arXivDaily arXiv每日学术速递 周一至周五更新
arXiv周末暂无论文更新,休息一下吧,周末愉快~~
arXiv 1709.09680cond-mat.str-elcond-mat.mtrl-sci
收藏

无序α- LiFeO2中的压力诱导自旋交叉

Pressure induced spin crossover in disordered α-LiFeO2

Samar Layek, Eran Greenberg, Weiming Xu, Gregory Kh. Rozenberg, Moshe P. Pasternak, Jean-Paul Itié, Dániel G. Merkel

摘要:

用同步辐射X射线衍射、~(57)Fe穆斯堡尔谱和金刚石压砧电阻测量等方法研究了在锂、铁离子随机分布的岩盐结构中结晶的α-LiFeO_2的结构、磁性和电输运性质。发现晶体结构至少在82 GPa下是稳定的,尽管在50 GPa以上观察到压缩性的显著变化。发现结构性质的变化与缓慢的Fe 3+从高自旋到低自旋(HS-LS)转变(S=5/2到S=1/2)相当,其开始于50 GPa,并且甚至在~100 GPa下也没有完成。HS-LS转变伴随着可观的电阻降低,直到115 GPa仍保持半导体,并且即使在约200 GPa下也不期望是金属的。观察到的压力诱导的HS-LS转变的特征不是铁氧化物在高压下的普通行为。讨论了Fe ~(3+)的最近邻和次近邻对自旋交叉特性的影响。

英文摘要:

Structural, magnetic and electrical-transport properties of α-LiFeO2, crystallizing in the rock salt structure with random distribution of Li and Fe ions, have been studied by synchrotron X-ray diffraction, 57Fe Mössbauer spectroscopy and electrical resistance measurements at pressures up to 100 GPa using diamond anvil cells. It was found that the crystal structure is stable at least to 82 GPa, though a significant change in compressibility has been observed above 50 GPa. The changes in the structural properties are found to be on a par with a sluggish Fe3+ high- to low-spin (HS-LS) transition (S=5/2 to S=1/2) starting at 50 GPa and not completed even at ~100 GPa. The HS-LS transition is accompanied by an appreciable resistance decrease remaining a semiconductor up to 115 GPa and is not expected to be metallic even at about 200 GPa. The observed feature of the pressure-induced HS-LS transition is not an ordinary behavior of ferric oxides at high pressures. The effect of Fe3+ nearest and next nearest neighbors on the features of the spin crossover is discussed.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

↑