated Clausius inequality form of the second law. However, its application to small quantum systems suffers from two cardinal problems: (i) The Clausius inequality does not hold when the system and environment are initially correlated - a commonly encountered scenario in microscopic setups. (ii) In some other cases, the Clausius inequality does not provide any useful information (e.g. in dephasing scenarios). We address these deficiencies by developing the notion of global passivity …
Using different optical setups based on squeezed state and photon subtraction we show how optical entanglement between a macroscopic and a microscopic state - the so-called Schrodinger cat state or micro-macro state - can be generated. The entangled state is heralded and is thus produced a priori in contrast to previous proposals. We define the macroscopicity of the macroscopic part of the state as their mean distance in phase space and the success rate in discriminating them with homodyne detection, and subsequently, based on these measures we investigate the macroscopicity of different state…
Hyperentanglement of photonic light modes is a valuable resource in quantum information processing and quantum communication. Here we propose a new protocol using the interference of two optical nonlinearities and control of the heralding (detection) basis in the orbital-angular-momentum degree of freedom. This setup is capable of generating states which are both maximally- and hyper- entangled in at least four dimensions. The resultant state in the four-dimensional case is a generalization of the so-called N00N state (a maximally path-entangled state well known in quantum optics). The product…
The aim of this book chapter is to indicate how quantum phenomena are affecting the operation of microscopic thermal machines, such as engines and refrigerators. As converting heat to work is one of the fundamental concerns in thermodynamics, the platform of quantum-thermal machines sheds light on thermodynamics in the quantum regime. This chapter focuses on the basic features of quantum mechanics, such as energy quantization, the uncertainty principle, quantum coherence and correlations, and their manifestation in microscopic thermal devices. In addition to indicating the peculiar behaviors o…
On the basis of general theoretical results developed previously in [I. M. Sokolov et al., J. Exp. Theor. Phys. 112, 246 (2011)], we analyze spontaneous decay of a single atom inside cold atomic clouds under conditions when the averaged interatomic separation is less or comparable with the wavelength of quasi resonant radiation. Beyond the decay dynamics we analyze shifts of resonance as well as distortion of the spectral shape of the atomic transition.
Trapping of single ultracold atoms is an important tool for applications ranging from quantum computation and communication to sensing. However, most experimental setups, while very precise and versatile, can only be operated in specialized laboratory environments due to their large size, complexity and high cost. Here, we introduce a new trapping concept for ultracold atoms in optical tweezers based on micrometer-scale lenses that are 3D printed onto the tip of standard optical fibers. The unique properties of these lenses make them suitable for both trapping individual atoms and capturing th…
It is commonly claimed that quantum mechanics makes reference to a microscopic realm constituted by elementary particles. However, as first famously noticed by Erwin Schrödinger, it is not at all clear what these quantum particles really are. According to the specialized literature, it is not even clear if each of these microscopic entities possess their own identity. Recently, Jonas Arenhart proposed a distinction of quantum objects in terms of a dilemma which forces a choice between their characterization either as individuals or as non-individuals. In this work we attempt to address the (me…
Irreversibility is one of the most intriguing concepts in physics. While microscopic physical laws are perfectly reversible, macroscopic average behavior has a preferred direction of time. According to the second law of thermodynamics, this arrow of time is associated with a positive mean entropy production. Using a nuclear magnetic resonance setup, we measure the nonequilibrium entropy produced in an isolated spin-1/2 system following fast quenches of an external magnetic field and experimentally demonstrate that it is equal to the entropic distance, expressed by the Kullback-Leibler divergen…
Deriving the laws of thermodynamics from a microscopic picture is a central quest of statistical mechanics. This tutorial focuses on the derivation of the first and second law for closed and open quantum systems far from equilibrium, where such foundational questions also become practically relevant for emergent nanotechnologies. The derivation is based on a microscopic definition of five essential quantities: internal energy, thermodynamic entropy, work, heat and temperature. These definitions are shown to satisfy the phenomenological laws of nonequilibrium thermodynamics for a large class of…
We study a quantum phase transition between a phase which is topologically ordered and one which is not. We focus on a spin model, an extension of the toric code, for which we obtain the exact ground state for all values of the coupling constant that takes the system across the phase transition. We compute the entanglement and the topological entropy of the system as a function of this coupling constant, and show that the topological entropy remains constant all the way up to the critical point, and jumps to zero beyond it. Despite the jump in the topological entropy, the transition is second …
We investigate the performance of a microscopic quantum heat engine consisting of V- or Lambda-type emitters interacting collectively or independently when being in contact with environmental thermal reservoirs. Though the efficiency of a Carnot's cycle is always higher than those associated with these setups, we have found that the performance of the cooperative Lambda-type heat engine may be larger than that of the V-type under similar conditions. Cooperativity among the emitters plays an important role for the Lambda-type setup, significantly improving its performance, while is less relevan…
Institut für Theoretische Physik, Universität zu Köln（科隆大学理论物理研究所）；Max Planck Institute for the Physics of Complex Systems（马克斯·普朗克复杂系统物理研究所）；School of Physics, Trinity College Dublin（都柏林三一学院物理学院）
Motivated by recent experiments, we study four-wave-mixing in an atomic double-Λ system driven by a far-detuned pump. Using the Heisenberg-Langevin formalism, and based on the microscopic properties of the medium, we calculate the classical and quantum properties of seed and conju- gate beams beyond the linear amplifier approximation. A continuous variable approach gives us access to relative-intensity noise spectra that can be directly compared to experiments. Restricting ourselves to the cold-atom regime, we predict the generation of quantum-correlated beams with a relative-intensity noise s…
Every measurement of the population in an uncorrelated ensemble of two-level systems is limited by what is known as the quantum projection noise limit. Here, we present quantum projection noise limited performance of a Ramsey type interferometer using freely propagating coherent atoms. The experimental setup is based on an electro-optic modulator in an inherently stable Sagnac interferometer, optically coupling the two interfering atomic states via a two-photon Raman transition. Going beyond the quantum projection noise limit requires the use of reduced quantum uncertainty (squeezed) states. T…
Following the emergence of superconducting granular aluminum (grAl) as a material for high-impedance quantum circuits, future development hinges on a microscopic understanding of its phase diagram, and whether the superconductor-to-insulator transition (SIT) is driven by disorder or charging effects. Beyond fundamental relevance, these mechanisms govern noise and dissipation in microwave circuits. Although the enhancement of the critical temperature, and the SIT in granular superconductors have been studied for more than fifty years, experimental studies have so far provided incomplete informa…
The development of qualitatively new measurement capabilities is often a prerequisite for critical scientific and technological advances. The dramatic progress made by modern probe techniques to uncover the microscopic structure of matter is fundamentally rooted in our control of two defining traits of quantum mechanics: discreteness of physical properties and interference phenomena. Magnetic Resonance Imaging, for instance, exploits the fact that protons have spin and can absorb photons at frequencies that depend on the medium to image the anatomy and physiology of living systems. Scattering …
